Meta-Atom Behavior in Clusters Revealing Large Spin Ground States
Abstract
The field of single molecule magnetism remains predicated on super- and double exchange mechanisms to engender large spin ground states. An alternative approach to achieving high-spin architectures involves synthesizing weak-field clusters featuring close M–M interactions to produce a single valence orbital manifold. Population of this orbital manifold in accordance with Hund’s rules could potentially yield thermally persistent high-spin ground states under which the valence electrons remain coupled. We now demonstrate this effect with a reduced hexanuclear iron cluster that achieves an S = 19/2 (χMT ≈ 53 cm3 K/mol) ground state that persists to 300 K, representing the largest spin ground state persistent to room temperature reported to date. The reduced cluster displays single molecule magnet behavior manifest in both variable-temperature zero-field 57Fe Mössbauer and magnetometry with a spin reversal barrier of 42.5(8) cm-1 and a magnetic blocking temperature of 2.9 K (0.059 K/min).
- Authors:
-
- Harvard Univ., Cambridge, MA (United States)
- Publication Date:
- Research Org.:
- Harvard Univ., Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1467660
- Grant/Contract Number:
- SC0008313
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 137; Journal Issue: 43; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Hernández Sánchez, Raúl, and Betley, Theodore A. Meta-Atom Behavior in Clusters Revealing Large Spin Ground States. United States: N. p., 2015.
Web. doi:10.1021/jacs.5b08962.
Hernández Sánchez, Raúl, & Betley, Theodore A. Meta-Atom Behavior in Clusters Revealing Large Spin Ground States. United States. https://doi.org/10.1021/jacs.5b08962
Hernández Sánchez, Raúl, and Betley, Theodore A. Tue .
"Meta-Atom Behavior in Clusters Revealing Large Spin Ground States". United States. https://doi.org/10.1021/jacs.5b08962. https://www.osti.gov/servlets/purl/1467660.
@article{osti_1467660,
title = {Meta-Atom Behavior in Clusters Revealing Large Spin Ground States},
author = {Hernández Sánchez, Raúl and Betley, Theodore A.},
abstractNote = {The field of single molecule magnetism remains predicated on super- and double exchange mechanisms to engender large spin ground states. An alternative approach to achieving high-spin architectures involves synthesizing weak-field clusters featuring close M–M interactions to produce a single valence orbital manifold. Population of this orbital manifold in accordance with Hund’s rules could potentially yield thermally persistent high-spin ground states under which the valence electrons remain coupled. We now demonstrate this effect with a reduced hexanuclear iron cluster that achieves an S = 19/2 (χMT ≈ 53 cm3 K/mol) ground state that persists to 300 K, representing the largest spin ground state persistent to room temperature reported to date. The reduced cluster displays single molecule magnet behavior manifest in both variable-temperature zero-field 57Fe Mössbauer and magnetometry with a spin reversal barrier of 42.5(8) cm-1 and a magnetic blocking temperature of 2.9 K (0.059 K/min).},
doi = {10.1021/jacs.5b08962},
journal = {Journal of the American Chemical Society},
number = 43,
volume = 137,
place = {United States},
year = {Tue Oct 06 00:00:00 EDT 2015},
month = {Tue Oct 06 00:00:00 EDT 2015}
}
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Works referenced in this record:
Single-molecule magnet engineering: building-block approaches
journal, January 2014
- Pedersen, Kasper S.; Bendix, Jesper; Clérac, Rodolphe
- Chem. Commun., Vol. 50, Issue 34
Single-Molecule Magnets
journal, November 2000
- Christou, George; Gatteschi, Dante; Hendrickson, David N.
- MRS Bulletin, Vol. 25, Issue 11
Magnetic bistability in a metal-ion cluster
journal, September 1993
- Sessoli, R.; Gatteschi, D.; Caneschi, A.
- Nature, Vol. 365, Issue 6442
A Three-Dimensional Ferrimagnet Composed of Mixed-Valence Mn4 Clusters Linked by an{Mn[N(CN)2]6}4− Unit
journal, January 2004
- Miyasaka, Hitoshi; Nakata, Kazuya; Sugiura, Ken-ichi
- Angewandte Chemie International Edition, Vol. 43, Issue 6
A Wheel-Shaped Single-Molecule Magnet of [MnII3MnIII4]: Quantum Tunneling of Magnetization under Static and Pulse Magnetic Fields
journal, October 2007
- Koizumi, Satoshi; Nihei, Masayuki; Shiga, Takuya
- Chemistry - A European Journal, Vol. 13, Issue 30
Alternating current susceptibility, high field magnetization, and millimeter band EPR evidence for a ground S = 10 state in [Mn12O12(Ch3COO)16(H2O)4].2CH3COOH.4H2O
journal, July 1991
- Caneschi, Andrea; Gatteschi, Dante; Sessoli, Roberta
- Journal of the American Chemical Society, Vol. 113, Issue 15
Magnetic properties of an octanuclear iron(III) cation
journal, July 1993
- Delfs, C.; Gatteschi, D.; Pardi, L.
- Inorganic Chemistry, Vol. 32, Issue 14
Superparamagnetic-like behavior in an octanuclear iron cluster
journal, July 1996
- Barra, A. -L; Debrunner, P.; Gatteschi, D.
- Europhysics Letters (EPL), Vol. 35, Issue 2
Preparation, crystal structure, and magnetic properties of an oligonuclear complex with 12 coupled spins and an S = 12 ground state
journal, April 1988
- Caneschi, Andrea.; Gatteschi, Dante.; Laugier, Jean.
- Journal of the American Chemical Society, Vol. 110, Issue 9
High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
journal, March 1993
- Sessoli, Roberta; Tsai, Hui Lien; Schake, Ann R.
- Journal of the American Chemical Society, Vol. 115, Issue 5
Macroscopic Measurement of Resonant Magnetization Tunneling in High-Spin Molecules
journal, May 1996
- Friedman, Jonathan R.; Sarachik, M. P.; Tejada, J.
- Physical Review Letters, Vol. 76, Issue 20
High-Spin Molecules: Hexanuclear [Mn 6 O 4 Cl 4 (Me 2 dbm) 6 ] (Me 2 dbmH = 4,4‘-Dimethyldibenzoylmethane) with a Near Tetrahedral [Mn 6 O 4 Cl 4 ] 6+ Core and a S = 12 Ground State
journal, April 1998
- Aromí, Guillem; Claude, Juan-Pablo; Knapp, Michael J.
- Journal of the American Chemical Society, Vol. 120, Issue 12
A Record Anisotropy Barrier for a Single-Molecule Magnet
journal, March 2007
- Milios, Constantinos J.; Vinslava, Alina; Wernsdorfer, Wolfgang
- Journal of the American Chemical Society, Vol. 129, Issue 10
A Family of 3D Coordination Polymers Composed of Mn19 Magnetic Units
journal, November 2006
- Moushi, Eleni E.; Stamatatos, Theocharis C.; Wernsdorfer, Wolfgang
- Angewandte Chemie International Edition, Vol. 45, Issue 46
Potential building blocks for molecular ferromagnets: [Mn12O12(O2CPh)16(H2O)4] with a S = 14 ground state
journal, December 1988
- Boyd, Peter D. W.; Li, Qiaoying.; Vincent, John B.
- Journal of the American Chemical Society, Vol. 110, Issue 25
A decanuclear mixed-valent manganese complex with a high spin multiplicity in the ground state
journal, October 1993
- Goldberg, David P.; Caneschi, Andrea; Lippard, Stephen J.
- Journal of the American Chemical Society, Vol. 115, Issue 20
Mn 7 Species with an S = 29 / 2 Ground State: High-Frequency EPR Studies of a Species at the Classical/Quantum Spin Interface
journal, November 2011
- Wang, Zhenxing; van Tol, Johan; Taguchi, Taketo
- Journal of the American Chemical Society, Vol. 133, Issue 44
Spin Maximization from S = 11 to S = 16 in Mn 7 Disk-Like Clusters: Spin Frustration Effects and Their Computational Rationalization
journal, September 2009
- Stamatatos, Theocharis C.; Foguet-Albiol, Dolos; Poole, Katye M.
- Inorganic Chemistry, Vol. 48, Issue 20
Self-assembled decanuclear NaI2MnII4MnIII4 complexes: from discrete clusters to 1-D and 2-D structures, with the MnII4MnIII4 unit displaying a large spin ground state and probable SMM behaviour
journal, January 2011
- Langley, Stuart K.; Chilton, Nicholas F.; Moubaraki, Boujemaa
- Dalton Transactions, Vol. 40, Issue 45
Synthesis, Structures, and Magnetic Properties of Fe2, Fe17, and Fe19 Oxo-Bridged Iron Clusters: The Stabilization of High Ground State Spins by Cluster Aggregates
journal, March 1995
- Powell, A. K.; Heath, S. L.; Gatteschi, D.
- Journal of the American Chemical Society, Vol. 117, Issue 9
Towards nanostructured arrays of single molecule magnets: new Fe19 oxyhydroxide clusters displaying high ground state spins and hysteresis †
journal, January 2000
- Goodwin, Jeremy C.; Sessoli, Roberta; Gatteschi, Dante
- Journal of the Chemical Society, Dalton Transactions, Issue 12
A High-Spin Cyanide-Bridged Mn 9 W 6 Cluster ( S = 39 / 2 ) with a Full-Capped Cubane Structure
journal, March 2000
- Zhong, Zhuang Jin; Seino, Hidetake; Mizobe, Yasushi
- Journal of the American Chemical Society, Vol. 122, Issue 12
High-Nuclearity, High-Symmetry, High-Spin Molecules: A Mixed-Valence Mn10 Cage Possessing RareT symmetry and anS=22 Ground State
journal, June 2006
- Stamatatos, Theocharis C.; Abboud, Khalil A.; Wernsdorfer, Wolfgang
- Angewandte Chemie International Edition, Vol. 45, Issue 25
A Ferromagnetic Mixed-Valent Mn Supertetrahedron: Towards Low-Temperature Magnetic Refrigeration with Molecular Clusters
journal, June 2007
- Manoli, Maria; Johnstone, Russell D. L.; Parsons, Simon
- Angewandte Chemie International Edition, Vol. 46, Issue 24
Ferromagnetically-coupled decanuclear, mixed-valence [Mn10O4(N3)4(hmp)12]2+ [hmpH=2-(hydroxymethyl)pyridine] clusters with rare T symmetry and an S=22 ground state
journal, June 2007
- Stamatatos, Theocharis C.; Abboud, Khalil A.; Wernsdorfer, Wolfgang
- Polyhedron, Vol. 26, Issue 9-11
High-Spin Mn 4 and Mn 10 Molecules: Large Spin Changes with Structure in Mixed-Valence Mn II 4 Mn III 6 Clusters with Azide and Alkoxide-Based Ligands
journal, May 2008
- Stamatatos, Theocharis C.; Poole, Katye M.; Abboud, Khalil A.
- Inorganic Chemistry, Vol. 47, Issue 11
S T = 22 [Mn 10 ] Supertetrahedral Building-Block to Design Extended Magnetic Networks
journal, September 2011
- Wu, Gang; Huang, Jian; Sun, Linlin
- Inorganic Chemistry, Vol. 50, Issue 17
Solvothermal Synthesis of a Tetradecametallic FeIII Cluster
journal, August 2003
- Low, David M.; Jones, Leigh F.; Bell, Aidan
- Angewandte Chemie International Edition, Vol. 42, Issue 32
1,2,3-Triazolate-Bridged Tetradecametallic Transition Metal Clusters [M 14 (L) 6 O 6 (OMe) 18 X 6 ] (M = Fe III , Cr III and V III/IV ) and Related Compounds: Ground-State Spins Ranging from S = 0 to S = 25 and Spin-Enhanced Magnetocaloric Effect
journal, June 2007
- Shaw, Rachel; Laye, Rebecca H.; Jones, Leigh F.
- Inorganic Chemistry, Vol. 46, Issue 12
High-Spin Molecules: A Novel Cyano-Bridged MnMo Molecular Cluster with aS=51/2 Ground State and Ferromagnetic Intercluster Ordering at Low Temperatures
journal, May 2000
- Larionova, Joulia; Gross, Mathias; Pilkington, Melanie
- Angewandte Chemie International Edition, Vol. 39, Issue 9
Single-Molecule Magnets: A Mn 25 Complex with a Record S = 51/2 Spin for a Molecular Species
journal, April 2004
- Murugesu, Muralee; Habrych, Malgorzata; Wernsdorfer, Wolfgang
- Journal of the American Chemical Society, Vol. 126, Issue 15
Large Mn 25 Single-Molecule Magnet with Spin S = 51 / 2 : Magnetic and High-Frequency Electron Paramagnetic Resonance Spectroscopic Characterization of a Giant Spin State
journal, September 2008
- Murugesu, Muralee; Takahashi, Susumu; Wilson, Anthony
- Inorganic Chemistry, Vol. 47, Issue 20
A Mn36Ni4 ‘loop-of-loops-and-supertetrahedra’ aggregate possessing a high ST = 26 ± 1 spin ground state
journal, January 2012
- Charalambous, Maria; Moushi, Eleni E.; Papatriantafyllopoulou, Constantina
- Chemical Communications, Vol. 48, Issue 44
Two edge-sharing MnII4MnIII6 supertetrahedra give an anisotropic S = 28 ± 1 MnII6MnIII11 complex
journal, January 2009
- Nayak, Sanjit; Beltran, Lianne M. C.; Lan, Yanhua
- Dalton Transactions, Issue 11
“Spin Tweaking” of a High-Spin Molecule: An Mn25 Single-Molecule Magnet with anS=61/2 Ground State
journal, January 2007
- Stamatatos, Theocharis C.; Abboud, Khalil A.; Wernsdorfer, Wolfgang
- Angewandte Chemie International Edition, Vol. 46, Issue 6
A new Mn25 single-molecule magnet with an S=61/2 ground state arising from ligand-induced ‘spin-tweaking’ in a high-spin molecule
journal, June 2007
- Stamatatos, Theocharis C.; Abboud, Khalil A.; Wernsdorfer, Wolfgang
- Polyhedron, Vol. 26, Issue 9-11
Nonadecanuclear Mn 7 II Mn 12 III
journal, June 2008
- Ge, Chun-Hua; Ni, Zhong-Hai; Liu, Cai-Ming
- Inorganic Chemistry Communications, Vol. 11, Issue 6
A Mn 17 Octahedron with a Giant Ground-State Spin: Occurrence in Discrete Form and as Multidimensional Coordination Polymers
journal, June 2009
- Moushi, Eleni E.; Stamatatos, Theocharis C.; Wernsdorfer, Wolfgang
- Inorganic Chemistry, Vol. 48, Issue 12
A Ferromagnetically Coupled Mn19 Aggregate with a RecordS=83/2 Ground Spin State
journal, July 2006
- Ako, Ayuk M.; Hewitt, Ian J.; Mereacre, Valeriu
- Angewandte Chemie International Edition, Vol. 45, Issue 30
Magnetic Properties of Largest-Spin Single Molecule Magnets: Mn 17 Complexes—A Density Functional Theory Approach
journal, October 2010
- Cremades, Eduard; Ruiz, Eliseo
- Inorganic Chemistry, Vol. 49, Issue 20
Coordination Cluster Analogues of the High-Spin [Mn 19 ] System with Functionalized 2,6-Bis(hydroxymethyl)phenol Ligands: Coordination Cluster Analogues of the High-Spin [Mn 19 ] System
journal, July 2014
- Mameri, Samir; Ako, Ayuk M.; Yesil, Fatma
- European Journal of Inorganic Chemistry, Vol. 2014, Issue 26
Strong exchange and magnetic blocking in N23−-radical-bridged lanthanide complexes
journal, May 2011
- Rinehart, Jeffrey D.; Fang, Ming; Evans, William J.
- Nature Chemistry, Vol. 3, Issue 7
A N 2 3– Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K
journal, September 2011
- Rinehart, Jeffrey D.; Fang, Ming; Evans, William J.
- Journal of the American Chemical Society, Vol. 133, Issue 36
An Azophenine Radical-Bridged Fe 2 Single-Molecule Magnet with Record Magnetic Exchange Coupling
journal, October 2013
- Jeon, Ie-Rang; Park, Jesse G.; Xiao, Dianne J.
- Journal of the American Chemical Society, Vol. 135, Issue 45
A Dinuclear Cobalt Complex Featuring Unprecedented Anodic and Cathodic Redox Switches for Single-Molecule Magnet Activity
journal, September 2013
- Fortier, Skye; Le Roy, Jennifer J.; Chen, Chun-Hsing
- Journal of the American Chemical Society, Vol. 135, Issue 39
High-Spin Ribbons and Antiferromagnetic Ordering of a Mn II -Biradical-Mn II Complex
journal, August 2013
- Fatila, Elisabeth M.; Clérac, Rodolphe; Rouzières, Mathieu
- Journal of the American Chemical Society, Vol. 135, Issue 36
Radical ligand-containing single-molecule magnets
journal, April 2015
- Demir, Selvan; Jeon, Ie-Rang; Long, Jeffrey R.
- Coordination Chemistry Reviews, Vol. 289-290
Influence of an Inner-Sphere K + Ion on the Magnetic Behavior of N 2 3– Radical-Bridged Dilanthanide Complexes Isolated Using an External Magnetic Field
journal, February 2014
- Meihaus, Katie R.; Corbey, Jordan F.; Fang, Ming
- Inorganic Chemistry, Vol. 53, Issue 6
Exchange coupling and magnetic blocking in dilanthanide complexes bridged by the multi-electron redox-active ligand 2,3,5,6-tetra(2-pyridyl)pyrazine
journal, January 2014
- Demir, Selvan; Nippe, Michael; Gonzalez, Miguel I.
- Chem. Sci., Vol. 5, Issue 12
Interplay of electron exchange and electron transfer in metal polynuclear complexes in proteins or chemical models
journal, December 1990
- Blondin, Genevieve; Girerd, Jean Jacques
- Chemical Reviews, Vol. 90, Issue 8
The novel mixed-valence, exchange-coupled, class III dimer [L 2 Fe 2 (µ-OH) 3 ] 2+ (L =N,N′,N″-trimethyl-1,4,7-triazacyclononane)
journal, January 1989
- Drüeke, S.; Chaudhuri, P.; Pohl, K.
- J. Chem. Soc., Chem. Commun., Issue 1
Mössbauer and electron paramagnetic resonance study of the double‐exchange and Heisenberg‐exchange interactions in a novel binuclear Fe(II/III) delocalized‐valence compound
journal, January 1990
- Ding, Xiao‐Qi; Bominaar, Emile L.; Bill, Eckhard
- The Journal of Chemical Physics, Vol. 92, Issue 1
A new class of dinuclear compounds: The synthesis and x-ray structural characterization of tris(μ-diphenyl-formamidinato) diiron
journal, May 1994
- Albert Cotton, F.; Daniels, Lee M.; Falvello, Larry R.
- Inorganica Chimica Acta, Vol. 219, Issue 1-2
Tri-bridged amidinato compounds of dicobalt 1: Co2[PhNC(R)NPh]3 with R H and C6H5
journal, August 1996
- Cotton, F. Albert; Daniels, Lee M.; Maloney, David J.
- Inorganica Chimica Acta, Vol. 249, Issue 1
Excited-State Contributions to Ground-State Properties of Mixed-Valence Dimers: Spectral and Electronic-Structural Studies of [Fe 2 (OH) 3 (tmtacn) 2 ] 2+ Related to the [Fe 2 S 2 ] + Active Sites of Plant-Type Ferredoxins
journal, January 1996
- Gamelin, Daniel R.; Bominaar, Emile L.; Kirk, Martin L.
- Journal of the American Chemical Society, Vol. 118, Issue 34
Trigonal-lantern dinuclear compounds of diiron(I,II): the synthesis and characterization of two highly paramagnetic Fe2(amidinato)3 species with short metal-metal bonds
journal, March 1997
- Cotton, F. Albert; Daniels, Lee M.; Falvello, Larry R.
- Inorganica Chimica Acta, Vol. 256, Issue 2
A Combined Spectroscopic and Computational Study of a High-Spin S = 7/2 Diiron Complex with a Short Iron–Iron Bond
journal, December 2011
- Zall, Christopher M.; Zherebetskyy, Danylo; Dzubak, Allison L.
- Inorganic Chemistry, Vol. 51, Issue 1
Mixed-Valent Dicobalt and Iron–Cobalt Complexes with High-Spin Configurations and Short Metal–Metal Bonds
journal, August 2013
- Zall, Christopher M.; Clouston, Laura J.; Young, Victor G.
- Inorganic Chemistry, Vol. 52, Issue 16
High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium complexes
journal, March 2010
- Bechlars, Bettina; D'Alessandro, Deanna M.; Jenkins, David M.
- Nature Chemistry, Vol. 2, Issue 5
What is not required to make a single molecule magnet
journal, January 2011
- Neese, Frank; Pantazis, Dimitrios A.
- Faraday Discuss., Vol. 148
Mononuclear and Polynuclear Chemistry of Rhenium (III): Its Pronounced Homophilicity
journal, September 1964
- Cotton, F. A.; Curtis, N. F.; Harris, C. B.
- Science, Vol. 145, Issue 3638
Multiple Bonds Between Metal Atoms
book, January 2005
- Cotton, F. Albert; Murillo, Carlos A.; Walton, Richard A.
Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers
journal, September 2005
- Nguyen, Tailuan; Sutton, Andrew D.; Brynda, Marcin
- Science, Vol. 310, Issue 5749
Giant Magnetic Anisotropy of Single Cobalt Atoms and Nanoparticles
journal, May 2003
- Gambardella, P.
- Science, Vol. 300, Issue 5622
Stabilizing the magnetic moment of single holmium atoms by symmetry
journal, November 2013
- Miyamachi, Toshio; Schuh, Tobias; Märkl, Tobias
- Nature, Vol. 503, Issue 7475
Reaching the magnetic anisotropy limit of a 3d metal atom
journal, May 2014
- Rau, I. G.; Baumann, S.; Rusponi, S.
- Science, Vol. 344, Issue 6187
Highly distorted diiron(II, II) complexes containing four amidinate ligands. A long and short metal-metal distance
journal, March 1997
- Cotton, F. Albert; Daniels, Lee M.; Matonic, John H.
- Inorganica Chimica Acta, Vol. 256, Issue 2
Valence-Delocalized Diiron(II,III) Cores Supported by Carboxylate-Only Bridging Ligands
journal, May 2000
- Lee, Dongwhan; Krebs, Carsten; Huynh, Boi Hanh
- Journal of the American Chemical Society, Vol. 122, Issue 20
Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ 3 -Nitride, [Fe 3 (μ 3 -N)] −
journal, March 2011
- Powers, Tamara M.; Fout, Alison R.; Zheng, Shao-Liang
- Journal of the American Chemical Society, Vol. 133, Issue 10
Modulation of magnetic behavior vialigand-field effects in the trigonal clusters ( Ph L)Fe 3 L * 3 (L * = thf, py, PMe 2 Ph)
journal, January 2012
- Eames, Emily V.; Harris, T. David; Betley, Theodore A.
- Chem. Sci., Vol. 3, Issue 2
[( H L) 2 Fe 6 (NCMe) m ] n + ( m = 0, 2, 4, 6; n = −1, 0, 1, 2, 3, 4, 6): An Electron-Transfer Series Featuring Octahedral Fe 6 Clusters Supported by a Hexaamide Ligand Platform
journal, June 2011
- Zhao, Qinliang; Harris, T. David; Betley, Theodore A.
- Journal of the American Chemical Society, Vol. 133, Issue 21
Diamagnetic Corrections and Pascal's Constants
journal, April 2008
- Bain, Gordon A.; Berry, John F.
- Journal of Chemical Education, Vol. 85, Issue 4
PHI: A powerful new program for the analysis of anisotropic monomeric and exchange-coupled polynuclear d - and f -block complexes
journal, February 2013
- Chilton, Nicholas F.; Anderson, Russell P.; Turner, Lincoln D.
- Journal of Computational Chemistry, Vol. 34, Issue 13
Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics
journal, April 1941
- Cole, Kenneth S.; Cole, Robert H.
- The Journal of Chemical Physics, Vol. 9, Issue 4
Reduced Anionic Mn 12 Molecules with Half-Integer Ground States as Single-Molecule Magnets
journal, November 1999
- Aubin, Sheila M. J.; Sun, Ziming; Pardi, Luca
- Inorganic Chemistry, Vol. 38, Issue 23
Metal-metal interactions in binuclear complexes exhibiting mixed valency; molecular wires and switches
journal, January 1995
- Ward, Michael D.
- Chemical Society Reviews, Vol. 24, Issue 2
Mössbauer Spectroscopy as a Probe of Magnetization Dynamics in the Linear Iron(I) and Iron(II) Complexes [Fe(C(SiMe 3 ) 3 ) 2 ] 1–/0
journal, October 2013
- Zadrozny, Joseph M.; Xiao, Dianne J.; Long, Jeffrey R.
- Inorganic Chemistry, Vol. 52, Issue 22
Magnetic blocking in a linear iron(I) complex
journal, May 2013
- Zadrozny, Joseph M.; Xiao, Dianne J.; Atanasov, Mihail
- Nature Chemistry, Vol. 5, Issue 7
On Spin Hamiltonian fits to Mössbauer spectra of high-spin Fe(II) porphyrinate systems
journal, December 2006
- Schulz, Charles E.; Hu, Chuanjiang; Scheidt, W. Robert
- Hyperfine Interactions, Vol. 170, Issue 1-3
Slow magnetic relaxation and electron delocalization in an S = 9 / 2 iron(II/III) complex with two crystallographically inequivalent iron sites
journal, May 2011
- Hazra, Susanta; Sasmal, Sujit; Fleck, Michel
- The Journal of Chemical Physics, Vol. 134, Issue 17
Valence-Delocalized and Valence-Trapped FeIIFeIII Complexes: Drastic Influence of the Ligands
journal, February 1997
- Dutta, Sujit K.; Ensling, Jürgen; Werner, Rüdiger
- Angewandte Chemie International Edition in English, Vol. 36, Issue 12
Macroscopic quantum tunnelling of magnetization in a single crystal of nanomagnets
journal, September 1996
- Thomas, L.; Lionti, F.; Ballou, R.
- Nature, Vol. 383, Issue 6596
Single-Molecule Magnets: A Large Mn 30 Molecular Nanomagnet Exhibiting Quantum Tunneling of Magnetization
journal, January 2004
- Soler, Monica; Wernsdorfer, Wolfgang; Folting, Kirsten
- Journal of the American Chemical Society, Vol. 126, Issue 7
Ligand Field Strength Mediates Electron Delocalization in Octahedral [( H L) 2 Fe 6 (L′) m ] n + Clusters
journal, August 2015
- Hernández Sánchez, Raúl; Zheng, Shao-Liang; Betley, Theodore A.
- Journal of the American Chemical Society, Vol. 137, Issue 34
On the meaning of spin-pairing energy in transition-metal ions
journal, June 1982
- Vanquickenborne, L. G.; Haspeslagh, L.
- Inorganic Chemistry, Vol. 21, Issue 6
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journal, September 2018
- Hernández Sánchez, Raúl; Champsaur, Anouck M.; Choi, Bonnie
- Angewandte Chemie, Vol. 130, Issue 42
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- Hernández Sánchez, Raúl; Champsaur, Anouck M.; Choi, Bonnie
- Angewandte Chemie International Edition, Vol. 57, Issue 42
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journal, January 2020
- Cook, Andrew W.; Bocarsly, Joshua D.; Lewis, Richard A.
- Chemical Science, Vol. 11, Issue 18
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journal, February 2017
- Gieshoff, Tim N.; Chakraborty, Uttam; Villa, Matteo
- Angewandte Chemie International Edition, Vol. 56, Issue 13
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journal, January 2019
- Chen, Zilu; Yu, Shui; Wang, Rongdong
- Dalton Transactions, Vol. 48, Issue 19
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journal, February 2019
- Shimamoto, Kento; Sunada, Yusuke
- Chemistry – A European Journal, Vol. 25, Issue 15
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journal, January 2020
- Kephart, Jonathan A.; Hecht, Zachary; Livesay, Brooke N.
- Chemical Communications, Vol. 56, Issue 37
Alkene Hydrogenations by Soluble Iron Nanocluster Catalysts
journal, February 2017
- Gieshoff, Tim N.; Chakraborty, Uttam; Villa, Matteo
- Angewandte Chemie, Vol. 129, Issue 13
Alkene Hydrogenations by Soluble Iron Nanocluster Catalysts
journal, February 2017
- Gieshoff, Tim N.; Chakraborty, Uttam; Villa, Matteo
- Angewandte Chemie International Edition, Vol. 56, Issue 13