Polymer non-fullerene solar cells of vastly different efficiencies for minor side-chain modification: impact of charge transfer, carrier lifetime, morphology and mobility
Abstract
The performance of the 11.25% efficient PBDB-T : ITIC system degraded to 4.35% after a minor side-chain modification in PBDB-O : ITIC. In this study, the underlying reasons behind this vast difference in efficiencies are investigated.
- Authors:
-
- Department of Physics and Organic and Carbon Electronics Laboratory (ORACEL), North Carolina State University, Raleigh, USA
- Department of Physics and Organic and Carbon Electronics Laboratory (ORACEL), North Carolina State University, Raleigh, USA, Department of Chemistry and Physics
- State Key Laboratory of Polymer Physics and Chemistry, Beijing National Laboratory of Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1454297
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Name: Journal of Materials Chemistry. A Journal Volume: 6 Journal Issue: 26; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Awartani, Omar M., Gautam, Bhoj, Zhao, Wenchao, Younts, Robert, Hou, Jianhui, Gundogdu, Kenan, and Ade, Harald. Polymer non-fullerene solar cells of vastly different efficiencies for minor side-chain modification: impact of charge transfer, carrier lifetime, morphology and mobility. United Kingdom: N. p., 2018.
Web. doi:10.1039/C7TA01746D.
Awartani, Omar M., Gautam, Bhoj, Zhao, Wenchao, Younts, Robert, Hou, Jianhui, Gundogdu, Kenan, & Ade, Harald. Polymer non-fullerene solar cells of vastly different efficiencies for minor side-chain modification: impact of charge transfer, carrier lifetime, morphology and mobility. United Kingdom. https://doi.org/10.1039/C7TA01746D
Awartani, Omar M., Gautam, Bhoj, Zhao, Wenchao, Younts, Robert, Hou, Jianhui, Gundogdu, Kenan, and Ade, Harald. Mon .
"Polymer non-fullerene solar cells of vastly different efficiencies for minor side-chain modification: impact of charge transfer, carrier lifetime, morphology and mobility". United Kingdom. https://doi.org/10.1039/C7TA01746D.
@article{osti_1454297,
title = {Polymer non-fullerene solar cells of vastly different efficiencies for minor side-chain modification: impact of charge transfer, carrier lifetime, morphology and mobility},
author = {Awartani, Omar M. and Gautam, Bhoj and Zhao, Wenchao and Younts, Robert and Hou, Jianhui and Gundogdu, Kenan and Ade, Harald},
abstractNote = {The performance of the 11.25% efficient PBDB-T : ITIC system degraded to 4.35% after a minor side-chain modification in PBDB-O : ITIC. In this study, the underlying reasons behind this vast difference in efficiencies are investigated.},
doi = {10.1039/C7TA01746D},
journal = {Journal of Materials Chemistry. A},
number = 26,
volume = 6,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C7TA01746D
https://doi.org/10.1039/C7TA01746D
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Cited by: 38 works
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Works referenced in this record:
Impact of the photo-induced degradation of electron acceptors on the photophysics, charge transport and device performance of all-polymer and fullerene–polymer solar cells
journal, January 2017
- Kim, Taesu; Younts, Robert; Lee, Wonho
- J. Mater. Chem. A, Vol. 5, Issue 42
Miscibility-Function Relations in Organic Solar Cells: Significance of Optimal Miscibility in Relation to Percolation
journal, January 2018
- Ye, Long; Collins, Brian A.; Jiao, Xuechen
- Advanced Energy Materials, Vol. 8, Issue 28
High-Performance Electron Acceptor with Thienyl Side Chains for Organic Photovoltaics
journal, March 2016
- Lin, Yuze; Zhao, Fuwen; He, Qiao
- Journal of the American Chemical Society, Vol. 138, Issue 14
Fast charge separation in a non-fullerene organic solar cell with a small driving force
journal, June 2016
- Liu, Jing; Chen, Shangshang; Qian, Deping
- Nature Energy, Vol. 1, Issue 7
Slower carriers limit charge generation in organic semiconductor light-harvesting systems
journal, June 2016
- Stolterfoht, Martin; Armin, Ardalan; Shoaee, Safa
- Nature Communications, Vol. 7, Issue 1
Fluorine Substituents Reduce Charge Recombination and Drive Structure and Morphology Development in Polymer Solar Cells
journal, January 2013
- Stuart, Andrew C.; Tumbleston, John R.; Zhou, Huaxing
- Journal of the American Chemical Society, Vol. 135, Issue 5
Soft x-ray scattering facility at the Advanced Light Source with real-time data processing and analysis
journal, April 2012
- Gann, E.; Young, A. T.; Collins, B. A.
- Review of Scientific Instruments, Vol. 83, Issue 4
Characterizing morphology in organic systems with resonant soft X-ray scattering
journal, April 2015
- Carpenter, Joshua H.; Hunt, Adrian; Ade, Harald
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 200
Impact of charge transport on current–voltage characteristics and power-conversion efficiency of organic solar cells
journal, April 2015
- Würfel, Uli; Neher, Dieter; Spies, Annika
- Nature Communications, Vol. 6, Issue 1
Solution-Processed, Molecular Photovoltaics that Exploit Hole Transfer from Non-Fullerene, n-Type Materials
journal, May 2014
- Douglas, Jessica D.; Chen, Mark S.; Niskala, Jeremy R.
- Advanced Materials, Vol. 26, Issue 25
Effect of Backbone Regioregularity on the Structure and Orientation of a Donor–Acceptor Semiconducting Copolymer
journal, February 2014
- Perez, Louis A.; Zalar, Peter; Ying, Lei
- Macromolecules, Vol. 47, Issue 4
Control of Mesoscale Morphology and Photovoltaic Performance in Diketopyrrolopyrrole-Based Small Band Gap Terpolymers
journal, October 2016
- Ye, Long; Jiao, Xuechen; Zhang, Shaoqing
- Advanced Energy Materials, Vol. 7, Issue 3
Design and Synthesis of a Low Bandgap Small Molecule Acceptor for Efficient Polymer Solar Cells
journal, July 2016
- Yao, Huifeng; Chen, Yu; Qin, Yunpeng
- Advanced Materials, Vol. 28, Issue 37
High-efficiency polymer solar cells with small photon energy loss
journal, December 2015
- Kawashima, Kazuaki; Tamai, Yasunari; Ohkita, Hideo
- Nature Communications, Vol. 6, Issue 1
The influence of molecular orientation on organic bulk heterojunction solar cells
journal, April 2014
- Tumbleston, John R.; Collins, Brian A.; Yang, Liqiang
- Nature Photonics, Vol. 8, Issue 5
A 3D star-shaped non-fullerene acceptor for solution-processed organic solar cells with a high open-circuit voltage of 1.18 V
journal, January 2012
- Lin, Yuze; Cheng, Pei; Li, Yongfang
- Chemical Communications, Vol. 48, Issue 39
Quantitative relations between interaction parameter, miscibility and function in organic solar cells
journal, February 2018
- Ye, Long; Hu, Huawei; Ghasemi, Masoud
- Nature Materials, Vol. 17, Issue 3
Charge Carrier Generation Followed by Triplet State Formation, Annihilation, and Carrier Recreation in PBDTTT-C/PC 60 BM Photovoltaic Blends
journal, June 2015
- Gehrig, Dominik W.; Howard, Ian A.; Laquai, Frédéric
- The Journal of Physical Chemistry C, Vol. 119, Issue 24
Quantitative Bimolecular Recombination in Organic Photovoltaics through Triplet Exciton Formation
journal, February 2014
- Chow, Philip C. Y.; Gélinas, Simon; Rao, Akshay
- Journal of the American Chemical Society, Vol. 136, Issue 9
Mobility-Controlled Performance of Thick Solar Cells Based on Fluorinated Copolymers
journal, October 2014
- Li, Wentao; Albrecht, Steve; Yang, Liqiang
- Journal of the American Chemical Society, Vol. 136, Issue 44
Non-Fullerene Electron Acceptors for Use in Organic Solar Cells
journal, October 2015
- Nielsen, Christian B.; Holliday, Sarah; Chen, Hung-Yang
- Accounts of Chemical Research, Vol. 48, Issue 11
Ultrafast Long-Range Charge Separation in Organic Semiconductor Photovoltaic Diodes
journal, December 2013
- Gelinas, S.; Rao, A.; Kumar, A.
- Science, Vol. 343, Issue 6170
Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells
journal, November 2014
- Liu, Yuhang; Zhao, Jingbo; Li, Zhengke
- Nature Communications, Vol. 5, Issue 1
Quantitative Morphology-Performance Correlations in Organic Solar Cells: Insights from Soft X-Ray Scattering
journal, May 2017
- Jiao, Xuechen; Ye, Long; Ade, Harald
- Advanced Energy Materials, Vol. 7, Issue 18
Disentangling the impact of side chains and fluorine substituents of conjugated donor polymers on the performance of photovoltaic blends
journal, January 2013
- Yang, Liqiang; Tumbleston, John R.; Zhou, Huaxing
- Energy Environ. Sci., Vol. 6, Issue 1
Importance of Domain Purity and Molecular Packing in Efficient Solution-Processed Small-Molecule Solar Cells
journal, December 2014
- Mukherjee, Subhrangsu; Proctor, Christopher M.; Tumbleston, John R.
- Advanced Materials, Vol. 27, Issue 6
A Narrow Optical Gap Small Molecule Acceptor for Organic Solar Cells
journal, September 2012
- Fang, Yuan; Pandey, Ajay K.; Nardes, Alexandre M.
- Advanced Energy Materials, Vol. 3, Issue 1
High-performance fullerene-free polymer solar cells with 6.31% efficiency
journal, January 2015
- Lin, Yuze; Zhang, Zhi-Guo; Bai, Huitao
- Energy & Environmental Science, Vol. 8, Issue 2
Charge generation and transport in efficient organic bulk heterojunction solar cells with a perylene acceptor
journal, January 2014
- Shivanna, Ravichandran; Shoaee, Safa; Dimitrov, Stoichko
- Energy Environ. Sci., Vol. 7, Issue 1
Sub-ns triplet state formation by non-geminate recombination in PSBTBT:PC 70 BM and PCPDTBT:PC 60 BM organic solar cells
journal, January 2015
- Etzold, Fabian; Howard, Ian A.; Forler, Nina
- Energy & Environmental Science, Vol. 8, Issue 5
Importance of the Donor:Fullerene Intermolecular Arrangement for High-Efficiency Organic Photovoltaics
journal, June 2014
- Graham, Kenneth R.; Cabanetos, Clement; Jahnke, Justin P.
- Journal of the American Chemical Society, Vol. 136, Issue 27
Manipulating Aggregation and Molecular Orientation in All-Polymer Photovoltaic Cells
journal, August 2015
- Ye, Long; Jiao, Xuechen; Zhou, Meng
- Advanced Materials, Vol. 27, Issue 39
Significance of Average Domain Purity and Mixed Domains on the Photovoltaic Performance of High-Efficiency Solution-Processed Small-Molecule BHJ Solar Cells
journal, July 2015
- Mukherjee, Subhrangsu; Proctor, Christopher M.; Bazan, Guillermo C.
- Advanced Energy Materials, Vol. 5, Issue 21
Competition between recombination and extraction of free charges determines the fill factor of organic solar cells
journal, May 2015
- Bartesaghi, Davide; Pérez, Irene del Carmen; Kniepert, Juliane
- Nature Communications, Vol. 6, Issue 1
Absolute Measurement of Domain Composition and Nanoscale Size Distribution Explains Performance in PTB7:PC 71 BM Solar Cells
journal, October 2012
- Collins, Brian A.; Li, Zhe; Tumbleston, John R.
- Advanced Energy Materials, Vol. 3, Issue 1
Selecting a Donor Polymer for Realizing Favorable Morphology in Efficient Non-fullerene Acceptor-based Solar Cells
journal, June 2014
- Ye, Long; Jiang, Wei; Zhao, Wenchao
- Small, Vol. 10, Issue 22
What Controls the Rate of Ultrafast Charge Transfer and Charge Separation Efficiency in Organic Photovoltaic Blends
journal, September 2016
- Jakowetz, Andreas C.; Böhm, Marcus L.; Zhang, Jiangbin
- Journal of the American Chemical Society, Vol. 138, Issue 36
Molecular Miscibility of Polymer−Fullerene Blends
journal, October 2010
- Collins, Brian A.; Gann, Eliot; Guignard, Lewis
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 21
Domain Purity, Miscibility, and Molecular Orientation at Donor/Acceptor Interfaces in High Performance Organic Solar Cells: Paths to Further Improvement
journal, March 2013
- Ma, Wei; Tumbleston, John R.; Wang, Ming
- Advanced Energy Materials, Vol. 3, Issue 7
The Importance of Fullerene Percolation in the Mixed Regions of Polymer-Fullerene Bulk Heterojunction Solar Cells
journal, October 2012
- Bartelt, Jonathan A.; Beiley, Zach M.; Hoke, Eric T.
- Advanced Energy Materials, Vol. 3, Issue 3
Interdiffusion of PCBM and P3HT Reveals Miscibility in a Photovoltaically Active Blend
journal, November 2010
- Treat, Neil D.; Brady, Michael A.; Smith, Gordon
- Advanced Energy Materials, Vol. 1, Issue 1, p. 82-89
11.4% Efficiency non-fullerene polymer solar cells with trialkylsilyl substituted 2D-conjugated polymer as donor
journal, December 2016
- Bin, Haijun; Gao, Liang; Zhang, Zhi-Guo
- Nature Communications, Vol. 7, Issue 1
A Facile Planar Fused-Ring Electron Acceptor for As-Cast Polymer Solar Cells with 8.71% Efficiency
journal, February 2016
- Lin, Yuze; He, Qiao; Zhao, Fuwen
- Journal of the American Chemical Society, Vol. 138, Issue 9
Design, Application, and Morphology Study of a New Photovoltaic Polymer with Strong Aggregation in Solution State
journal, December 2012
- Qian, Deping; Ye, Long; Zhang, Maojie
- Macromolecules, Vol. 45, Issue 24
Abnormal strong burn-in degradation of highly efficient polymer solar cells caused by spinodal donor-acceptor demixing
journal, February 2017
- Li, Ning; Perea, José Darío; Kassar, Thaer
- Nature Communications, Vol. 8, Issue 1
Efficient Charge Transfer and Fine-Tuned Energy Level Alignment in a THF-Processed Fullerene-Free Organic Solar Cell with 11.3% Efficiency
journal, November 2016
- Zheng, Zhong; Awartani, Omar M.; Gautam, Bhoj
- Advanced Materials, Vol. 29, Issue 5
Fullerene-Free Polymer Solar Cells with over 11% Efficiency and Excellent Thermal Stability
journal, April 2016
- Zhao, Wenchao; Qian, Deping; Zhang, Shaoqing
- Advanced Materials, Vol. 28, Issue 23
Quantification of Nano- and Mesoscale Phase Separation and Relation to Donor and Acceptor Quantum Efficiency, J sc , and FF in Polymer:Fullerene Solar Cells
journal, March 2014
- Ma, Wei; Tumbleston, John R.; Ye, Long
- Advanced Materials, Vol. 26, Issue 25
How High Local Charge Carrier Mobility and an Energy Cascade in a Three-Phase Bulk Heterojunction Enable >90% Quantum Efficiency
journal, December 2013
- Burke, Timothy M.; McGehee, Michael D.
- Advanced Materials, Vol. 26, Issue 12
Charge Generation Dynamics in Efficient All-Polymer Solar Cells: Influence of Polymer Packing and Morphology
journal, December 2015
- Gautam, Bhoj R.; Lee, Changyeon; Younts, Robert
- ACS Applied Materials & Interfaces, Vol. 7, Issue 50
Singlet Exciton Lifetimes in Conjugated Polymer Films for Organic Solar Cells
journal, January 2016
- Dimitrov, Stoichko; Schroeder, Bob; Nielsen, Christian
- Polymers, Vol. 8, Issue 1
Impact of Molecular Orientation and Spontaneous Interfacial Mixing on the Performance of Organic Solar Cells
journal, August 2015
- Ngongang Ndjawa, Guy O.; Graham, Kenneth R.; Li, Ruipeng
- Chemistry of Materials, Vol. 27, Issue 16