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Title: Hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over supported Pt–Co bimetallic catalysts under mild conditions

Abstract

Here, Pt–Co bimetallic catalysts were prepared by atomic layer deposition for the hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran reaction, and the yield was up to 92% under mild reaction conditions.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [1]
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  1. Missouri Univ. of Science and Technology, Rolla, MO (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
OSTI Identifier:
1461202
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Green Chemistry
Additional Journal Information:
Journal Volume: 20; Journal Issue: 12; Journal ID: ISSN 1463-9262
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Wang, Xiaofeng, Liu, Yuzi, and Liang, Xinhua. Hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over supported Pt–Co bimetallic catalysts under mild conditions. United States: N. p., 2018. Web. doi:10.1039/c8gc00716k.
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Wang, Xiaofeng, Liu, Yuzi, & Liang, Xinhua. Hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over supported Pt–Co bimetallic catalysts under mild conditions. United States. https://doi.org/10.1039/c8gc00716k
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Wang, Xiaofeng, Liu, Yuzi, and Liang, Xinhua. Thu . "Hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over supported Pt–Co bimetallic catalysts under mild conditions". United States. https://doi.org/10.1039/c8gc00716k. https://www.osti.gov/servlets/purl/1461202.
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@article{osti_1461202,
title = {Hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over supported Pt–Co bimetallic catalysts under mild conditions},
author = {Wang, Xiaofeng and Liu, Yuzi and Liang, Xinhua},
abstractNote = {Here, Pt–Co bimetallic catalysts were prepared by atomic layer deposition for the hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran reaction, and the yield was up to 92% under mild reaction conditions.},
doi = {10.1039/c8gc00716k},
journal = {Green Chemistry},
number = 12,
volume = 20,
place = {United States},
year = {Thu May 24 00:00:00 EDT 2018},
month = {Thu May 24 00:00:00 EDT 2018}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/c8gc00716k
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Cited by: 52 works
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Figures / Tables:

Scheme 1 Scheme 1: Proposed reaction pathways for the conversion of HMF, and the desired product is encircled. Compounds: 5-(hydroxymethyl)furfural (HMF); 2,5-dimethylfuran (DMF); 2,5-bis(hydroxymethyl)furan (DHMF); 5-mmethyl furfural (5-MF); 5-methyl furfuryl alcohol (MFA); 5-bis(hydroxymethyl)tetrahydrofuran (DHTHF); 5,5-(oxybis(methylene))bis(2- methylfuran) (OMBM); Tetrahydro-5-methyl 2-furammethanol (MTHFA).
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