Homoleptic uranium and lanthanide phosphinodiboranates

Blake, Anastasia V.; Fetrow, Taylor V.; Theiler, Zachary J.; Vlaisavljevich, Bess; Daly, Scott R.

doi:10.1039/C8CC02862A

Title: Homoleptic uranium and lanthanide phosphinodiboranates

Abstract

The synthesis and structures of a new class of homoleptic f-metal borohydride complexes (phosphinodiboranates) are described with U, Nd, and Er.

Authors:

Blake, Anastasia V. ^[1]; Fetrow, Taylor V. ^[1]; Theiler, Zachary J. ^[1];

^[2];

^[1]

Department of Chemistry, The University of Iowa, Iowa City, USA
Department of Chemistry, University of South Dakota, Vermillion, USA

Publication Date:: Mon Jan 01 00:00:00 EST 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1437877

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Chemical Communications

Additional Journal Information:: Journal Name: Chemical Communications Journal Volume: 54 Journal Issue: 44; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Blake, Anastasia V., Fetrow, Taylor V., Theiler, Zachary J., Vlaisavljevich, Bess, and Daly, Scott R. Homoleptic uranium and lanthanide phosphinodiboranates.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C8CC02862A.

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                    Blake, Anastasia V., Fetrow, Taylor V., Theiler, Zachary J., Vlaisavljevich, Bess, & Daly, Scott R. Homoleptic uranium and lanthanide phosphinodiboranates.  United Kingdom.  https://doi.org/10.1039/C8CC02862A

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                    Blake, Anastasia V., Fetrow, Taylor V., Theiler, Zachary J., Vlaisavljevich, Bess, and Daly, Scott R. Mon .  
"Homoleptic uranium and lanthanide phosphinodiboranates".  United Kingdom.  https://doi.org/10.1039/C8CC02862A.

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@article{osti_1437877,

  title        = {Homoleptic uranium and lanthanide phosphinodiboranates},

  author       = {Blake, Anastasia V. and Fetrow, Taylor V. and Theiler, Zachary J. and Vlaisavljevich, Bess and Daly, Scott R.},

  abstractNote = {The synthesis and structures of a new class of homoleptic f-metal borohydride complexes (phosphinodiboranates) are described with U, Nd, and Er.},

  doi          = {10.1039/C8CC02862A},

  journal      = {Chemical Communications},

  number       = 44,

  volume       = 54,

  place        = {United Kingdom},

  year         = {Mon Jan 01 00:00:00 EST 2018},

  month        = {Mon Jan 01 00:00:00 EST 2018}

}

Copy to clipboard

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Title: Homoleptic uranium and lanthanide phosphinodiboranates

Abstract

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Formation of the monoanion [Ar*P(BH3)(µ-BH2)2H]– with a symmetrically bridging hydride from the attempted synthesis of the dianion [Ar*P(BH3)3]2– journal, January 2001

Synthesis and Characterization of Calcium N , N -Dimethylaminodiboranates as Possible Chemical Vapor Deposition Precursors journal, December 2013

Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr journal, April 1994

Uranium(iv) amido-borohydrides as highly active diene polymerisation catalysts journal, January 2013

Synthesis, structures and stabilities of thioanisole-functionalised phosphido-borane complexes of the alkali metals journal, January 2011

Uranium(IV) Borohydride 1 journal, January 1953

The Methyl Derivatives of Uranium(IV) Borohydride 1 journal, January 1953

Improved Synthesis of Bis(borano)hypophosphite Salts journal, September 2010

Uranium–hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(iii)
journal, January 2010

Phosphanylborohydrides: First Assessment of the Relative Lewis Basicities of [BH3PPh2]–, CH3PPh2, and HPPh2
journal, May 2006

Lanthanide N , N -Dimethylaminodiboranates: Highly Volatile Precursors for the Deposition of Lanthanide-Containing Thin Films
journal, February 2010

Lanthanide(III) and Actinide(III) Complexes [M(BH ₄ ) ₂ (THF) ₅ ][BPh ₄ ] and [M(BH ₄ ) ₂ (18-crown-6)][BPh ₄ ] (M = Nd, Ce, U): Synthesis, Crystal Structure, and Density Functional Theory Investigation of the Covalent Contribution to Metal-Borohydride Bonding
journal, January 2009

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Synthesis, Characterization, and Structures of Divalent Europium and Ytterbium N , N -Dimethylaminodiboranates
journal, May 2010

Bis(borano)hypophosphite-based ionic liquids as ultrafast-igniting hypergolic fuels
journal, January 2016

Phosphido-Borane and Phosphido-Bis(Borane) Complexes of the Alkali Metals, a Comparative Study
journal, January 2013

Tetrahydroborate complexes of uranium with 2-(diphenylphosphino)pyridine
journal, January 1984

Synthesis and crystal structure of tricyclopentadienyl(cyclooctane-1,5-diyl)-uranium dihydroborate
journal, April 1987

Application of Imidazole-2-thione Substituents in Low-Coordinate Phosphorus Chemistry - Probing the Scope: Application of Imidazole-2-thione Substituents in Low-Coordinate Phosphorus Chemistry - Probing the Scope
journal, July 2016

(18-Crown-6)potassium di- tert -butylphospanylbisborohydride
journal, November 2006

An Operationally Simple Method for Separating the Rare-Earth Elements Neodymium and Dysprosium
journal, May 2015

Synthesis and reactivity of iron(II) hydride complexes containing diphenylphosphine ligands
journal, August 2015

Lanthanide N , N -Dimethylaminodiboranates as a New Class of Highly Volatile Chemical Vapor Deposition Precursors
journal, June 2012

Metallboranate und Boranatometallate. 13 [1]. Darstellung und Molek�lstruktur von Uran(III)-tetrahydridoborat-3-Tetrahydrofuran
journal, December 1986

Reaktion von Phosphinboran, Phenylphosphinboran und Phosphoniumjodid mit Natriumtetrahydridoborat
journal, January 1970

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010

Accomplishing simple, solubility-based separations of rare earth elements with complexes bearing size-sensitive molecular apertures
journal, December 2016

Preparation and structure of ammonia and alkylamine addition compounds of phosphine diborane, B2H6.PH3.NR3
journal, October 1967

Synthesis and Structural Diversity of Barium ( N , N -Dimethylamino)diboranates
journal, June 2012

Syntheses and crystal structures of the tetrakis(methyltrihydroborato) compounds of zirconium(IV), thorium(IV), uranium(IV), and neptunium(IV)
journal, August 1983

Preparation and Properties of Diborane Diphosphine
journal, April 1940

1169. The preparation and some reactions of potassium phosphinidodiborane and potassium dimethylphosphinidobis(trimethylboron)
journal, January 1965

Synthese und Struktur von assoziiertem μ-Phosphinodiboran und von phosphorsubstituierten Derivaten
journal, July 1974

A fully direct RI-HF algorithm: Implementation, optimised auxiliary basis sets, demonstration of accuracy and efficiency
journal, August 2002

Covalent transition metal, lanthanide, and actinide tetrahydroborate complexes
journal, April 1977

Synthesis, Structure, and Reactions of Hydride, Borohydride, and Aluminohydride Compounds of the f-Elements
journal, October 1997

Preparation and properties of the actinide borohydrides: protactinium(IV), neptunium(IV), and plutonium(IV) borohydrides
journal, March 1978

Highly Volatile Magnesium Complexes with the Aminodiboranate Anion, a New Chelating Borohydride. Synthesis and Characterization of Mg(H ₃ BNMe ₂ BH ₃ ) ₂ and Related Compounds
journal, June 2010

Synthesis, Characterization, and Structures of Uranium(III) N , N -Dimethylaminodiboranates
journal, June 2010

The Preparation and Properties of the Group IV-B Metal Borohydrides
journal, July 1949

RI-MP2: optimized auxiliary basis sets and demonstration of efficiency
journal, September 1998

New Developments in the Chemistry of Diborane and the Borohydrides. I. General Summary ¹
journal, January 1953

Preparation and properties of lithium bis(borane)dimethylphosphide(1-)
journal, March 1971

Climbing the Density Functional Ladder: Nonempirical Meta–Generalized Gradient Approximation Designed for Molecules and Solids
journal, September 2003

Synthesis and Properties of a Fifteen-Coordinate Complex: The Thorium Aminodiboranate [Th(H3BNMe2BH3)4]
journal, March 2010

Uranium Hydridoborates: Synthesis, Magnetism, and X-ray/Neutron Diffraction Structures
journal, August 2015

New Chemistry from an Old Reagent: Mono- and Dinuclear Macrocyclic Uranium(III) Complexes from [U(BH ₄ ) ₃ (THF) ₂ ]
journal, July 2014

Metal borohydrides and derivatives – synthesis, structure and properties
journal, January 2017

Volatilities of Actinide and Lanthanide N , N -Dimethylaminodiboranate Chemical Vapor Deposition Precursors: A DFT Study
journal, October 2012

Zur Chemie der Bor?Phosphor-Verbindungen
journal, March 1970

Novel hydroboration of highly substituted alkenes catalysed by borohydride complexes of uranium, neodymium and zirconium
journal, January 1995

Formation of the monoanion [ArP(BH3)(µ-BH2)2H]– with a symmetrically bridging hydride from the attempted synthesis of the dianion [ArP(BH3)3]2–
journal, January 2001

Synthesis and Characterization of Calcium N , N -Dimethylaminodiboranates as Possible Chemical Vapor Deposition Precursors
journal, December 2013

Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr
journal, April 1994

Uranium(iv) amido-borohydrides as highly active diene polymerisation catalysts
journal, January 2013

Synthesis, structures and stabilities of thioanisole-functionalised phosphido-borane complexes of the alkali metals
journal, January 2011

Uranium(IV) Borohydride ¹
journal, January 1953

The Methyl Derivatives of Uranium(IV) Borohydride ¹
journal, January 1953

Improved Synthesis of Bis(borano)hypophosphite Salts
journal, September 2010