High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite

Zhao, Baohuai; Yan, Binhang; Jiang, Zhao; Yao, Siyu; Liu, Zongyuan; Wu, Qiyuan; Ran, Rui; Senanayake, Sanjaya D.; Weng, Duan; Chen, Jingguang G.

doi:10.1039/C8CC03829E

Title: High selectivity of CO₂ hydrogenation to CO by controlling the valence state of nickel using perovskite

Abstract

The selectivity of CO₂ hydrogenation can be significantly tuned by controlling the valence state of nickel using lanthanum-iron-nickel perovskites. Nickel with higher valence states weakens the binding of CO and increases the activation barrier for further CO hydrogenation, leading to a higher CO selectivity than the metallic nickel.

Authors:

Zhao, Baohuai ^[1]; Yan, Binhang ^[1]; Jiang, Zhao ^[2]; Yao, Siyu ^[3];

^[3];

^[4]; Ran, Rui ^[5];

^[3]; Weng, Duan ^[5];

^[6]

Brookhaven National Lab. (BNL), Upton, NY (United States); Tsinghua Univ., Beijing (China)
Columbia Univ., New York, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Stony Brook Univ., NY (United States)
Tsinghua Univ., Beijing (China)
Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)

Publication Date:: Mon Jun 11 00:00:00 EDT 2018

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1466617

Alternate Identifier(s):: OSTI ID: 1454637

Report Number(s):: BNL-207967-2018-JAAM
Journal ID: ISSN 1359-7345; CHCOFS

Grant/Contract Number:: SC0012704; AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 54; Journal Issue: 53; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats


                    Zhao, Baohuai, Yan, Binhang, Jiang, Zhao, Yao, Siyu, Liu, Zongyuan, Wu, Qiyuan, Ran, Rui, Senanayake, Sanjaya D., Weng, Duan, and Chen, Jingguang G. High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite.  United States: N. p., 2018. 
Web.  doi:10.1039/C8CC03829E.

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                    Zhao, Baohuai, Yan, Binhang, Jiang, Zhao, Yao, Siyu, Liu, Zongyuan, Wu, Qiyuan, Ran, Rui, Senanayake, Sanjaya D., Weng, Duan, & Chen, Jingguang G. High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite.  United States.  https://doi.org/10.1039/C8CC03829E

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                    Zhao, Baohuai, Yan, Binhang, Jiang, Zhao, Yao, Siyu, Liu, Zongyuan, Wu, Qiyuan, Ran, Rui, Senanayake, Sanjaya D., Weng, Duan, and Chen, Jingguang G. Mon .  
"High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite".  United States.  https://doi.org/10.1039/C8CC03829E.  https://www.osti.gov/servlets/purl/1466617.

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@article{osti_1466617,

  title        = {High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite},

  author       = {Zhao, Baohuai and Yan, Binhang and Jiang, Zhao and Yao, Siyu and Liu, Zongyuan and Wu, Qiyuan and Ran, Rui and Senanayake, Sanjaya D. and Weng, Duan and Chen, Jingguang G.},

  abstractNote = {The selectivity of CO2 hydrogenation can be significantly tuned by controlling the valence state of nickel using lanthanum-iron-nickel perovskites. Nickel with higher valence states weakens the binding of CO and increases the activation barrier for further CO hydrogenation, leading to a higher CO selectivity than the metallic nickel.},

  doi          = {10.1039/C8CC03829E},

  journal      = {ChemComm},

  number       = 53,

  volume       = 54,

  place        = {United States},

  year         = {Mon Jun 11 00:00:00 EDT 2018},

  month        = {Mon Jun 11 00:00:00 EDT 2018}

}

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Journal Article:

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https://doi.org/10.1039/C8CC03829E

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Cited by: 47 works

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Figures / Tables:

Fig. 1: TEM images and particle size distributions of the spent catalysts (a–c) LaNiO₃; (d–f) LaFe_0.5Ni_0.5O₃.

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Works referenced in this record:

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Works referencing / citing this record:

Cooperative Co ⁰ /Co ^II Sites Stabilized by a Perovskite Matrix Enable Selective C−O and C−C bond Hydrogenolysis of Oxygenated Arenes
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Figures / Tables found in this record:

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

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Title: High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite

Abstract

Citation Formats

Figures / Tables:

Mechanism of CO2 reduction by H2 on Ru(0 0 0 1) and general selectivity descriptors for late-transition metal catalysts journal, November 2016

Active Site Dependent Reaction Mechanism over Ru/CeO 2 Catalyst toward CO 2 Methanation journal, May 2016

Study of bimetallic Cu–Ni/γ-Al2O3 catalysts for carbon dioxide hydrogenation journal, April 1999

CO2 hydrogenation on Pt, Pt/SiO2 and Pt/TiO2: Importance of synergy between Pt and oxide support journal, November 2016

Trends in the catalytic reduction of CO2 by hydrogen over supported monometallic and bimetallic catalysts journal, May 2013

Recent advances in catalytic hydrogenation of carbon dioxide journal, January 2011

Hydrogen from biogas: Catalytic tri-reforming process with Ni/LaCeO mixed oxides journal, April 2014

Methanation of CO 2 and reverse water gas shift reactions on Ni/SiO 2 catalysts: the influence of particle size on selectivity and reaction pathway journal, January 2015

Catalytic reduction of CO 2 by H 2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities journal, January 2016

Effect of the structure of Ni/TiO2 catalyst on CO2 methanation journal, December 2016

Selective hydrogenation of CO 2 into CO on a highly dispersed nickel catalyst obtained by magnetron sputtering deposition: A step towards liquid fuels journal, July 2017

Tuning Selectivity of CO 2 Hydrogenation Reactions at the Metal/Oxide Interface journal, July 2017

Optimizing Binding Energies of Key Intermediates for CO 2 Hydrogenation to Methanol over Oxide-Supported Copper journal, September 2016

CO 2 Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity journal, May 2016

Mechanisms of Hydrogen-Assisted CO 2 Reduction on Nickel journal, March 2017

Structural Reversibility and Nickel Particle stability in Lanthanum Iron Nickel Perovskite-Type Catalysts journal, May 2017

Direct observation of Ni 3+ and Ni 2+ in correlated LaNiO 3−δ films journal, March 2011

XPS study of the surface properties and Ni particle size determination of Ni-supported catalysts: Surface properties and Ni particle size determination of Ni catalysts journal, June 2014

Electrochemical property assessment of Sr-doped LaNi0.5Mn0.5O3− as cathode for intermediate-temperature solid oxide fuel cells journal, December 2016

Recycling of CO 2 : Probing the Chemical State of the Ni(111) Surface during the Methanation Reaction with Ambient-Pressure X-Ray Photoelectron Spectroscopy journal, September 2016

Scaled Degree of Rate Control: Identifying Elementary Steps That Control Differences in Performance of Transition-Metal Catalysts journal, July 2016

Ni–perovskite interaction and its structural and catalytic consequences in methane steam reforming and methanation reactions journal, May 2016

Catalytic behavior of metal catalysts in high-temperature RWGS reaction: In-situ FT-IR experiments and first-principles calculations journal, January 2017

Carbon dioxide hydrogenation on potassium-promoted nickel catalysts journal, May 1989

Methanation of CO2: Structural response of a Ni-based catalyst under fluctuating reaction conditions unraveled by operando spectroscopy journal, July 2015

Absence of Ni on the outer surface of Sr doped La 2 NiO 4 single crystals journal, January 2014

Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution journal, September 2015

Oxidative Methane Reforming with an Intelligent Catalyst: Sintering-Tolerant Supported Nickel Nanoparticles journal, October 2013

Cooperative Co 0 /Co II Sites Stabilized by a Perovskite Matrix Enable Selective C−O and C−C bond Hydrogenolysis of Oxygenated Arenes journal, April 2019

Hydrogenation of Carbon Dioxide to Value-Added Chemicals by Heterogeneous Catalysis and Plasma Catalysis journal, March 2019

Title: High selectivity of CO₂ hydrogenation to CO by controlling the valence state of nickel using perovskite

Mechanism of CO2 reduction by H2 on Ru(0 0 0 1) and general selectivity descriptors for late-transition metal catalysts
journal, November 2016

Active Site Dependent Reaction Mechanism over Ru/CeO ₂ Catalyst toward CO ₂ Methanation
journal, May 2016

Study of bimetallic Cu–Ni/γ-Al2O3 catalysts for carbon dioxide hydrogenation
journal, April 1999

CO2 hydrogenation on Pt, Pt/SiO2 and Pt/TiO2: Importance of synergy between Pt and oxide support
journal, November 2016

Trends in the catalytic reduction of CO2 by hydrogen over supported monometallic and bimetallic catalysts
journal, May 2013

Recent advances in catalytic hydrogenation of carbon dioxide
journal, January 2011

Hydrogen from biogas: Catalytic tri-reforming process with Ni/LaCeO mixed oxides
journal, April 2014

Methanation of CO ₂ and reverse water gas shift reactions on Ni/SiO ₂ catalysts: the influence of particle size on selectivity and reaction pathway
journal, January 2015

Catalytic reduction of CO ₂ by H ₂ for synthesis of CO, methanol and hydrocarbons: challenges and opportunities
journal, January 2016

Effect of the structure of Ni/TiO2 catalyst on CO2 methanation
journal, December 2016

Selective hydrogenation of CO 2 into CO on a highly dispersed nickel catalyst obtained by magnetron sputtering deposition: A step towards liquid fuels
journal, July 2017

Tuning Selectivity of CO ₂ Hydrogenation Reactions at the Metal/Oxide Interface
journal, July 2017

Optimizing Binding Energies of Key Intermediates for CO ₂ Hydrogenation to Methanol over Oxide-Supported Copper
journal, September 2016

CO ₂ Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity
journal, May 2016

Mechanisms of Hydrogen-Assisted CO ₂ Reduction on Nickel
journal, March 2017

Structural Reversibility and Nickel Particle stability in Lanthanum Iron Nickel Perovskite-Type Catalysts
journal, May 2017

Direct observation of Ni ³⁺ and Ni ²⁺ in correlated LaNiO _3−δ films
journal, March 2011

XPS study of the surface properties and Ni particle size determination of Ni-supported catalysts: Surface properties and Ni particle size determination of Ni catalysts
journal, June 2014

Electrochemical property assessment of Sr-doped LaNi0.5Mn0.5O3− as cathode for intermediate-temperature solid oxide fuel cells
journal, December 2016

Recycling of CO ₂ : Probing the Chemical State of the Ni(111) Surface during the Methanation Reaction with Ambient-Pressure X-Ray Photoelectron Spectroscopy
journal, September 2016

Scaled Degree of Rate Control: Identifying Elementary Steps That Control Differences in Performance of Transition-Metal Catalysts
journal, July 2016

Ni–perovskite interaction and its structural and catalytic consequences in methane steam reforming and methanation reactions
journal, May 2016

Catalytic behavior of metal catalysts in high-temperature RWGS reaction: In-situ FT-IR experiments and first-principles calculations
journal, January 2017

Carbon dioxide hydrogenation on potassium-promoted nickel catalysts
journal, May 1989

Methanation of CO2: Structural response of a Ni-based catalyst under fluctuating reaction conditions unraveled by operando spectroscopy
journal, July 2015

Absence of Ni on the outer surface of Sr doped La ₂ NiO ₄ single crystals
journal, January 2014

Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution
journal, September 2015

Oxidative Methane Reforming with an Intelligent Catalyst: Sintering-Tolerant Supported Nickel Nanoparticles
journal, October 2013

Cooperative Co ⁰ /Co ^II Sites Stabilized by a Perovskite Matrix Enable Selective C−O and C−C bond Hydrogenolysis of Oxygenated Arenes
journal, April 2019

Hydrogenation of Carbon Dioxide to Value-Added Chemicals by Heterogeneous Catalysis and Plasma Catalysis
journal, March 2019