skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Direct ink writing of organic and carbon aerogels

Abstract

Additive manufacturing is used to overcome inherent aerogel limitations. 3D printed aerogels simultaneously exhibit large capacitance and fast ion transport in millimeter-thick electrodes.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [2];  [2];  [2]; ORCiD logo [1];  [3];  [3]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [1]
  1. Physics and Life Science Directorate, Lawrence Livermore National Laboratory, Livermore, USA
  2. Department of Chemistry and Biochemistry, University of California, Santa Cruz, USA
  3. Engineering Directorate, Lawrence Livermore National Laboratory, Livermore, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1471143
Grant/Contract Number:  
16-ERD-051
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Materials Horizons
Additional Journal Information:
Journal Name: Materials Horizons Journal Volume: 5 Journal Issue: 6; Journal ID: ISSN 2051-6347
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Chandrasekaran, Swetha, Yao, Bin, Liu, Tianyu, Xiao, Wang, Song, Yu, Qian, Fang, Zhu, Cheng, Duoss, Eric B., Spadaccini, Christopher M., Li, Yat, and Worsley, Marcus A. Direct ink writing of organic and carbon aerogels. United Kingdom: N. p., 2018. Web. doi:10.1039/C8MH00603B.
Chandrasekaran, Swetha, Yao, Bin, Liu, Tianyu, Xiao, Wang, Song, Yu, Qian, Fang, Zhu, Cheng, Duoss, Eric B., Spadaccini, Christopher M., Li, Yat, & Worsley, Marcus A. Direct ink writing of organic and carbon aerogels. United Kingdom. doi:10.1039/C8MH00603B.
Chandrasekaran, Swetha, Yao, Bin, Liu, Tianyu, Xiao, Wang, Song, Yu, Qian, Fang, Zhu, Cheng, Duoss, Eric B., Spadaccini, Christopher M., Li, Yat, and Worsley, Marcus A. Mon . "Direct ink writing of organic and carbon aerogels". United Kingdom. doi:10.1039/C8MH00603B.
@article{osti_1471143,
title = {Direct ink writing of organic and carbon aerogels},
author = {Chandrasekaran, Swetha and Yao, Bin and Liu, Tianyu and Xiao, Wang and Song, Yu and Qian, Fang and Zhu, Cheng and Duoss, Eric B. and Spadaccini, Christopher M. and Li, Yat and Worsley, Marcus A.},
abstractNote = {Additive manufacturing is used to overcome inherent aerogel limitations. 3D printed aerogels simultaneously exhibit large capacitance and fast ion transport in millimeter-thick electrodes.},
doi = {10.1039/C8MH00603B},
journal = {Materials Horizons},
number = 6,
volume = 5,
place = {United Kingdom},
year = {2018},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8MH00603B

Citation Metrics:
Cited by: 4 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

3D Printing of Reduced Graphene Oxide Nanowires
journal, November 2014


Advanced carbon aerogels for energy applications
journal, January 2011

  • Biener, Juergen; Stadermann, Michael; Suss, Matthew
  • Energy & Environmental Science, Vol. 4, Issue 3, p. 656-667
  • DOI: 10.1039/c0ee00627k

High capacity supercapacitors based on modified activated carbon aerogel
journal, March 2005


Pristine Graphene Aerogels by Room-Temperature Freeze Gelation
journal, July 2016


The investigation of the adsorption character of carbon aerogels
journal, May 1999


Generalized 3D Printing of Graphene-Based Mixed-Dimensional Hybrid Aerogels
journal, March 2018


3D printed functional nanomaterials for electrochemical energy storage
journal, August 2017


An Electrochemical Capacitor with Applicable Energy Density of 7.4 Wh/kg at Average Power Density of 3000 W/kg
journal, April 2015


Ostwald Ripening Improves Rate Capability of High Mass Loading Manganese Oxide for Supercapacitors
journal, July 2017


Carbon aerogels for catalysis applications: An overview
journal, January 2005


Toward New Candidates for Hydrogen Storage:  High-Surface-Area Carbon Aerogels
journal, December 2006

  • Kabbour, Houria; Baumann, Theodore F.; Satcher,, Joe H.
  • Chemistry of Materials, Vol. 18, Issue 26, p. 6085-6087
  • DOI: 10.1021/cm062329a

Optimizing supercapacitor electrode density: achieving the energy of organic electrolytes with the power of aqueous electrolytes
journal, January 2014

  • Merrill, M. D.; Montalvo, E.; Campbell, P. G.
  • RSC Advances, Vol. 4, Issue 81
  • DOI: 10.1039/C4RA08114E

Ion Intercalation Induced Capacitance Improvement for Graphene-Based Supercapacitor Electrodes
journal, May 2016


Supercapacitors Based on Three-Dimensional Hierarchical Graphene Aerogels with Periodic Macropores
journal, January 2016


Flexible solid-state electrochemical supercapacitors
journal, September 2014


Activated Carbon Aerogels
journal, January 1996

  • Hanzawa, Y.; Kaneko, K.; Pekala, R. W.
  • Langmuir, Vol. 12, Issue 26
  • DOI: 10.1021/la960481t

Hierarchically porous carbon foams for electric double layer capacitors
journal, July 2016


High surface area carbon aerogel monoliths with hierarchical porosity
journal, July 2008

  • Baumann, Theodore F.; Worsley, Marcus A.; Han, T. Yong-Jin
  • Journal of Non-Crystalline Solids, Vol. 354, Issue 29, p. 3513-3515
  • DOI: 10.1016/j.jnoncrysol.2008.03.006

Carbonization and activation of sol–gel derived carbon xerogels
journal, January 2000


Probing electrochemical reactions in organic cathode materials via in operando infrared spectroscopy
journal, February 2018


Activated carbon cryogels for low pressure methane storage
journal, March 2006


High surface area carbon aerogels for supercapacitors
journal, April 1998


Carbon Aerogels and Xerogels
journal, January 1992

  • Pekala, Richard W.; Alviso, Cynthia T.
  • MRS Proceedings, Vol. 270
  • DOI: 10.1557/PROC-270-3

Capacitive desalination with flow-through electrodes
journal, January 2012

  • Suss, Matthew E.; Baumann, Theodore F.; Bourcier, William L.
  • Energy & Environmental Science, Vol. 5, Issue 11
  • DOI: 10.1039/c2ee21498a

Direct 3D Printing of Ultralight Graphene Oxide Aerogel Microlattices
journal, February 2018

  • Jiang, Yanqiu; Xu, Zhen; Huang, Tieqi
  • Advanced Functional Materials, Vol. 28, Issue 16
  • DOI: 10.1002/adfm.201707024

Correlating electrochemical impedance with hierarchical structure for porous carbon-based supercapacitors using a truncated transmission line model
journal, September 2018


Highly compressible 3D periodic graphene aerogel microlattices
journal, April 2015

  • Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7962

Approaching theoretical strength in glassy carbon nanolattices
journal, February 2016

  • Bauer, J.; Schroer, A.; Schwaiger, R.
  • Nature Materials, Vol. 15, Issue 4
  • DOI: 10.1038/nmat4561

3D Printing of Graphene Aerogels
journal, February 2016

  • Zhang, Qiangqiang; Zhang, Feng; Medarametla, Sai Pradeep
  • Small, Vol. 12, Issue 13
  • DOI: 10.1002/smll.201503524