DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Sustainable one step process for making carbon-free TiO 2 anodes and sodium-ion battery electrochemistry

Abstract

The ultra durable monolithic dendritic anatase TiO 2 provides a mechanistic inner-view via a rotational moiré pattern, resulting in 99.55% coulombic efficiency with only 41 mV polarization loss at the 1000 th cycle, while retaining the columnar morphology.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Aerosol and Air Quality Research Laboratory, Department of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, St. Louis, USA
  2. Electrochemical Energy Laboratory, Department of Energy Science and Engineering, Indian Institute of Technology Bombay, Mumbai, India
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1438088
Grant/Contract Number:  
DE AC36-08G028308
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Sustainable Energy & Fuels
Additional Journal Information:
Journal Name: Sustainable Energy & Fuels Journal Volume: 2 Journal Issue: 7; Journal ID: ISSN 2398-4902
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Chadha, Tandeep S., Dutta, Prasit Kumar, Raliya, Ramesh, Mitra, Sagar, and Biswas, Pratim. Sustainable one step process for making carbon-free TiO 2 anodes and sodium-ion battery electrochemistry. United Kingdom: N. p., 2018. Web. doi:10.1039/C8SE00082D.
Chadha, Tandeep S., Dutta, Prasit Kumar, Raliya, Ramesh, Mitra, Sagar, & Biswas, Pratim. Sustainable one step process for making carbon-free TiO 2 anodes and sodium-ion battery electrochemistry. United Kingdom. https://doi.org/10.1039/C8SE00082D
Chadha, Tandeep S., Dutta, Prasit Kumar, Raliya, Ramesh, Mitra, Sagar, and Biswas, Pratim. Mon . "Sustainable one step process for making carbon-free TiO 2 anodes and sodium-ion battery electrochemistry". United Kingdom. https://doi.org/10.1039/C8SE00082D.
@article{osti_1438088,
title = {Sustainable one step process for making carbon-free TiO 2 anodes and sodium-ion battery electrochemistry},
author = {Chadha, Tandeep S. and Dutta, Prasit Kumar and Raliya, Ramesh and Mitra, Sagar and Biswas, Pratim},
abstractNote = {The ultra durable monolithic dendritic anatase TiO 2 provides a mechanistic inner-view via a rotational moiré pattern, resulting in 99.55% coulombic efficiency with only 41 mV polarization loss at the 1000 th cycle, while retaining the columnar morphology.},
doi = {10.1039/C8SE00082D},
journal = {Sustainable Energy & Fuels},
number = 7,
volume = 2,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C8SE00082D

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Graphene-Rich Wrapped Petal-Like Rutile TiO 2 tuned by Carbon Dots for High-Performance Sodium Storage
journal, August 2016

  • Zhang, Yan; Foster, Christopher W.; Banks, Craig E.
  • Advanced Materials, Vol. 28, Issue 42
  • DOI: 10.1002/adma.201601621

High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications
journal, June 2006

  • Taberna, P. L.; Mitra, S.; Poizot, P.
  • Nature Materials, Vol. 5, Issue 7, p. 567-573
  • DOI: 10.1038/nmat1672

Amorphous TiO 2 Nanotube Anode for Rechargeable Sodium Ion Batteries
journal, September 2011

  • Xiong, Hui; Slater, Michael D.; Balasubramanian, Mahalingam
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 20
  • DOI: 10.1021/jz2012066

Model based prediction of nanostructured thin film morphology in an aerosol chemical vapor deposition process
journal, February 2017


Self-Assembled TiO 2 –Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion
journal, March 2009

  • Wang, Donghai; Choi, Daiwon; Li, Juan
  • ACS Nano, Vol. 3, Issue 4, p. 907-914
  • DOI: 10.1021/nn900150y

Anatase Titania Nanorods as an Intercalation Anode Material for Rechargeable Sodium Batteries
journal, January 2014

  • Kim, Ki-Tae; Ali, Ghulam; Chung, Kyung Yoon
  • Nano Letters, Vol. 14, Issue 2
  • DOI: 10.1021/nl402747x

Prussian Blue@C Composite as an Ultrahigh-Rate and Long-Life Sodium-Ion Battery Cathode
journal, May 2016

  • Jiang, Yinzhu; Yu, Shenglan; Wang, Baoqi
  • Advanced Functional Materials, Vol. 26, Issue 29
  • DOI: 10.1002/adfm.201600747

One-Dimensional, Additive-Free, Single-Crystal TiO 2 Nanostructured Anodes Synthesized by a Single-Step Aerosol Process for High-Rate Lithium-Ion Batteries
journal, September 2014

  • Chadha, Tandeep S.; Tripathi, Alok M.; Mitra, Sagar
  • Energy Technology, Vol. 2, Issue 11
  • DOI: 10.1002/ente.201402054

Electrochemical sodium storage of TiO2(B) nanotubes for sodium ion batteries
journal, January 2013

  • Huang, J. P.; Yuan, D. D.; Zhang, H. Z.
  • RSC Advances, Vol. 3, Issue 31
  • DOI: 10.1039/c3ra42413h

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

  • Chan, Candace K.; Peng, Hailin; Liu, Gao
  • Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35
  • DOI: 10.1038/nnano.2007.411

Growth of single crystal, oriented SnO 2 nanocolumn arrays by aerosol chemical vapour deposition
journal, January 2016

  • Haddad, K.; Abokifa, A.; Kavadiya, S.
  • CrystEngComm, Vol. 18, Issue 39
  • DOI: 10.1039/C6CE01443G

Room-temperature sodium-ion batteries: Improving the rate capability of carbon anode materials by templating strategies
journal, January 2011

  • Wenzel, Sebastian; Hara, Takeshi; Janek, Jürgen
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01744f

Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
journal, January 2012

  • Palomares, Verónica; Serras, Paula; Villaluenga, Irune
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee02781j

Layer-by-Layer Na 3 V 2 (PO 4 ) 3 Embedded in Reduced Graphene Oxide as Superior Rate and Ultralong-Life Sodium-Ion Battery Cathode
journal, May 2016


High energy density lithium cells
journal, February 1976

  • Besenhard, J. O.; Eichinger, G.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 68, Issue 1
  • DOI: 10.1016/S0022-0728(76)80298-7

Unfolding the Mechanism of Sodium Insertion in Anatase TiO 2 Nanoparticles
journal, August 2014

  • Wu, Liming; Bresser, Dominic; Buchholz, Daniel
  • Advanced Energy Materials, Vol. 5, Issue 2
  • DOI: 10.1002/aenm.201401142

Cycle Life of Commercial Lithium-Ion Batteries with Lithium Titanium Oxide Anodes in Electric Vehicles
journal, July 2014

  • Han, Xuebing; Ouyang, Minggao; Lu, Languang
  • Energies, Vol. 7, Issue 8
  • DOI: 10.3390/en7084895

Metal-Organic Framework-Derived Materials for Sodium Energy Storage
journal, December 2017


Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

Sodium-ion batteries: present and future
journal, January 2017

  • Hwang, Jang-Yeon; Myung, Seung-Taek; Sun, Yang-Kook
  • Chemical Society Reviews, Vol. 46, Issue 12
  • DOI: 10.1039/C6CS00776G

Long-Cycle-Life Na-Ion Anodes Based on Amorphous Titania Nanotubes—Interfaces and Diffusion
journal, November 2015

  • Prutsch, Denise; Wilkening, Martin; Hanzu, Ilie
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 46
  • DOI: 10.1021/acsami.5b07508

In Situ X-Ray Diffraction of Lithium Intercalation in Nanostructured and Thin Film Anatase TiO[sub 2]
journal, January 1999

  • van de Krol, Roel
  • Journal of The Electrochemical Society, Vol. 146, Issue 9
  • DOI: 10.1149/1.1392447

Tin-Nanoparticles Encapsulated in Elastic Hollow Carbon Spheres for High-Performance Anode Material in Lithium-Ion Batteries
journal, March 2008


Efficient sodium storage: Experimental study of anode with additive-free ether-based electrolyte system
journal, May 2017