Direct ink writing of organic and carbon aerogels

Chandrasekaran, Swetha; Yao, Bin; Liu, Tianyu; Xiao, Wang; Song, Yu; Qian, Fang; Zhu, Cheng; Duoss, Eric B.; Spadaccini, Christopher M.; Li, Yat; Worsley, Marcus A.

doi:10.1039/C8MH00603B

Title: Direct ink writing of organic and carbon aerogels

Abstract

Additive manufacturing is used to overcome inherent aerogel limitations. 3D printed aerogels simultaneously exhibit large capacitance and fast ion transport in millimeter-thick electrodes.

Authors:

^[1]; Yao, Bin ^[2];

^[2]; Xiao, Wang ^[2]; Song, Yu ^[2];

^[1]; Zhu, Cheng ^[3]; Duoss, Eric B. ^[3];

^[3];

^[2];

^[1]

Physics and Life Science Directorate, Lawrence Livermore National Laboratory, Livermore, USA
Department of Chemistry and Biochemistry, University of California, Santa Cruz, USA
Engineering Directorate, Lawrence Livermore National Laboratory, Livermore, USA

Publication Date:: Mon Oct 29 00:00:00 EDT 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1471143

Grant/Contract Number:: 16-ERD-051

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Materials Horizons

Additional Journal Information:: Journal Name: Materials Horizons Journal Volume: 5 Journal Issue: 6; Journal ID: ISSN 2051-6347

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Chandrasekaran, Swetha, Yao, Bin, Liu, Tianyu, Xiao, Wang, Song, Yu, Qian, Fang, Zhu, Cheng, Duoss, Eric B., Spadaccini, Christopher M., Li, Yat, and Worsley, Marcus A. Direct ink writing of organic and carbon aerogels.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C8MH00603B.

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                    Chandrasekaran, Swetha, Yao, Bin, Liu, Tianyu, Xiao, Wang, Song, Yu, Qian, Fang, Zhu, Cheng, Duoss, Eric B., Spadaccini, Christopher M., Li, Yat, & Worsley, Marcus A. Direct ink writing of organic and carbon aerogels.  United Kingdom.  https://doi.org/10.1039/C8MH00603B

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                    Chandrasekaran, Swetha, Yao, Bin, Liu, Tianyu, Xiao, Wang, Song, Yu, Qian, Fang, Zhu, Cheng, Duoss, Eric B., Spadaccini, Christopher M., Li, Yat, and Worsley, Marcus A. Mon .  
"Direct ink writing of organic and carbon aerogels".  United Kingdom.  https://doi.org/10.1039/C8MH00603B.

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@article{osti_1471143,

  title        = {Direct ink writing of organic and carbon aerogels},

  author       = {Chandrasekaran, Swetha and Yao, Bin and Liu, Tianyu and Xiao, Wang and Song, Yu and Qian, Fang and Zhu, Cheng and Duoss, Eric B. and Spadaccini, Christopher M. and Li, Yat and Worsley, Marcus A.},

  abstractNote = {Additive manufacturing is used to overcome inherent aerogel limitations. 3D printed aerogels simultaneously exhibit large capacitance and fast ion transport in millimeter-thick electrodes.},

  doi          = {10.1039/C8MH00603B},

  journal      = {Materials Horizons},

  number       = 6,

  volume       = 5,

  place        = {United Kingdom},

  year         = {Mon Oct 29 00:00:00 EDT 2018},

  month        = {Mon Oct 29 00:00:00 EDT 2018}

}

Copy to clipboard

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Works referenced in this record:

3D Printing of Reduced Graphene Oxide Nanowires
journal, November 2014

Kim, Jung Hyun; Chang, Won Suk; Kim, Daeho
Advanced Materials, Vol. 27, Issue 1
DOI: 10.1002/adma.201404380

Carbon-Nanotube-Decorated Nano-LiFePO ₄ @C Cathode Material with Superior High-Rate and Low-Temperature Performances for Lithium-Ion Batteries
journal, May 2013

Wu, Xing-Long; Guo, Yu-Guo; Su, Jing
Advanced Energy Materials, Vol. 3, Issue 9
DOI: 10.1002/aenm.201300159

Advanced carbon aerogels for energy applications
journal, January 2011

Biener, Juergen; Stadermann, Michael; Suss, Matthew
Energy & Environmental Science, Vol. 4, Issue 3, p. 656-667
DOI: 10.1039/c0ee00627k

High capacity supercapacitors based on modified activated carbon aerogel
journal, March 2005

Fang, B.; Wei, Y. Z.; Maruyama, K.
Journal of Applied Electrochemistry, Vol. 35, Issue 3
DOI: 10.1007/s10800-004-3462-6

Pristine Graphene Aerogels by Room-Temperature Freeze Gelation
journal, July 2016

Lin, Yue; Liu, Fei; Casano, Gabriel
Advanced Materials, Vol. 28, Issue 36
DOI: 10.1002/adma.201602393

The investigation of the adsorption character of carbon aerogels
journal, May 1999

Zhang, S. Q.; Wang, J.; Shen, J.
Nanostructured Materials, Vol. 11, Issue 3
DOI: 10.1016/S0965-9773(99)00054-9

Generalized 3D Printing of Graphene-Based Mixed-Dimensional Hybrid Aerogels
journal, March 2018

Tang, Xingwei; Zhou, Han; Cai, Zuocheng
ACS Nano, Vol. 12, Issue 4
DOI: 10.1021/acsnano.8b00304

3D printed functional nanomaterials for electrochemical energy storage
journal, August 2017

Zhu, Cheng; Liu, Tianyu; Qian, Fang
Nano Today, Vol. 15
DOI: 10.1016/j.nantod.2017.06.007

An Electrochemical Capacitor with Applicable Energy Density of 7.4 Wh/kg at Average Power Density of 3000 W/kg
journal, April 2015

Zhai, Teng; Lu, Xihong; Wang, Hanyu
Nano Letters, Vol. 15, Issue 5
DOI: 10.1021/acs.nanolett.5b00321

Ostwald Ripening Improves Rate Capability of High Mass Loading Manganese Oxide for Supercapacitors
journal, July 2017

Song, Yu; Liu, Tianyu; Yao, Bin
ACS Energy Letters, Vol. 2, Issue 8
DOI: 10.1021/acsenergylett.7b00405

Carbon aerogels for catalysis applications: An overview
journal, January 2005

Moreno-Castilla, C.; Maldonado-Hódar, F. J.
Carbon, Vol. 43, Issue 3, p. 455-465
DOI: 10.1016/j.carbon.2004.10.022

Toward New Candidates for Hydrogen Storage: High-Surface-Area Carbon Aerogels
journal, December 2006

Kabbour, Houria; Baumann, Theodore F.; Satcher,, Joe H.
Chemistry of Materials, Vol. 18, Issue 26, p. 6085-6087
DOI: 10.1021/cm062329a

Optimizing supercapacitor electrode density: achieving the energy of organic electrolytes with the power of aqueous electrolytes
journal, January 2014

Merrill, M. D.; Montalvo, E.; Campbell, P. G.
RSC Advances, Vol. 4, Issue 81
DOI: 10.1039/C4RA08114E

Ion Intercalation Induced Capacitance Improvement for Graphene-Based Supercapacitor Electrodes
journal, May 2016

Liu, Tianyu; Zhu, Cheng; Kou, Tianyi
ChemNanoMat, Vol. 2, Issue 7
DOI: 10.1002/cnma.201600107

Supercapacitors Based on Three-Dimensional Hierarchical Graphene Aerogels with Periodic Macropores
journal, January 2016

Zhu, Cheng; Liu, Tianyu; Qian, Fang
Nano Letters, Vol. 16, Issue 6, p. 3448-3456
DOI: 10.1021/acs.nanolett.5b04965

Flexible solid-state electrochemical supercapacitors
journal, September 2014

Yang, Peihua; Mai, Wenjie
Nano Energy, Vol. 8
DOI: 10.1016/j.nanoen.2014.05.022

Activated Carbon Aerogels
journal, January 1996

Hanzawa, Y.; Kaneko, K.; Pekala, R. W.
Langmuir, Vol. 12, Issue 26
DOI: 10.1021/la960481t

Hierarchically porous carbon foams for electric double layer capacitors
journal, July 2016

Zhang, Feng; Liu, Tianyu; Hou, Guihua
Nano Research, Vol. 9, Issue 10
DOI: 10.1007/s12274-016-1173-z

High surface area carbon aerogel monoliths with hierarchical porosity
journal, July 2008

Baumann, Theodore F.; Worsley, Marcus A.; Han, T. Yong-Jin
Journal of Non-Crystalline Solids, Vol. 354, Issue 29, p. 3513-3515
DOI: 10.1016/j.jnoncrysol.2008.03.006

Carbonization and activation of sol–gel derived carbon xerogels
journal, January 2000

Lin, Chuan; Ritter, James A.
Carbon, Vol. 38, Issue 6
DOI: 10.1016/S0008-6223(99)00189-X

Probing electrochemical reactions in organic cathode materials via in operando infrared spectroscopy
journal, February 2018

Vizintin, Alen; Bitenc, Jan; Kopač Lautar, Anja
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-018-03114-1

Activated carbon cryogels for low pressure methane storage
journal, March 2006

Feaver, Aaron; Cao, Guozhong
Carbon, Vol. 44, Issue 3
DOI: 10.1016/j.carbon.2005.10.004

Porous structure of organic and carbon aerogels synthesized by sol-gel polycondensation of resorcinol with formaldehyde
journal, January 1997

Tamon, H.; Ishizaka, H.; Mikami, M.
Carbon, Vol. 35, Issue 6
DOI: 10.1016/S0008-6223(97)00024-9

High surface area carbon aerogels for supercapacitors
journal, April 1998

Saliger, R.; Fischer, U.; Herta, C.
Journal of Non-Crystalline Solids, Vol. 225, p. 81-85
DOI: 10.1016/S0022-3093(98)00104-5

Carbon Aerogels and Xerogels
journal, January 1992

Pekala, Richard W.; Alviso, Cynthia T.
MRS Proceedings, Vol. 270
DOI: 10.1557/PROC-270-3

Capacitive desalination with flow-through electrodes
journal, January 2012

Suss, Matthew E.; Baumann, Theodore F.; Bourcier, William L.
Energy & Environmental Science, Vol. 5, Issue 11
DOI: 10.1039/c2ee21498a

Direct 3D Printing of Ultralight Graphene Oxide Aerogel Microlattices
journal, February 2018

Jiang, Yanqiu; Xu, Zhen; Huang, Tieqi
Advanced Functional Materials, Vol. 28, Issue 16
DOI: 10.1002/adfm.201707024

Correlating electrochemical impedance with hierarchical structure for porous carbon-based supercapacitors using a truncated transmission line model
journal, September 2018

Abouelamaiem, Dina Ibrahim; He, Guanjie; Neville, Tobias P.
Electrochimica Acta, Vol. 284
DOI: 10.1016/j.electacta.2018.07.190

Highly compressible 3D periodic graphene aerogel microlattices
journal, April 2015

Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms7962

Approaching theoretical strength in glassy carbon nanolattices
journal, February 2016

Bauer, J.; Schroer, A.; Schwaiger, R.
Nature Materials, Vol. 15, Issue 4
DOI: 10.1038/nmat4561

3D Printing of Graphene Aerogels
journal, February 2016

Zhang, Qiangqiang; Zhang, Feng; Medarametla, Sai Pradeep
Small, Vol. 12, Issue 13
DOI: 10.1002/smll.201503524

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Title: Direct ink writing of organic and carbon aerogels

Abstract

Citation Formats

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Carbon-Nanotube-Decorated Nano-LiFePO 4 @C Cathode Material with Superior High-Rate and Low-Temperature Performances for Lithium-Ion Batteries journal, May 2013

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Probing electrochemical reactions in organic cathode materials via in operando infrared spectroscopy journal, February 2018

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Porous structure of organic and carbon aerogels synthesized by sol-gel polycondensation of resorcinol with formaldehyde journal, January 1997

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3D Printing of Graphene Aerogels journal, February 2016

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Carbon-Nanotube-Decorated Nano-LiFePO ₄ @C Cathode Material with Superior High-Rate and Low-Temperature Performances for Lithium-Ion Batteries
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