High-pressure behavior and thermoelastic properties of niobium studied by in situ x-ray diffraction
Abstract
In this study, in situ synchrotron energy dispersive x-ray diffraction (XRD) experiments on Nb have been conducted at pressures up to 6.4 GPa and temperatures up to 1073 K. From the pressure-volume-temperature measurements, thermoelastic parameters were derived for the first time for Nb based on the thermal pressure (ΔPth) equation of state (EOS), modified high-T Birch-Murnaghan EOS, and Mie-Grüneisen-Debye EOS. With the pressure derivative of the bulk modulus K'T fixed at 4.0, we obtained the ambient isothermal bulk modulus KT0 = 174(5) GPa, the temperature derivative of bulk modulus at constant pressure (∂KT/∂T)P=-0.060(8) GPa K-1 and at constant volume (∂KT/∂T)V=-0.046(8) GPa K-1, the volumetric thermal expansivity αT(T)=2.3(3)×10-5+0.3(2)×10-8T (K-1), as well as the pressure dependence of thermal expansion (∂α/∂P)T=(-2.0±0.4)×10-6 K-1 GPa-1. Fitting the present data to the Mie-Grüneisen-Debye EOS with Debye temperature Θ0 = 276.6 K gives γ0 = 1.27(8) and KT0 = 171(3) GPa at a fixed value of q = 3.0. The ambient isothermal bulk modulus and Grüneisen parameter derived from this work are comparable to previously reported values from both experimental and theoretical studies. Finally, an in situ high-resolution, angle dispersive XRD study on Nb did not indicate any anomalous behavior related to pressure-induced electronic topological transitions atmore »
- Authors:
-
- State University of New York, Stony Brook, NY (United States). Mineral Physics Institute
- State University of New York, Stony Brook, NY (United States). Department of Materials Science and Engineering
- State University of New York, Stony Brook, NY (United States). Department of Geosciences
- State University of New York, Stony Brook, NY (United States). Mineral Physics Institute; Jilin Normal University, Siping (China). Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education
- State University of New York, Stony Brook, NY (United States). Department of Materials Science and Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Department
- Publication Date:
- Research Org.:
- Stony Brook Univ., NY (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1466786
- Grant/Contract Number:
- NA0001815
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 116; Journal Issue: 1; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; niobium; thermoelasticity; pressure
Citation Formats
Zou, Yongtao, Qi, Xintong, Wang, Xuebing, Chen, Ting, Li, Xuefei, Welch, David, and Li, Baosheng. High-pressure behavior and thermoelastic properties of niobium studied by in situ x-ray diffraction. United States: N. p., 2014.
Web. doi:10.1063/1.4887436.
Zou, Yongtao, Qi, Xintong, Wang, Xuebing, Chen, Ting, Li, Xuefei, Welch, David, & Li, Baosheng. High-pressure behavior and thermoelastic properties of niobium studied by in situ x-ray diffraction. United States. https://doi.org/10.1063/1.4887436
Zou, Yongtao, Qi, Xintong, Wang, Xuebing, Chen, Ting, Li, Xuefei, Welch, David, and Li, Baosheng. Mon .
"High-pressure behavior and thermoelastic properties of niobium studied by in situ x-ray diffraction". United States. https://doi.org/10.1063/1.4887436. https://www.osti.gov/servlets/purl/1466786.
@article{osti_1466786,
title = {High-pressure behavior and thermoelastic properties of niobium studied by in situ x-ray diffraction},
author = {Zou, Yongtao and Qi, Xintong and Wang, Xuebing and Chen, Ting and Li, Xuefei and Welch, David and Li, Baosheng},
abstractNote = {In this study, in situ synchrotron energy dispersive x-ray diffraction (XRD) experiments on Nb have been conducted at pressures up to 6.4 GPa and temperatures up to 1073 K. From the pressure-volume-temperature measurements, thermoelastic parameters were derived for the first time for Nb based on the thermal pressure (ΔPth) equation of state (EOS), modified high-T Birch-Murnaghan EOS, and Mie-Grüneisen-Debye EOS. With the pressure derivative of the bulk modulus K'T fixed at 4.0, we obtained the ambient isothermal bulk modulus KT0 = 174(5) GPa, the temperature derivative of bulk modulus at constant pressure (∂KT/∂T)P=-0.060(8) GPa K-1 and at constant volume (∂KT/∂T)V=-0.046(8) GPa K-1, the volumetric thermal expansivity αT(T)=2.3(3)×10-5+0.3(2)×10-8T (K-1), as well as the pressure dependence of thermal expansion (∂α/∂P)T=(-2.0±0.4)×10-6 K-1 GPa-1. Fitting the present data to the Mie-Grüneisen-Debye EOS with Debye temperature Θ0 = 276.6 K gives γ0 = 1.27(8) and KT0 = 171(3) GPa at a fixed value of q = 3.0. The ambient isothermal bulk modulus and Grüneisen parameter derived from this work are comparable to previously reported values from both experimental and theoretical studies. Finally, an in situ high-resolution, angle dispersive XRD study on Nb did not indicate any anomalous behavior related to pressure-induced electronic topological transitions at ~5 GPa as has been reported previously.},
doi = {10.1063/1.4887436},
journal = {Journal of Applied Physics},
number = 1,
volume = 116,
place = {United States},
year = {Mon Jul 07 00:00:00 EDT 2014},
month = {Mon Jul 07 00:00:00 EDT 2014}
}
Web of Science
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Works referencing / citing this record:
Pressure-induced anomalies and structural instability in compressed β-Sb 2 O 3
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Thermoelasticity and anomalies in the pressure dependence of phonon velocities in niobium
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Structure and properties of pseudomorphically transformed bcc Mg in Mg/Nb multilayered nanolaminates studied using synchrotron X-ray diffraction
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