[U(bipy) 4 ]: A Mistaken Case of U 0 ?
Abstract
Abstract After more than 50 years, the synthesis and electronic structure of the first and only reported “U 0 complex” [U(bipy) 4 ] ( 1 ) has been reinvestigated. Additionally, its one‐electron reduced product [Na(THF) 6 ][U(bipy) 4 ] ( 2 ) has been newly discovered. High resolution crystallographic analyses combined with magnetic and computational data show that 1 and its derivative 2 are best described as highly reduced species containing mid‐to‐high‐valent uranium ligated by redox non‐innocent ligands.
- Authors:
-
[1];
- Department of Chemistry University of Texas at El Paso El Paso TX 79968 USA
- Department of Chemistry University of Ottawa Ottawa ON K1N 6N5 Canada
- Department of Chemistry University of California, Davis Davis CA 95616 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1454904
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Name: Chemistry - A European Journal Journal Volume: 22 Journal Issue: 6; Journal ID: ISSN 0947-6539
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Fortier, Skye, Veleta, José, Pialat, Amélie, Le Roy, Jennifer, Ghiassi, Kamran B., Olmstead, Marilyn M., Metta‐Magaña, Alejandro, Murugesu, Muralee, and Villagrán, Dino. [U(bipy) 4 ]: A Mistaken Case of U 0 ?. Germany: N. p., 2016.
Web. doi:10.1002/chem.201504982.
Fortier, Skye, Veleta, José, Pialat, Amélie, Le Roy, Jennifer, Ghiassi, Kamran B., Olmstead, Marilyn M., Metta‐Magaña, Alejandro, Murugesu, Muralee, & Villagrán, Dino. [U(bipy) 4 ]: A Mistaken Case of U 0 ?. Germany. https://doi.org/10.1002/chem.201504982
Fortier, Skye, Veleta, José, Pialat, Amélie, Le Roy, Jennifer, Ghiassi, Kamran B., Olmstead, Marilyn M., Metta‐Magaña, Alejandro, Murugesu, Muralee, and Villagrán, Dino. Thu .
"[U(bipy) 4 ]: A Mistaken Case of U 0 ?". Germany. https://doi.org/10.1002/chem.201504982.
@article{osti_1454904,
title = {[U(bipy) 4 ]: A Mistaken Case of U 0 ?},
author = {Fortier, Skye and Veleta, José and Pialat, Amélie and Le Roy, Jennifer and Ghiassi, Kamran B. and Olmstead, Marilyn M. and Metta‐Magaña, Alejandro and Murugesu, Muralee and Villagrán, Dino},
abstractNote = {Abstract After more than 50 years, the synthesis and electronic structure of the first and only reported “U 0 complex” [U(bipy) 4 ] ( 1 ) has been reinvestigated. Additionally, its one‐electron reduced product [Na(THF) 6 ][U(bipy) 4 ] ( 2 ) has been newly discovered. High resolution crystallographic analyses combined with magnetic and computational data show that 1 and its derivative 2 are best described as highly reduced species containing mid‐to‐high‐valent uranium ligated by redox non‐innocent ligands.},
doi = {10.1002/chem.201504982},
journal = {Chemistry - A European Journal},
number = 6,
volume = 22,
place = {Germany},
year = {Thu Jan 07 00:00:00 EST 2016},
month = {Thu Jan 07 00:00:00 EST 2016}
}
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