Gold as a modifier of metal nanoparticles: effect on structure and catalysis

Prati, Laura; Villa, Alberto; Jouve, Andrea; Beck, Andrea; Evangelisti, C.; Savara, Aditya Ashi

doi:10.1039/C7FD00223H

Title: Gold as a modifier of metal nanoparticles: effect on structure and catalysis

Abstract

Bimetallic gold based catalysts have been prepared using a sol immobilisation technique. Depending on the second metal different structure have been obtained.

Authors:

^[1];

^[1]; Jouve, Andrea ^[1]; Beck, Andrea ^[2];

^[3];

^[4]

Univ. degli Studi di Milano, Milano (Italy); CNR-ISTM, Milan (Italy)
Centre for Energy Research, Budapest (Hungary)
CNR-ISTM, Milan (Italy)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Fri Feb 23 00:00:00 EST 2018

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1440818

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Faraday Discussions

Additional Journal Information:: Journal Volume: 208; Journal ID: ISSN 1359-6640

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Prati, Laura, Villa, Alberto, Jouve, Andrea, Beck, Andrea, Evangelisti, C., and Savara, Aditya Ashi. Gold as a modifier of metal nanoparticles: effect on structure and catalysis.  United States: N. p., 2018. 
Web.  doi:10.1039/C7FD00223H.

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                    Prati, Laura, Villa, Alberto, Jouve, Andrea, Beck, Andrea, Evangelisti, C., & Savara, Aditya Ashi. Gold as a modifier of metal nanoparticles: effect on structure and catalysis.  United States.  https://doi.org/10.1039/C7FD00223H

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                    Prati, Laura, Villa, Alberto, Jouve, Andrea, Beck, Andrea, Evangelisti, C., and Savara, Aditya Ashi. Fri .  
"Gold as a modifier of metal nanoparticles: effect on structure and catalysis".  United States.  https://doi.org/10.1039/C7FD00223H.  https://www.osti.gov/servlets/purl/1440818.

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@article{osti_1440818,

  title        = {Gold as a modifier of metal nanoparticles: effect on structure and catalysis},

  author       = {Prati, Laura and Villa, Alberto and Jouve, Andrea and Beck, Andrea and Evangelisti, C. and Savara, Aditya Ashi},

  abstractNote = {Bimetallic gold based catalysts have been prepared using a sol immobilisation technique. Depending on the second metal different structure have been obtained.},

  doi          = {10.1039/C7FD00223H},

  journal      = {Faraday Discussions},

  number       = ,

  volume       = 208,

  place        = {United States},

  year         = {Fri Feb 23 00:00:00 EST 2018},

  month        = {Fri Feb 23 00:00:00 EST 2018}

}

Copy to clipboard

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https://doi.org/10.1039/C7FD00223H

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Cited by: 8 works

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Figures / Tables:

Figure 2: Representative TEM image of Pd/AC. B) Representative HRTEM image of a AuPd particle with insets showing the fast Fourier transformations (C). D) EDX representative spectrum taken from an individual single particle. The Au–Pd ratio is similar for each particle. The strong Cu signals are from the Cu gridmore »

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Works referencing / citing this record:

Perspectives on the design of nanoparticle systems for catalysis
journal, January 2018

Friend, Cynthia M.; Xu, Fang
Faraday Discussions, Vol. 208
DOI: 10.1039/c8fd00124c

Au-based bimetallic catalysts: how the synergy between two metals affects their catalytic activity
journal, January 2019

Sha, Jin; Paul, Sébastien; Dumeignil, Franck
RSC Advances, Vol. 9, Issue 51
DOI: 10.1039/c9ra06001d

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Title: Gold as a modifier of metal nanoparticles: effect on structure and catalysis

Abstract

Citation Formats

Figures / Tables:

Vapor phase hydrochlorination of acetylene: Correlation of catalytic activity of supported metal chloride catalysts journal, November 1985

Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide journal, February 1989

Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature far Below 0 °C journal, February 1987

Gold Catalysis journal, December 2006

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Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology journal, December 2003

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Supported gold nanoparticles as catalysts for organic reactions journal, January 2008

Catalysis by gold dispersed on supports: the importance of cationic gold journal, January 2008

Catalytically active gold on ordered titania supports journal, January 2008

Gold-Catalyzed Organic Transformations journal, August 2008

Nano-Gold Catalysis in Fine Chemical Synthesis journal, November 2011

Designing bimetallic catalysts for a green and sustainable future journal, January 2012

Selective oxidation of glycerol to glyceric acid using a gold catalyst in aqueous sodium hydroxide journal, March 2002

Liquid phase oxidation of glycerol over carbon supported gold catalysts journal, May 2005

Efficient chemoselective alcohol oxidation using oxygen as oxidant. Superior performance of gold over palladium catalysts journal, July 2006

Selective oxidation of glycerol with oxygen using mono and bimetallic catalysts based on Au, Pd and Pt metals journal, May 2005

Synergetic effect of platinum or palladium on gold catalyst in the selective oxidation of D-sorbitol journal, February 2005

Gold on Carbon as a New Catalyst for Selective Liquid Phase Oxidation of Diols journal, June 1998

Oxidation of glycerol using supported Pt, Pd and Au catalysts journal, February 2003

Selective oxidation of glycerol to sodium glycerate with gold-on-carbon catalyst: an insight into reaction selectivity journal, June 2004

Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts journal, June 2004

Selective liquid phase oxidation with supported metal nanoparticles journal, January 2012

Selective oxidation of alcohols and aldehydes over supported metal nanoparticles journal, January 2013

Seeded growth of robust SERS-active 2D Au@Ag nanoparticulate films journal, January 2008

One-Pot Synthesis of Oleylamine Coated AuAg Alloy NPs and Their Catalysis for CO Oxidation journal, February 2009

Electrocatalytic oxidation of glucose at gold–silver alloy, silver and gold nanoparticles in an alkaline solution journal, May 2006

Synergistic Effect in an Au−Ag Alloy Nanocatalyst: CO Oxidation journal, January 2005

Fabrication of Au–Ag Alloy Nanoprisms with Enhanced Catalytic Activity journal, November 2007

Effect of Ag-Doping on the Catalytic Activity of Polymer-Stabilized Au Clusters in Aerobic Oxidation of Alcohol journal, April 2007

AuPt Alloy Nanoparticles for CO-Tolerant Hydrogen Activation: Architectural Effects in Au-Pt Bimetallic Nanocatalysts journal, September 2007

Enhanced CO Tolerance for Hydrogen Activation in Au−Pt Dendritic Heteroaggregate Nanostructures journal, January 2006

Keggin ion-mediated synthesis of aqueous phase-pure Au@Pd and Au@Pt core–shell nanoparticles journal, January 2004

Synthesis and Characterization of Dendrimer Templated Supported Bimetallic Pt−Au Nanoparticles journal, October 2004

Bimetallic Gold/Palladium Catalysts: Correlation between Nanostructure and Synergistic Effects journal, May 2008

Designing Pd-on-Au Bimetallic Nanoparticle Catalysts for Trichloroethene Hydrodechlorination journal, March 2005

Improved Pd-on-Au bimetallic nanoparticle catalysts for aqueous-phase trichloroethene hydrodechlorination journal, December 2006

Bimetallic Palladium−Gold Nanostructures: Application in Ethanol Oxidation journal, August 2009

The Microcatalytic Hydrogenation of Benzene over Groups VIII and Ib Metals and Alloys journal, November 1966

Carbon dioxide reforming of methane on modified Ni/α-A12O3 catalysts journal, May 1996

AuRu/AC as an effective catalyst for hydrogenation reactions journal, January 2015

Pd and Pt catalysts modified by alloying with Au in the selective oxidation of alcohols journal, November 2006

Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO 2 Catalysts journal, January 2006

Strategies for Designing Supported Gold–Palladium Bimetallic Catalysts for the Direct Synthesis of Hydrogen Peroxide journal, October 2013

Bimetallic catalysts for upgrading of biomass to fuels and chemicals journal, January 2012

Glucoseoxidation using Au-containing bimetallic and trimetallic nanoparticles journal, January 2013

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Molecular Origin of the Selectivity Differences between Palladium and Gold-Palladium in Benzyl Alcohol Oxidation: Different Oxygen Adsorption Properties journal, December 2016

Benzyl Alcohol Oxidation on Carbon-Supported Pd Nanoparticles: Elucidating the Reaction Mechanism journal, September 2014

Gas phase hydrogenation of benzaldehyde over supported copper catalysts journal, December 2000

Reduction of Benzaldehyde on Metal Oxides journal, November 1997

The Effect of Metal-Support Interactions on the Hydrogenation of Benzaldehyde and Benzyl Alcohol journal, July 1997

Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts journal, September 2004

Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications Toward Biology, Catalysis, and Nanotechnology. journal, April 2004

Heterogeneous Gold-Based Catalysis for Green Chemistry: Low-Temperature CO Oxidation and Propene Oxidation journal, September 2007

Gold Catalysis journal, March 2007

Gold-Catalyzed Organic Reactions journal, October 2007

Perspectives on the design of nanoparticle systems for catalysis journal, January 2018

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Vapor phase hydrochlorination of acetylene: Correlation of catalytic activity of supported metal chloride catalysts
journal, November 1985

Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide
journal, February 1989

Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature far Below 0 °C
journal, February 1987

Gold Catalysis
journal, December 2006

Gold-Catalyzed Organic Reactions
journal, July 2007

Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology
journal, December 2003

Heterogeneous Gold-Based Catalysis for Green Chemistry: Low-Temperature CO Oxidation and Propene Oxidation
journal, June 2007

Selective oxidation using gold
journal, January 2008

Supported gold nanoparticles as catalysts for organic reactions
journal, January 2008

Catalysis by gold dispersed on supports: the importance of cationic gold
journal, January 2008

Catalytically active gold on ordered titania supports
journal, January 2008

Gold-Catalyzed Organic Transformations
journal, August 2008

Nano-Gold Catalysis in Fine Chemical Synthesis
journal, November 2011

Designing bimetallic catalysts for a green and sustainable future
journal, January 2012

Selective oxidation of glycerol to glyceric acid using a gold catalyst in aqueous sodium hydroxide
journal, March 2002

Liquid phase oxidation of glycerol over carbon supported gold catalysts
journal, May 2005

Efficient chemoselective alcohol oxidation using oxygen as oxidant. Superior performance of gold over palladium catalysts
journal, July 2006

Selective oxidation of glycerol with oxygen using mono and bimetallic catalysts based on Au, Pd and Pt metals
journal, May 2005

Synergetic effect of platinum or palladium on gold catalyst in the selective oxidation of D-sorbitol
journal, February 2005

Gold on Carbon as a New Catalyst for Selective Liquid Phase Oxidation of Diols
journal, June 1998

Oxidation of glycerol using supported Pt, Pd and Au catalysts
journal, February 2003

Selective oxidation of glycerol to sodium glycerate with gold-on-carbon catalyst: an insight into reaction selectivity
journal, June 2004

Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts
journal, June 2004

Selective liquid phase oxidation with supported metal nanoparticles
journal, January 2012

Selective oxidation of alcohols and aldehydes over supported metal nanoparticles
journal, January 2013

Seeded growth of robust SERS-active 2D Au@Ag nanoparticulate films
journal, January 2008

One-Pot Synthesis of Oleylamine Coated AuAg Alloy NPs and Their Catalysis for CO Oxidation
journal, February 2009

Electrocatalytic oxidation of glucose at gold–silver alloy, silver and gold nanoparticles in an alkaline solution
journal, May 2006

Synergistic Effect in an Au−Ag Alloy Nanocatalyst: CO Oxidation
journal, January 2005

Fabrication of Au–Ag Alloy Nanoprisms with Enhanced Catalytic Activity
journal, November 2007

Effect of Ag-Doping on the Catalytic Activity of Polymer-Stabilized Au Clusters in Aerobic Oxidation of Alcohol
journal, April 2007

AuPt Alloy Nanoparticles for CO-Tolerant Hydrogen Activation: Architectural Effects in Au-Pt Bimetallic Nanocatalysts
journal, September 2007

Enhanced CO Tolerance for Hydrogen Activation in Au−Pt Dendritic Heteroaggregate Nanostructures
journal, January 2006

Keggin ion-mediated synthesis of aqueous phase-pure Au@Pd and Au@Pt core–shell nanoparticles
journal, January 2004

Synthesis and Characterization of Dendrimer Templated Supported Bimetallic Pt−Au Nanoparticles
journal, October 2004

Bimetallic Gold/Palladium Catalysts: Correlation between Nanostructure and Synergistic Effects
journal, May 2008

Designing Pd-on-Au Bimetallic Nanoparticle Catalysts for Trichloroethene Hydrodechlorination
journal, March 2005

Improved Pd-on-Au bimetallic nanoparticle catalysts for aqueous-phase trichloroethene hydrodechlorination
journal, December 2006

Bimetallic Palladium−Gold Nanostructures: Application in Ethanol Oxidation
journal, August 2009

The Microcatalytic Hydrogenation of Benzene over Groups VIII and Ib Metals and Alloys
journal, November 1966

Carbon dioxide reforming of methane on modified Ni/α-A12O3 catalysts
journal, May 1996

AuRu/AC as an effective catalyst for hydrogenation reactions
journal, January 2015

Pd and Pt catalysts modified by alloying with Au in the selective oxidation of alcohols
journal, November 2006

Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO ₂ Catalysts
journal, January 2006

Strategies for Designing Supported Gold–Palladium Bimetallic Catalysts for the Direct Synthesis of Hydrogen Peroxide
journal, October 2013

Bimetallic catalysts for upgrading of biomass to fuels and chemicals
journal, January 2012

Glucoseoxidation using Au-containing bimetallic and trimetallic nanoparticles
journal, January 2013

Single-phase bimetallic system for the selective oxidation of glycerol to glycerate
journal, January 2006

Molecular Origin of the Selectivity Differences between Palladium and Gold-Palladium in Benzyl Alcohol Oxidation: Different Oxygen Adsorption Properties
journal, December 2016

Benzyl Alcohol Oxidation on Carbon-Supported Pd Nanoparticles: Elucidating the Reaction Mechanism
journal, September 2014

Gas phase hydrogenation of benzaldehyde over supported copper catalysts
journal, December 2000

Reduction of Benzaldehyde on Metal Oxides
journal, November 1997

The Effect of Metal-Support Interactions on the Hydrogenation of Benzaldehyde and Benzyl Alcohol
journal, July 1997

Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts
journal, September 2004

Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications Toward Biology, Catalysis, and Nanotechnology.
journal, April 2004

Heterogeneous Gold-Based Catalysis for Green Chemistry: Low-Temperature CO Oxidation and Propene Oxidation
journal, September 2007

Gold Catalysis
journal, March 2007

Gold-Catalyzed Organic Reactions
journal, October 2007

Perspectives on the design of nanoparticle systems for catalysis
journal, January 2018

Au-based bimetallic catalysts: how the synergy between two metals affects their catalytic activity
journal, January 2019