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Title: Modeling uranium(VI) adsorption onto montmorillonite under varying carbonate concentrations: A surface complexation model accounting for the spillover effect on surface potential

Abstract

The prediction of U(VI) adsorption onto montmorillonite clay is confounded by the complexities of: (1) the montmorillonite structure in terms of adsorption sites on basal and edge surfaces, and the complex interactions between the electrical double layers at these surfaces, and (2) U(VI) solution speciation, which can include cationic, anionic and neutral species. Previous U(VI)-montmorillonite adsorption and modeling studies have typically expanded classical surface complexation modeling approaches, initially developed for simple oxides, to include both cation exchange and surface complexation reactions. However, previous models have not taken into account the unique characteristics of electrostatic surface potentials that occur at montmorillonite edge sites, where the electrostatic surface potential of basal plane cation exchange sites influences the surface potential of neighboring edge sites (‘spillover’ effect).

Authors:
; ; ;
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE)
OSTI Identifier:
1437748
Alternate Identifier(s):
OSTI ID: 1419466
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Geochimica et Cosmochimica Acta
Additional Journal Information:
Journal Name: Geochimica et Cosmochimica Acta Journal Volume: 220 Journal Issue: C; Journal ID: ISSN 0016-7037
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
58 GEOSCIENCES; 54 ENVIRONMENTAL SCIENCES; Uranium; Adsorption; Clay; Montmorilonite; Spillover; Surface complexation modeling

Citation Formats

Tournassat, C., Tinnacher, R. M., Grangeon, S., and Davis, J. A. Modeling uranium(VI) adsorption onto montmorillonite under varying carbonate concentrations: A surface complexation model accounting for the spillover effect on surface potential. United States: N. p., 2018. Web. doi:10.1016/j.gca.2017.09.049.
Tournassat, C., Tinnacher, R. M., Grangeon, S., & Davis, J. A. Modeling uranium(VI) adsorption onto montmorillonite under varying carbonate concentrations: A surface complexation model accounting for the spillover effect on surface potential. United States. doi:10.1016/j.gca.2017.09.049.
Tournassat, C., Tinnacher, R. M., Grangeon, S., and Davis, J. A. Mon . "Modeling uranium(VI) adsorption onto montmorillonite under varying carbonate concentrations: A surface complexation model accounting for the spillover effect on surface potential". United States. doi:10.1016/j.gca.2017.09.049.
@article{osti_1437748,
title = {Modeling uranium(VI) adsorption onto montmorillonite under varying carbonate concentrations: A surface complexation model accounting for the spillover effect on surface potential},
author = {Tournassat, C. and Tinnacher, R. M. and Grangeon, S. and Davis, J. A.},
abstractNote = {The prediction of U(VI) adsorption onto montmorillonite clay is confounded by the complexities of: (1) the montmorillonite structure in terms of adsorption sites on basal and edge surfaces, and the complex interactions between the electrical double layers at these surfaces, and (2) U(VI) solution speciation, which can include cationic, anionic and neutral species. Previous U(VI)-montmorillonite adsorption and modeling studies have typically expanded classical surface complexation modeling approaches, initially developed for simple oxides, to include both cation exchange and surface complexation reactions. However, previous models have not taken into account the unique characteristics of electrostatic surface potentials that occur at montmorillonite edge sites, where the electrostatic surface potential of basal plane cation exchange sites influences the surface potential of neighboring edge sites (‘spillover’ effect).},
doi = {10.1016/j.gca.2017.09.049},
journal = {Geochimica et Cosmochimica Acta},
number = C,
volume = 220,
place = {United States},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1016/j.gca.2017.09.049

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Cited by: 12 works
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