Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources
Abstract
Diverse lignin samples have been subjected to a catalytic aerobic oxidation process, followed by formic-acid-induced hydrolytic depolymerization. The yield of monomeric aromatic compounds varies depending on the lignin plant source and pretreatment method. The best results are obtained from poplar lignin isolated via a acidolysis pretreatment method, which gives 42 wt% yield of low-molecular-weight aromatics. Use of other pretreatment methods and/or use of maple and maize lignins afford yields of aromatics ranging from 3 to 31 wt%. These results thus establish useful references for the development of improved oxidation/depolymerization protocols.
- Authors:
-
[1];
[3];
[2];
[3];
[6];
[7];
[1]
- Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemistry
- Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemical and Biological Engineering
- Michigan State Univ., East Lansing, MI (United States). Dept. of Biochemistry and Molecular Biology
- Michigan State Univ., East Lansing, MI (United States). Dept. of Chemical Engineering and Material Science
- Michigan State Univ., East Lansing, MI (United States). Dept. of Chemical Engineering and Material Science; Univ. of Houston, Houston, TX (United States). School of Technology, Biotechnology Division and Dept. of Engineering Technology
- Univ. of Wisconsin, Madison, WI (United States). Wisconsin Energy Inst. and Great Lakes Bioenergy Research Center (GLBRC)
- Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemistry and Dept. of Biomolecular Chemistry
- Publication Date:
- Research Org.:
- Univ. of Wisconsin, Madison, WI (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1471683
- Grant/Contract Number:
- FC02-07ER64494
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Sustainable Chemistry & Engineering
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 3; Journal ID: ISSN 2168-0485
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Biomass; Catalysis; Depolymerization; Poplar; Pretreatment
Citation Formats
Das, Amit, Rahimi, Alireza, Ulbrich, Arne, Alherech, Manar, Motagamwala, Ali Hussain, Bhalla, Aditya, da Costa Sousa, Leonardo, Balan, Venkatesh, Dumesic, James A., Hegg, Eric L., Dale, Bruce E., Ralph, John, Coon, Joshua J., and Stahl, Shannon S. Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources. United States: N. p., 2018.
Web. doi:10.1021/acssuschemeng.7b03541.
Das, Amit, Rahimi, Alireza, Ulbrich, Arne, Alherech, Manar, Motagamwala, Ali Hussain, Bhalla, Aditya, da Costa Sousa, Leonardo, Balan, Venkatesh, Dumesic, James A., Hegg, Eric L., Dale, Bruce E., Ralph, John, Coon, Joshua J., & Stahl, Shannon S. Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources. United States. https://doi.org/10.1021/acssuschemeng.7b03541
Das, Amit, Rahimi, Alireza, Ulbrich, Arne, Alherech, Manar, Motagamwala, Ali Hussain, Bhalla, Aditya, da Costa Sousa, Leonardo, Balan, Venkatesh, Dumesic, James A., Hegg, Eric L., Dale, Bruce E., Ralph, John, Coon, Joshua J., and Stahl, Shannon S. Fri .
"Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources". United States. https://doi.org/10.1021/acssuschemeng.7b03541. https://www.osti.gov/servlets/purl/1471683.
@article{osti_1471683,
title = {Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources},
author = {Das, Amit and Rahimi, Alireza and Ulbrich, Arne and Alherech, Manar and Motagamwala, Ali Hussain and Bhalla, Aditya and da Costa Sousa, Leonardo and Balan, Venkatesh and Dumesic, James A. and Hegg, Eric L. and Dale, Bruce E. and Ralph, John and Coon, Joshua J. and Stahl, Shannon S.},
abstractNote = {Diverse lignin samples have been subjected to a catalytic aerobic oxidation process, followed by formic-acid-induced hydrolytic depolymerization. The yield of monomeric aromatic compounds varies depending on the lignin plant source and pretreatment method. The best results are obtained from poplar lignin isolated via a acidolysis pretreatment method, which gives 42 wt% yield of low-molecular-weight aromatics. Use of other pretreatment methods and/or use of maple and maize lignins afford yields of aromatics ranging from 3 to 31 wt%. These results thus establish useful references for the development of improved oxidation/depolymerization protocols.},
doi = {10.1021/acssuschemeng.7b03541},
journal = {ACS Sustainable Chemistry & Engineering},
number = 3,
volume = 6,
place = {United States},
year = {Fri Jan 19 00:00:00 EST 2018},
month = {Fri Jan 19 00:00:00 EST 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 101 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
The pros and cons of lignin valorisation in an integrated biorefinery
journal, January 2014
- Strassberger, Zea; Tanase, Stefania; Rothenberg, Gadi
- RSC Adv., Vol. 4, Issue 48
Lignins: Natural polymers from oxidative coupling of 4-hydroxyphenyl- propanoids
journal, January 2004
- Ralph, John; Lundquist, Knut; Brunow, Gösta
- Phytochemistry Reviews, Vol. 3, Issue 1-2, p. 29-60
Lignin Valorization: Improving Lignin Processing in the Biorefinery
journal, May 2014
- Ragauskas, A. J.; Beckham, G. T.; Biddy, M. J.
- Science, Vol. 344, Issue 6185, p. 1246843-1246843
Lignin Refinery: Towards the Preparation of Renewable Aromatic Building Blocks
journal, December 2015
- Graglia, Micaela; Kanna, Narasimharao; Esposito, Davide
- ChemBioEng Reviews, Vol. 2, Issue 6
Lignocellulose: A chewy problem
journal, June 2011
- Sanderson, Katharine
- Nature, Vol. 474, Issue 7352, p. S12-S14
Review: Oxidation of Lignin Using Ionic Liquids—An Innovative Strategy To Produce Renewable Chemicals
journal, November 2013
- Chatel, Gregory; Rogers, Robin D.
- ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 3
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006
- Huber, George W.; Iborra, Sara; Corma, Avelino
- Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
journal, June 2010
- Zakzeski, Joseph; Bruijnincx, Pieter C. A.; Jongerius, Anna L.
- Chemical Reviews, Vol. 110, Issue 6, p. 3552-3599
The catalytic oxidation of biomass to new materials focusing on starch, cellulose and lignin
journal, August 2010
- Collinson, S. R.; Thielemans, W.
- Coordination Chemistry Reviews, Vol. 254, Issue 15-16
Lignin Depolymerization and Conversion A Review of Thermochemical Methods
journal, November 2010
- Pandey, M. P.; Kim, C. S.
- Chemical Engineering & Technology, Vol. 34, Issue 1, p. 29-41
Knocking on Wood: Base Metal Complexes as Catalysts for Selective Oxidation of Lignin Models and Extracts
journal, June 2015
- Hanson, Susan K.; Baker, R. Tom
- Accounts of Chemical Research, Vol. 48, Issue 7
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
journal, October 2015
- Li, Changzhi; Zhao, Xiaochen; Wang, Aiqin
- Chemical Reviews, Vol. 115, Issue 21, p. 11559-11624
From models to lignin: Transition metal catalysis for selective bond cleavage reactions
journal, January 2016
- Deuss, Peter J.; Barta, Katalin
- Coordination Chemistry Reviews, Vol. 306
Paving the Way for Lignin Valorisation: Recent Advances in Bioengineering, Biorefining and Catalysis
journal, June 2016
- Rinaldi, Roberto; Jastrzebski, Robin; Clough, Matthew T.
- Angewandte Chemie International Edition, Vol. 55, Issue 29
Catalytic Transformation of Lignocellulose into Chemicals and Fuel Products in Ionic Liquids
journal, November 2016
- Zhang, Zhanrong; Song, Jinliang; Han, Buxing
- Chemical Reviews, Vol. 117, Issue 10
Singlet oxygen mediated degradation of lignin—isolation of oxidation products from steam-exploded lignin from pine
journal, January 2002
- Bonini, Carlo; D'Auria, Maurizio; Ferri, Rachele
- Photochem. Photobiol. Sci., Vol. 1, Issue 8
Selective Degradation of Wood Lignin over Noble‐Metal Catalysts in a Two‐Step Process
journal, July 2008
- Yan, Ning; Zhao, Chen; Dyson, Paul J.
- ChemSusChem, Vol. 1, Issue 7
Activity and Stability of Perovskite-Type Oxide LaCoO 3 Catalyst in Lignin Catalytic Wet Oxidation to Aromatic Aldehydes Process
journal, January 2009
- Deng, Haibo; Lin, Lu; Sun, Yong
- Energy & Fuels, Vol. 23, Issue 1
Catalytic disassembly of an organosolv lignin via hydrogen transfer from supercritical methanol
journal, January 2010
- Barta, Katalin; Matson, Theodore D.; Fettig, Makayla L.
- Green Chemistry, Vol. 12, Issue 9
Towards Quantitative Catalytic Lignin Depolymerization
journal, April 2011
- Roberts, Virginia. M.; Stein, Valentin; Reiner, Thomas
- Chemistry - A European Journal, Vol. 17, Issue 21, p. 5939-5948
One-pot catalytic hydrocracking of raw woody biomass into chemicals over supported carbide catalysts: simultaneous conversion of cellulose, hemicellulose and lignin
journal, January 2012
- Li, Changzhi; Zheng, Mingyuan; Wang, Aiqin
- Energy Environ. Sci., Vol. 5, Issue 4
Conversion of lignin to aromatic-based chemicals (L-chems) and biofuels (L-fuels)
journal, October 2012
- Beauchet, R.; Monteil-Rivera, F.; Lavoie, J. M.
- Bioresource Technology, Vol. 121
Catalytic Lignin Valorization Process for the Production of Aromatic Chemicals and Hydrogen
journal, June 2012
- Zakzeski, Joseph; Jongerius, Anna L.; Bruijnincx, Pieter C. A.
- ChemSusChem, Vol. 5, Issue 8
Process of lignin oxidation in an ionic liquid coupled with separation
journal, January 2013
- Liu, Shiwei; Shi, Zhongliang; Li, Lu
- RSC Advances, Vol. 3, Issue 17
Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin
journal, April 2013
- Chan, Julian M. W.; Bauer, Stefan; Sorek, Hagit
- ACS Catalysis, Vol. 3, Issue 6
A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass
journal, January 2015
- Parsell, Trenton; Yohe, Sara; Degenstein, John
- Green Chemistry, Vol. 17, Issue 3
Aromatic Monomers by in Situ Conversion of Reactive Intermediates in the Acid-Catalyzed Depolymerization of Lignin
journal, June 2015
- Deuss, Peter J.; Scott, Martin; Tran, Fanny
- Journal of the American Chemical Society, Vol. 137, Issue 23
Isolation of Functionalized Phenolic Monomers through Selective Oxidation and CO Bond Cleavage of the β-O-4 Linkages in Lignin
journal, November 2014
- Lancefield, Christopher S.; Ojo, O. Stephen; Tran, Fanny
- Angewandte Chemie International Edition, Vol. 54, Issue 1
Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization
journal, October 2016
- Shuai, Li; Amiri, Masoud Talebi; Questell-Santiago, Ydna M.
- Science, Vol. 354, Issue 6310
Redox Catalysis Facilitates Lignin Depolymerization
journal, June 2017
- Bosque, Irene; Magallanes, Gabriel; Rigoulet, Mathilde
- ACS Central Science, Vol. 3, Issue 6
Pathways for degradation of lignin in bacteria and fungi
journal, January 2011
- Bugg, Timothy D. H.; Ahmad, Mark; Hardiman, Elizabeth M.
- Natural Product Reports, Vol. 28, Issue 12, p. 1883-1896
Biochemical transformation of lignin for deriving valued commodities from lignocellulose
journal, June 2017
- Gall, Daniel L.; Ralph, John; Donohue, Timothy J.
- Current Opinion in Biotechnology, Vol. 45
Lignin Biosynthesis and Structure
journal, May 2010
- Vanholme, R.; Demedts, B.; Morreel, K.
- Plant Physiology, Vol. 153, Issue 3, p. 895-905
Pretreatment Methods for Bioethanol Production
journal, June 2014
- Xu, Zhaoyang; Huang, Fang
- Applied Biochemistry and Biotechnology, Vol. 174, Issue 1
Structural changes in lignin during organosolv pretreatment of Liriodendron tulipifera and the effect on enzymatic hydrolysis
journal, July 2012
- Koo, Bon-Wook; Min, Byeong-Cheol; Gwak, Ki-Seob
- Biomass and Bioenergy, Vol. 42
In-Depth 2D NMR Study of Lignin Modification During Pretreatment of Eucalyptus Wood with Laccase and Mediators
journal, August 2014
- Rico, Alejandro; Rencoret, Jorge; del Río, José C.
- BioEnergy Research, Vol. 8, Issue 1
Chemoselective Metal-Free Aerobic Alcohol Oxidation in Lignin
journal, April 2013
- Rahimi, Alireza; Azarpira, Ali; Kim, Hoon
- Journal of the American Chemical Society, Vol. 135, Issue 17, p. 6415-6418
Model Compound Studies of the β-O-4 Linkage in Lignin: Absolute Rate Expressions for β-Scission of Phenoxyl Radical from 1-Phenyl-2-phenoxyethanol-1-yl Radical
journal, November 2002
- Kandanarachchi, Pramod H.; Autrey, Tom; Franz, James A.
- The Journal of Organic Chemistry, Vol. 67, Issue 23
Cleaving the βO4 Bonds of Lignin Model Compounds in an Acidic Ionic Liquid, 1-H-3-Methylimidazolium Chloride: An Optional Strategy for the Degradation of Lignin
journal, July 2010
- Jia, Songyan; Cox, Blair J.; Guo, Xinwen
- ChemSusChem, Vol. 3, Issue 9
Catalytic C−O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin-Related Polymers
journal, September 2010
- Nichols, Jason M.; Bishop, Lee M.; Bergman, Robert G.
- Journal of the American Chemical Society, Vol. 132, Issue 36
Comparison of Copper and Vanadium Homogeneous Catalysts for Aerobic Oxidation of Lignin Models
journal, May 2011
- Sedai, Baburam; Díaz-Urrutia, Christian; Baker, R. Tom
- ACS Catalysis, Vol. 1, Issue 7
C-C or C-O Bond Cleavage in a Phenolic Lignin Model Compound: Selectivity Depends on Vanadium Catalyst
journal, January 2012
- Hanson, Susan K.; Wu, Ruilian; Silks, Louis A. “Pete”
- Angewandte Chemie International Edition, Vol. 51, Issue 14, p. 3410-3413
Efficient Cobalt-Catalyzed Oxidative Conversion of Lignin Models to Benzoquinones
journal, May 2013
- Biannic, Berenger; Bozell, Joseph J.
- Organic Letters, Vol. 15, Issue 11
Aerobic Oxidation of β-1 Lignin Model Compounds with Copper and Oxovanadium Catalysts
journal, November 2013
- Sedai, Baburam; Díaz-Urrutia, Christian; Baker, R. Tom
- ACS Catalysis, Vol. 3, Issue 12
A Photochemical Strategy for Lignin Degradation at Room Temperature
journal, January 2014
- Nguyen, John D.; Matsuura, Bryan S.; Stephenson, Corey R. J.
- Journal of the American Chemical Society, Vol. 136, Issue 4
Steric effects in the design of Co-Schiff base complexes for the catalytic oxidation of lignin models to para-benzoquinones
journal, January 2014
- Biannic, Berenger; Bozell, Joseph J.; Elder, Thomas
- Green Chem., Vol. 16, Issue 7
Solar Photochemical Oxidation of Alcohols using Catalytic Hydroquinone and Copper Nanoparticles under Oxygen: Oxidative Cleavage of Lignin Models
journal, November 2014
- Mitchell, Lorna J.; Moody, Christopher J.
- The Journal of Organic Chemistry, Vol. 79, Issue 22
Copper- and Vanadium-Catalyzed Oxidative Cleavage of Lignin using Dioxygen
journal, May 2015
- Mottweiler, Jakob; Puche, Marta; Räuber, Christoph
- ChemSusChem, Vol. 8, Issue 12
Fragmentation of structural units of lignin promoted by persulfate through selective C–C cleavage under mild conditions
journal, January 2015
- Luo, Fei-Xian; Zhou, Tai-Gang; Li, Xin
- Organic Chemistry Frontiers, Vol. 2, Issue 9
Formic-acid-induced depolymerization of oxidized lignin to aromatics
journal, November 2014
- Rahimi, Alireza; Ulbrich, Arne; Coon, Joshua J.
- Nature, Vol. 515, Issue 7526, p. 249-252
Comparative Studies on Cellulolytic Enzyme Lignin and Milled Wood Lignin of Sweetgum and Spruce
journal, January 1975
- Chang, Hou-min; Cowling, Ellis B.; Brown, Wynford
- Holzforschung, Vol. 29, Issue 5
Chemical properties of lignin from Aralia cordata
journal, January 1994
- Hibino, Takashi; Shibata, Daisuke; Ito, Takashi
- Phytochemistry, Vol. 37, Issue 2, p. 445-448
Nonenzymatic Sugar Production from Biomass Using Biomass-Derived -Valerolactone
journal, January 2014
- Luterbacher, J. S.; Rand, J. M.; Alonso, D. M.
- Science, Vol. 343, Issue 6168
Isolation and characterization of new lignin streams derived from extractive-ammonia (EA) pretreatment
journal, January 2016
- da Costa Sousa, Leonardo; Foston, Marcus; Bokade, Vijay
- Green Chemistry, Vol. 18, Issue 15
Next-generation ammonia pretreatment enhances cellulosic biofuel production
journal, January 2016
- da Costa Sousa, Leonardo; Jin, Mingjie; Chundawat, Shishir P. S.
- Energy & Environmental Science, Vol. 9, Issue 4
Effective alkaline metal-catalyzed oxidative delignification of hybrid poplar
journal, February 2016
- Bhalla, Aditya; Bansal, Namita; Stoklosa, Ryan J.
- Biotechnology for Biofuels, Vol. 9, Issue 1
Naturally p-Hydroxybenzoylated Lignins in Palms
journal, February 2015
- Lu, Fachuang; Karlen, Steven D.; Regner, Matt
- BioEnergy Research, Vol. 8, Issue 3
Whole plant cell wall characterization using solution-state 2D NMR
journal, August 2012
- Mansfield, Shawn D.; Kim, Hoon; Lu, Fachuang
- Nature Protocols, Vol. 7, Issue 9
Feruloylation in Grasses: Current and Future Perspectives
journal, September 2009
- de O. Buanafina, Marcia M.
- Molecular Plant, Vol. 2, Issue 5
Lignin monomer production integrated into the γ-valerolactone sugar platform
journal, January 2015
- Luterbacher, Jeremy S.; Azarpira, Ali; Motagamwala, Ali H.
- Energy & Environmental Science, Vol. 8, Issue 9
Chemical and structural changes associated with Cu-catalyzed alkaline-oxidative delignification of hybrid poplar
journal, August 2015
- Li, Zhenglun; Bansal, Namita; Azarpira, Ali
- Biotechnology for Biofuels, Vol. 8, Issue 1
Engineered Lignin in Poplar Biomass Facilitates Cu-Catalyzed Alkaline-Oxidative Pretreatment
journal, January 2018
- Bhalla, Aditya; Bansal, Namita; Pattathil, Sivakumar
- ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 3
Works referencing / citing this record:
Perspective on Lignin Oxidation: Advances, Challenges, and Future Directions
journal, July 2018
- Vangeel, Thijs; Schutyser, Wouter; Renders, Tom
- Topics in Current Chemistry, Vol. 376, Issue 4
Establishing lignin structure-upgradeability relationships using quantitative 1 H– 13 C heteronuclear single quantum coherence nuclear magnetic resonance (HSQC-NMR) spectroscopy
journal, January 2019
- Talebi Amiri, Masoud; Bertella, Stefania; Questell-Santiago, Ydna M.
- Chemical Science, Vol. 10, Issue 35
Lignin oxidation by MnO 2 under the irradiation of blue light
journal, January 2019
- Dai, Jinhuo; Patti, Antonio F.; Styles, Gavin N.
- Green Chemistry, Vol. 21, Issue 8
Highly Selective Oxidation and Depolymerization of α,γ‐Diol‐Protected Lignin
journal, February 2019
- Lan, Wu; de Bueren, Jean Behaghel; Luterbacher, Jeremy S.
- Angewandte Chemie International Edition, Vol. 58, Issue 9
Funneling aromatic products of chemically depolymerized lignin into 2-pyrone-4-6-dicarboxylic acid with Novosphingobium aromaticivorans
journal, January 2019
- Perez, Jose M.; Kontur, Wayne S.; Alherech, Manar
- Green Chemistry, Vol. 21, Issue 6
Highly Selective Oxidation and Depolymerization of α,γ‐Diol‐Protected Lignin
journal, January 2019
- Lan, Wu; de Bueren, Jean Behaghel; Luterbacher, Jeremy S.
- Angewandte Chemie, Vol. 131, Issue 9
Efficient Mild Organosolv Lignin Extraction in a Flow-Through Setup Yielding Lignin with High β-O-4 Content
journal, November 2019
- Zijlstra, Douwe S.; Analbers, Coen A.; de Korte, Joren
- Polymers, Vol. 11, Issue 12
Cleavage of lignin model compounds and lignin ox using aqueous oxalic acid
journal, January 2019
- Lindsay, Ashley C.; Kudo, Shinji; Sperry, Jonathan
- Organic & Biomolecular Chemistry, Vol. 17, Issue 31
A comparative study of secondary depolymerization methods on oxidized lignins
journal, January 2019
- Song, Yang; Motagamwala, Ali Hussain; Karlen, Steven D.
- Green Chemistry, Vol. 21, Issue 14
Mechanistic insight in the selective delignification of wheat straw by three white-rot fungal species through quantitative 13C-IS py-GC–MS and whole cell wall HSQC NMR
journal, September 2018
- van Erven, Gijs; Nayan, Nazri; Sonnenberg, Anton S. M.
- Biotechnology for Biofuels, Vol. 11, Issue 1
Grafting strategies for hydroxy groups of lignin for producing materials
journal, January 2019
- Eraghi Kazzaz, Armin; Hosseinpour Feizi, Zahra; Fatehi, Pedram
- Green Chemistry, Vol. 21, Issue 21
Chemocatalytic Conversion of Cellulose into Key Platform Chemicals
journal, August 2018
- Li, Guangbi; Liu, Wei; Ye, Chenliang
- International Journal of Polymer Science, Vol. 2018
Electrocatalytic Upgrading of Lignin‐Derived Bio‐Oil Based on Surface‐Engineered PtNiB Nanostructure
journal, March 2019
- Zhou, Yulin; Gao, Yijing; Zhong, Xing
- Advanced Functional Materials, Vol. 29, Issue 10
Isolation of a novel platform bacterium for lignin valorization and its application in glucose-free cis,cis-muconate production
journal, May 2019
- Shinoda, Eri; Takahashi, Kenji; Abe, Nanase
- Journal of Industrial Microbiology & Biotechnology, Vol. 46, Issue 8
Supercritical methanol depolymerization and hydrodeoxygenation of lignin and biomass over reduced copper porous metal oxides
journal, January 2019
- McClelland, Daniel J.; Galebach, Peter H.; Motagamwala, Ali Hussain
- Green Chemistry, Vol. 21, Issue 11
Mechanistic studies of milled and Kraft lignin oxidation by radical species
journal, January 2020
- Davaritouchaee, Maryam; Hiscox, William C.; Terrell, Evan
- Green Chemistry, Vol. 22, Issue 4
Activating molecular oxygen with Au/CeO 2 for the conversion of lignin model compounds and organosolv lignin
journal, January 2019
- Song, Wu-Lin; Dong, Qingmeng; Hong, Liang
- RSC Advances, Vol. 9, Issue 53
Cascade utilization of lignocellulosic biomass to high-value products
journal, January 2019
- Liu, Yanrong; Nie, Yi; Lu, Xingmei
- Green Chemistry, Vol. 21, Issue 13
Efficient Oxidation of Benzylic and Aliphatic Alcohols Using a Bioinspired Cross-Bridged Cyclam Manganese Complex with H 2 O 2: Efficient Oxidation of Benzylic and Aliphatic Alcohols Using a Bioinspired Cross-Bridged Cyclam Manganese Complex with H 2 O 2
journal, November 2018
- Zhang, Zhan; Khrouz, Lhoussain; Yin, Guochuan
- European Journal of Organic Chemistry, Vol. 2019, Issue 2-3
Gold-catalyzed conversion of lignin to low molecular weight aromatics
journal, January 2018
- Song, Yang; Mobley, Justin K.; Motagamwala, Ali Hussain
- Chemical Science, Vol. 9, Issue 42
Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor
journal, January 2019
- Li, Yanding; Demir, Benginur; Vázquez Ramos, Leida M.
- Green Chemistry, Vol. 21, Issue 13
Efficient Mild Organosolv Lignin Extraction in a Flow-Through Setup Yielding Lignin with High β-O-4 Content
journal, November 2019
- Zijlstra, Douwe S.; Analbers, Coen A.; de Korte, Joren
- Polymers, Vol. 11, Issue 12