Vacuum Ultraviolet Photoionization of Complex Chemical Systems

Kostko, Oleg; Bandyopadhyay, Biswajit; Ahmed, Musahid

doi:10.1146/annurev-physchem-040215-112553

Title: Vacuum Ultraviolet Photoionization of Complex Chemical Systems

Journal Article · Tue Feb 23 23:00:00 EST 2016 · Annual Review of Physical Chemistry

DOI: https://doi.org/10.1146/annurev-physchem-040215-112553 · OSTI ID:1456939

Kostko, Oleg ^[1]; Bandyopadhyay, Biswajit ^[1]; Ahmed, Musahid ^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division

Tunable vacuum ultraviolet (VUV) radiation coupled to mass spectrometry is applied to the study of complex chemical systems in this paper. The identification of novel reactive intermediates and radicals is revealed in flame, pulsed photolysis, and pyrolysis reactors, leading to the elucidation of spectroscopy, reaction mechanisms, and kinetics. Mass-resolved threshold photoelectron photoion coincidence measurements provide unprecedented access to vibrationally resolved spectra of free radicals present in high-temperature reactors. Photoionization measurements in water clusters, nucleic acid base dimers, and their complexes with water provide signatures of proton transfer in hydrogen-bonded and π-stacked systems. Experimental and theoretical methods to track ion–molecule reactions and fragmentation pathways in intermolecular and intramolecular hydrogen-bonded systems in sugars and alcohols are described. Photoionization of laser-ablated molecules, clusters, and their reaction products inform thermodynamics and spectroscopy that are relevant to astrochemistry and catalysis. Finally, new directions in coupling VUV radiation to interrogate complex chemical systems are discussed.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1456939

Journal Information:: Annual Review of Physical Chemistry, Journal Name: Annual Review of Physical Chemistry Journal Issue: 1 Vol. 67; ISSN 0066-426X

Publisher:: Annual ReviewsCopyright Statement

Country of Publication:: United States

Language:: English

References (133)

Molecular Beam Photoionization Studies of Molecules and Clusters Ng, C. Y. Advances in Chemical Physics https://doi.org/10.1002/9780470142769.ch4	book	January 1982
Experimental Confirmation of the Low-Temperature Oxidation Scheme of Alkanes Battin-Leclerc, Frédérique; Herbinet, Olivier; Glaude, Pierre-Alexandre Angewandte Chemie International Edition, Vol. 49, Issue 18 https://doi.org/10.1002/anie.200906850	journal	April 2010
Vacuum Ultraviolet Photoionization Studies of PtCH 2 and H-Pt-CH 3 : A Potential Energy Surface for the Pt+CH 4 Reaction Perera, Manori; Metz, Ricardo B.; Kostko, Oleg Angewandte Chemie International Edition, Vol. 52, Issue 3 https://doi.org/10.1002/anie.201207931	journal	November 2012
Hydrogen Abstraction/Acetylene Addition Revealed Parker, Dorian S. N.; Kaiser, Ralf I.; Troy, Tyler P. Angewandte Chemie International Edition, Vol. 53, Issue 30 https://doi.org/10.1002/anie.201404537	journal	June 2014
Unexpected Chemistry from the Reaction of Naphthyl and Acetylene at Combustion-Like Temperatures Parker, Dorian S. N.; Kaiser, Ralf. I.; Bandyopadhyay, Biswajit Angewandte Chemie International Edition, Vol. 54, Issue 18 https://doi.org/10.1002/anie.201411987	journal	March 2015
Desorption Dynamics, Internal Energies, and Imaging of Organic Molecules from Surfaces with Laser Desorption and Vacuum Ultraviolet (VUV) Photoionization Kostko, Oleg; Takahashi, Lynelle K.; Ahmed, Musahid Chemistry - An Asian Journal, Vol. 6, Issue 11 https://doi.org/10.1002/asia.201100419	journal	August 2011
Unimolecular Reaction Mechanism of an Imidazolin-2-ylidene: An iPEPICO Study on the Complex Dissociation of an Arduengo-Type Carbene Hemberger, Patrick; Bodi, Andras; Gerber, Thomas Chemistry - A European Journal, Vol. 19, Issue 22 https://doi.org/10.1002/chem.201204465	journal	March 2013
Intramolecular CN Bond Activation and Ring-Expansion Reactions of N-Heterocyclic Carbenes Hemberger, Patrick; Bodi, Andras; Berthel, Johannes H. J. Chemistry - A European Journal, Vol. 21, Issue 4 https://doi.org/10.1002/chem.201406036	journal	November 2014
Slow Photoelectron Spectroscopy of δ-Valerolactam and Its Dimer Mahjoub, Ahmed; Hochlaf, Majdi; Poisson, Lionel ChemPhysChem, Vol. 12, Issue 10 https://doi.org/10.1002/cphc.201100090	journal	May 2011
Selective Formation of Indene through the Reaction of Benzyl Radicals with Acetylene Parker, Dorian S. N.; Kaiser, Ralf. I.; Kostko, Oleg ChemPhysChem, Vol. 16, Issue 10 https://doi.org/10.1002/cphc.201500313	journal	April 2015
Contribution of synchrotron radiation to photoactivation studies of biomolecular ions in the gas phase: ION ACTIVATION BY SYNCHROTRON RADIATION Giuliani, Alexandre; Milosavljević, Aleksandar R.; Canon, Francis Mass Spectrometry Reviews, Vol. 33, Issue 6 https://doi.org/10.1002/mas.21398	journal	December 2013
Photoionization Spectroscopy of Nucleobases and Analogues in the Gas Phase Using Synchrotron Radiation as Excitation Light Source Schwell, Martin; Hochlaf, Majdi Topics in Current Chemistry https://doi.org/10.1007/128_2014_550	book	January 2014
Photoelectron spectroscopy of size-selected cluster ions using synchrotron radiation Schramm, Thomas; Ganteför, Gerd; Bodi, Andras Applied Physics A, Vol. 115, Issue 3 https://doi.org/10.1007/s00339-014-8434-z	journal	April 2014
The predictive capability of an automatically generated combustion chemistry mechanism: Chemical structures of premixed iso-butanol flames Hansen, Nils; Merchant, Shamel S.; Harper, Michael R. Combustion and Flame, Vol. 160, Issue 11 https://doi.org/10.1016/j.combustflame.2013.05.013	journal	November 2013
Novel techniques in VUV high-resolution spectroscopy Ubachs, W.; Salumbides, E. J.; Eikema, K. S. E. Journal of Electron Spectroscopy and Related Phenomena, Vol. 196 https://doi.org/10.1016/j.elspec.2013.11.016	journal	October 2014
New generation of light sources: Present and future Couprie, M. E. Journal of Electron Spectroscopy and Related Phenomena, Vol. 196 https://doi.org/10.1016/j.elspec.2013.12.007	journal	October 2014
Gas phase chemistry of neutral metal clusters: Distribution, reactivity and catalysis Yin, Shi; Bernstein, Elliot R. International Journal of Mass Spectrometry, Vol. 321-322 https://doi.org/10.1016/j.ijms.2012.06.001	journal	May 2012
Dissociative VUV photoionization of butanediol isomers Daly, Steven; Powis, Ivan; Tia, Maurice International Journal of Mass Spectrometry, Vol. 376 https://doi.org/10.1016/j.ijms.2014.11.013	journal	January 2015
Near-threshold photoionization mass spectra of combustion-generated high-molecular-weight soot precursors Skeen, Scott A.; Michelsen, Hope A.; Wilson, Kevin R. Journal of Aerosol Science, Vol. 58 https://doi.org/10.1016/j.jaerosci.2012.12.008	journal	April 2013
On-line spectral diagnostic system for Dalian Coherent Light Source Li, Chaoyang; Wei, Shen; Du, Xuewei Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 783 https://doi.org/10.1016/j.nima.2015.01.089	journal	May 2015
New experimental evidences about the formation and consumption of ketohydroperoxides Battin-Leclerc, Frédérique; Herbinet, Olivier; Glaude, Pierre-Alexandre Proceedings of the Combustion Institute, Vol. 33, Issue 1 https://doi.org/10.1016/j.proci.2010.05.001	journal	January 2011
Combustion chemistry probed by synchrotron VUV photoionization mass spectrometry Qi, Fei Proceedings of the Combustion Institute, Vol. 34, Issue 1 https://doi.org/10.1016/j.proci.2012.09.002	journal	January 2013
Electron ionization, photoionization and photoelectron/photoion coincidence spectroscopy in mass-spectrometric investigations of a low-pressure ethylene/oxygen flame Felsmann, Daniel; Moshammer, Kai; Krüger, Julia Proceedings of the Combustion Institute, Vol. 35, Issue 1 https://doi.org/10.1016/j.proci.2014.05.151	journal	January 2015
Improved Resolution of Hydrocarbon Structures and Constitutional Isomers in Complex Mixtures Using Gas Chromatography-Vacuum Ultraviolet-Mass Spectrometry Isaacman, Gabriel; Wilson, Kevin R.; Chan, Arthur W. H. Analytical Chemistry, Vol. 84, Issue 5 https://doi.org/10.1021/ac2030464	journal	February 2012
Synchrotron-Based Mass Spectrometry to Investigate the Molecular Properties of Mineral–Organic Associations Liu, Suet Yi; Kleber, Markus; Takahashi, Lynelle K. Analytical Chemistry, Vol. 85, Issue 12 https://doi.org/10.1021/ac400976z	journal	May 2013
Probing Combustion Chemistry in a Miniature Shock Tube with Synchrotron VUV Photo Ionization Mass Spectrometry Lynch, Patrick T.; Troy, Tyler P.; Ahmed, Musahid Analytical Chemistry, Vol. 87, Issue 4 https://doi.org/10.1021/ac5041633	journal	January 2015
Light and Molecular Ions: The Emergence of Vacuum UV Single-Photon Ionization in MS Hanley, Luke; Zimmermann, Ralf Analytical Chemistry, Vol. 81, Issue 11 https://doi.org/10.1021/ac8013675	journal	June 2009
Detection and Identification of the Keto-Hydroperoxide (HOOCH ₂ OCHO) and Other Intermediates during Low-Temperature Oxidation of Dimethyl Ether Moshammer, Kai; Jasper, Ahren W.; Popolan-Vaida, Denisia M. The Journal of Physical Chemistry A, Vol. 119, Issue 28 https://doi.org/10.1021/acs.jpca.5b00101	journal	February 2015
Probing Methanol Cluster Growth by Vacuum Ultraviolet Ionization Bandyopadhyay, Biswajit; Kostko, Oleg; Fang, Yigang The Journal of Physical Chemistry A, Vol. 119, Issue 18 https://doi.org/10.1021/acs.jpca.5b00912	journal	April 2015
Threshold Photoelectron Spectra of Combustion Relevant C ₄ H ₅ and C ₄ H ₇ Isomers Lang, Melanie; Holzmeier, Fabian; Hemberger, Patrick The Journal of Physical Chemistry A, Vol. 119, Issue 17 https://doi.org/10.1021/acs.jpca.5b02153	journal	April 2015
Photoelectron Wave Function in Photoionization: Plane Wave or Coulomb Wave? Gozem, Samer; Gunina, Anastasia O.; Ichino, Takatoshi The Journal of Physical Chemistry Letters, Vol. 6, Issue 22 https://doi.org/10.1021/acs.jpclett.5b01891	journal	October 2015
Ionization-Induced Structural Changes in Uracil Dimers and Their Spectroscopic Signatures Zadorozhnaya, Anna A.; Krylov, Anna I. Journal of Chemical Theory and Computation, Vol. 6, Issue 3 https://doi.org/10.1021/ct900515a	journal	January 2010
Heterogeneous OH Oxidation of Motor Oil Particles Causes Selective Depletion of Branched and Less Cyclic Hydrocarbons Isaacman, Gabriel; Chan, Arthur W. H.; Nah, Theodora Environmental Science & Technology, Vol. 46, Issue 19 https://doi.org/10.1021/es302768a	journal	September 2012
Lubricating Oil Dominates Primary Organic Aerosol Emissions from Motor Vehicles Worton, David R.; Isaacman, Gabriel; Gentner, Drew R. Environmental Science & Technology, Vol. 48, Issue 7 https://doi.org/10.1021/es405375j	journal	March 2014
An Experimental and Theoretical Study of the Gas Phase Reactions between Small Linear Alkanes and the Platinum and Iridium Atoms Carroll, John J.; Weisshaar, James C.; Siegbahn, Per E. M. The Journal of Physical Chemistry, Vol. 99, Issue 39 https://doi.org/10.1021/j100039a028	journal	September 1995
Electronic structure considerations for methane activation by third-row transition-metal ions Irikura, Karl K.; Beauchamp, J. L. The Journal of Physical Chemistry, Vol. 95, Issue 21 https://doi.org/10.1021/j100174a057	journal	October 1991
Photoionization mass spectroscopy with synchrotron radiation of hydrogen-bonded alkylamine clusters produced in supersonic beams Bisling, Peter G. F.; Ruehl, Eckart.; Brutschy, Bernhard. The Journal of Physical Chemistry, Vol. 91, Issue 16 https://doi.org/10.1021/j100300a022	journal	July 1987
Potential Energy Surface for Activation of Methane by Pt ⁺ : A Combined Guided Ion Beam and DFT Study Zhang, Xiao-Guang; Liyanage, Rohana; Armentrout, P. B. Journal of the American Chemical Society, Vol. 123, Issue 23 https://doi.org/10.1021/ja010382o	journal	June 2001
Energy-Resolved Photoionization of Alkylperoxy Radicals and the Stability of Their Cations Meloni, Giovanni; Zou, Peng; Klippenstein, Stephen J. Journal of the American Chemical Society, Vol. 128, Issue 41 https://doi.org/10.1021/ja064556j	journal	October 2006
Ionization Thresholds of Small Carbon Clusters: Tunable VUV Experiments and Theory Belau, Leonid; Wheeler, Steven E.; Ticknor, Brian W. Journal of the American Chemical Society, Vol. 129, Issue 33 https://doi.org/10.1021/ja072526q	journal	July 2007
Dissociative Photoionization of Glycerol and its Dimer Occurs Predominantly via a Ternary Hydrogen-Bridged Ion–Molecule Complex Bell, Franziska; Ruan, Qiao N.; Golan, Amir Journal of the American Chemical Society, Vol. 135, Issue 38 https://doi.org/10.1021/ja405511v	journal	September 2013
Direct Observation of the Gas-Phase Criegee Intermediate (CH ₂ OO) Taatjes, Craig A.; Meloni, Giovanni; Selby, Talitha M. Journal of the American Chemical Society, Vol. 130, Issue 36 https://doi.org/10.1021/ja804165q	journal	September 2008
Activation of O ₂ , CO, and CO ₂ by Pt ⁺ : The Thermochemistry of PtO ⁺ Zhang, Xiao-Guang; Armentrout, P. B. The Journal of Physical Chemistry A, Vol. 107, Issue 42 https://doi.org/10.1021/jp036014j	journal	October 2003
Activation of O ₂ and CO ₂ by PtO ⁺ : The Thermochemistry of PtO ₂ ⁺ Zhang, Xiao-Guang; Armentrout, P. B. The Journal of Physical Chemistry A, Vol. 107, Issue 42 https://doi.org/10.1021/jp036015b	journal	October 2003
Why I Love Science: A Personal Statement Baer, Tomas The Journal of Physical Chemistry A, Vol. 108, Issue 45, p. 9627-9628 https://doi.org/10.1021/jp040577t	journal	November 2004
Identification and Chemistry of C ₄ H ₃ and C ₄ H ₅ Isomers in Fuel-Rich Flames Hansen, Nils; Klippenstein, Stephen J.; Taatjes, Craig A. The Journal of Physical Chemistry A, Vol. 110, Issue 10 https://doi.org/10.1021/jp056769l	journal	March 2006
Vacuum Ultraviolet (VUV) Photoionization of Small Water Clusters Belau, Leonid; Wilson, Kevin R.; Leone, Stephen R. The Journal of Physical Chemistry A, Vol. 111, Issue 40 https://doi.org/10.1021/jp075263v	journal	October 2007
Electronic Structure and Spectroscopy of Nucleic Acid Bases: Ionization Energies, Ionization-Induced Structural Changes, and Photoelectron Spectra Bravaya, Ksenia B.; Kostko, Oleg; Dolgikh, Stanislav The Journal of Physical Chemistry A, Vol. 114, Issue 46 https://doi.org/10.1021/jp1063726	journal	November 2010
Gas phase Photo-Formation and Vacuum UV Photofragmentation Spectroscopy of Tryptophan and Tyrosine Radical-Containing Peptides Brunet, Claire; Antoine, Rodolphe; Allouche, Abdul-Rahman The Journal of Physical Chemistry A, Vol. 115, Issue 32 https://doi.org/10.1021/jp205617x	journal	August 2011
A VUV Photoionization Study of the Combustion-Relevant Reaction of the Phenyl Radical (C ₆ H ₅ ) with Propylene (C ₃ H ₆ ) in a High Temperature Chemical Reactor Zhang, Fangtong; Kaiser, Ralf I.; Golan, Amir The Journal of Physical Chemistry A, Vol. 116, Issue 14 https://doi.org/10.1021/jp300875s	journal	March 2012
State-Selected Unimolecular Decomposition of δ-Valerolactam⁺ and δ-Valerolactam₂⁺ Cations: Theory and Experiment Mahjoub, A.; Hochlaf, M.; Garcia, G. A. The Journal of Physical Chemistry A, Vol. 116, Issue 34 https://doi.org/10.1021/jp3056976	journal	August 2012
Proton Transfer in Nucleobases is Mediated by Water Khistyaev, Kirill; Golan, Amir; Bravaya, Ksenia B. The Journal of Physical Chemistry A, Vol. 117, Issue 31 https://doi.org/10.1021/jp406029p	journal	July 2013
VUV Photodynamics and Chiral Asymmetry in the Photoionization of Gas Phase Alanine Enantiomers Tia, Maurice; Cunha de Miranda, Barbara; Daly, Steven The Journal of Physical Chemistry A, Vol. 118, Issue 15 https://doi.org/10.1021/jp5016142	journal	April 2014
Mechanism of Fast Pyrolysis of Lignin: Studying Model Compounds Custodis, Victoria B. F.; Hemberger, Patrick; Ma, Zhiqiang The Journal of Physical Chemistry B, Vol. 118, Issue 29 https://doi.org/10.1021/jp5036579	journal	July 2014
Isomeric Product Detection in the Heterogeneous Reaction of Hydroxyl Radicals with Aerosol Composed of Branched and Linear Unsaturated Organic Molecules Nah, Theodora; Zhang, Haofei; Worton, David R. The Journal of Physical Chemistry A, Vol. 118, Issue 49 https://doi.org/10.1021/jp508378z	journal	November 2014
Toward the Oxidation of the Phenyl Radical and Prevention of PAH Formation in Combustion Systems Parker, Dorian S. N.; Kaiser, Ralf I.; Troy, Tyler P. The Journal of Physical Chemistry A, Vol. 119, Issue 28 https://doi.org/10.1021/jp509170x	journal	November 2014
Pyrolysis of Cyclopentadienone: Mechanistic Insights from a Direct Measurement of Product Branching Ratios Ormond, Thomas K.; Scheer, Adam M.; Nimlos, Mark R. The Journal of Physical Chemistry A, Vol. 119, Issue 28 https://doi.org/10.1021/jp511390f	journal	February 2015
Higher Ionization Energies from Sequential Vacuum-Ultraviolet Multiphoton Ionization of Size-Selected Silicon Cluster Cations Kasigkeit, Christian; Hirsch, Konstantin; Langenberg, Andreas The Journal of Physical Chemistry C, Vol. 119, Issue 20 https://doi.org/10.1021/jp511928m	journal	February 2015
Evaluation of Different Implementations of the Thomson Liquid Drop Model: Comparison to Monovalent and Divalent Cluster Ion Experimental Data Donald, William A.; Williams, Evan R. The Journal of Physical Chemistry A, Vol. 112, Issue 16 https://doi.org/10.1021/jp711012b	journal	March 2008
Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol−Water Clusters ^† Kostko, Oleg; Belau, Leonid; Wilson, Kevin R. The Journal of Physical Chemistry A, Vol. 112, Issue 39 https://doi.org/10.1021/jp8020479	journal	October 2008
Direct Determination of the Ionization Energies of PtC, PtO, and PtO ₂ with VUV Radiation ^† Citir, Murat; Metz, Ricardo B.; Belau, Leonid The Journal of Physical Chemistry A, Vol. 112, Issue 39 https://doi.org/10.1021/jp8024733	journal	October 2008
Vacuum-Ultraviolet Photoionization Measurement and ab Initio Calculation of the Ionization Energy of Gas-Phase SiO ₂ Kostko, Oleg; Ahmed, Musahid; Metz, Ricardo B. The Journal of Physical Chemistry A, Vol. 113, Issue 7 https://doi.org/10.1021/jp8091495	journal	February 2009
Mass-Analyzed Threshold Ionization (MATI) Spectroscopy of Atoms and Molecules Using VUV Synchrotron Radiation ^† Kostko, Oleg; Kim, Sang Kyu; Leone, Stephen R. The Journal of Physical Chemistry A, Vol. 113, Issue 52 https://doi.org/10.1021/jp9008338	journal	December 2009
Valence Ionization of Water Clusters: From Isolated Molecules to Bulk Barth, Silko; Ončák, Milan; Ulrich, Volker The Journal of Physical Chemistry A, Vol. 113, Issue 48 https://doi.org/10.1021/jp906113e	journal	October 2009
Determination of Ionization Energies of Small Silicon Clusters with Vacuum Ultraviolet Radiation Kostko, Oleg; Leone, Stephen R.; Duncan, Michael A. The Journal of Physical Chemistry A, Vol. 114, Issue 9 https://doi.org/10.1021/jp9091688	journal	December 2009
Zooming into π-Stacked Manifolds of Nucleobases: Ionized States of Dimethylated Uracil Dimers Zadorozhnaya, Anna A.; Krylov, Anna I. The Journal of Physical Chemistry A, Vol. 114, Issue 4 https://doi.org/10.1021/jp910440d	journal	February 2010
Gas Phase Kinetics of Neutral Transition Metal Atoms: Reactions of Hf, Ta, Ir, Pt, and Au with Alkanes and Alkenes Carroll, John J.; Weisshaar, James C. The Journal of Physical Chemistry, Vol. 100, Issue 30 https://doi.org/10.1021/jp960408b	journal	January 1996
Pt⁺-Catalyzed Oxidation of Methane: Theory and Experiment Pavlov, Maria; Blomberg, Margareta R. A.; Siegbahn, Per E. M. The Journal of Physical Chemistry A, Vol. 101, Issue 8 https://doi.org/10.1021/jp962966w	journal	February 1997
Rapid Evaporative Cooling Suppresses Fragmentation in Mass Spectrometry: Synthesis of “Unprotonated” Water Cluster Ions Jongma, Rienk T.; Huang, Yuhui; Shi, Shiming The Journal of Physical Chemistry A, Vol. 102, Issue 45 https://doi.org/10.1021/jp983366v	journal	November 1998
A VUV Photoionization Study of the Formation of the Indene Molecule and Its Isomers Zhang, Fangtong; Kaiser, Ralf I.; Kislov, Vadim V. The Journal of Physical Chemistry Letters, Vol. 2, Issue 14 https://doi.org/10.1021/jz200715u	journal	June 2011
Ionization of Water Clusters Mediated by Exciton Energy Transfer from Argon Clusters Golan, Amir; Ahmed, Musahid The Journal of Physical Chemistry Letters, Vol. 3, Issue 4 https://doi.org/10.1021/jz2016654	journal	January 2012
Direct Observation of para -Xylylene as the Decomposition Product of the meta -Xylyl Radical Using VUV Synchrotron Radiation Hemberger, Patrick; Trevitt, Adam J.; Ross, Edward The Journal of Physical Chemistry Letters, Vol. 4, Issue 15 https://doi.org/10.1021/jz401207z	journal	July 2013
Mass-Resolved Isomer-Selective Chemical Analysis with Imaging Photoelectron Photoion Coincidence Spectroscopy Bodi, Andras; Hemberger, Patrick; Osborn, David L. The Journal of Physical Chemistry Letters, Vol. 4, Issue 17 https://doi.org/10.1021/jz401500c	journal	August 2013
Ionization of dimethyluracil dimers leads to facile proton transfer in the absence of hydrogen bonds Golan, Amir; Bravaya, Ksenia B.; Kudirka, Romas Nature Chemistry, Vol. 4, Issue 4 https://doi.org/10.1038/nchem.1298	journal	March 2012
Structural trends of ionized water networks: Infrared spectroscopy of watercluster radical cations (H2O)n+ (n = 3–11) Mizuse, Kenta; Kuo, Jer-Lai; Fujii, Asuka Chem. Sci., Vol. 2, Issue 5 https://doi.org/10.1039/C0SC00604A	journal	January 2011
A VUV photoionization study of the multichannel reaction of phenyl radicals with 1,3-butadiene under combustion relevant conditions Golan, Amir; Ahmed, Musahid; Mebel, Alexander M. Phys. Chem. Chem. Phys., Vol. 15, Issue 1 https://doi.org/10.1039/C2CP42848B	journal	January 2013
Association mechanisms of unsaturated C2 hydrocarbons with their cations: acetylene and ethylene Bera, Partha P.; Head-Gordon, Martin; Lee, Timothy J. Phys. Chem. Chem. Phys., Vol. 15, Issue 6 https://doi.org/10.1039/C2CP43740F	journal	January 2013
Photoelectron–photoion coincidence spectroscopy for multiplexed detection of intermediate species in a flame Krüger, Julia; Garcia, Gustavo A.; Felsmann, Daniel Phys. Chem. Chem. Phys., Vol. 16, Issue 41 https://doi.org/10.1039/C4CP02857K	journal	January 2014
Elucidation of the chemical composition of avian melanin Liu, Suet Yi; Shawkey, Matthew D.; Parkinson, Dilworth RSC Adv., Vol. 4, Issue 76 https://doi.org/10.1039/C4RA06606E	journal	January 2014
On the protonation of water Bodi, A.; Csontos, J.; Kállay, M. Chem. Sci., Vol. 5, Issue 8 https://doi.org/10.1039/C4SC00791C	journal	January 2014
Gas-phase kinetics of ground-state platinum with O2,NO, N2Oand CH4 Campbell, Mark L. Journal of the Chemical Society, Faraday Transactions, Vol. 94, Issue 3 https://doi.org/10.1039/a705892f	journal	January 1998
The effect of π-stacking, H-bonding, and electrostatic interactions on the ionization energies of nucleic acid bases: adenine–adenine, thymine–thymine and adenine–thymine dimers Bravaya, Ksenia B.; Kostko, Oleg; Ahmed, Musahid Physical Chemistry Chemical Physics, Vol. 12, Issue 10 https://doi.org/10.1039/b919930f	journal	January 2010
Ionization of cytosine monomer and dimer studied by VUV photoionization and electronic structure calculations Kostko, Oleg; Bravaya, Ksenia; Krylov, Anna Physical Chemistry Chemical Physics, Vol. 12, Issue 12 https://doi.org/10.1039/b921498d	journal	January 2010
Chemical dynamics, molecular energetics, and kinetics at the synchrotron Leone, Stephen R.; Ahmed, Musahid; Wilson, Kevin R. Physical Chemistry Chemical Physics, Vol. 12, Issue 25 https://doi.org/10.1039/c001707h	journal	January 2010
Untangling the chemical evolution of Titan's atmosphere and surface–from homogeneous to heterogeneous chemistry Kaiser, Ralf I.; Maksyutenko, Pavlo; Ennis, Courtney Faraday Discussions, Vol. 147 https://doi.org/10.1039/c003599h	journal	January 2010
Photoionization of a protein isolated in vacuo Milosavljević, Aleksandar R.; Nicolas, Christophe; Lemaire, Joel Physical Chemistry Chemical Physics, Vol. 13, Issue 34 https://doi.org/10.1039/c1cp21211g	journal	January 2011
Research frontiers in the chemistry of Criegee intermediates and tropospheric ozonolysis Taatjes, Craig A.; Shallcross, Dudley E.; Percival, Carl J. Physical Chemistry Chemical Physics, Vol. 16, Issue 5 https://doi.org/10.1039/c3cp52842a	journal	January 2014
Performance of the vacuum ultraviolet high-resolution and high-flux beamline for chemical dynamics studies at the Advanced Light Source Heimann, P. A.; Koike, M.; Hsu, C. W. Review of Scientific Instruments, Vol. 68, Issue 5 https://doi.org/10.1063/1.1148082	journal	May 1997
Selective detection of isomers with photoionization mass spectrometry for studies of hydrocarbon flame chemistry Cool, Terrill A.; Nakajima, Koichi; Mostefaoui, Toufik A. The Journal of Chemical Physics, Vol. 119, Issue 16 https://doi.org/10.1063/1.1611173	journal	October 2003
A photoionization mass spectrometer utilizing a high intensity molecular beam sampling system and synchrotron radiation Parr, Gary R.; Taylor, James W. Review of Scientific Instruments, Vol. 44, Issue 11 https://doi.org/10.1063/1.1686004	journal	November 1973
Photon Impact Studies of Molecules Using a Mass Spectrometer Hurzeler, H.; Inghram, Mark G.; Morrison, J. D. The Journal of Chemical Physics, Vol. 28, Issue 1 https://doi.org/10.1063/1.1744084	journal	January 1958
Direct determination of the ionization energies of FeO and CuO with VUV radiation Metz, Ricardo B.; Nicolas, Christophe; Ahmed, Musahid The Journal of Chemical Physics, Vol. 123, Issue 11 https://doi.org/10.1063/1.2032947	journal	September 2005
The multiplexed chemical kinetic photoionization mass spectrometer: A new approach to isomer-resolved chemical kinetics Osborn, David L.; Zou, Peng; Johnsen, Howard Review of Scientific Instruments, Vol. 79, Issue 10 https://doi.org/10.1063/1.3000004	journal	October 2008
A threshold photoelectron-photoion coincidence spectrometer with double velocity imaging using synchrotron radiation Tang, Xiaofeng; Zhou, Xiaoguo; Niu, Mingli Review of Scientific Instruments, Vol. 80, Issue 11 https://doi.org/10.1063/1.3250872	journal	November 2009
Spectroscopic signatures of proton transfer dynamics in the water dimer cation Kamarchik, Eugene; Kostko, Oleg; Bowman, Joel M. The Journal of Chemical Physics, Vol. 132, Issue 19 https://doi.org/10.1063/1.3432198	journal	May 2010
Photodissociation of protonated leucine-enkephalin in the VUV range of 8–40 eV Bari, S.; Gonzalez-Magaña, O.; Reitsma, G. The Journal of Chemical Physics, Vol. 134, Issue 2 https://doi.org/10.1063/1.3515301	journal	January 2011
Invited Review Article: Laser vaporization cluster sources Duncan, Michael A. Review of Scientific Instruments, Vol. 83, Issue 4 https://doi.org/10.1063/1.3697599	journal	April 2012
Photoionization of water clusters at 11.83 eV: Observation of unprotonated cluster ions (H ₂ O) ⁺ _n (2≤ n ≤10) Shinohara, Hisanori; Nishi, Nobuyuki; Washida, Nobuaki The Journal of Chemical Physics, Vol. 84, Issue 10 https://doi.org/10.1063/1.449914	journal	May 1986
A new double imaging velocity focusing coincidence experiment: i ² PEPICO Bodi, Andras; Hemberger, Patrick; Gerber, Thomas Review of Scientific Instruments, Vol. 83, Issue 8 https://doi.org/10.1063/1.4742769	journal	August 2012
Thermal decomposition of CH ₃ CHO studied by matrix infrared spectroscopy and photoionization mass spectroscopy Vasiliou, AnGayle K.; Piech, Krzysztof M.; Reed, Beth The Journal of Chemical Physics, Vol. 137, Issue 16 https://doi.org/10.1063/1.4759050	journal	October 2012
Photo-induced electron detachment of protein polyanions in the VUV range Brunet, Claire; Antoine, Rodolphe; Dugourd, Philippe The Journal of Chemical Physics, Vol. 138, Issue 6 https://doi.org/10.1063/1.4790165	journal	February 2013
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Internal energy selection in vacuum ultraviolet photoionization of ethanol and ethanol dimers Bodi, Andras The Journal of Chemical Physics, Vol. 139, Issue 14 https://doi.org/10.1063/1.4824135	journal	October 2013
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The thermal decomposition of the benzyl radical in a heated micro-reactor. I. Experimental findings Buckingham, Grant T.; Ormond, Thomas K.; Porterfield, Jessica P. The Journal of Chemical Physics, Vol. 142, Issue 4 https://doi.org/10.1063/1.4906156	journal	January 2015
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Synchrotron-based double imaging photoelectron/photoion coincidence spectroscopy of radicals produced in a flow tube: OH and OD Garcia, Gustavo A.; Tang, Xiaofeng; Gil, Jean-François The Journal of Chemical Physics, Vol. 142, Issue 16 https://doi.org/10.1063/1.4918634	journal	April 2015
Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed characterization of organic carbon emissions Gentner, D. R.; Isaacman, G.; Worton, D. R. Proceedings of the National Academy of Sciences, Vol. 109, Issue 45 https://doi.org/10.1073/pnas.1212272109	journal	October 2012
The ionisation energy of cyclopentadienone: a photoelectron–photoion coincidence study Ormond, Thomas K.; Hemberger, Patrick; Troy, Tyler P. Molecular Physics, Vol. 113, Issue 15-16 https://doi.org/10.1080/00268976.2015.1042936	journal	May 2014
Photoionisation and photodissociation studies of nonvolatile organic molecules by synchrotron VUV photoionisation mass spectrometry and theoretical calculations Pan, Yang; Zhang, Lidong; Guo, Huijun International Reviews in Physical Chemistry, Vol. 29, Issue 2 https://doi.org/10.1080/01442351003668697	journal	April 2010
DETERMINATION OF IONIZATION ENERGIES OF C _n N ( n = 4-12): VACUUM ULTRAVIOLET PHOTOIONIZATION EXPERIMENTS AND THEORETICAL CALCULATIONS Kostko, Oleg; Zhou, Jia; Sun, Bian Jian The Astrophysical Journal, Vol. 717, Issue 2 https://doi.org/10.1088/0004-637X/717/2/674	journal	June 2010
AN EXPERIMENTAL AND THEORETICAL STUDY ON THE IONIZATION ENERGIES OF POLYYNES (H-(C≡C) _n -H; n = 1-9) Kaiser, Ralf I.; Sun, Bian Jian; Lin, Hong Mao The Astrophysical Journal, Vol. 719, Issue 2 https://doi.org/10.1088/0004-637X/719/2/1884	journal	August 2010
AN EXPERIMENTAL AND THEORETICAL STUDY OF THE IONIZATION ENERGIES OF SiC ₂ H _x ( x = 0, 1, 2) ISOMERS Kaiser, Ralf I.; Krishtal, Sergey P.; Mebel, Alexander M. The Astrophysical Journal, Vol. 761, Issue 2 https://doi.org/10.1088/0004-637X/761/2/178	journal	December 2012
Optical properties of argon clusters in the VUV Wörmer, J.; Guzielski, V.; Stapelfeldt, J. Physica Scripta, Vol. 41, Issue 4 https://doi.org/10.1088/0031-8949/41/4/025	journal	April 1990
XUV frequency combs via femtosecond enhancement cavities Mills, Arthur K.; Hammond, T. J.; Lam, Matthew H. C. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 45, Issue 14 https://doi.org/10.1088/0953-4075/45/14/142001	journal	July 2012
Interatomic and intermolecular Coulombic decay: the coming of age story Jahnke, T. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 48, Issue 8 https://doi.org/10.1088/0953-4075/48/8/082001	journal	March 2015
Valence shell direct double photodetachment in polyanions Brunet, Claire; Antoine, Rodolphe; Dugourd, Philippe New Journal of Physics, Vol. 15, Issue 6 https://doi.org/10.1088/1367-2630/15/6/063024	journal	June 2013
Autoionizing Rydberg series(np′,nf′)of Ar investigated by stepwise excitations with lasers and synchrotron radiation Lee, Yin-Yu; Dung, Tzan-Yi; Hsieh, Re-Ming Physical Review A, Vol. 78, Issue 2 https://doi.org/10.1103/PhysRevA.78.022509	journal	August 2008
Rovibrational-State-Selected Photoionization of Acetylene by the Two-Color I R + V U V Scheme: Observation of Rotationally Resolved Rydberg Transitions Qian, X. -M.; Kung, A. H.; Zhang, Tao Physical Review Letters, Vol. 91, Issue 23 https://doi.org/10.1103/PhysRevLett.91.233001	journal	December 2003
Diffraction-limited storage rings – a window to the science of tomorrow Eriksson, Mikael; van der Veen, J. Friso; Quitmann, Christoph Journal of Synchrotron Radiation, Vol. 21, Issue 5 https://doi.org/10.1107/S1600577514019286	journal	August 2014
Enols Are Common Intermediates in Hydrocarbon Oxidation Taatjes, C. A. Science, Vol. 308, Issue 5730 https://doi.org/10.1126/science.1112532	journal	June 2005
Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2 Welz, O.; Savee, J. D.; Osborn, D. L. Science, Vol. 335, Issue 6065 https://doi.org/10.1126/science.1213229	journal	January 2012
Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH3CHOO Taatjes, C. A.; Welz, O.; Eskola, A. J. Science, Vol. 340, Issue 6129 https://doi.org/10.1126/science.1234689	journal	April 2013
Direct observation and kinetics of a hydroperoxyalkyl radical (QOOH) Savee, John D.; Papajak, Ewa; Rotavera, Brandon Science, Vol. 347, Issue 6222 https://doi.org/10.1126/science.aaa1495	journal	February 2015
State-to-State Spectroscopy and Dynamics of Ions and Neutrals by Photoionization and Photoelectron Methods Ng, Cheuk-Yiu Annual Review of Physical Chemistry, Vol. 65, Issue 1 https://doi.org/10.1146/annurev-physchem-040412-110002	journal	April 2014
Vacuum UV Photophysics and Photoionization Spectroscopy Baer, Tomas Annual Review of Physical Chemistry, Vol. 40, Issue 1 https://doi.org/10.1146/annurev.pc.40.100189.003225	journal	October 1989
V ACUUM U LTRAVIOLET S PECTROSCOPY AND C HEMISTRY BY P HOTOIONIZATION AND P HOTOELECTRON M ETHODS Ng, Cheuk-Yiu Annual Review of Physical Chemistry, Vol. 53, Issue 1 https://doi.org/10.1146/annurev.physchem.53.082001.144416	journal	October 2002
Gas-Phase Spectroscopy of Biomolecular Building Blocks de Vries, Mattanjah S.; Hobza, Pavel Annual Review of Physical Chemistry, Vol. 58, Issue 1 https://doi.org/10.1146/annurev.physchem.57.032905.104722	journal	May 2007

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