Efficient direct solar-to-hydrogen conversion by in situ interface transformation of a tandem structure
Abstract
Photosynthesis is nature's route to convert intermittent solar irradiation into storable energy, while its use for an industrial energy supply is impaired by low efficiency. Artificial photosynthesis provides a promising alternative for efficient robust carbon-neutral renewable energy generation. The approach of direct hydrogen generation by photoelectrochemical water splitting utilizes customized tandem absorber structures to mimic the Z-scheme of natural photosynthesis. Here a combined chemical surface transformation of a tandem structure and catalyst deposition at ambient temperature yields photocurrents approaching the theoretical limit of the absorber and results in a solar-to-hydrogen efficiency of 14%. The potentiostatically assisted photoelectrode efficiency is 17%. Present benchmarks for integrated systems are clearly exceeded. Details of the in situ interface transformation, the electronic improvement and chemical passivation are presented. The surface functionalization procedure is widely applicable and can be precisely controlled, allowing further developments of high-efficiency robust hydrogen generators.
- Authors:
-
[1];
- Institute for Solar Fuels, Berlin (Germany). Helmholtz-Zentrum Berlin für Materialien und Energie GmbH; Technische Universität Ilmenau (Germany). Department of Physcis; Humboldt-Universität zu Berlin (Germany). Department of Physics
- California Inst. of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP)
- Fraunhofer Institute for Solar Energy Systems ISE, Freiburg (Germany)
- Technische Universität Ilmenau (Germany). Department of Physcis
- Publication Date:
- Research Org.:
- California Institute of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1457517
- Grant/Contract Number:
- SC0004993
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 30 DIRECT ENERGY CONVERSION
Citation Formats
May, Matthias M., Lewerenz, Hans-Joachim, Lackner, David, Dimroth, Frank, and Hannappel, Thomas. Efficient direct solar-to-hydrogen conversion by in situ interface transformation of a tandem structure. United States: N. p., 2015.
Web. doi:10.1038/ncomms9286.
May, Matthias M., Lewerenz, Hans-Joachim, Lackner, David, Dimroth, Frank, & Hannappel, Thomas. Efficient direct solar-to-hydrogen conversion by in situ interface transformation of a tandem structure. United States. https://doi.org/10.1038/ncomms9286
May, Matthias M., Lewerenz, Hans-Joachim, Lackner, David, Dimroth, Frank, and Hannappel, Thomas. Tue .
"Efficient direct solar-to-hydrogen conversion by in situ interface transformation of a tandem structure". United States. https://doi.org/10.1038/ncomms9286. https://www.osti.gov/servlets/purl/1457517.
@article{osti_1457517,
title = {Efficient direct solar-to-hydrogen conversion by in situ interface transformation of a tandem structure},
author = {May, Matthias M. and Lewerenz, Hans-Joachim and Lackner, David and Dimroth, Frank and Hannappel, Thomas},
abstractNote = {Photosynthesis is nature's route to convert intermittent solar irradiation into storable energy, while its use for an industrial energy supply is impaired by low efficiency. Artificial photosynthesis provides a promising alternative for efficient robust carbon-neutral renewable energy generation. The approach of direct hydrogen generation by photoelectrochemical water splitting utilizes customized tandem absorber structures to mimic the Z-scheme of natural photosynthesis. Here a combined chemical surface transformation of a tandem structure and catalyst deposition at ambient temperature yields photocurrents approaching the theoretical limit of the absorber and results in a solar-to-hydrogen efficiency of 14%. The potentiostatically assisted photoelectrode efficiency is 17%. Present benchmarks for integrated systems are clearly exceeded. Details of the in situ interface transformation, the electronic improvement and chemical passivation are presented. The surface functionalization procedure is widely applicable and can be precisely controlled, allowing further developments of high-efficiency robust hydrogen generators.},
doi = {10.1038/ncomms9286},
journal = {Nature Communications},
number = 1,
volume = 6,
place = {United States},
year = {Tue Sep 15 00:00:00 EDT 2015},
month = {Tue Sep 15 00:00:00 EDT 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 207 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Photoelectrochemistry and heterogeneous photo-catalysis at semiconductors
journal, January 1979
- Bard, Allen J.
- Journal of Photochemistry, Vol. 10, Issue 1
Silicon based tandem cells: novel photocathodes for hydrogen production
journal, January 2014
- Calvet, W.; Murugasen, E.; Klett, J.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 24
Electrochemical Photolysis of Water at a Semiconductor Electrode
journal, July 1972
- Fujishima, Akira; Honda, Kenichi
- Nature, Vol. 238, Issue 5358, p. 37-38
Coulometric Analysis with Gas Volume Measurement.
journal, November 1964
- King, D. M.; Bard, A. J.
- Analytical Chemistry, Vol. 36, Issue 12
Basic Concepts and Interfacial Aspects of High-Efficiency III-V Multijunction Solar Cells
journal, December 2007
- Sağol, B. Erol; Seidel, Ulf; Szabó, Nadine
- CHIMIA International Journal for Chemistry, Vol. 61, Issue 12
Net primary energy balance of a solar-driven photoelectrochemical water-splitting device
journal, January 2013
- Zhai, Pei; Haussener, Sophia; Ager, Joel
- Energy & Environmental Science, Vol. 6, Issue 8
Electrochemical Stability of p-GaInP[sub 2] in Aqueous Electrolytes Toward Photoelectrochemical Water Splitting
journal, January 1998
- Khaselev, Oscar
- Journal of The Electrochemical Society, Vol. 145, Issue 10
Current-voltage characteristics of coupled photodiode-electrocatalyst devices
journal, September 2013
- Shaner, Matthew R.; Fountaine, Katherine T.; Lewerenz, Hans-Joachim
- Applied Physics Letters, Vol. 103, Issue 14
Heterogeneous electrochemical systems for solar energy conversion
journal, January 1980
- Gerischer, Heinz
- Pure and Applied Chemistry, Vol. 52, Issue 12
In-situ monitoring and analysis of GaSb(100) substrate deoxidation
journal, April 2005
- Möller, K.; Töben, L.; Kollonitsch, Z.
- Applied Surface Science, Vol. 242, Issue 3-4
Surface recombination at semiconductor electrodes
journal, May 1984
- Li, J.; Peat, R.; Peter, L. M.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 165, Issue 1-2
Core-Shell Assembled Nanoparticles as Catalysts
journal, September 2001
- Zhong, C. J.; Maye, M. M.
- Advanced Materials, Vol. 13, Issue 19
Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen
journal, March 1995
- Bard, Allen J.; Fox, Marye Anne
- Accounts of Chemical Research, Vol. 28, Issue 3
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
journal, September 2014
- Luo, J.; Im, J. -H.; Mayer, M. T.
- Science, Vol. 345, Issue 6204
Photoelectrochemical Conditioning of MOVPE p-InP Films for Light-Induced Hydrogen Evolution: Chemical, Electronic and Optical Properties
journal, January 2013
- Muñoz, A. G.; Heine, C.; Lublow, M.
- ECS Journal of Solid State Science and Technology, Vol. 2, Issue 4
Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO 4
journal, November 2011
- Zhong, Diane K.; Choi, Sujung; Gamelin, Daniel R.
- Journal of the American Chemical Society, Vol. 133, Issue 45
Optical in Situ Study of InP(100) Surface Chemistry: Dissociative Adsorption of Water and Oxygen
journal, August 2014
- May, Matthias M.; Lewerenz, Hans-Joachim; Hannappel, Thomas
- The Journal of Physical Chemistry C, Vol. 118, Issue 33
Photoelectrocatalysis: principles, nanoemitter applications and routes to bio-inspired systems
journal, January 2010
- Lewerenz, H. J.; Heine, C.; Skorupska, K.
- Energy & Environmental Science, Vol. 3, Issue 6
Structure-sensitive oxidation of the indium phosphide (001) surface
journal, June 2002
- Chen, G.; Visbeck, S. B.; Law, D. C.
- Journal of Applied Physics, Vol. 91, Issue 11
Surface Chemistry of GaP(001) and InP(001) in Contact with Water
journal, December 2013
- Wood, Brandon C.; Schwegler, Eric; Choi, Woon Ih
- The Journal of Physical Chemistry C, Vol. 118, Issue 2
Amorphous TiO2 coatings stabilize Si, GaAs, and GaP photoanodes for efficient water oxidation
journal, May 2014
- Hu, S.; Shaner, M. R.; Beardslee, J. A.
- Science, Vol. 344, Issue 6187
2-Photon tandem device for water splitting: comparing photocathode first versus photoanode first designs
journal, January 2014
- Seger, Brian; Castelli, Ivano E.; Vesborg, Peter C. K.
- Energy Environ. Sci., Vol. 7, Issue 8
Solar Hydrogen Generation with Wide-Band-Gap Semiconductors: GaP(100) Photoelectrodes and Surface Modification
journal, August 2012
- Kaiser, Bernhard; Fertig, Dominic; Ziegler, Jürgen
- ChemPhysChem, Vol. 13, Issue 12
Band parameters for III–V compound semiconductors and their alloys
journal, June 2001
- Vurgaftman, I.; Meyer, J. R.; Ram-Mohan, L. R.
- Journal of Applied Physics, Vol. 89, Issue 11, p. 5815-5875
Technical and economic feasibility of centralized facilities for solar hydrogen production via photocatalysis and photoelectrochemistry
journal, January 2013
- Pinaud, Blaise A.; Benck, Jesse D.; Seitz, Linsey C.
- Energy & Environmental Science, Vol. 6, Issue 7
A Monolithic Photovoltaic-Photoelectrochemical Device for Hydrogen Production via Water Splitting
journal, April 1998
- Khaselev, O.
- Science, Vol. 280, Issue 5362
Passivation of InP using In(PO 3 ) 3 ‐condensed phosphates: From oxide growth properties to metal‐insulator‐semiconductor field‐effect‐transistor devices
journal, March 1992
- Robach, Y.; Besland, M. P.; Joseph, J.
- Journal of Applied Physics, Vol. 71, Issue 6
Metamorphic GayIn1?yP/Ga1?xInxAs tandem solar cells for space and for terrestrial concentrator applications at C > 1000 suns
journal, January 2001
- Dimroth, F.; Beckert, R.; Meusel, M.
- Progress in Photovoltaics: Research and Applications, Vol. 9, Issue 3
Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells
journal, March 1961
- Shockley, William; Queisser, Hans J.
- Journal of Applied Physics, Vol. 32, Issue 3, p. 510-519
An analysis of the optimal band gaps of light absorbers in integrated tandem photoelectrochemical water-splitting systems
journal, January 2013
- Hu, Shu; Xiang, Chengxiang; Haussener, Sophia
- Energy & Environmental Science, Vol. 6, Issue 10
Anthropogenic Chemical Carbon Cycle for a Sustainable Future
journal, August 2011
- Olah, George A.; Prakash, G. K. Surya; Goeppert, Alain
- Journal of the American Chemical Society, Vol. 133, Issue 33
Underpotential deposition of metals and work function differences
journal, July 1974
- Kolb, D. M.; Przasnyski, M.; Gerischer, H.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 54, Issue 1
Over 18% solar energy conversion to generation of hydrogen fuel; theory and experiment for efficient solar water splitting
journal, July 2001
- Licht, S.
- International Journal of Hydrogen Energy, Vol. 26, Issue 7
The interface of GaP(100) and H 2 O studied by photoemission and reflection anisotropy spectroscopy
journal, October 2013
- May, Matthias M.; Supplie, Oliver; Höhn, Christian
- New Journal of Physics, Vol. 15, Issue 10
A model for electrochemical oscillations at the Si∣electrolyte contact
journal, May 2000
- Grzanna, J.; Jungblut, H.; Lewerenz, H. J.
- Journal of Electroanalytical Chemistry, Vol. 486, Issue 2
How Solar Cells Work
conference, January 2010
- Würfel, Peter
- Optical Nanostructures for Photovoltaics, Advanced Photonics & Renewable Energy
ChemInform Abstract: Experimental Demonstrations of Spontaneous, Solar-Driven Photoelectrochemical Water Splitting
journal, March 2016
- Ager, Joel W.; Shaner, Matthew R.; Walczak, Karl A.
- ChemInform, Vol. 47, Issue 12
A model for electrochemical oscillations at the Si∣electrolyte contact
journal, May 2000
- Grzanna, J.; Jungblut, H.; Lewerenz, H. J.
- Journal of Electroanalytical Chemistry, Vol. 486, Issue 2
Surface recombination at semiconductor electrodes
journal, May 1984
- Peter, L. M.; Li, J.; Peat, R.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 165, Issue 1-2
ChemInform Abstract: A Model for Electrochemical Oscillations at the Si Electrolyte Contact. Part 1. Theoretical Development. Part 2. Simulations and Experimental Results.
journal, September 2000
- Grzanna, J.; Jungblut, H.; Lewerenz, H. J.
- ChemInform, Vol. 31, Issue 37
Interface condition of n-Si(111) during photocurrent oscillations in NH4F solutions
journal, February 1995
- Aggour, M.; Giersig, M.; Lewerenz, H. J.
- Journal of Electroanalytical Chemistry, Vol. 383, Issue 1-2
Guide to references on III–V semiconductor chemical etching
journal, January 2001
- Clawson, A. R.
- Materials Science and Engineering: R: Reports, Vol. 31, Issue 1-6
Anthropogenic Chemical Carbon Cycle for a Sustainable Future
journal, August 2011
- Olah, George A.; Prakash, G. K. Surya; Goeppert, Alain
- Journal of the American Chemical Society, Vol. 133, Issue 33
Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO 4
journal, November 2011
- Zhong, Diane K.; Choi, Sujung; Gamelin, Daniel R.
- Journal of the American Chemical Society, Vol. 133, Issue 45
Optical in Situ Study of InP(100) Surface Chemistry: Dissociative Adsorption of Water and Oxygen
journal, August 2014
- May, Matthias M.; Lewerenz, Hans-Joachim; Hannappel, Thomas
- The Journal of Physical Chemistry C, Vol. 118, Issue 33
Silicon based tandem cells: novel photocathodes for hydrogen production
journal, January 2014
- Calvet, W.; Murugasen, E.; Klett, J.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 24
An analysis of the optimal band gaps of light absorbers in integrated tandem photoelectrochemical water-splitting systems
journal, January 2013
- Hu, Shu; Xiang, Chengxiang; Haussener, Sophia
- Energy & Environmental Science, Vol. 6, Issue 10
Experimental demonstrations of spontaneous, solar-driven photoelectrochemical water splitting
journal, January 2015
- Ager, Joel W.; Shaner, Matthew R.; Walczak, Karl A.
- Energy & Environmental Science, Vol. 8, Issue 10
Band parameters for III–V compound semiconductors and their alloys
journal, June 2001
- Vurgaftman, I.; Meyer, J. R.; Ram-Mohan, L. R.
- Journal of Applied Physics, Vol. 89, Issue 11, p. 5815-5875
Current-voltage characteristics of coupled photodiode-electrocatalyst devices
journal, September 2013
- Shaner, Matthew R.; Fountaine, Katherine T.; Lewerenz, Hans-Joachim
- Applied Physics Letters, Vol. 103, Issue 14
Heterogeneous electrochemical systems for solar energy conversion
journal, January 1980
- Gerischer, Heinz
- Pure and Applied Chemistry, Vol. 52, Issue 12
Basic Concepts and Interfacial Aspects of High-Efficiency III-V Multijunction Solar Cells
journal, December 2007
- Sağol, B. Erol; Seidel, Ulf; Szabó, Nadine
- CHIMIA International Journal for Chemistry, Vol. 61, Issue 12
Works referencing / citing this record:
Ni x S y Nanowalls/Nitrogen-Doped Graphene Foam Is an Efficient Trifunctional Catalyst for Unassisted Artificial Photosynthesis
journal, January 2018
- Zou, Haiyuan; He, Bowen; Kuang, Panyong
- Advanced Functional Materials, Vol. 28, Issue 13
Carbon-Based Photocathode Materials for Solar Hydrogen Production
journal, September 2018
- Bellani, Sebastiano; Antognazza, Maria Rosa; Bonaccorso, Francesco
- Advanced Materials, Vol. 31, Issue 9
Water Splitting Progress in Tandem Devices: Moving Photolysis beyond Electrolysis
journal, June 2016
- Zhang, Kan; Ma, Ming; Li, Ping
- Advanced Energy Materials, Vol. 6, Issue 15
A Monolithically Integrated InGaN Nanowire/Si Tandem Photoanode Approaching the Ideal Bandgap Configuration of 1.75/1.13 eV
journal, September 2016
- Fan, Shizhao; Shih, Ishiang; Mi, Zetian
- Advanced Energy Materials, Vol. 7, Issue 2
Scalable Triple Cation Mixed Halide Perovskite-BiVO 4 Tandems for Bias-Free Water Splitting
journal, July 2018
- Andrei, Virgil; Hoye, Robert L. Z.; Crespo-Quesada, Micaela
- Advanced Energy Materials, Vol. 8, Issue 25
Tailored TiO 2 Protection Layer Enabled Efficient and Stable Microdome Structured p‐GaAs Photoelectrochemical Cathodes
journal, January 2020
- Cao, Shiyao; Kang, Zhuo; Yu, Yanhao
- Advanced Energy Materials, Vol. 10, Issue 9
Durability Testing of Photoelectrochemical Hydrogen Production under Day/Night Light Cycled Conditions
journal, September 2018
- Bae, Dowon; Seger, Brian; Hansen, Ole
- ChemElectroChem, Vol. 6, Issue 1
Modeling and Simulations in Photoelectrochemical Water Oxidation: From Single Level to Multiscale Modeling
journal, May 2016
- Zhang, Xueqing; Bieberle-Hütter, Anja
- ChemSusChem, Vol. 9, Issue 11
Charge Transport in Two-Photon Semiconducting Structures for Solar Fuels
journal, September 2016
- Liu, Guohua; Du, Kang; Haussener, Sophia
- ChemSusChem, Vol. 9, Issue 20
Computational Approaches to Photoelectrode Design through Molecular Functionalization for Enhanced Photoelectrochemical Water Splitting
journal, November 2018
- Iyer, Ashwathi; Kearney, Kara; Ertekin, Elif
- ChemSusChem, Vol. 12, Issue 9
Artificial Leaf for Water Splitting Based on a Triple-Junction Thin-Film Silicon Solar Cell and a PEDOT:PSS/Catalyst Blend
journal, January 2016
- Bogdanoff, Peter; Stellmach, Diana; Gabriel, Onno
- Energy Technology, Vol. 4, Issue 1
Electrochemical CO 2 and Proton Reduction by a Co(dithiacyclam) Complex: Electrochemical CO 2 and Proton Reduction by a Co(dithiacyclam) Complex
journal, February 2020
- Iffland, Linda; Siegmund, Daniel; Apfel, Ulf-Peter
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 646, Issue 13
Semiconducting materials for photoelectrochemical energy conversion
journal, January 2016
- Sivula, Kevin; van de Krol, Roel
- Nature Reviews Materials, Vol. 1, Issue 2
Mesoporous materials for energy conversion and storage devices
journal, May 2016
- Li, Wei; Liu, Jun; Zhao, Dongyuan
- Nature Reviews Materials, Vol. 1, Issue 6
Direct solar-to-hydrogen conversion via inverted metamorphic multi-junction semiconductor architectures
journal, March 2017
- Young, James L.; Steiner, Myles A.; Döscher, Henning
- Nature Energy, Vol. 2, Issue 4
Modelling heterogeneous interfaces for solar water splitting
journal, January 2017
- Pham, Tuan Anh; Ping, Yuan; Galli, Giulia
- Nature Materials, Vol. 16, Issue 4
Photoelectrochemical water splitting in separate oxygen and hydrogen cells
journal, March 2017
- Landman, Avigail; Dotan, Hen; Shter, Gennady E.
- Nature Materials, Vol. 16, Issue 6
Gallium nitride nanowire as a linker of molybdenum sulfides and silicon for photoelectrocatalytic water splitting
journal, September 2018
- Zhou, Baowen; Kong, Xianghua; Vanka, Srinivas
- Nature Communications, Vol. 9, Issue 1
Femtosecond time-resolved two-photon photoemission studies of ultrafast carrier relaxation in Cu2O photoelectrodes
journal, May 2019
- Borgwardt, Mario; Omelchenko, Stefan T.; Favaro, Marco
- Nature Communications, Vol. 10, Issue 1
An efficient and stable photoelectrochemical system with 9% solar-to-hydrogen conversion efficiency via InGaP/GaAs double junction
journal, November 2019
- Varadhan, Purushothaman; Fu, Hui-Chun; Kao, Yu-Cheng
- Nature Communications, Vol. 10, Issue 1
Unusual oxidation-induced core-level shifts at the HfO2/InP interface
journal, February 2019
- Mäkelä, Jaakko; Lahti, Antti; Tuominen, Marjukka
- Scientific Reports, Vol. 9, Issue 1
Overall water splitting by Ta3N5 nanorod single crystals grown on the edges of KTaO3 particles
journal, September 2018
- Wang, Zheng; Inoue, Yasunobu; Hisatomi, Takashi
- Nature Catalysis, Vol. 1, Issue 10
Quantum dot activated indium gallium nitride on silicon as photoanode for solar hydrogen generation
journal, January 2019
- Kumar, Praveen; Devi, Pooja; Jain, Rishabh
- Communications Chemistry, Vol. 2, Issue 1
A miniature solar device for overall water splitting consisting of series-connected spherical silicon solar cells
journal, April 2016
- Kageshima, Yosuke; Shinagawa, Tatsuya; Kuwata, Takaaki
- Scientific Reports, Vol. 6, Issue 1
Photoelectrochemical devices for solar water splitting – materials and challenges
journal, January 2017
- Jiang, Chaoran; Moniz, Savio J. A.; Wang, Aiqin
- Chemical Society Reviews, Vol. 46, Issue 15
Strategies for stable water splitting via protected photoelectrodes
journal, January 2017
- Bae, Dowon; Seger, Brian; Vesborg, Peter C. K.
- Chemical Society Reviews, Vol. 46, Issue 7
On the benchmarking of multi-junction photoelectrochemical fuel generating devices
journal, January 2017
- May, Matthias M.; Lackner, David; Ohlmann, Jens
- Sustainable Energy & Fuels, Vol. 1, Issue 3
Water splitting to hydrogen over epitaxially grown InGaN nanowires on a metallic titanium/silicon template: reduced interfacial transfer resistance and improved stability to hydrogen
journal, January 2018
- Ebaid, Mohamed; Min, Jung-Wook; Zhao, Chao
- Journal of Materials Chemistry A, Vol. 6, Issue 16
Interaction of liquid water with the p-GaInP 2 (100) surface covered with submonolayer oxide
journal, January 2018
- Hajduk, Andreas; Lebedev, Mikhail V.; Kaiser, Bernhard
- Physical Chemistry Chemical Physics, Vol. 20, Issue 32
Recent developments in heterogeneous photocatalysts for solar-driven overall water splitting
journal, January 2019
- Wang, Zheng; Li, Can; Domen, Kazunari
- Chemical Society Reviews, Vol. 48, Issue 7
Single-crystal silicon-based electrodes for unbiased solar water splitting: current status and prospects
journal, January 2019
- Luo, Zhibin; Wang, Tuo; Gong, Jinlong
- Chemical Society Reviews, Vol. 48, Issue 7
Development of highly efficient CuIn 0.5 Ga 0.5 Se 2 -based photocathode and application to overall solar driven water splitting
journal, January 2018
- Kobayashi, Hiroyuki; Sato, Naotoshi; Orita, Masahiro
- Energy & Environmental Science, Vol. 11, Issue 10
Advancing semiconductor–electrocatalyst systems: application of surface transformation films and nanosphere lithography
journal, January 2018
- Brinkert, Katharina; Richter, Matthias H.; Akay, Ömer
- Faraday Discussions, Vol. 208
Water oxidation catalysed by quantum-sized BiVO 4
journal, January 2018
- Olmo, Lourdes del; Dommett, Michael; Oevreeide, Ingrid H.
- Journal of Materials Chemistry A, Vol. 6, Issue 48
Construction of an artificial inorganic leaf CdS–BiVO 4 Z-scheme and its enhancement activities for pollutant degradation and hydrogen evolution
journal, January 2019
- Yang, Ruijie; Zhu, Rongshu; Fan, Yingying
- Catalysis Science & Technology, Vol. 9, Issue 10
Efficiency and stability of narrow-gap semiconductor-based photoelectrodes
journal, January 2019
- Zheng, Jianyun; Zhou, Huaijuan; Zou, Yuqin
- Energy & Environmental Science, Vol. 12, Issue 8
A highly [001]-textured Sb 2 Se 3 photocathode for efficient photoelectrochemical water reduction
journal, January 2019
- Zhou, Hongpeng; Feng, Menglei; Song, Kena
- Nanoscale, Vol. 11, Issue 47
Solar hydrogen production: a bottom-up analysis of different photovoltaic–electrolysis pathways
journal, January 2019
- Reuß, M.; Reul, J.; Grube, T.
- Sustainable Energy & Fuels, Vol. 3, Issue 3
Photoelectrochemical water oxidation of GaP 1−x Sb x with a direct band gap of 1.65 eV for full spectrum solar energy harvesting
journal, January 2019
- Alqahtani, Mahdi; Sathasivam, Sanjayan; Chen, Lipin
- Sustainable Energy & Fuels, Vol. 3, Issue 7
Photoelectrochemical water splitting using strain-balanced multiple quantum well photovoltaic cells
journal, January 2019
- Steiner, Myles A.; Barraugh, Collin D.; Aldridge, Chase W.
- Sustainable Energy & Fuels, Vol. 3, Issue 10
Grain size control of crystalline III–V semiconductors at ambient conditions using electrochemically mediated growth
journal, January 2020
- Valenti, Marco; Bleiji, Yorick; Portals, Javier Blanco
- Journal of Materials Chemistry A, Vol. 8, Issue 5
Photoelectrochemical cells for solar hydrogen production: Challenges and opportunities
journal, August 2019
- Chiu, Yi-Hsuan; Lai, Ting-Hsuan; Kuo, Ming-Yu
- APL Materials, Vol. 7, Issue 8
Water adsorption on the P-rich GaP(100) surface: optical spectroscopy from first principles
journal, March 2018
- May, Matthias M.; Sprik, Michiel
- New Journal of Physics, Vol. 20, Issue 3
CdS/TiO 2 photoanodes via solution ion transfer method for highly efficient solar hydrogen generation
journal, March 2018
- Karuturi, Siva Krishna; Yew, Rowena; Narangari, Parvathala Reddy
- Nano Futures, Vol. 2, Issue 1
InN/InGaN quantum dot electrochemical devices: new solutions for energy and health
journal, January 2017
- Nötzel, Richard
- National Science Review, Vol. 4, Issue 2
Enhanced hydrogen evolution reaction on hybrids of cobalt phosphide and molybdenum phosphide
journal, March 2017
- Fang, Si-Ling; Chou, Tsu-Chin; Samireddi, Satyanarayana
- Royal Society Open Science, Vol. 4, Issue 3
Solar Charged Redox Flow Battery: A Tandem Photoelectrochemical Approach
journal, September 2018
- Durant, Brandon K.; She, Yuqi; Wang, Peng
- Journal of The Electrochemical Society, Vol. 166, Issue 5
Integrated Membrane-Electrode-Assembly Photoelectrochemical Cell under Various Feed Conditions for Solar Water Splitting
journal, December 2018
- Kistler, Tobias A.; Larson, David; Walczak, Karl
- Journal of The Electrochemical Society, Vol. 166, Issue 5
Nanostructured LaFeO 3 Photocathodes with Onset Potentials for the Hydrogen Evolution Reaction Over 1.4 V vs. RHE
journal, January 2019
- Sun, Xin; Tiwari, Devendra; Fermin, David J.
- Journal of The Electrochemical Society, Vol. 166, Issue 15
Editors' Choice—A Monolithic Photoelectrochemical Device Evolving Hydrogen in Pure Water
journal, January 2019
- Kistler, Tobias A.; Danilovic, Nemanja; Agbo, Peter
- Journal of The Electrochemical Society, Vol. 166, Issue 13
Perspectives on the photoelectrochemical storage of solar energy
journal, January 2017
- van de Krol, Roel; Parkinson, Bruce A.
- MRS Energy & Sustainability, Vol. 4
Perovskites in the Energy Grid and CO2 Conversion: Current Context and Future Directions
journal, January 2020
- Tabish, Ahmad; Varghese, Anish Mathai; Wahab, Md A.
- Catalysts, Vol. 10, Issue 1
Photocatalytic Water Oxidation on ZnO: A Review
journal, March 2017
- Hamid, Sharifah Bee Abdul; Teh, Swe Jyan; Lai, Chin Wei
- Catalysts, Vol. 7, Issue 12
On the benchmarking of multi-junction photoelectrochemical fuel generating devices
text, January 2017
- May, Matthias; Lackner, David; Ohlmann, Jens
- Apollo - University of Cambridge Repository
Advancing semiconductor–electrocatalyst systems
text, January 2018
- Brinkert, Katharina; Richter, Matthias H.; Akay, Ömer
- Freie Universität Berlin
Monolithic Photoelectrochemical Device for Direct Water Splitting with 19% Efficiency
journal, June 2018
- Cheng, Wen-Hui; Richter, Matthias H.; May, Matthias M.
- ACS Energy Letters, Vol. 3, Issue 8
Selective Deposition of an Ultrathin Pt Layer on a Au-Nanoisland-Modified Si Photocathode for Hydrogen Generation
journal, April 2017
- Das, Chittaranjan; Kot, Malgorzata; Rouissi, Zied
- ACS Omega, Vol. 2, Issue 4
Pentlandite rocks as sustainable and stable efficient electrocatalysts for hydrogen generation
journal, July 2016
- Konkena, Bharathi; junge Puring, Kai; Sinev, Ilya
- Nature Communications, Vol. 7, Issue 1
Efficiency limits for photoelectrochemical water-splitting
journal, December 2016
- Fountaine, Katherine T.; Lewerenz, Hans Joachim; Atwater, Harry A.
- Nature Communications, Vol. 7, Issue 1
Efficient solar hydrogen generation in microgravity environment
journal, July 2018
- Brinkert, Katharina; Richter, Matthias H.; Akay, Ömer
- Nature Communications, Vol. 9, Issue 1
An efficient and stable photoelectrochemical system with 9% solar-to-hydrogen conversion efficiency via InGaP/GaAs double junction
journal, November 2019
- Varadhan, Purushothaman; Fu, Hui-Chun; Kao, Yu-Cheng
- Nature Communications, Vol. 10, Issue 1
A miniature solar device for overall water splitting consisting of series-connected spherical silicon solar cells
journal, April 2016
- Kageshima, Yosuke; Shinagawa, Tatsuya; Kuwata, Takaaki
- Scientific Reports, Vol. 6, Issue 1
Enhanced hydrogen evolution reaction on hybrids of cobalt phosphide and molybdenum phosphide
journal, March 2017
- Fang, Si-Ling; Chou, Tsu-Chin; Samireddi, Satyanarayana
- Royal Society Open Science, Vol. 4, Issue 3
Efficiency gains for thermally coupled solar hydrogen production in extreme cold
text, January 2021
- Kölbach, Moritz; Rehfeld, Kira; May, Matthias M.
- Universität Ulm