Localized resistance measurements of wrinkled reduced graphene oxide using in-situ transmission electron microscopy

Nilsson, Hanna M.; de Knoop, Ludvig; Cumings, John; Olsson, Eva

doi:10.1016/j.carbon.2016.10.086

Title: Localized resistance measurements of wrinkled reduced graphene oxide using in-situ transmission electron microscopy

Abstract

The tunable electrical properties of reduced graphene oxide (rGO) make it an ideal candidate for many applications including energy storage. However, in order to utilize the material for applications it is essential to understand the behavior of the material on the nanoscale, especially how naturally occurring phenomena like wrinkling affect the electronic transport. Here, we use a transmission electron microscope (TEM) with electrical probe in-situ holder to perform localized electrical measurements on wrinkled, supported rGO flakes. The TEM allows for observation of the local wrinkled structure of the rGO and simultaneously an electrical probe is used to perform localized resistance measurements. For these measurements, there is no correlation between the electrode distance and the measured resistance indicating that contact resistance varies and dominates the measurements. There is, however, a correlation between increasing number of wrinkles underneath the probe and decreasing resistance, indicating that the wrinkles can provide surface area for contact with the probe and thus lower the resistance. The overall resistance is on the order of single kΩ, if the contact between the probe and the rGO is optimized. Furthermore, these measurements give evidence that rGO with wrinkling can compete as a leading type of graphene for certain applications.

Authors:: Nilsson, Hanna M.; de Knoop, Ludvig; Cumings, John; Olsson, Eva

Publication Date:: Wed Mar 01 00:00:00 EST 2017

Research Org.:: Univ. of Maryland, College Park, MD (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1398684

Alternate Identifier(s):: OSTI ID: 1469197

Grant/Contract Number:: FG02-10ER46742; SC0005456

Resource Type:: Published Article

Journal Name:: Carbon

Additional Journal Information:: Journal Name: Carbon Journal Volume: 113 Journal Issue: C; Journal ID: ISSN 0008-6223

Publisher:: Elsevier

Country of Publication:: United Kingdom

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Nilsson, Hanna M., de Knoop, Ludvig, Cumings, John, and Olsson, Eva. Localized resistance measurements of wrinkled reduced graphene oxide using in-situ transmission electron microscopy.  United Kingdom: N. p., 2017. 
Web.  doi:10.1016/j.carbon.2016.10.086.

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                    Nilsson, Hanna M., de Knoop, Ludvig, Cumings, John, & Olsson, Eva. Localized resistance measurements of wrinkled reduced graphene oxide using in-situ transmission electron microscopy.  United Kingdom.  https://doi.org/10.1016/j.carbon.2016.10.086

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                    Nilsson, Hanna M., de Knoop, Ludvig, Cumings, John, and Olsson, Eva. Wed .  
"Localized resistance measurements of wrinkled reduced graphene oxide using in-situ transmission electron microscopy".  United Kingdom.  https://doi.org/10.1016/j.carbon.2016.10.086.

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@article{osti_1398684,

  title        = {Localized resistance measurements of wrinkled reduced graphene oxide using in-situ transmission electron microscopy},

  author       = {Nilsson, Hanna M. and de Knoop, Ludvig and Cumings, John and Olsson, Eva},

  abstractNote = {The tunable electrical properties of reduced graphene oxide (rGO) make it an ideal candidate for many applications including energy storage. However, in order to utilize the material for applications it is essential to understand the behavior of the material on the nanoscale, especially how naturally occurring phenomena like wrinkling affect the electronic transport. Here, we use a transmission electron microscope (TEM) with electrical probe in-situ holder to perform localized electrical measurements on wrinkled, supported rGO flakes. The TEM allows for observation of the local wrinkled structure of the rGO and simultaneously an electrical probe is used to perform localized resistance measurements. For these measurements, there is no correlation between the electrode distance and the measured resistance indicating that contact resistance varies and dominates the measurements. There is, however, a correlation between increasing number of wrinkles underneath the probe and decreasing resistance, indicating that the wrinkles can provide surface area for contact with the probe and thus lower the resistance. The overall resistance is on the order of single kΩ, if the contact between the probe and the rGO is optimized. Furthermore, these measurements give evidence that rGO with wrinkling can compete as a leading type of graphene for certain applications.},

  doi          = {10.1016/j.carbon.2016.10.086},

  journal      = {Carbon},

  number       = C,

  volume       = 113,

  place        = {United Kingdom},

  year         = {Wed Mar 01 00:00:00 EST 2017},

  month        = {Wed Mar 01 00:00:00 EST 2017}

}

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Title: Localized resistance measurements of wrinkled reduced graphene oxide using in-situ transmission electron microscopy

Abstract

Citation Formats

Epitaxial-Graphene/Graphene-Oxide Junction: An Essential Step towards Epitaxial Graphene Electronics journal, July 2008

Contact properties to CVD-graphene on GaAs substrates for optoelectronic applications journal, July 2014

Nanoscale Tunable Reduction of Graphene Oxide for Graphene Electronics journal, June 2010

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Spatial Mapping of the Dirac Point in Monolayer and Bilayer Graphene journal, January 2011

Raman Spectra of Graphite Oxide and Functionalized Graphene Sheets journal, January 2008

Up-Scaling Graphene Electronics by Reproducible Metal–Graphene Contacts journal, May 2015

Tunable Electrical Conductivity of Individual Graphene Oxide Sheets Reduced at “Low” Temperatures journal, December 2008

Tunable assembly of graphene oxide surfactant sheets: wrinkles, overlaps and impacts on thin film properties journal, January 2010

Scanning Tunneling Microscopy Characterization of the Electrical Properties of Wrinkles in Exfoliated Graphene Monolayers journal, December 2009

Observation of wrinkle induced potential drops in biased chemically derived graphene thin film networks journal, November 2013

Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy journal, January 2009

Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide journal, June 2007

Controllable chemical vapor deposition of large area uniform nanocrystalline graphene directly on silicon dioxide journal, February 2012

Formation and Characterization of Wrinkle Structures of Chemically-Derived Graphene Thin Films and Micropatterns journal, May 2014

Evolution of Electrical, Chemical, and Structural Properties of Transparent and Conducting Chemically Derived Graphene Thin Films journal, August 2009

Stripe distributions of graphene-coated Cu foils and their effects on the reduction of graphene wrinkles journal, January 2015

Origin of the Chemical and Kinetic Stability of Graphene Oxide journal, August 2013

Routine fabrication of reduced graphene oxide microarray devices via all solution processing: Routine fabrication of reduced graphene oxide microarray devices journal, March 2013

Periodically Rippled Graphene: Growth and Spatially Resolved Electronic Structure journal, February 2008

Understanding and strain-engineering wrinkle networks in supported graphene through simulations journal, December 2014

A roadmap for graphene journal, October 2012

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Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material journal, April 2008

Optimizing the preparation parameters of GO and rGO for large-scale production journal, March 2016

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Contacting graphene journal, January 2011

Gauge fields, ripples and wrinkles in graphene layers journal, July 2009

Structure and Electronic Transport in Graphene Wrinkles journal, June 2012

Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes journal, March 2016

Electronic and optical properties of reduced graphene oxide journal, January 2015

Metal–Graphene–Metal Sandwich Contacts for Enhanced Interface Bonding and Work Function Control journal, May 2012

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Electron Thermal Microscopy journal, February 2008

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Electromechanical oscillations in bilayer graphene journal, October 2015

Influence of Substrate Microstructure on the Transport Properties of CVD-Graphene journal, December 2015

Epitaxial-Graphene/Graphene-Oxide Junction: An Essential Step towards Epitaxial Graphene Electronics
journal, July 2008

Contact properties to CVD-graphene on GaAs substrates for optoelectronic applications
journal, July 2014

Nanoscale Tunable Reduction of Graphene Oxide for Graphene Electronics
journal, June 2010

Insulator to Semimetal Transition in Graphene Oxide
journal, August 2009

Spatial Mapping of the Dirac Point in Monolayer and Bilayer Graphene
journal, January 2011

Raman Spectra of Graphite Oxide and Functionalized Graphene Sheets
journal, January 2008

Up-Scaling Graphene Electronics by Reproducible Metal–Graphene Contacts
journal, May 2015

Tunable Electrical Conductivity of Individual Graphene Oxide Sheets Reduced at “Low” Temperatures
journal, December 2008

Tunable assembly of graphene oxide surfactant sheets: wrinkles, overlaps and impacts on thin film properties
journal, January 2010

Scanning Tunneling Microscopy Characterization of the Electrical Properties of Wrinkles in Exfoliated Graphene Monolayers
journal, December 2009

Observation of wrinkle induced potential drops in biased chemically derived graphene thin film networks
journal, November 2013

Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy
journal, January 2009

Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
journal, June 2007

Controllable chemical vapor deposition of large area uniform nanocrystalline graphene directly on silicon dioxide
journal, February 2012

Formation and Characterization of Wrinkle Structures of Chemically-Derived Graphene Thin Films and Micropatterns
journal, May 2014

Evolution of Electrical, Chemical, and Structural Properties of Transparent and Conducting Chemically Derived Graphene Thin Films
journal, August 2009

Stripe distributions of graphene-coated Cu foils and their effects on the reduction of graphene wrinkles
journal, January 2015

Origin of the Chemical and Kinetic Stability of Graphene Oxide
journal, August 2013

Routine fabrication of reduced graphene oxide microarray devices via all solution processing: Routine fabrication of reduced graphene oxide microarray devices
journal, March 2013

Periodically Rippled Graphene: Growth and Spatially Resolved Electronic Structure
journal, February 2008

Understanding and strain-engineering wrinkle networks in supported graphene through simulations
journal, December 2014

A roadmap for graphene
journal, October 2012

Local Voltage Drop in a Single Functionalized Graphene Sheet Characterized by Kelvin Probe Force Microscopy
journal, September 2011

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journal, April 2008

Optimizing the preparation parameters of GO and rGO for large-scale production
journal, March 2016

Ammonium Laurate Surfactant for Cleaner Deposition of Carbon Nanotubes
journal, June 2015

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journal, January 2011

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journal, March 2016

Electronic and optical properties of reduced graphene oxide
journal, January 2015

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journal, May 2012

Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets
journal, November 2007

Electron Thermal Microscopy
journal, February 2008

Small Temperature Coefficient of Resistivity of Graphene/Graphene Oxide Hybrid Membranes
journal, September 2013

Electromechanical oscillations in bilayer graphene
journal, October 2015

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journal, December 2015