Synthesis of highly-active Fe–N–C catalysts for PEMFC with carbide-derived carbons
Abstract
We study the physico-chemical properties and electrocatalytic activity towards oxygen reduction of two Fe–N–C catalysts based on carbide derived carbon.
- Authors:
-
- Institute of Chemistry, University of Tartu, 50411 Tartu, Estonia
- Institut Charles Gerhardt Montpellier, Laboratory for Aggregates, Interfaces and Materials for Energy, UMR 5253, CNRS, Université de Montpellier, ENSCM
- Institute of Physics, University of Tartu, 50411 Tartu, Estonia
- Institute of Ecology and Earth Sciences, University of Tartu, 51014 Tartu, Estonia
- Department of Chemistry and Chemical Biology, Northeastern University, Boston, USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1460014
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry A
- Additional Journal Information:
- Journal Name: Journal of Materials Chemistry A Journal Volume: 6 Journal Issue: 30; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Ratso, Sander, Ranjbar Sahraie, Nastaran, Sougrati, Moulay Tahar, Käärik, Maike, Kook, Mati, Saar, Rando, Paiste, Päärn, Jia, Qingying, Leis, Jaan, Mukerjee, Sanjeev, Jaouen, Frédéric, and Tammeveski, Kaido. Synthesis of highly-active Fe–N–C catalysts for PEMFC with carbide-derived carbons. United Kingdom: N. p., 2018.
Web. doi:10.1039/C8TA02325E.
Ratso, Sander, Ranjbar Sahraie, Nastaran, Sougrati, Moulay Tahar, Käärik, Maike, Kook, Mati, Saar, Rando, Paiste, Päärn, Jia, Qingying, Leis, Jaan, Mukerjee, Sanjeev, Jaouen, Frédéric, & Tammeveski, Kaido. Synthesis of highly-active Fe–N–C catalysts for PEMFC with carbide-derived carbons. United Kingdom. https://doi.org/10.1039/C8TA02325E
Ratso, Sander, Ranjbar Sahraie, Nastaran, Sougrati, Moulay Tahar, Käärik, Maike, Kook, Mati, Saar, Rando, Paiste, Päärn, Jia, Qingying, Leis, Jaan, Mukerjee, Sanjeev, Jaouen, Frédéric, and Tammeveski, Kaido. Mon .
"Synthesis of highly-active Fe–N–C catalysts for PEMFC with carbide-derived carbons". United Kingdom. https://doi.org/10.1039/C8TA02325E.
@article{osti_1460014,
title = {Synthesis of highly-active Fe–N–C catalysts for PEMFC with carbide-derived carbons},
author = {Ratso, Sander and Ranjbar Sahraie, Nastaran and Sougrati, Moulay Tahar and Käärik, Maike and Kook, Mati and Saar, Rando and Paiste, Päärn and Jia, Qingying and Leis, Jaan and Mukerjee, Sanjeev and Jaouen, Frédéric and Tammeveski, Kaido},
abstractNote = {We study the physico-chemical properties and electrocatalytic activity towards oxygen reduction of two Fe–N–C catalysts based on carbide derived carbon.},
doi = {10.1039/C8TA02325E},
journal = {Journal of Materials Chemistry A},
number = 30,
volume = 6,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C8TA02325E
https://doi.org/10.1039/C8TA02325E
Other availability
Cited by: 81 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Ordered mesoporous porphyrinic carbons with very high electrocatalytic activity for the oxygen reduction reaction
journal, September 2013
- Cheon, Jae Yeong; Kim, Taeyoung; Choi, YongMan
- Scientific Reports, Vol. 3, Issue 1
Electrochemical characteristics of nanoporous carbide-derived carbon materials in non-aqueous electrolyte solutions
journal, March 2004
- Jänes, A.; Permann, L.; Arulepp, M.
- Electrochemistry Communications, Vol. 6, Issue 3, p. 313-318
The influence of pore size distribution on the oxygen reduction reaction performance in nitrogen doped carbon microspheres
journal, January 2016
- Ferrero, G. A.; Preuss, K.; Fuertes, A. B.
- Journal of Materials Chemistry A, Vol. 4, Issue 7
In Situ Polymer Graphenization Ingrained with Nanoporosity in a Nitrogenous Electrocatalyst Boosting the Performance of Polymer-Electrolyte-Membrane Fuel Cells
journal, December 2016
- Fu, Xiaogang; Zamani, Pouyan; Choi, Ja-Yeon
- Advanced Materials, Vol. 29, Issue 7
Atomically Dispersed Iron–Nitrogen Active Sites within Porphyrinic Triazine-Based Frameworks for Oxygen Reduction Reaction in Both Alkaline and Acidic Media
journal, March 2018
- Yi, Jun-Dong; Xu, Rui; Wu, Qiao
- ACS Energy Letters, Vol. 3, Issue 4
Spectroscopic insights into the nature of active sites in iron–nitrogen–carbon electrocatalysts for oxygen reduction in acid
journal, November 2016
- Jia, Qingying; Ramaswamy, Nagappan; Tylus, Urszula
- Nano Energy, Vol. 29
Review—Electromobility: Batteries or Fuel Cells?
journal, January 2015
- Gröger, Oliver; Gasteiger, Hubert A.; Suchsland, Jens-Peter
- Journal of The Electrochemical Society, Vol. 162, Issue 14
A metal–organic framework-derived bifunctional oxygen electrocatalyst
journal, January 2016
- Xia, Bao Yu; Yan, Ya; Li, Nan
- Nature Energy, Vol. 1, Issue 1
Nano-structured non-platinum catalysts for automotive fuel cell application
journal, September 2015
- Serov, Alexey; Artyushkova, Kateryna; Niangar, Ellazar
- Nano Energy, Vol. 16
Multitechnique Characterization of a Polyaniline–Iron–Carbon Oxygen Reduction Catalyst
journal, July 2012
- Ferrandon, Magali; Kropf, A. Jeremy; Myers, Deborah J.
- The Journal of Physical Chemistry C, Vol. 116, Issue 30
Activity, Performance, and Durability for the Reduction of Oxygen in PEM Fuel Cells, of Fe/N/C Electrocatalysts Obtained from the Pyrolysis of Metal-Organic-Framework and Iron Porphyrin Precursors
journal, March 2015
- Yang, Lijun; Larouche, Nicholas; Chenitz, Régis
- Electrochimica Acta, Vol. 159
Carbon Materials for Chemical Capacitive Energy Storage
journal, September 2011
- Zhai, Yunpu; Dou, Yuqian; Zhao, Dongyuan
- Advanced Materials, Vol. 23, Issue 42
Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts
journal, December 2016
- Armel, Vanessa; Hindocha, Sheena; Salles, Fabrice
- Journal of the American Chemical Society, Vol. 139, Issue 1
Nanoscale fine-tuning of porosity of carbide-derived carbon prepared from molybdenum carbide
journal, January 2009
- Jänes, Alar; Thomberg, Thomas; Kurig, Heisi
- Carbon, Vol. 47, Issue 1
Highly efficient nonprecious metal catalyst prepared with metal–organic framework in a continuous carbon nanofibrous network
journal, August 2015
- Shui, Jianglan; Chen, Chen; Grabstanowicz, Lauren
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 34
Mesoporous Metal–Nitrogen-Doped Carbon Electrocatalysts for Highly Efficient Oxygen Reduction Reaction
journal, October 2013
- Liang, Hai-Wei; Wei, Wei; Wu, Zhong-Shuai
- Journal of the American Chemical Society, Vol. 135, Issue 43
Correlations between Mass Activity and Physicochemical Properties of Fe/N/C Catalysts for the ORR in PEM Fuel Cell via 57 Fe Mössbauer Spectroscopy and Other Techniques
journal, January 2014
- Kramm, Ulrike I.; Lefèvre, Michel; Larouche, Nicholas
- Journal of the American Chemical Society, Vol. 136, Issue 3
Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination
journal, June 2015
- Strickland, Kara; Miner, Elise; Jia, Qingying
- Nature Communications, Vol. 6, Issue 1
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
journal, April 2011
- Wu, G.; More, K. L.; Johnston, C. M.
- Science, Vol. 332, Issue 6028, p. 443-447
A review of the stability and durability of non-precious metal catalysts for the oxygen reduction reaction in proton exchange membrane fuel cells
journal, July 2015
- Banham, Dustin; Ye, Siyu; Pei, Katie
- Journal of Power Sources, Vol. 285
Heat-Treated Fe/N/C Catalysts for O2 Electroreduction: Are Active Sites Hosted in Micropores?
journal, March 2006
- Jaouen, Frédéric; Lefèvre, Michel; Dodelet, Jean-Pol
- The Journal of Physical Chemistry B, Vol. 110, Issue 11, p. 5553-5558
Electrocatalyst approaches and challenges for automotive fuel cells
journal, June 2012
- Debe, Mark K.
- Nature, Vol. 486, Issue 7401
Chemical applications of the mössbauer effect. Part 1.—The bonding in iron borides
journal, January 1964
- Cooper, J. D.; Gibb, T. C.; Greenwood, N. N.
- Trans. Faraday Soc., Vol. 60, Issue 0
Chemistry of Multitudinous Active Sites for Oxygen Reduction Reaction in Transition Metal–Nitrogen–Carbon Electrocatalysts
journal, November 2015
- Artyushkova, Kateryna; Serov, Alexey; Rojas-Carbonell, Santiago
- The Journal of Physical Chemistry C, Vol. 119, Issue 46
Kinetics of Oxygen Reduction on Pt(hkl) Electrodes: Implications for the Crystallite Size Effect with Supported Pt Electrocatalysts
journal, January 1997
- Markovic, Nenad
- Journal of The Electrochemical Society, Vol. 144, Issue 5
Fuel cell and battery electric vehicles compared
journal, August 2009
- Thomas, C. E.
- International Journal of Hydrogen Energy, Vol. 34, Issue 15
Catalytic effects of metals of the iron subgroup on the chlorination of titanium carbide to form nanostructural carbon
journal, August 2002
- Leis, Jaan; Perkson, Anti; Arulepp, Mati
- Carbon, Vol. 40, Issue 9
Is iron involved in the lack of stability of Fe/N/C electrocatalysts used to reduce oxygen at the cathode of PEM fuel cells?
journal, November 2016
- Zhang, Gaixia; Chenitz, Régis; Lefèvre, Michel
- Nano Energy, Vol. 29
Metal-Free Catalysts for Oxygen Reduction Reaction
journal, May 2015
- Dai, Liming; Xue, Yuhua; Qu, Liangti
- Chemical Reviews, Vol. 115, Issue 11
Cobalt-nitrogen-doped ordered macro-/mesoporous carbon for highly efficient oxygen reduction reaction
journal, September 2016
- Sun, Tingting; Xu, Lianbin; Li, Shengyu
- Applied Catalysis B: Environmental, Vol. 193
Cross-Laboratory Experimental Study of Non-Noble-Metal Electrocatalysts for the Oxygen Reduction Reaction
journal, July 2009
- Jaouen, Frédéric; Herranz, Juan; Lefèvre, Michel
- ACS Applied Materials & Interfaces, Vol. 1, Issue 8, p. 1623-1639
Interpretation of Mössbauer Spectra of β-FeB and Its Low Temperature Modification, α-FeB
journal, February 1982
- Kanaizuka, T.
- physica status solidi (a), Vol. 69, Issue 2
Mechanical alloying and milling
journal, January 2001
- Suryanarayana, C.
- Progress in Materials Science, Vol. 46, Issue 1-2, p. 1-184
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
journal, February 2016
- Shao, Minhua; Chang, Qiaowan; Dodelet, Jean-Pol
- Chemical Reviews, Vol. 116, Issue 6
Electrocatalysis of oxygen reduction on heteroatom-doped nanocarbons and transition metal–nitrogen–carbon catalysts for alkaline membrane fuel cells
journal, January 2018
- Sarapuu, Ave; Kibena-Põldsepp, Elo; Borghei, Maryam
- Journal of Materials Chemistry A, Vol. 6, Issue 3
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials
journal, August 2015
- Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa
- Nature Materials, Vol. 14, Issue 9
Fast production of monolithic carbide-derived carbons with secondary porosity produced by chlorination of carbides containing a free metal phase
journal, November 2011
- Schmirler, Martina; Knorr, Tilman; Fey, Tobias
- Carbon, Vol. 49, Issue 13
Oxygen Electrochemistry as a Cornerstone for Sustainable Energy Conversion
journal, December 2013
- Katsounaros, Ioannis; Cherevko, Serhiy; Zeradjanin, Aleksandar R.
- Angewandte Chemie International Edition, Vol. 53, Issue 1
Increasing the activity of Fe/N/C catalysts in PEM fuel cell cathodes using carbon blacks with a high-disordered carbon content
journal, October 2008
- Charreteur, Fanny; Ruggeri, Stéphane; Jaouen, Frédéric
- Electrochimica Acta, Vol. 53, Issue 23
Revealing the Role of the Metal in Non-Precious-Metal Catalysts for Oxygen Reduction via Selective Removal of Fe
journal, March 2018
- Varnell, Jason A.; Sotiropoulos, James S.; Brown, Therese M.
- ACS Energy Letters, Vol. 3, Issue 4
Binding energy shifts for nitrogen-containing graphene-based electrocatalysts - experiments and DFT calculations: Analyzing structure-property relationships of functionalized materials
journal, January 2016
- Kabir, S.; Artyushkova, K.; Serov, A.
- Surface and Interface Analysis, Vol. 48, Issue 5
Novel highly active and selective Fe-N-C oxygen reduction electrocatalysts derived from in-situ polymerization pyrolysis
journal, August 2017
- Chen, Yechuan; Gokhale, Rohan; Serov, Alexey
- Nano Energy, Vol. 38
Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation
journal, September 2017
- Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu
- Journal of the American Chemical Society, Vol. 139, Issue 40
Design of N-Coordinated Dual-Metal Sites: A Stable and Active Pt-Free Catalyst for Acidic Oxygen Reduction Reaction
journal, November 2017
- Wang, Jing; Huang, Zhengqing; Liu, Wei
- Journal of the American Chemical Society, Vol. 139, Issue 48
Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction
journal, January 2016
- Li, Jingkun; Ghoshal, Shraboni; Liang, Wentao
- Energy & Environmental Science, Vol. 9, Issue 7
Unraveling the Nature of Sites Active toward Hydrogen Peroxide Reduction in Fe-N-C Catalysts
journal, June 2017
- Choi, Chang Hyuck; Choi, Won Seok; Kasian, Olga
- Angewandte Chemie International Edition, Vol. 56, Issue 30
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure
journal, September 1998
- Ankudinov, A. L.; Ravel, B.; Rehr, J. J.
- Physical Review B, Vol. 58, Issue 12
Engineering Favorable Morphology and Structure of Fe-N-C Oxygen-Reduction Catalysts through Tuning of Nitrogen/Carbon Precursors
journal, January 2017
- Gupta, Shiva; Zhao, Shuai; Ogoke, Ogechi
- ChemSusChem, Vol. 10, Issue 4
Activity Descriptor Identification for Oxygen Reduction on Nonprecious Electrocatalysts: Linking Surface Science to Coordination Chemistry
journal, October 2013
- Ramaswamy, Nagappan; Tylus, Urszula; Jia, Qingying
- Journal of the American Chemical Society, Vol. 135, Issue 41
Highly efficient nitrogen-doped carbide-derived carbon materials for oxygen reduction reaction in alkaline media
journal, March 2017
- Ratso, Sander; Kruusenberg, Ivar; Käärik, Maike
- Carbon, Vol. 113
The Solid-Phase Synthesis of an Fe-N-C Electrocatalyst for High-Power Proton-Exchange Membrane Fuel Cells
journal, January 2018
- Liu, Qingtao; Liu, Xiaofang; Zheng, Lirong
- Angewandte Chemie International Edition, Vol. 57, Issue 5
Synthesis, structure and porosity analysis of microporous and mesoporous carbon derived from zirconium carbide
journal, November 2005
- Dash, R. K.; Yushin, G.; Gogotsi, Y.
- Microporous and Mesoporous Materials, Vol. 86, Issue 1-3
Oxygen Binding to Active Sites of Fe–N–C ORR Electrocatalysts Observed by Ambient-Pressure XPS
journal, January 2017
- Artyushkova, Kateryna; Matanovic, Ivana; Halevi, Barr
- The Journal of Physical Chemistry C, Vol. 121, Issue 5
Nonprecious Metal Catalysts for Oxygen Reduction in Heterogeneous Aqueous Systems
journal, December 2017
- Gewirth, Andrew A.; Varnell, Jason A.; DiAscro, Angela M.
- Chemical Reviews, Vol. 118, Issue 5
Transition metal-nitrogen co-doped carbide-derived carbon catalysts for oxygen reduction reaction in alkaline direct methanol fuel cell
journal, December 2017
- Ratso, Sander; Kruusenberg, Ivar; Käärik, Maike
- Applied Catalysis B: Environmental, Vol. 219
A specific demetalation of Fe–N 4 catalytic sites in the micropores of NC_Ar + NH 3 is at the origin of the initial activity loss of the highly active Fe/N/C catalyst used for the reduction of oxygen in PEM fuel cells
journal, January 2018
- Chenitz, Régis; Kramm, Ulrike I.; Lefèvre, Michel
- Energy & Environmental Science, Vol. 11, Issue 2
From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media
journal, June 2018
- Jiao, Long; Wan, Gang; Zhang, Rui
- Angewandte Chemie International Edition, Vol. 57, Issue 28
Recent advances in non-precious metal catalysis for oxygen-reduction reaction in polymer electrolyte fuelcells
journal, January 2011
- Jaouen, Frédéric; Proietti, Eric; Lefèvre, Michel
- Energy Environ. Sci., Vol. 4, Issue 1, p. 114-130
Characterisation of steam-treated nanoporous carbide-derived carbon of TiC origin: structure and enhanced electrochemical performance
journal, October 2017
- Käärik, Maike; Arulepp, Mati; Kook, Mati
- Journal of Porous Materials, Vol. 25, Issue 4
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells
journal, April 2009
- Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric
- Science, Vol. 324, Issue 5923, p. 71-74
Metal-free doped carbon materials as electrocatalysts for the oxygen reduction reaction
journal, January 2014
- Daems, Nick; Sheng, Xia; Vankelecom, Ivo F. J.
- J. Mater. Chem. A, Vol. 2, Issue 12
The effect of boron doping into Co-C-N and Fe-C-N electrocatalysts on the oxygen reduction reaction
journal, January 2008
- Garsuch, Arnd; Yang, Ruizhi; Bonakdarpour, Arman
- Electrochimica Acta, Vol. 53, Issue 5
Development of high performance carbon composite catalyst for oxygen reduction reaction in PEM Proton Exchange Membrane fuel cells
journal, August 2008
- Nallathambi, Vijayadurga; Lee, Jong-Won; Kumaraguru, Swaminatha P.
- Journal of Power Sources, Vol. 183, Issue 1, p. 34-42
The effect of graphitization catalyst on the structure and porosity of SiC derived carbons
journal, October 2008
- Käärik, Maike; Arulepp, Mati; Karelson, Mati
- Carbon, Vol. 46, Issue 12