Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

Martin, Daniel J.; McCarthy, Brian D.; Donley, Carrie L.; Dempsey, Jillian L.

doi:10.1039/C4CC08662G

Title: Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

Abstract

Here, a Ni(ii) complex with nitrogen and sulfur donor ligands degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen.

Authors:

Martin, Daniel J. ^[1]; McCarthy, Brian D. ^[1]; Donley, Carrie L. ^[1]; Dempsey, Jillian L. ^[1]

Univ. of North Carolina, Chapel Hill, NC (United States)

Publication Date:: Thu Dec 04 00:00:00 EST 2014

Research Org.:: University of North Carolina, Chapel Hill, NC (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1454548

Grant/Contract Number:: SC0001011

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 51; Journal Issue: 25; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Martin, Daniel J., McCarthy, Brian D., Donley, Carrie L., and Dempsey, Jillian L. Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species.  United States: N. p., 2014. 
Web.  doi:10.1039/C4CC08662G.

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                    Martin, Daniel J., McCarthy, Brian D., Donley, Carrie L., & Dempsey, Jillian L. Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species.  United States.  https://doi.org/10.1039/C4CC08662G

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                    Martin, Daniel J., McCarthy, Brian D., Donley, Carrie L., and Dempsey, Jillian L. Thu .  
"Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species".  United States.  https://doi.org/10.1039/C4CC08662G.  https://www.osti.gov/servlets/purl/1454548.

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@article{osti_1454548,

  title        = {Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species},

  author       = {Martin, Daniel J. and McCarthy, Brian D. and Donley, Carrie L. and Dempsey, Jillian L.},

  abstractNote = {Here, a Ni(ii) complex with nitrogen and sulfur donor ligands degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen.},

  doi          = {10.1039/C4CC08662G},

  journal      = {ChemComm},

  number       = 25,

  volume       = 51,

  place        = {United States},

  year         = {Thu Dec 04 00:00:00 EST 2014},

  month        = {Thu Dec 04 00:00:00 EST 2014}

}

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https://doi.org/10.1039/C4CC08662G

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Works referenced in this record:

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Shuttling of Nickel Oxidation States in N ₄ S ₂ Coordination Geometry versus Donor Strength of Tridentate N ₂ S Donor Ligands
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[Ni(Et ₂ PCH ₂ NMeCH ₂ PEt ₂ ) ₂ ] ²⁺ as a Functional Model for Hydrogenases
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Use of oxygen/nickel ratios in the XPS characterisation of oxide phases on nickel metal and nickel alloy surfaces
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Evidence for near-Surface NiOOH Species in Solution-Processed NiO _x Selective Interlayer Materials: Impact on Energetics and the Performance of Polymer Bulk Heterojunction Photovoltaics
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Ratcliff, Erin L.; Meyer, Jens; Steirer, K. Xerxes
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Wasylenko, Derek J.; Rodríguez, Carlos; Pegis, Michael L.
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New interpretations of XPS spectra of nickel metal and oxides
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El Ghachtouli, Sanae; Fournier, Maxime; Cherdo, Stéphanie
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Works referencing / citing this record:

Spectroscopic Characterisation of a Bio‐Inspired Ni‐Based Proton Reduction Catalyst Bearing a Pentadentate N ₂ S ₃ Ligand with Improved Photocatalytic Activity
journal, January 2020

Gotico, Philipp; Moonshiram, Dooshaye; Liu, Cunming
Chemistry – A European Journal, Vol. 26, Issue 13
DOI: 10.1002/chem.201904934

Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS) ₂ Complex : Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS)
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Jain, Rahul; Mashuta, Mark S.; Buchanan, Robert M.
European Journal of Inorganic Chemistry, Vol. 2017, Issue 31
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Electrocatalytic hydrogen evolution with cobalt–poly(4-vinylpyridine) metallopolymers
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Kap, Zeynep; Ülker, Emine; Nune, Satya Vijaya Kumar
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A platinum( ii )–palladium( ii )–nickel( ii ) heterotrimetallic coordination polymer showing a cooperative effect on catalytic hydrogen evolution
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Kuwamura, Naoto; Kurioka, Yoshinari; Konno, Takumi
Chemical Communications, Vol. 53, Issue 5
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Proton reduction by a nickel complex with an internal quinoline moiety for proton relay
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Majee, Karunamay; Patel, Jully; Rai, Surabhi
Physical Chemistry Chemical Physics, Vol. 18, Issue 31
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H ₂ evolution by a cobalt selenolate electrocatalyst and related mechanistic studies
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Chemical Communications, Vol. 53, Issue 53
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Electroreduction of a Co ^II coordination complex producing a metal–organic film with high performance toward electrocatalytic hydrogen evolution
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Bezerra, Leticia S.; Rosa, Persiely P.; Fortunato, Guilherme V.
Journal of Materials Chemistry A, Vol. 6, Issue 40
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Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands
journal, January 2020

Inoue, Satoshi; Yan, Yin-Nan; Yamanishi, Katsunori
Chemical Communications, Vol. 56, Issue 19
DOI: 10.1039/c9cc09568c

Cover Feature: Spectroscopic Characterisation of a Bio‐Inspired Ni‐Based Proton Reduction Catalyst Bearing a Pentadentate N ₂ S ₃ Ligand with Improved Photocatalytic Activity (Chem. Eur. J. 13/2020)
journal, January 2020

Gotico, Philipp; Moonshiram, Dooshaye; Liu, Cunming
Chemistry – A European Journal, Vol. 26, Issue 13
DOI: 10.1002/chem.202000227

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Title: Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

Abstract

Citation Formats

Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions journal, January 2013

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects journal, July 2008

Reactions of nickel chelates derived from 2-aminobenzenethiol journal, June 1968

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Electrochemical Reduction of Brønsted Acids by Glassy Carbon in Acetonitrile—Implications for Electrocatalytic Hydrogen Evolution journal, July 2014

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Boron-Capped Tris(glyoximato) Cobalt Clathrochelate as a Precursor for the Electrodeposition of Nanoparticles Catalyzing H 2 Evolution in Water journal, March 2012

Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis? journal, January 2013

A nickel dimethyl glyoximato complex to form nickel based nanoparticles for electrocatalytic H 2 production journal, January 2014

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Electrodeposition from Acidic Solutions of Nickel Bis(benzenedithiolate) Produces a Hydrogen-Evolving Ni–S Film on Glassy Carbon journal, December 2013

Shuttling of Nickel Oxidation States in N 4 S 2 Coordination Geometry versus Donor Strength of Tridentate N 2 S Donor Ligands journal, April 2012

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A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions journal, May 2003

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Evidence for near-Surface NiOOH Species in Solution-Processed NiO x Selective Interlayer Materials: Impact on Energetics and the Performance of Polymer Bulk Heterojunction Photovoltaics journal, November 2011

Direct Comparison of Electrochemical and Spectrochemical Kinetics for Catalytic Oxygen Reduction journal, August 2014

New interpretations of XPS spectra of nickel metal and oxides journal, May 2006

Monometallic Cobalt–Trisglyoximato Complexes as Precatalysts for Catalytic H 2 Evolution in Water journal, August 2013

Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry journal, September 2014

Fuel from Water: The Photochemical Generation of Hydrogen from Water journal, June 2014

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Electrocatalytic hydrogen evolution with cobalt–poly(4-vinylpyridine) metallopolymers journal, January 2018

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journal, January 2013

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
journal, July 2008

Reactions of nickel chelates derived from 2-aminobenzenethiol
journal, June 1968

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Electrochemical Reduction of Brønsted Acids by Glassy Carbon in Acetonitrile—Implications for Electrocatalytic Hydrogen Evolution
journal, July 2014

Cobalt-Bisglyoximato Diphenyl Complex as a Precatalyst for Electrocatalytic H ₂ Evolution
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The roles of the first and second coordination spheres in the design of molecular catalysts for H ₂ production and oxidation
journal, January 2009

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journal, March 2012

Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis?
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A nickel dimethyl glyoximato complex to form nickel based nanoparticles for electrocatalytic H ₂ production
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journal, October 2013

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Shuttling of Nickel Oxidation States in N ₄ S ₂ Coordination Geometry versus Donor Strength of Tridentate N ₂ S Donor Ligands
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journal, February 2007

Some general principles for designing electrocatalysts with hydrogenase activity
journal, August 2005

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journal, January 2014

A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions
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[Ni(Et ₂ PCH ₂ NMeCH ₂ PEt ₂ ) ₂ ] ²⁺ as a Functional Model for Hydrogenases
journal, January 2003

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journal, November 2011

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journal, August 2014

New interpretations of XPS spectra of nickel metal and oxides
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Monometallic Cobalt–Trisglyoximato Complexes as Precatalysts for Catalytic H ₂ Evolution in Water
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