Microstructural evolution and deformation behavior of Al-Cu alloys: A Transmission X-ray Microscopy (TXM) and micropillar compression study
Abstract
In this paper, a unique approach to correlating an evolving 3D microstructure in an Al-Cu alloy and its micro-scale mechanical properties has been introduced. Using these nanoscale three-dimensional microstructures derived from Transmission X-ray Microscopy (TXM), individual contributions from different strengthening mechanisms were quantified. The spatial distribution and morphology of the individual θ' and θ phases were seen to play an important role in influencing dislocation storage. Uniaxial micro-compression experiments were used to quantify the stress-strain response of the alloy at different aging times. Transmission electron microscopy (TEM) aided in discerning dislocation activity at these precipitates. A model is proposed to accurately predict the variation in yield stress by using appropriate morphological parameters from the 3D microstructure and its validity has been corroborated using experimental measurements. Distributions of 2D and 3D inter-precipitate spacing were seen to provide crucial insights on influencing deformation in such precipitation-strengthened alloys. In conclusion, the transition in deformation behavior and origin of numerous strain bursts were investigated using in situ micropillar compression testing.
- Authors:
-
- Arizona State Univ., Tempe, AZ (United States). Center for 4D Materials Science
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States); Arizona State Univ., Tempe, AZ (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); US Army Research Office (ARO)
- OSTI Identifier:
- 1437370
- Alternate Identifier(s):
- OSTI ID: 1549107
- Grant/Contract Number:
- AC02-06CH11357; W911NF1410550
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Acta Materialia
- Additional Journal Information:
- Journal Volume: 144; Journal ID: ISSN 1359-6454
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; aluminum alloys; nanoindentation; TEM; FIB; Transmission X-ray Microscopy (TXM)
Citation Formats
Kaira, C. Shashank, Kantzos, Christopher, Williams, Jason J., De Andrade, Vincent, De Carlo, Francesco, and Chawla, Nikhilesh. Microstructural evolution and deformation behavior of Al-Cu alloys: A Transmission X-ray Microscopy (TXM) and micropillar compression study. United States: N. p., 2017.
Web. doi:10.1016/j.actamat.2017.11.009.
Kaira, C. Shashank, Kantzos, Christopher, Williams, Jason J., De Andrade, Vincent, De Carlo, Francesco, & Chawla, Nikhilesh. Microstructural evolution and deformation behavior of Al-Cu alloys: A Transmission X-ray Microscopy (TXM) and micropillar compression study. United States. https://doi.org/10.1016/j.actamat.2017.11.009
Kaira, C. Shashank, Kantzos, Christopher, Williams, Jason J., De Andrade, Vincent, De Carlo, Francesco, and Chawla, Nikhilesh. Tue .
"Microstructural evolution and deformation behavior of Al-Cu alloys: A Transmission X-ray Microscopy (TXM) and micropillar compression study". United States. https://doi.org/10.1016/j.actamat.2017.11.009. https://www.osti.gov/servlets/purl/1437370.
@article{osti_1437370,
title = {Microstructural evolution and deformation behavior of Al-Cu alloys: A Transmission X-ray Microscopy (TXM) and micropillar compression study},
author = {Kaira, C. Shashank and Kantzos, Christopher and Williams, Jason J. and De Andrade, Vincent and De Carlo, Francesco and Chawla, Nikhilesh},
abstractNote = {In this paper, a unique approach to correlating an evolving 3D microstructure in an Al-Cu alloy and its micro-scale mechanical properties has been introduced. Using these nanoscale three-dimensional microstructures derived from Transmission X-ray Microscopy (TXM), individual contributions from different strengthening mechanisms were quantified. The spatial distribution and morphology of the individual θ' and θ phases were seen to play an important role in influencing dislocation storage. Uniaxial micro-compression experiments were used to quantify the stress-strain response of the alloy at different aging times. Transmission electron microscopy (TEM) aided in discerning dislocation activity at these precipitates. A model is proposed to accurately predict the variation in yield stress by using appropriate morphological parameters from the 3D microstructure and its validity has been corroborated using experimental measurements. Distributions of 2D and 3D inter-precipitate spacing were seen to provide crucial insights on influencing deformation in such precipitation-strengthened alloys. In conclusion, the transition in deformation behavior and origin of numerous strain bursts were investigated using in situ micropillar compression testing.},
doi = {10.1016/j.actamat.2017.11.009},
journal = {Acta Materialia},
number = ,
volume = 144,
place = {United States},
year = {Tue Nov 07 00:00:00 EST 2017},
month = {Tue Nov 07 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Structure and energetics of the coherent interface between the θ′ precipitate phase and aluminium in Al–Cu
journal, October 2011
- Bourgeois, Laure; Dwyer, Christian; Weyland, Matthew
- Acta Materialia, Vol. 59, Issue 18
Mechanical properties enhanced by deformation-modified precipitation of θ′-phase approximants in an Al-Cu alloy
journal, October 2016
- Ma, P. P.; Liu, C. H.; Wu, C. L.
- Materials Science and Engineering: A, Vol. 676
Small-volume aluminum alloys with native oxide shell deliver unprecedented strength and toughness
journal, March 2017
- Li, Shi-Hao; Han, Wei-Zhong; Li, Ju
- Acta Materialia, Vol. 126
Multiscale modeling of θ′ precipitation in Al–Cu binary alloys
journal, June 2004
- Vaithyanathan, V.; Wolverton, C.; Chen, L. Q.
- Acta Materialia, Vol. 52, Issue 10
The effect of time and temperature on the precipitation behavior and hardness of Al–4wt%Cu alloy using design of experiments
journal, August 2008
- Hassan, Adel Mahmood; Bataineh, Omar M.; Abed, Khalil M.
- Journal of Materials Processing Technology, Vol. 204, Issue 1-3
Interrupted aging and secondary precipitation in aluminium alloys
journal, November 2003
- Lumley, R. N.; Polmear, I. J.; Morton, A. J.
- Materials Science and Technology, Vol. 19, Issue 11
The coarsening behaviour of θ″ and θ′ precipitates in two Al-Cu alloys
journal, December 1971
- Boyd, J. D.; Nicholson, R. B.
- Acta Metallurgica, Vol. 19, Issue 12
Mechanisms of formation of θ and dissolution of θ′ precipitates in an Al-4% Cu alloy
journal, February 1966
- Laird, C.; Aaronson, H. I.
- Acta Metallurgica, Vol. 14, Issue 2
Precipitation in thin foils of Al-4 wt.% Cu alloy—II. Growth kinetics of θ precipitates
journal, January 1975
- Kang, S. K.; Laird, C.
- Acta Metallurgica, Vol. 23, Issue 1
Coarsening of θ′ plates in al-cu alloys—I. experimental determination of mechanisms
journal, December 1981
- Merle, P.; Fouquet, F.
- Acta Metallurgica, Vol. 29, Issue 12
Structure of Age-Hardened Aluminium-Copper Alloys
journal, September 1938
- Guinier, AndrÉ
- Nature, Vol. 142, Issue 3595
Age-hardening of copper-aluminium alloys
journal, January 1940
- Preston, G. D.
- Proceedings of the Physical Society, Vol. 52, Issue 1
Predicting slip behavior in alloys containing shearable and strong particles
journal, September 1993
- Blankenship, C. P.; Hornbogen, E.; Starke, E. A.
- Materials Science and Engineering: A, Vol. 169, Issue 1-2
Distribution of plastic strain in alloys containing small particles
journal, June 1975
- Hornbogen, Erhard; Zum Gahr, Karl-Heinz
- Metallography, Vol. 8, Issue 3
Strengthening effect of unshearable particles of finite size: a computer experimental study
journal, September 1999
- Zhu, A. W.; Starke, E. A.
- Acta Materialia, Vol. 47, Issue 11
Computer experiment on superposition of strengthening effects of different particles
journal, April 1999
- Zhu, A. W.; Csontos, A.; Starke, E. A.
- Acta Materialia, Vol. 47, Issue 6
Precipitation hardening
journal, December 1985
- Ardell, A. J.
- Metallurgical Transactions A, Vol. 16, Issue 12
Microstructural design of high-strength aluminum alloys
journal, December 1998
- Nie, J. F.; Muddle, B. C.
- Journal of Phase Equilibria, Vol. 19, Issue 6
On the strengthening response of aluminum alloys containing shear-resistant plate-shaped precipitates
journal, December 2008
- da Costa Teixeira, J.; Cram, D. G.; Bourgeois, L.
- Acta Materialia, Vol. 56, Issue 20
On the form of the age-hardening response in high strength aluminium alloys
journal, December 2001
- Nie, J. F.; Muddle, B. C.
- Materials Science and Engineering: A, Vol. 319-321
Strengthening of an Al–Cu–Sn alloy by deformation-resistant precipitate plates
journal, August 2008
- Nie, J. F.; Muddle, B. C.
- Acta Materialia, Vol. 56, Issue 14
Probing Novel Microstructural Evolution Mechanisms in Aluminum Alloys Using 4D Nanoscale Characterization
journal, September 2017
- Kaira, C. Shashank; De Andrade, V.; Singh, Sudhanshu S.
- Advanced Materials, Vol. 29, Issue 41
High-efficiency Fresnel zone plates for hard X-rays by 100 keV e-beam lithography and electroplating
journal, March 2011
- Gorelick, Sergey; Vila-Comamala, Joan; Guzenko, Vitaliy A.
- Journal of Synchrotron Radiation, Vol. 18, Issue 3
Nanoscale Three-Dimensional Microstructural Characterization of an Sn-Rich Solder Alloy Using High-Resolution Transmission X-Ray Microscopy (TXM)
journal, July 2016
- Kaira, Chandrashekara S.; Mayer, Carl R.; De Andrade, V.
- Microscopy and Microanalysis, Vol. 22, Issue 4
Probing three-dimensional sodiation–desodiation equilibrium in sodium-ion batteries by in situ hard X-ray nanotomography
journal, June 2015
- Wang, Jiajun; Eng, Christopher; Chen-Wiegart, Yu-chen Karen
- Nature Communications, Vol. 6, Issue 1
Nanoscale X-ray imaging
journal, December 2010
- Sakdinawat, Anne; Attwood, David
- Nature Photonics, Vol. 4, Issue 12, p. 840-848
Size dependence of mechanical properties of gold at the micron scale in the absence of strain gradients
journal, April 2005
- Greer, Julia R.; Oliver, Warren C.; Nix, William D.
- Acta Materialia, Vol. 53, Issue 6
Correlation between Critical Temperature and Strength of Small-Scale bcc Pillars
journal, August 2009
- Schneider, A. S.; Kaufmann, D.; Clark, B. G.
- Physical Review Letters, Vol. 103, Issue 10
Microcompression of single-crystal magnesium
journal, April 2010
- Byer, Cynthia M.; Li, Bin; Cao, Buyang
- Scripta Materialia, Vol. 62, Issue 8
Microscale deformation behavior of bicrystal boundaries in pure tin (Sn) using micropillar compression
journal, November 2016
- Kaira, C. Shashank; Singh, Sudhanshu S.; Kirubanandham, Antony
- Acta Materialia, Vol. 120
Effect of interfacial solute segregation on ductile fracture of Al–Cu–Sc alloys
journal, March 2013
- Chen, B. A.; Liu, G.; Wang, R. H.
- Acta Materialia, Vol. 61, Issue 5
Cyclic stress—strain response of two-phase alloys Part II. Particles not penetrated by dislocations
journal, February 1974
- Calabrese, C.; Laird, C.
- Materials Science and Engineering, Vol. 13, Issue 2
Slip in aluminum crystals containing strong, plate-like particles
journal, August 1970
- Russell, Kathryn G.; Ashby, M. F.
- Acta Metallurgica, Vol. 18, Issue 8
TomoPy: a framework for the analysis of synchrotron tomographic data
journal, August 2014
- Gürsoy, Dogˇa; De Carlo, Francesco; Xiao, Xianghui
- Journal of Synchrotron Radiation, Vol. 21, Issue 5
Scientific data exchange: a schema for HDF5-based storage of raw and analyzed data
journal, October 2014
- De Carlo, Francesco; Gürsoy, Dogˇa; Marone, Federica
- Journal of Synchrotron Radiation, Vol. 21, Issue 6
FIB damage of Cu and possible consequences for miniaturized mechanical tests
journal, June 2007
- Kiener, D.; Motz, C.; Rester, M.
- Materials Science and Engineering: A, Vol. 459, Issue 1-2
Effects of focused ion beam milling on the compressive behavior of directionally solidified micropillars and the nanoindentation response of an electropolished surface
journal, January 2009
- Shim, S.; Bei, H.; Miller, M. K.
- Acta Materialia, Vol. 57, Issue 2
Investigation of the deformation behavior of aluminum micropillars produced by focused ion beam machining using Ga and Xe ions
journal, January 2017
- Xiao, Y.; Wehrs, J.; Ma, H.
- Scripta Materialia, Vol. 127
The effect of shear-resistant, plate-shaped precipitates on the work hardening of Al alloys: Towards a prediction of the strength–elongation correlation
journal, December 2009
- da Costa Teixeira, J.; Bourgeois, L.; Sinclair, C. W.
- Acta Materialia, Vol. 57, Issue 20
The Deformation and Ageing of Mild Steel: III Discussion of Results
journal, September 1951
- Hall, E. O.
- Proceedings of the Physical Society. Section B, Vol. 64, Issue 9
Microstructural Evolution and Age Hardening in Aluminium Alloys
journal, January 2000
- Ringer, S. P.; Hono, K.
- Materials Characterization, Vol. 44, Issue 1-2
Nucleation-Mediated Structural Refinement and Aluminium Alloy Design
journal, July 2006
- Muddle, Barry C.; Nie, Jian Feng
- Materials Science Forum, Vol. 519-521
Multiscale microstructural characterization of Sn-rich alloys by three dimensional (3D) X-ray synchrotron tomography and focused ion beam (FIB) tomography
journal, August 2012
- Yazzie, K. E.; Williams, J. J.; Phillips, N. C.
- Materials Characterization, Vol. 70
The Effect of Precipitate Shape and Orientation on Dispersion Strengthening in High Strength Aluminium Alloys
journal, May 1996
- Nie, Jian Feng; Muddle, Barry C.; Polmear, Ian J.
- Materials Science Forum, Vol. 217-222
The deformation of plastically non-homogeneous materials
journal, February 1970
- Ashby, M. F.
- The Philosophical Magazine: A Journal of Theoretical Experimental and Applied Physics, Vol. 21, Issue 170
The work-hardening of copper-silica
journal, May 1971
- Brown, L. M.; Stobbs, W. M.
- Philosophical Magazine, Vol. 23, Issue 185
Substitutional solutes in AlRu—I. Effects of solute on moduli, lattice parameters and vacancy production
journal, March 1993
- Fleischer, R. L.
- Acta Metallurgica et Materialia, Vol. 41, Issue 3
Works referencing / citing this record:
A “water window” tomography based on a laser-plasma double-stream gas-puff target soft X-ray source
journal, April 2019
- Wachulak, P. W.; Torrisi, A.; Krauze, W.
- Applied Physics B, Vol. 125, Issue 5