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Title: Achieving Highly Efficient Nonfullerene Organic Solar Cells with Improved Intermolecular Interaction and Open-Circuit Voltage

Abstract

Here, a new acceptor–donor–acceptor-structured nonfullerene acceptor ITCC (3,9-bis(4-(1,1-dicyanomethylene)-3-methylene-2-oxo-cyclopenta[b]thiophen)-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3- d':2,3- d'] -s-indaceno[1,2- b:5,6- b']-dithiophene) is designed and synthesized via simple end-group modification. ITCC shows improved electron-transport properties and a high-lying lowest unoccupied molecular orbital level. A power conversion efficiency of 11.4% with an impressive V OC of over 1 V is recorded in photovoltaic devices, suggesting that ITCC has great potential for applications in tandem organic solar cells.

Authors:
 [1];  [2];  [3];  [4];  [1];  [1];  [5];  [5];  [1];  [1];  [1];  [1];  [4];  [2];  [1]
  1. Chinese Academy of Science, Beijing (P. R. China); Univ. of Chinese Academy of Science, Beijing (P. R. China)
  2. North Carolina State Univ., Raleigh, NC (United States)
  3. Hebei Univ. of Engineering, Handan (P. R. China)
  4. Korea Univ., Seoul (Republic of Korea)
  5. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1436630
Alternate Identifier(s):
OSTI ID: 1400827
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 29; Journal Issue: 21; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
14 SOLAR ENERGY

Citation Formats

Yao, Huifeng, Ye, Long, Hou, Junxian, Jang, Bomee, Han, Guangchao, Cui, Yong, Su, Gregory M., Wang, Cheng, Gao, Bowei, Yu, Runnan, Zhang, Hao, Yi, Yuanping, Woo, Han Young, Ade, Harald, and Hou, Jianhui. Achieving Highly Efficient Nonfullerene Organic Solar Cells with Improved Intermolecular Interaction and Open-Circuit Voltage. United States: N. p., 2017. Web. doi:10.1002/adma.201700254.
Yao, Huifeng, Ye, Long, Hou, Junxian, Jang, Bomee, Han, Guangchao, Cui, Yong, Su, Gregory M., Wang, Cheng, Gao, Bowei, Yu, Runnan, Zhang, Hao, Yi, Yuanping, Woo, Han Young, Ade, Harald, & Hou, Jianhui. Achieving Highly Efficient Nonfullerene Organic Solar Cells with Improved Intermolecular Interaction and Open-Circuit Voltage. United States. doi:10.1002/adma.201700254.
Yao, Huifeng, Ye, Long, Hou, Junxian, Jang, Bomee, Han, Guangchao, Cui, Yong, Su, Gregory M., Wang, Cheng, Gao, Bowei, Yu, Runnan, Zhang, Hao, Yi, Yuanping, Woo, Han Young, Ade, Harald, and Hou, Jianhui. Wed . "Achieving Highly Efficient Nonfullerene Organic Solar Cells with Improved Intermolecular Interaction and Open-Circuit Voltage". United States. doi:10.1002/adma.201700254. https://www.osti.gov/servlets/purl/1436630.
@article{osti_1436630,
title = {Achieving Highly Efficient Nonfullerene Organic Solar Cells with Improved Intermolecular Interaction and Open-Circuit Voltage},
author = {Yao, Huifeng and Ye, Long and Hou, Junxian and Jang, Bomee and Han, Guangchao and Cui, Yong and Su, Gregory M. and Wang, Cheng and Gao, Bowei and Yu, Runnan and Zhang, Hao and Yi, Yuanping and Woo, Han Young and Ade, Harald and Hou, Jianhui},
abstractNote = {Here, a new acceptor–donor–acceptor-structured nonfullerene acceptor ITCC (3,9-bis(4-(1,1-dicyanomethylene)-3-methylene-2-oxo-cyclopenta[b]thiophen)-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d':2,3-d'] -s-indaceno[1,2-b:5,6-b']-dithiophene) is designed and synthesized via simple end-group modification. ITCC shows improved electron-transport properties and a high-lying lowest unoccupied molecular orbital level. A power conversion efficiency of 11.4% with an impressive V OC of over 1 V is recorded in photovoltaic devices, suggesting that ITCC has great potential for applications in tandem organic solar cells.},
doi = {10.1002/adma.201700254},
journal = {Advanced Materials},
number = 21,
volume = 29,
place = {United States},
year = {2017},
month = {3}
}

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Works referenced in this record:

Integrated Molecular, Interfacial, and Device Engineering towards High-Performance Non-Fullerene Based Organic Solar Cells
journal, June 2014

  • Zang, Yue; Li, Chang-Zhi; Chueh, Chu-Chen
  • Advanced Materials, Vol. 26, Issue 32, p. 5708-5714
  • DOI: 10.1002/adma.201401992

Molecular Design and Ordering Effects in ?-Functional Materials for Transistor and Solar Cell Applications
journal, December 2011

  • Beaujuge, Pierre M.; Fr�chet, Jean M. J.
  • Journal of the American Chemical Society, Vol. 133, Issue 50, p. 20009-20029
  • DOI: 10.1021/ja2073643