Semiconductor-to-Metal Transition and Quasiparticle Renormalization in Doped Graphene Nanoribbons
Abstract
A semiconductor-to-metal transition in N = 7 armchair graphene nanoribbons causes drastic changes in its electron and phonon system. In this paper, by using angle-resolved photoemission spectroscopy of lithium-doped graphene nanoribbons, a quasiparticle band gap renormalization from 2.4 to 2.1 eV is observed. Reaching high doping levels (0.05 electrons per atom), it is found that the effective mass of the conduction band carriers increases to a value equal to the free electron mass. This giant increase in the effective mass by doping is a means to enhance the density of states at the Fermi level which can have palpable impact on the transport and optical properties. Electron doping also reduces the Raman intensity by one order of magnitude, and results in relatively small (4 cm-1) hardening of the G phonon and softening of the D phonon. This suggests the importance of both lattice expansion and dynamic effects. Finally, the present work highlights that doping of a semiconducting 1D system is strikingly different from its 2D or 3D counterparts and introduces doped graphene nanoribbons as a new tunable quantum material with high potential for basic research and applications.
- Authors:
-
- Univ. of Cologne (Germany). Inst. of Physics
- Univ. of Cologne (Germany). Inst. of Physics; Saint Petersburg State Univ. (Russian Federation); Leibniz Inst. for Solid State and Materials Research (IFW Dresden), Dresden (Germany)
- Univ. of California, Berkeley, CA (United States)
- Inst. for Research in Fundamental Sciences (IPM), Tehran (Iran). School of Nano Science
- Uppsala Univ. (Sweden). Dept. of Physics and Astronomy; Lund Univ. (Sweden). MAX IV Lab.
- Lund Univ. (Sweden). MAX IV Lab.
- Uppsala Univ. (Sweden). Dept. of Physics and Astronomy
- Forschungszentrum Julich (Germany). Peter Grünberg Inst. Inst. for Advanced Simulation
- Univ. of Cologne (Germany). Inst. for Theoretical Physics
- Univ. of Cologne (Germany). Inst. of Physics; Univ. of Vienna (Austria). Faculty of Physics; Moscow State Univ., Moscow (Russian Federation). Dept. of Materials Science
- Helmholtz Center for Materials and Energy, Berlin (Germany). Electron Storage Ring BESSY II
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); European Research Council (ERC); German Research Foundation (DFG); Russian Science Foundation; Swedish Research Council (SRC)
- OSTI Identifier:
- 1461116
- Grant/Contract Number:
- SC0010409; 0939514; 648589; 321319; CRC1238; GR 3708/2-1; 14-13-00747
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Electronic Materials
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 4; Journal ID: ISSN 2199-160X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; ARPES; charge transfer doping; graphene; graphene nanoribbons; Raman
Citation Formats
Senkovskiy, Boris V., Fedorov, Alexander V., Haberer, Danny, Farjam, Mani, Simonov, Konstantin A., Preobrajenski, Alexei B., Martensson, Niels, Atodiresei, Nicolae, Caciuc, Vasile, Blugel, Stefan, Rosch, Achim, Verbitskiy, Nikolay I., Hell, Martin, Evtushinsky, Daniil V., German, Raphael, Marangoni, Tomas, van Loosdrecht, Paul H. M., Fischer, Felix R., and Gruneis, Alexander. Semiconductor-to-Metal Transition and Quasiparticle Renormalization in Doped Graphene Nanoribbons. United States: N. p., 2017.
Web. doi:10.1002/aelm.201600490.
Senkovskiy, Boris V., Fedorov, Alexander V., Haberer, Danny, Farjam, Mani, Simonov, Konstantin A., Preobrajenski, Alexei B., Martensson, Niels, Atodiresei, Nicolae, Caciuc, Vasile, Blugel, Stefan, Rosch, Achim, Verbitskiy, Nikolay I., Hell, Martin, Evtushinsky, Daniil V., German, Raphael, Marangoni, Tomas, van Loosdrecht, Paul H. M., Fischer, Felix R., & Gruneis, Alexander. Semiconductor-to-Metal Transition and Quasiparticle Renormalization in Doped Graphene Nanoribbons. United States. https://doi.org/10.1002/aelm.201600490
Senkovskiy, Boris V., Fedorov, Alexander V., Haberer, Danny, Farjam, Mani, Simonov, Konstantin A., Preobrajenski, Alexei B., Martensson, Niels, Atodiresei, Nicolae, Caciuc, Vasile, Blugel, Stefan, Rosch, Achim, Verbitskiy, Nikolay I., Hell, Martin, Evtushinsky, Daniil V., German, Raphael, Marangoni, Tomas, van Loosdrecht, Paul H. M., Fischer, Felix R., and Gruneis, Alexander. Fri .
"Semiconductor-to-Metal Transition and Quasiparticle Renormalization in Doped Graphene Nanoribbons". United States. https://doi.org/10.1002/aelm.201600490. https://www.osti.gov/servlets/purl/1461116.
@article{osti_1461116,
title = {Semiconductor-to-Metal Transition and Quasiparticle Renormalization in Doped Graphene Nanoribbons},
author = {Senkovskiy, Boris V. and Fedorov, Alexander V. and Haberer, Danny and Farjam, Mani and Simonov, Konstantin A. and Preobrajenski, Alexei B. and Martensson, Niels and Atodiresei, Nicolae and Caciuc, Vasile and Blugel, Stefan and Rosch, Achim and Verbitskiy, Nikolay I. and Hell, Martin and Evtushinsky, Daniil V. and German, Raphael and Marangoni, Tomas and van Loosdrecht, Paul H. M. and Fischer, Felix R. and Gruneis, Alexander},
abstractNote = {A semiconductor-to-metal transition in N = 7 armchair graphene nanoribbons causes drastic changes in its electron and phonon system. In this paper, by using angle-resolved photoemission spectroscopy of lithium-doped graphene nanoribbons, a quasiparticle band gap renormalization from 2.4 to 2.1 eV is observed. Reaching high doping levels (0.05 electrons per atom), it is found that the effective mass of the conduction band carriers increases to a value equal to the free electron mass. This giant increase in the effective mass by doping is a means to enhance the density of states at the Fermi level which can have palpable impact on the transport and optical properties. Electron doping also reduces the Raman intensity by one order of magnitude, and results in relatively small (4 cm-1) hardening of the G phonon and softening of the D phonon. This suggests the importance of both lattice expansion and dynamic effects. Finally, the present work highlights that doping of a semiconducting 1D system is strikingly different from its 2D or 3D counterparts and introduces doped graphene nanoribbons as a new tunable quantum material with high potential for basic research and applications.},
doi = {10.1002/aelm.201600490},
journal = {Advanced Electronic Materials},
number = 4,
volume = 3,
place = {United States},
year = {Fri Mar 10 00:00:00 EST 2017},
month = {Fri Mar 10 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Voltage-dependent conductance of a single graphene nanoribbon
journal, October 2012
- Koch, Matthias; Ample, Francisco; Joachim, Christian
- Nature Nanotechnology, Vol. 7, Issue 11
Controlled synthesis of single-chirality carbon nanotubes
journal, August 2014
- Sanchez-Valencia, Juan Ramon; Dienel, Thomas; Gröning, Oliver
- Nature, Vol. 512, Issue 7512
Optical properties of graphene nanoribbons: The role of many-body effects
journal, January 2008
- Prezzi, Deborah; Varsano, Daniele; Ruini, Alice
- Physical Review B, Vol. 77, Issue 4
Tunable Band Gaps and Excitons in Doped Semiconducting Carbon Nanotubes Made Possible by Acoustic Plasmons
journal, April 2010
- Spataru, Catalin D.; Léonard, François
- Physical Review Letters, Vol. 104, Issue 17
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
On-Surface Synthesis of Atomically Precise Graphene Nanoribbons
journal, February 2016
- Talirz, Leopold; Ruffieux, Pascal; Fasel, Roman
- Advanced Materials, Vol. 28, Issue 29
van der Waals density functional made accurate
journal, March 2014
- Hamada, Ikutaro
- Physical Review B, Vol. 89, Issue 12
Tuning the Band Gap of Graphene Nanoribbons Synthesized from Molecular Precursors
journal, June 2013
- Chen, Yen-Chia; de Oteyza, Dimas G.; Pedramrazi, Zahra
- ACS Nano, Vol. 7, Issue 7
Electronic Structure and Stability of Semiconducting Graphene Nanoribbons
journal, December 2006
- Barone, Verónica; Hod, Oded; Scuseria, Gustavo E.
- Nano Letters, Vol. 6, Issue 12
Ultra-narrow metallic armchair graphene nanoribbons
journal, December 2015
- Kimouche, Amina; Ervasti, Mikko M.; Drost, Robert
- Nature Communications, Vol. 6, Issue 1
Dynamical Excitonic Effects in Doped Two-Dimensional Semiconductors
journal, August 2016
- Gao, Shiyuan; Liang, Yufeng; Spataru, Catalin D.
- Nano Letters, Vol. 16, Issue 9
Chemically Derived, Ultrasmooth Graphene Nanoribbon Semiconductors
journal, February 2008
- Li, Xiaolin; Wang, Xinran; Zhang, Li
- Science, Vol. 319, Issue 5867, p. 1229-1232
Quasiparticle Energies and Band Gaps in Graphene Nanoribbons
journal, November 2007
- Yang, Li; Park, Cheol-Hwan; Son, Young-Woo
- Physical Review Letters, Vol. 99, Issue 18
Exciton-dominated optical response of ultra-narrow graphene nanoribbons
journal, July 2014
- Denk, Richard; Hohage, Michael; Zeppenfeld, Peter
- Nature Communications, Vol. 5, Issue 1
Giant edge state splitting at atomically precise graphene zigzag edges
journal, May 2016
- Wang, Shiyong; Talirz, Leopold; Pignedoli, Carlo A.
- Nature Communications, Vol. 7, Issue 1
Band-gap renormalization in carbon nanotubes: Origin of the ideal diode behavior in carbon nanotube structures
journal, February 2007
- Lee, Ji Ung
- Physical Review B, Vol. 75, Issue 7
Molecular bandgap engineering of bottom-up synthesized graphene nanoribbon heterojunctions
journal, January 2015
- Chen, Yen-Chia; Cao, Ting; Chen, Chen
- Nature Nanotechnology, Vol. 10, Issue 2
Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor
journal, March 2008
- Das, A.; Pisana, S.; Chakraborty, B.
- Nature Nanotechnology, Vol. 3, Issue 4
Ab initiomolecular dynamics for liquid metals
journal, January 1993
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 47, Issue 1, p. 558-561
Many-Body Renormalization of Semiconductor Quantum Wire Excitons: Absorption, Gain, Binding, and Unbinding
journal, February 2000
- Das Sarma, S.; Wang, D. W.
- Physical Review Letters, Vol. 84, Issue 9
Doping and phonon renormalization in carbon nanotubes
journal, October 2007
- Tsang, J. C.; Freitag, M.; Perebeinos, V.
- Nature Nanotechnology, Vol. 2, Issue 11
Tunable electronic correlation effects in nanotube-light interactions
journal, November 2015
- Miyauchi, Yuhei; Zhang, Zhengyi; Takekoshi, Mitsuhide
- Physical Review B, Vol. 92, Issue 20
Electronic Structure of Spatially Aligned Graphene Nanoribbons on Au(788)
journal, May 2012
- Linden, S.; Zhong, D.; Timmer, A.
- Physical Review Letters, Vol. 108, Issue 21
Electric Field Effect Tuning of Electron-Phonon Coupling in Graphene
journal, April 2007
- Yan, Jun; Zhang, Yuanbo; Kim, Philip
- Physical Review Letters, Vol. 98, Issue 16
Symmetry-dependent phonon renormalization in monolayer MoS transistor
journal, April 2012
- Chakraborty, Biswanath; Bera, Achintya; Muthu, D. V. S.
- Physical Review B, Vol. 85, Issue 16
Room-Temperature All-Semiconducting Sub-10-nm Graphene Nanoribbon Field-Effect Transistors
journal, May 2008
- Wang, Xinran; Ouyang, Yijian; Li, Xiaolin
- Physical Review Letters, Vol. 100, Issue 20
Energy Band-Gap Engineering of Graphene Nanoribbons
journal, May 2007
- Han, Melinda Y.; Özyilmaz, Barbaros; Zhang, Yuanbo
- Physical Review Letters, Vol. 98, Issue 20
Giant bandgap renormalization and excitonic effects in a monolayer transition metal dichalcogenide semiconductor
journal, August 2014
- Ugeda, Miguel M.; Bradley, Aaron J.; Shi, Su-Fei
- Nature Materials, Vol. 13, Issue 12
Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965
- Kohn, W.; Sham, L. J.
- Physical Review, Vol. 140, Issue 4A, p. A1133-A1138
Evidence for Strong Electronic Correlations in the Spectra of Gate-Doped Single-Wall Carbon Nanotubes
journal, September 2015
- Hartleb, Holger; Späth, Florian; Hertel, Tobias
- ACS Nano, Vol. 9, Issue 10
Energy Gaps in Graphene Nanoribbons
journal, November 2006
- Son, Young-Woo; Cohen, Marvin L.; Louie, Steven G.
- Physical Review Letters, Vol. 97, Issue 21
On-surface synthesis of graphene nanoribbons with zigzag edge topology
journal, March 2016
- Ruffieux, Pascal; Wang, Shiyong; Yang, Bo
- Nature, Vol. 531, Issue 7595
Top-Gated Graphene Nanoribbon Transistors with Ultrathin High- k Dielectrics
journal, May 2010
- Liao, Lei; Bai, Jingwei; Cheng, Rui
- Nano Letters, Vol. 10, Issue 5
Higher-accuracy van der Waals density functional
journal, August 2010
- Lee, Kyuho; Murray, Éamonn D.; Kong, Lingzhu
- Physical Review B, Vol. 82, Issue 8
Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires
journal, January 2016
- Vasseur, Guillaume; Fagot-Revurat, Yannick; Sicot, Muriel
- Nature Communications, Vol. 7, Issue 1
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Atomically precise bottom-up fabrication of graphene nanoribbons
journal, July 2010
- Cai, Jinming; Ruffieux, Pascal; Jaafar, Rached
- Nature, Vol. 466, Issue 7305
Electronic states of graphene nanoribbons and analytical solutions
journal, October 2010
- Wakabayashi, Katsunori; Sasaki, Ken-ichi; Nakanishi, Takeshi
- Science and Technology of Advanced Materials, Vol. 11, Issue 5
Atomically controlled substitutional boron-doping of graphene nanoribbons
journal, August 2015
- Kawai, Shigeki; Saito, Shohei; Osumi, Shinichiro
- Nature Communications, Vol. 6, Issue 1
Electronic band dispersion of graphene nanoribbons via Fourier-transformed scanning tunneling spectroscopy
journal, January 2015
- Söde, Hajo; Talirz, Leopold; Gröning, Oliver
- Physical Review B, Vol. 91, Issue 4
Edge state in graphene ribbons: Nanometer size effect and edge shape dependence
journal, December 1996
- Nakada, Kyoko; Fujita, Mitsutaka; Dresselhaus, Gene
- Physical Review B, Vol. 54, Issue 24
Graphene nano-ribbon electronics
journal, December 2007
- Chen, Zhihong; Lin, Yu-Ming; Rooks, Michael J.
- Physica E: Low-dimensional Systems and Nanostructures, Vol. 40, Issue 2, p. 228-232
Breakdown of the adiabatic Born–Oppenheimer approximation in graphene
journal, February 2007
- Pisana, Simone; Lazzeri, Michele; Casiraghi, Cinzia
- Nature Materials, Vol. 6, Issue 3
Gate-Variable Light Absorption and Emission in a Semiconducting Carbon Nanotube
journal, October 2009
- Steiner, Mathias; Freitag, Marcus; Perebeinos, Vasili
- Nano Letters, Vol. 9, Issue 10
Ab Initio Many-Body Effects in Graphene
journal, November 2008
- Trevisanutto, Paolo E.; Giorgetti, Christine; Reining, Lucia
- Physical Review Letters, Vol. 101, Issue 22
Electronic Structure of Atomically Precise Graphene Nanoribbons
journal, July 2012
- Ruffieux, Pascal; Cai, Jinming; Plumb, Nicholas C.
- ACS Nano, Vol. 6, Issue 8
Renormalization of the phonon spectrum in semiconducting single-walled carbon nanotubes studied by Raman spectroscopy
journal, June 2009
- Das, Anindya; Sood, A. K.
- Physical Review B, Vol. 79, Issue 23
Environmental control of electron–phonon coupling in barium doped graphene
journal, September 2016
- Verbitskiy, N. I.; Fedorov, A. V.; Tresca, C.
- 2D Materials, Vol. 3, Issue 4
Kohn anomalies and nonadiabaticity in doped carbon nanotubes
journal, March 2007
- Caudal, Nicolas; Saitta, A. Marco; Lazzeri, Michele
- Physical Review B, Vol. 75, Issue 11
Nano-architectures by covalent assembly of molecular building blocks
journal, October 2007
- Grill, Leonhard; Dyer, Matthew; Lafferentz, Leif
- Nature Nanotechnology, Vol. 2, Issue 11
Observation of a universal donor-dependent vibrational mode in graphene
journal, February 2014
- Fedorov, A. V.; Verbitskiy, N. I.; Haberer, D.
- Nature Communications, Vol. 5, Issue 1
Site-Specific Substitutional Boron Doping of Semiconducting Armchair Graphene Nanoribbons
journal, July 2015
- Cloke, Ryan R.; Marangoni, Tomas; Nguyen, Giang D.
- Journal of the American Chemical Society, Vol. 137, Issue 28
Effect of Substrate Chemistry on the Bottom-Up Fabrication of Graphene Nanoribbons: Combined Core-Level Spectroscopy and STM Study
journal, May 2014
- Simonov, Konstantin A.; Vinogradov, Nikolay A.; Vinogradov, Alexander S.
- The Journal of Physical Chemistry C, Vol. 118, Issue 23
Determination of SWCNT diameters from the Raman response of the radial breathing mode
journal, August 2001
- Kuzmany, H.; Plank, W.; Hulman, M.
- The European Physical Journal B, Vol. 22, Issue 3
WSXM : A software for scanning probe microscopy and a tool for nanotechnology
journal, January 2007
- Horcas, I.; Fernández, R.; Gómez-Rodríguez, J. M.
- Review of Scientific Instruments, Vol. 78, Issue 1
Works referencing / citing this record:
Ion Impact Induced Ultrafast Electron Dynamics in Finite Graphene‐Type Hubbard Clusters
journal, February 2019
- Bonitz, Michael; Balzer, Karsten; Schlünzen, Niclas
- physica status solidi (b), Vol. 256, Issue 7
Femtosecond Electron Dynamics in Graphene Nanoribbons – A Nonequilibrium Green Functions Approach Within an Extended Hubbard Model
journal, January 2019
- Joost, Jan‐Philip; Schlünzen, Niclas; Bonitz, Michael
- physica status solidi (b), Vol. 256, Issue 7
Exciton and phonon dynamics in highly aligned 7-atom wide armchair graphene nanoribbons as seen by time-resolved spontaneous Raman scattering
journal, January 2018
- Zhu, Jingyi; German, Raphael; Senkovskiy, Boris V.
- Nanoscale, Vol. 10, Issue 37
Effect of lithium doping on the optical properties of monolayer MoS 2
journal, March 2018
- Saigal, Nihit; Wielert, Isabelle; Čapeta, Davor
- Applied Physics Letters, Vol. 112, Issue 12
Finding the hidden valence band of N = 7 armchair graphene nanoribbons with angle-resolved photoemission spectroscopy
journal, April 2018
- Senkovskiy, Boris V.; Usachov, Dmitry Yu; Fedorov, Alexander V.
- 2D Materials, Vol. 5, Issue 3
Narrow photoluminescence and Raman peaks of epitaxial MoS 2 on graphene/Ir(1 1 1)
journal, November 2018
- Ehlen, Niels; Hall, Joshua; Senkovskiy, Boris V.
- 2D Materials, Vol. 6, Issue 1
Reversible crystalline-to-amorphous phase transformation in monolayer MoS 2 under grazing ion irradiation
journal, January 2020
- Valerius, Philipp; Kretschmer, Silvan; Senkovskiy, Boris V.
- 2D Materials, Vol. 7, Issue 2
Superconducting nanoribbon with a constriction: A quantum-confined Josephson junction
journal, April 2018
- Flammia, L.; Zhang, L. -F.; Covaci, L.
- Physical Review B, Vol. 97, Issue 13
Superconducting nanoribbon with a constriction: A quantum-confined Josephson junction
text, January 2018
- Flammia, L.; Zhang, L. -F.; Covaci, L.
- arXiv
Controlling a Chemical Coupling Reaction on a Surface: Tools and Strategies for On-Surface Synthesis
journal, March 2019
- Clair, Sylvain; de Oteyza, Dimas G.
- Chemical Reviews, Vol. 119, Issue 7
Field-Effect Transistors Based on Networks of Highly Aligned, Chemically Synthesized N = 7 Armchair Graphene Nanoribbons
journal, March 2018
- Passi, Vikram; Gahoi, Amit; Senkovskiy, Boris V.
- ACS Applied Materials & Interfaces, Vol. 10, Issue 12
Ion Impact Induced Ultrafast Electron Dynamics in Correlated Materials and Finite Graphene Clusters
text, January 2018
- Bonitz, M.; Balzer, K.; Schlünzen, N.
- arXiv