Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Systematic Structure–Property Relationship Studies in Palladium-Catalyzed Methane Complete Combustion

Abstract

To limit further rising levels in methane emissions from stationary and mobile sources and to enable promising technologies based on methane, the development of efficient combustion catalysts that completely oxidize CH4 to CO2 and H2O at low temperatures in the presence of high steam concentrations is required. Palladium is widely considered as one of the most promising materials for this reaction, and a better understanding of the factors affecting its activity and stability is crucial to design even more improved catalysts that efficiently utilize this precious metal. Here we report a study of the effect of three important variables (particle size, support, and reaction conditions including water) on the activity of supported Pd catalysts. We use uniform palladium nanocrystals as catalyst precursors to prepare a library of well-defined catalysts to systematically describe structure–property relationships with help from theory and in situ X-ray absorption spectroscopy. With this approach, we confirm that PdO is the most active phase and that small differences in reaction rates as a function of size are likely due to variations in the surface crystal structure. We further demonstrate that the support exerts a limited influence on the PdO activity, with inert (SiO2), acidic (Al2O3), and redox-active (Ce0.8Zr0.2O2)more » supports providing similar rates, while basic (MgO) supports show remarkably lower activity. Finally, we show that the introduction of steam leads to a considerable decrease in rates that is due to coverage effects, rather than structural and/or phase changes. Altogether, the data suggest that to further increase the activity and stability of Pd-based catalysts for methane combustion, increasing the surface area of supported PdO phases while avoiding strong adsorption of water on the catalytic surfaces is required. This study clarifies contrasting reports in the literature about the active phase and stability of Pd-based materials for methane combustion.« less

Authors:
 [1];  [2];  [3];  [1];  [3];  [1];  [2];  [3]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
+ Show Author Affiliations
  1. Stanford Univ., Stanford, CA (United States)
  2. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  3. SLAC National Accelerator Lab., Menlo Park, CA (United States)
Publication Date:
Research Org.:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1457139
Alternate Identifier(s):
OSTI ID: 1485426
Grant/Contract Number:  
DGE-1656518; AC02-76SF00515
Resource Type:
Accepted Manuscript
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Volume: 7; Journal Issue: 11; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; in situ XAS; methane complete combustion; nanocrystals; palladium catalysts; structure−property relationships

Citation Formats

Willis, Joshua J., Gallo, Alessandro, Sokaras, Dimosthenis, Aljama, Hassan, Nowak, Stanislaw H., Goodman, Emmett D., Wu, Liheng, Tassone, Christopher J., Jaramillo, Thomas F., Abild-Pedersen, Frank, and Cargnello, Matteo. Systematic Structure–Property Relationship Studies in Palladium-Catalyzed Methane Complete Combustion. United States: N. p., 2017. Web. doi:10.1021/acscatal.7b02414.
Copy to clipboard
Willis, Joshua J., Gallo, Alessandro, Sokaras, Dimosthenis, Aljama, Hassan, Nowak, Stanislaw H., Goodman, Emmett D., Wu, Liheng, Tassone, Christopher J., Jaramillo, Thomas F., Abild-Pedersen, Frank, & Cargnello, Matteo. Systematic Structure–Property Relationship Studies in Palladium-Catalyzed Methane Complete Combustion. United States. https://doi.org/10.1021/acscatal.7b02414
Copy to clipboard
Willis, Joshua J., Gallo, Alessandro, Sokaras, Dimosthenis, Aljama, Hassan, Nowak, Stanislaw H., Goodman, Emmett D., Wu, Liheng, Tassone, Christopher J., Jaramillo, Thomas F., Abild-Pedersen, Frank, and Cargnello, Matteo. Mon . "Systematic Structure–Property Relationship Studies in Palladium-Catalyzed Methane Complete Combustion". United States. https://doi.org/10.1021/acscatal.7b02414. https://www.osti.gov/servlets/purl/1457139.
Copy to clipboard
@article{osti_1457139,
title = {Systematic Structure–Property Relationship Studies in Palladium-Catalyzed Methane Complete Combustion},
author = {Willis, Joshua J. and Gallo, Alessandro and Sokaras, Dimosthenis and Aljama, Hassan and Nowak, Stanislaw H. and Goodman, Emmett D. and Wu, Liheng and Tassone, Christopher J. and Jaramillo, Thomas F. and Abild-Pedersen, Frank and Cargnello, Matteo},
abstractNote = {To limit further rising levels in methane emissions from stationary and mobile sources and to enable promising technologies based on methane, the development of efficient combustion catalysts that completely oxidize CH4 to CO2 and H2O at low temperatures in the presence of high steam concentrations is required. Palladium is widely considered as one of the most promising materials for this reaction, and a better understanding of the factors affecting its activity and stability is crucial to design even more improved catalysts that efficiently utilize this precious metal. Here we report a study of the effect of three important variables (particle size, support, and reaction conditions including water) on the activity of supported Pd catalysts. We use uniform palladium nanocrystals as catalyst precursors to prepare a library of well-defined catalysts to systematically describe structure–property relationships with help from theory and in situ X-ray absorption spectroscopy. With this approach, we confirm that PdO is the most active phase and that small differences in reaction rates as a function of size are likely due to variations in the surface crystal structure. We further demonstrate that the support exerts a limited influence on the PdO activity, with inert (SiO2), acidic (Al2O3), and redox-active (Ce0.8Zr0.2O2) supports providing similar rates, while basic (MgO) supports show remarkably lower activity. Finally, we show that the introduction of steam leads to a considerable decrease in rates that is due to coverage effects, rather than structural and/or phase changes. Altogether, the data suggest that to further increase the activity and stability of Pd-based catalysts for methane combustion, increasing the surface area of supported PdO phases while avoiding strong adsorption of water on the catalytic surfaces is required. This study clarifies contrasting reports in the literature about the active phase and stability of Pd-based materials for methane combustion.},
doi = {10.1021/acscatal.7b02414},
journal = {ACS Catalysis},
number = 11,
volume = 7,
place = {United States},
year = {Mon Oct 09 00:00:00 EDT 2017},
month = {Mon Oct 09 00:00:00 EDT 2017}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acscatal.7b02414
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 114 works
Citation information provided by
Web of Science

Figures / Tables:

Figure 1 Figure 1: Representative TEM images (A-E), small angle X-ray scattering patterns (F-J), and particle size distributions (K-O) for uniform Pd NCS (from left to right x-small, small, medium, large, and x-large, respectively). For TEM measurements, N ≥ 300 counts.
All figures and tables (6 total)
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

From shale gas to renewable energy based transportation solutions
journal, April 2014

Durable and High-Performance Direct-Methane Fuel Cells with Coke-Tolerant Ceria-Coated Ni Catalysts at Reduced Temperatures
journal, February 2016

Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen
journal, May 2014

Methane Activation by Heterogeneous Catalysis
journal, November 2014

Influence of Methane Emissions and Vehicle Efficiency on the Climate Implications of Heavy-Duty Natural Gas Trucks
journal, May 2015

  • Camuzeaux, Jonathan R.; Alvarez, Ramón A.; Brooks, Susanne A.
  • Environmental Science & Technology, Vol. 49, Issue 11
  • DOI: 10.1021/acs.est.5b00412

Nanofaceted PdO Sites in PdCe Surface Superstructures: Enhanced Activity in Catalytic Combustion of Methane
journal, October 2009

  • Colussi, Sara; Gayen, Arup; Farnesi Camellone, Matteo
  • Angewandte Chemie International Edition, Vol. 48, Issue 45
  • DOI: 10.1002/anie.200903581

Conversion of Methane to Methanol with a Bent Mono(μ-oxo)dinickel Anchored on the Internal Surfaces of Micropores
journal, July 2014

  • Shan, Junjun; Huang, Weixin; Nguyen, Luan
  • Langmuir, Vol. 30, Issue 28
  • DOI: 10.1021/la501184b

An Introduction of CO 2 Conversion by Dry Reforming with Methane and New Route of Low-Temperature Methanol Synthesis
journal, March 2013

  • Shi, Lei; Yang, Guohui; Tao, Kai
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300217j

Understanding complete oxidation of methane on spinel oxides at a molecular level
journal, August 2015

  • Tao, Franklin Feng; Shan, Jun-jun; Nguyen, Luan
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8798

Methane combustion over supported cobalt catalysts
journal, October 2001

Structure and Reactivity of PdOx/ZrO2Catalysts for Methane Oxidation at Low Temperatures
journal, October 1998

  • Fujimoto, Ken-ichiro; Ribeiro, Fabio H.; Avalos-Borja, Miguel
  • Journal of Catalysis, Vol. 179, Issue 2
  • DOI: 10.1006/jcat.1998.2178

Kinetics of the Complete Oxidation of Methane over Supported Palladium Catalysts
journal, April 1994

  • Ribeiro, F. H.; Chow, M.; Dallabetta, R. A.
  • Journal of Catalysis, Vol. 146, Issue 2
  • DOI: 10.1006/jcat.1994.1092

The Turnover Rate for the Catalytic Combustion of Methane over Palladium Is Not Sensitive to the Structure of the Catalyst
journal, August 2004

  • Zhu, Guanghui; Han, Jinyi; Zemlyanov, Dmitri Y.
  • Journal of the American Chemical Society, Vol. 126, Issue 32
  • DOI: 10.1021/ja049406s

Temperature Dependence of the Kinetics for the Complete Oxidation of Methane on Palladium and Palladium Oxide †
journal, February 2005

  • Zhu, Guanghui; Han, Jinyi; Zemlyanov, Dmitri Yu.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 6
  • DOI: 10.1021/jp0488665

Catalyst-controlled selectivity in the C-H borylation of methane and ethane
journal, March 2016

Catalytic borylation of methane
journal, March 2016

Catalytic Oxidation of Methane
journal, October 1961

  • Anderson, R. B.; Stein, K. C.; Feenan, J. J.
  • Industrial & Engineering Chemistry, Vol. 53, Issue 10
  • DOI: 10.1021/ie50622a024

Oxidation of methane over supported precious metal catalysts
journal, October 1983

Consequences of Metal–Oxide Interconversion for C–H Bond Activation during CH 4 Reactions on Pd Catalysts
journal, October 2013

  • Chin, Ya-Huei (Cathy); Buda, Corneliu; Neurock, Matthew
  • Journal of the American Chemical Society, Vol. 135, Issue 41
  • DOI: 10.1021/ja405004m

Catalytic chemistry of supported palladium for combustion of methane
journal, February 1992

Turnover Rate and Reaction Orders for the Complete Oxidation of Methane on a Palladium Foil in Excess Dioxygen
journal, April 2001

  • Monteiro, R. S.; Zemlyanov, D.; Storey, J. M.
  • Journal of Catalysis, Vol. 199, Issue 2
  • DOI: 10.1006/jcat.2001.3176

Kinetics of Heterogeneous Catalytic Reactions
book, January 1984

Catalytic combustion of methane over supported palladium catalysts
journal, November 1990

Structure sensitivity of methane oxidation over platinum and palladium
journal, April 1990

Intrinsic Ligand Effect Governing the Catalytic Activity of Pd Oxide Thin Films
journal, August 2014

  • Martin, Natalia M.; Van den Bossche, Maxime; Hellman, Anders
  • ACS Catalysis, Vol. 4, Issue 10
  • DOI: 10.1021/cs5010163

Molecular adsorption of small alkanes on a PdO(101) thin film: Evidence of σ-complex formation
journal, January 2010

  • Weaver, Jason F.; Hakanoglu, Can; Hawkins, Jeffery M.
  • The Journal of Chemical Physics, Vol. 132, Issue 2
  • DOI: 10.1063/1.3277672

Support effect on methane combustion over palladium catalysts
journal, February 2007

  • Yoshida, Hisao; Nakajima, Tomoyuki; Yazawa, Yoshiteru
  • Applied Catalysis B: Environmental, Vol. 71, Issue 1-2
  • DOI: 10.1016/j.apcatb.2006.08.010

Thermal decomposition and reformation of PdO catalysts; support effects
journal, August 1995

  • Farrauto, Robert J.; Lampert, Jordan K.; Hobson, Melvin C.
  • Applied Catalysis B: Environmental, Vol. 6, Issue 3
  • DOI: 10.1016/0926-3373(95)00015-1

Influence of co-metals on bimetallic palladium catalysts for methane combustion
journal, April 2005

Catalytic combustion of propane and natural gas over Cu and Pd modified ZSM zeolite catalysts
journal, December 1995

  • Neyestanaki, A. Kalantar; Kumar, N.; Lindfors, L. -E.
  • Applied Catalysis B: Environmental, Vol. 7, Issue 1-2
  • DOI: 10.1016/0926-3373(95)00029-1

Support effect of zeolite on the methane combustion activity of palladium
journal, January 2003

The effect of CeO2 on the dynamics of Pd–PdO transformation over Pd/Al2O3 combustion catalysts
journal, August 2007

Low-Temperature Oxidation of Methane over Pd Supported on SnO 2 -Based Oxides
journal, February 1999

  • Widjaja, Hardiyanto; Sekizawa, Koshi; Eguchi, Koichi
  • Bulletin of the Chemical Society of Japan, Vol. 72, Issue 2
  • DOI: 10.1246/bcsj.72.313

Effect of ceria on palladium supported catalysts for high temperature combustion of CH4 under lean conditions
journal, April 1999

Contributions of Lattice Oxygen in Methane Combustion over PdO-Based Catalysts
journal, October 2001

  • Ciuparu, Dragos; Altman, Eric; Pfefferle, Lisa
  • Journal of Catalysis, Vol. 203, Issue 1
  • DOI: 10.1006/jcat.2001.3331

Oxygen Exchange between Palladium and Oxide Supports in Combustion Catalysts
journal, April 2002

  • Ciuparu, Dragos; Bozon-Verduraz, Francois; Pfefferle, Lisa
  • The Journal of Physical Chemistry B, Vol. 106, Issue 13
  • DOI: 10.1021/jp013577r

Combustion of Methane over Palladium-Based Catalysts: Support Interactions
journal, April 2012

  • Schwartz, William R.; Pfefferle, Lisa D.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 15
  • DOI: 10.1021/jp2119668

Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts
journal, July 2013

Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al 2 O 3 and TiO 2
journal, February 2012

  • Shekhar, Mayank; Wang, Jun; Lee, Wen-Sheng
  • Journal of the American Chemical Society, Vol. 134, Issue 10
  • DOI: 10.1021/ja210083d

Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis
journal, October 2010

  • Williams, W. Damion; Shekhar, Mayank; Lee, Wen-Sheng
  • Journal of the American Chemical Society, Vol. 132, Issue 40
  • DOI: 10.1021/ja1064262

Methane Catalytic Combustion over Hierarchical Pd@CeO 2 /Si-Al 2 O 3 : Effect of the Presence of Water
journal, October 2014

Methane combustion over palladium catalysts: The effect of carbon dioxide and water on activity
journal, March 1995

Catalytic behaviour of Cl-free and Cl-containing Pd/Al2O3 catalysts in the total oxidation of methane at low temperature
journal, September 2000

Combustion of Methane over Palladium-Based Catalysts: Catalytic Deactivation and Role of the Support
journal, April 2012

  • Schwartz, William R.; Ciuparu, Dragos; Pfefferle, Lisa D.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 15
  • DOI: 10.1021/jp212236e

Engineering uniform nanocrystals: Mechanism of formation and self-assembly into bimetallic nanocrystal superlattices
journal, October 2015

  • Cargnello, Matteo; Doan-Nguyen, Vicky V. T.; Murray, Christopher B.
  • AIChE Journal, Vol. 62, Issue 2
  • DOI: 10.1002/aic.15063

Synthesis of Monodisperse Palladium Nanoparticles
journal, September 2003

  • Kim, Sang-Wook; Park, Jongnam; Jang, Youngjin
  • Nano Letters, Vol. 3, Issue 9
  • DOI: 10.1021/nl0343405

Gas-Bubble Effects on the Formation of Colloidal Iron Oxide Nanocrystals
journal, August 2011

  • Lynch, Jared; Zhuang, Jiaqi; Wang, Tie
  • Journal of the American Chemical Society, Vol. 133, Issue 32
  • DOI: 10.1021/ja2032597

Novel embedded Pd@CeO 2 catalysts: a way to active and stable catalysts
journal, January 2010

  • Cargnello, Matteo; Montini, Tiziano; Polizzi, Stefano
  • Dalton Trans., Vol. 39, Issue 8
  • DOI: 10.1039/B916035C

Simple method to synthesize high surface area magnesium oxide and its use as a heterogeneous base catalyst
journal, November 2012

Efficient Removal of Organic Ligands from Supported Nanocrystals by Fast Thermal Annealing Enables Catalytic Studies on Well-Defined Active Phases
journal, May 2015

  • Cargnello, Matteo; Chen, Chen; Diroll, Benjamin T.
  • Journal of the American Chemical Society, Vol. 137, Issue 21
  • DOI: 10.1021/jacs.5b03333

Low temperature CO pulse adsorption for the determination of Pt particle size in a Pt/cerium-based oxide catalyst
journal, November 2009

  • Tanabe, Toshitaka; Nagai, Yasutaka; Hirabayashi, Takeshi
  • Applied Catalysis A: General, Vol. 370, Issue 1-2
  • DOI: 10.1016/j.apcata.2009.09.030

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009

  • Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola
  • Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502
  • DOI: 10.1088/0953-8984/21/39/395502

Implementation of ultrasoft pseudopotentials in ab initio molecular dynamics
journal, March 1991

An object-oriented scripting interface to a legacy electronic structure code
journal, January 2002

  • Bahn, S. R.; Jacobsen, K. W.
  • Computing in Science & Engineering, Vol. 4, Issue 3
  • DOI: 10.1109/5992.998641

A climbing image nudged elastic band method for finding saddle points and minimum energy paths
journal, December 2000

  • Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes
  • The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904
  • DOI: 10.1063/1.1329672

CatMAP: A Software Package for Descriptor-Based Microkinetic Mapping of Catalytic Trends
journal, February 2015

A Method for Evaluating and Correlating Thermodynamic Da ta
journal, April 1954

  • Shomate, C. Howard
  • The Journal of Physical Chemistry, Vol. 58, Issue 4
  • DOI: 10.1021/j150514a018

The statistics of surface atoms and surface sites on metal crystals
journal, June 1969

100° Temperature Reduction of Wet Methane Combustion: Highly Active Pd–Ni/Al 2 O 3 Catalyst versus Pd/NiAl 2 O 4
journal, March 2015

Oxidation behaviour and catalytic properties of Pd/Al2O3 catalysts in the total oxidation of methane
journal, March 2006

Dynamics and Thermodynamics of Pd–PdO Phase Transitions: Effects of Pd Cluster Size and Kinetic Implications for Catalytic Methane Combustion
journal, January 2016

  • Chin, Ya-Huei (Cathy); García-Diéguez, Mónica; Iglesia, Enrique
  • The Journal of Physical Chemistry C, Vol. 120, Issue 3
  • DOI: 10.1021/acs.jpcc.5b06677

How Strain Affects the Reactivity of Surface Metal Oxide Catalysts
journal, November 2013

  • Amakawa, Kazuhiko; Sun, Lili; Guo, Chunsheng
  • Angewandte Chemie International Edition, Vol. 52, Issue 51
  • DOI: 10.1002/anie.201306620

Direct and continuous strain control of catalysts with tunable battery electrode materials
journal, November 2016

Balance of Nanostructure and Bimetallic Interactions in Pt Model Fuel Cell Catalysts: In Situ XAS and DFT Study
journal, May 2012

  • Friebel, Daniel; Viswanathan, Venkatasubramanian; Miller, Daniel J.
  • Journal of the American Chemical Society, Vol. 134, Issue 23
  • DOI: 10.1021/ja3003765

The Active Phase of Palladium during Methane Oxidation
journal, February 2012

  • Hellman, A.; Resta, A.; Martin, N. M.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 6
  • DOI: 10.1021/jz300069s

Surface Chemistry of Late Transition Metal Oxides
journal, December 2012

Thermodynamic stability of PdO surfaces
journal, February 2004

Methane Oxidation over PdO(101) Revealed by First-Principles Kinetic Modeling
journal, September 2015

  • Bossche, Maxime Van den; Grönbeck, Henrik
  • Journal of the American Chemical Society, Vol. 137, Issue 37
  • DOI: 10.1021/jacs.5b06069

A comparison of CO oxidation on ceria-supported Pt, Pd, and Rh
journal, January 1996

  • Bunluesin, T.; Putna, E. S.; Gorte, R. J.
  • Catalysis Letters, Vol. 41, Issue 1-2
  • DOI: 10.1007/BF00811703

The support effect on platinum catalyst under oxidizing atmosphere: improvement in the oxidation-resistance of platinum by the electrophilic property of support materials
journal, November 2002

CO2 absorption and regeneration of alkali metal-based solid sorbents
journal, February 2006

Synthesis of highly coke resistant Ni nanoparticles supported MgO/ZnO catalyst for reforming of methane with carbon dioxide
journal, August 2016

Role of Site Stability in Methane Activation on Pd x Ce 1 –x O δ Surfaces
journal, September 2015

  • Senftle, Thomas P.; van Duin, Adri C. T.; Janik, Michael J.
  • ACS Catalysis, Vol. 5, Issue 10
  • DOI: 10.1021/acscatal.5b00741

Methane Activation at the Pd/CeO 2 Interface
journal, December 2016

  • Senftle, Thomas P.; van Duin, Adri C. T.; Janik, Michael J.
  • ACS Catalysis, Vol. 7, Issue 1
  • DOI: 10.1021/acscatal.6b02447

Exceptional Activity for Methane Combustion over Modular Pd@CeO2 Subunits on Functionalized Al2O3
journal, August 2012

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Accessing the C–C transition state energy on transition metals
    journal, January 2019

    • Aljama, Hassan; Abild-Pedersen, Frank
    • Physical Chemistry Chemical Physics, Vol. 21, Issue 45
    • DOI: 10.1039/c9cp04897a

    Palladium oxidation leads to methane combustion activity: Effects of particle size and alloying with platinum
    journal, October 2019

    • Goodman, Emmett D.; Ye, Angela A.; Aitbekova, Aisulu
    • The Journal of Chemical Physics, Vol. 151, Issue 15
    • DOI: 10.1063/1.5126219

    Catalytic Oxidation of Methane: Pd and Beyond: Catalytic Oxidation of Methane: Pd and Beyond
    journal, June 2018

    • Monai, Matteo; Montini, Tiziano; Gorte, Raymond J.
    • European Journal of Inorganic Chemistry, Vol. 2018, Issue 25
    • DOI: 10.1002/ejic.201800326

    Transition state and product diffusion control by polymer–nanocrystal hybrid catalysts
    journal, August 2019

    Catalyst deactivation via decomposition into single atoms and the role of metal loading
    journal, August 2019

    • Goodman, Emmett D.; Johnston-Peck, Aaron C.; Dietze, Elisabeth M.
    • Nature Catalysis, Vol. 2, Issue 9
    • DOI: 10.1038/s41929-019-0328-1

    Pentacoordinated Al 3+ ‐Stabilized Active Pd Structures on Al 2 O 3 ‐Coated Palladium Catalysts for Methane Combustion
    journal, July 2019

    Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO 2 Tolerance in Methane Combustion
    journal, June 2018

    • Peng, Honggen; Rao, Cheng; Zhang, Ning
    • Angewandte Chemie International Edition, Vol. 57, Issue 29
    • DOI: 10.1002/anie.201803393

    Pentacoordinated Al 3+ ‐Stabilized Active Pd Structures on Al 2 O 3 ‐Coated Palladium Catalysts for Methane Combustion
    journal, August 2019

    • Duan, Huimei; You, Rui; Xu, Shutao
    • Angewandte Chemie International Edition, Vol. 58, Issue 35
    • DOI: 10.1002/anie.201904883

    N-Doped Carbon–Silica Composite Confined Pd Nanoparticles for Abatement of Methane Emission From Automobiles
    journal, November 2018

    In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts
    journal, June 2019

    Ultrafast X-ray Absorption Studies of the Structural Dynamics of Molecular and Biological Systems in Solution
    journal, May 2011

    • Milne, Christopher J.; Van der Veen, Renske M.; Pham, Van-Thai
    • CHIMIA International Journal for Chemistry, Vol. 65, Issue 5
    • DOI: 10.2533/chimia.2011.303

    Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO 2 Tolerance in Methane Combustion
    journal, June 2018

      Sort by:
      [ × clear filter / sort ]

      Figures / Tables found in this record:

      Figure 1 (p. 5)figure
      Figure 2 (p. 6)figure
      Figure 3 (p. 7)figure
      Figure 4 (p. 8)figure
      Figure 5 (p. 10)figure
      Figure 6 (p. 10)figure
        [ × clear filter / sort ]
        Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

        Similar Records in DOE PAGES and OSTI.GOV collections: