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Title: Nonequilibrium Synthesis of Highly Porous Single-Crystalline Oxide Nanostructures

Abstract

A novel synthesis route to the formation of vertically aligned single–crystalline oxide nanostructures is found by precisely controlling the nonequilibrium pulsed laser deposition process. Here, the columnar nanostructures with deep crevices offering a large surface area are generated owing to the diffusion limited geometric shadowing effect.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
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  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1436958
Alternate Identifier(s):
OSTI ID: 1401742
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials Interfaces
Additional Journal Information:
Journal Volume: 4; Journal Issue: 3; Journal ID: ISSN 2196-7350
Publisher:
Wiley-VCH
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; vertical oxide nanostructures; pulsed laser deposition; diffusion limited aggregation; binary oxides; porous nanostructures

Citation Formats

Lee, Dongkyu, Gao, Xiang, Fan, Lisha, Guo, Er-Jia, Farmer, Thomas O., Heller, William T., Ward, T. Z., Eres, Gyula, Fitzsimmons, Michael R., Chisholm, Matthew F., and Lee, Ho Nyung. Nonequilibrium Synthesis of Highly Porous Single-Crystalline Oxide Nanostructures. United States: N. p., 2017. Web. doi:10.1002/admi.201601034.
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Lee, Dongkyu, Gao, Xiang, Fan, Lisha, Guo, Er-Jia, Farmer, Thomas O., Heller, William T., Ward, T. Z., Eres, Gyula, Fitzsimmons, Michael R., Chisholm, Matthew F., & Lee, Ho Nyung. Nonequilibrium Synthesis of Highly Porous Single-Crystalline Oxide Nanostructures. United States. https://doi.org/10.1002/admi.201601034
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Lee, Dongkyu, Gao, Xiang, Fan, Lisha, Guo, Er-Jia, Farmer, Thomas O., Heller, William T., Ward, T. Z., Eres, Gyula, Fitzsimmons, Michael R., Chisholm, Matthew F., and Lee, Ho Nyung. Fri . "Nonequilibrium Synthesis of Highly Porous Single-Crystalline Oxide Nanostructures". United States. https://doi.org/10.1002/admi.201601034. https://www.osti.gov/servlets/purl/1436958.
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@article{osti_1436958,
title = {Nonequilibrium Synthesis of Highly Porous Single-Crystalline Oxide Nanostructures},
author = {Lee, Dongkyu and Gao, Xiang and Fan, Lisha and Guo, Er-Jia and Farmer, Thomas O. and Heller, William T. and Ward, T. Z. and Eres, Gyula and Fitzsimmons, Michael R. and Chisholm, Matthew F. and Lee, Ho Nyung},
abstractNote = {A novel synthesis route to the formation of vertically aligned single–crystalline oxide nanostructures is found by precisely controlling the nonequilibrium pulsed laser deposition process. Here, the columnar nanostructures with deep crevices offering a large surface area are generated owing to the diffusion limited geometric shadowing effect.},
doi = {10.1002/admi.201601034},
journal = {Advanced Materials Interfaces},
number = 3,
volume = 4,
place = {United States},
year = {Fri Jan 20 00:00:00 EST 2017},
month = {Fri Jan 20 00:00:00 EST 2017}
}
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https://doi.org/10.1002/admi.201601034
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Works referenced in this record:

Pulsed laser deposition of tungsten and tungsten oxide thin films with tailored structure at the nano- and mesoscale
journal, July 2007

One-Dimensional Nanostructures: Synthesis, Characterization, and Applications
journal, June 2003

Atomic and electronic structure of unreduced and reduced CeO2 surfaces: A first-principles study
journal, April 2004

  • Yang, Zongxian; Woo, Tom K.; Baudin, Micael
  • The Journal of Chemical Physics, Vol. 120, Issue 16
  • DOI: 10.1063/1.1688316

Mantid—Data analysis and visualization package for neutron scattering and μ SR experiments
journal, November 2014

  • Arnold, O.; Bilheux, J. C.; Borreguero, J. M.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 764
  • DOI: 10.1016/j.nima.2014.07.029

On diffusion limited deposition
journal, January 2016

  • Asselah, Amine; Cirillo, Emilio N. M.; Scoppola, Benedetto
  • Electronic Journal of Probability, Vol. 21, Issue 0
  • DOI: 10.1214/16-EJP4310

Thin-film solid oxide fuel cell with high performance at low-temperature
journal, June 1997

Columnar growth and kinetic roughening in electrochemical deposition
journal, June 1992

  • Kahanda, Galathara L. M. K. S.; Zou, Xiao-qun; Farrell, Robert
  • Physical Review Letters, Vol. 68, Issue 25
  • DOI: 10.1103/PhysRevLett.68.3741

Reversible redox reactions in an epitaxially stabilized SrCoOx oxygen sponge
journal, August 2013

  • Jeen, Hyoungjeen; Choi, Woo Seok; Biegalski, Michael D.
  • Nature Materials, Vol. 12, Issue 11
  • DOI: 10.1038/nmat3736

Growth and characterization of non-c-oriented epitaxial ferroelectric SrBi2Ta2O9 films on buffered Si(100)
journal, November 2000

  • Lee, Ho Nyung; Senz, Stephan; Zakharov, Nikolai D.
  • Applied Physics Letters, Vol. 77, Issue 20
  • DOI: 10.1063/1.1324982

Diffusion-Limited Aggregation, a Kinetic Critical Phenomenon
journal, November 1981

Nucleation and growth of thin films
journal, April 1984

  • Venables, J. A.; Spiller, G. D. T.; Hanbucken, M.
  • Reports on Progress in Physics, Vol. 47, Issue 4
  • DOI: 10.1088/0034-4885/47/4/002

Angular laser cleaning for effective removal of particles. from a solid surface
journal, December 2000

  • Lee, J. M.; Watkins, K. G.; Steen, W. M.
  • Applied Physics A Materials Science & Processing, Vol. 71, Issue 6
  • DOI: 10.1007/s003390000583

One-Dimensional Nanostructures: Synthesis, Characterization, and Applications
journal, March 2003

Growth of aligned ZnO nanorod arrays by catalyst-free pulsed laser deposition methods
journal, September 2004

Diffusion-limited aggregation: A kinetic critical phenomenon?
journal, July 2000

Multiparticle biased diffusion-limited aggregation with surface diffusion: A comprehensive model of electrodeposition
journal, July 2000

Hierarchical TiO 2 Photoanode for Dye-Sensitized Solar Cells
journal, July 2010

  • Sauvage, F.; Di Fonzo, F.; Li Bassi, A.
  • Nano Letters, Vol. 10, Issue 7
  • DOI: 10.1021/nl101198b

Repeated temperature modulation epitaxy for p-type doping and light-emitting diode based on ZnO
journal, December 2004

  • Tsukazaki, Atsushi; Ohtomo, Akira; Onuma, Takeyoshi
  • Nature Materials, Vol. 4, Issue 1
  • DOI: 10.1038/nmat1284

Imposed layer-by-layer growth by pulsed laser interval deposition
journal, June 1999

  • Koster, Gertjan; Rijnders, Guus J. H. M.; Blank, Dave H. A.
  • Applied Physics Letters, Vol. 74, Issue 24
  • DOI: 10.1063/1.123235

High electrochemical activity of the oxide phase in model ceria–Pt and ceria–Ni composite anodes
journal, December 2011

  • Chueh, William C.; Hao, Yong; Jung, WooChul
  • Nature Materials, Vol. 11, Issue 2
  • DOI: 10.1038/nmat3184

Growth control of oxygen stoichiometry in homoepitaxial SrTiO3 films by pulsed laser epitaxy in high vacuum
journal, January 2016

  • Lee, Ho Nyung; Ambrose Seo, Sung S.; Choi, Woo Seok
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep19941

Epitaxial yttria‐stabilized zirconia on hydrogen‐terminated Si by pulsed laser deposition
journal, September 1990

  • Fork, D. K.; Fenner, D. B.; Connell, G. A. N.
  • Applied Physics Letters, Vol. 57, Issue 11
  • DOI: 10.1063/1.104220

Characterization of Thin-Film Rechargeable Lithium Batteries with Lithium Cobalt Oxide Cathodes
journal, January 1996

  • Wang, B.
  • Journal of The Electrochemical Society, Vol. 143, Issue 10
  • DOI: 10.1149/1.1837188

Microstructures of CGO and YSZ Thin Films by Pulsed Laser Deposition
journal, December 2007

  • Infortuna, A.; Harvey, A. S.; Gauckler, L. J.
  • Advanced Functional Materials, Vol. 18, Issue 1
  • DOI: 10.1002/adfm.200700136

Microscopic view of epitaxial metal growth: nucleation and aggregation
journal, January 1998

Resonant tunnelling in a quantum oxide superlattice
journal, June 2015

  • Choi, Woo Seok; Lee, Sang A.; You, Jeong Ho
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8424

Plasma plume characteristics and properties of pulsed laser deposited diamond-like carbon films
journal, March 2003

  • Haverkamp, J.; Mayo, R. M.; Bourham, M. A.
  • Journal of Applied Physics, Vol. 93, Issue 6
  • DOI: 10.1063/1.1555695

High power density thin film SOFCs with YSZ/GDC bilayer electrolyte
journal, June 2011

Nucleation And Growth Of Thin Films
journal, June 1984

Electrical conductivity of thin film ceria grown by pulsed laser deposition
journal, January 2007

Thin-Film Growth and the Shadow Instability
journal, February 1989

Instabilities in crystal growth by atomic or molecular beams
journal, February 2000

Structure, stability and work functions of the low index surfaces of pure indium oxide and Sn-doped indium oxide (ITO) from density functional theory
journal, January 2010

  • Walsh, Aron; Catlow, C. Richard A.
  • Journal of Materials Chemistry, Vol. 20, Issue 46
  • DOI: 10.1039/c0jm01816c

Columnar growth in oblique incidence ballistic deposition: Faceting, noise reduction, and mean-field theory
journal, January 1991

Thin-Film Growth and the Shadow Instability
journal, June 1989

High proton conduction in grain-boundary-free yttrium-doped barium zirconate films grown by pulsed laser deposition
journal, September 2010

  • Pergolesi, Daniele; Fabbri, Emiliana; D’Epifanio, Alessandra
  • Nature Materials, Vol. 9, Issue 10
  • DOI: 10.1038/nmat2837

Atomic Layer Engineering of Perovskite Oxides for Chemically Sharp Heterointerfaces
journal, October 2012

  • Choi, Woo Seok; Rouleau, Christopher M.; Seo, Sung Seok A.
  • Advanced Materials, Vol. 24, Issue 48
  • DOI: 10.1002/adma.201202691

Thousandfold Change in Resistivity in Magnetoresistive La-Ca-Mn-O Films
journal, April 1994

Oxygen Reduction Kinetics Enhancement on a Heterostructured Oxide Surface for Solid Oxide Fuel Cells
journal, October 2010

  • Crumlin, Ethan J.; Mutoro, Eva; Ahn, Sung-Jin
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 21
  • DOI: 10.1021/jz101217d

Morphological instability of a terrace edge during step-flow growth
journal, March 1990

Chemistry and Physics in One Dimension: Synthesis and Properties of Nanowires and Nanotubes
journal, February 1999

  • Hu, Jiangtao; Odom, Teri Wang; Lieber, Charles M.
  • Accounts of Chemical Research, Vol. 32, Issue 5, p. 435-445
  • DOI: 10.1021/ar9700365

High electrode activity of nanostructured, columnar ceria films for solid oxide fuel cells
journal, January 2012

  • Jung, WooChul; Dereux, Julien O.; Chueh, William C.
  • Energy & Environmental Science, Vol. 5, Issue 9
  • DOI: 10.1039/c2ee22151a

Microscopic view of epitaxial metal growth: Nucleation and aggregation
journal, May 1998

Atomic layer engineering of perovskite oxides for chemically sharp heterointerfaces
text, January 2012

Instabilities in crystal growth by atomic or molecular beams
text, January 1999

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