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Title: Non-aqueous neptunium and plutonium redox behaviour in THF – access to a rare Np( iii ) synthetic precursor

Redox stability of tetravalent Np and Pu in THF is explored, leading to facile access routes into anhydrous Np( iii ) chemistry.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [3] ; ORCiD logo [2] ; ORCiD logo [4]
  1. Chemistry Division, Los Alamos National Laboratory, Los Alamos, USA, H. C. Brown Laboratory
  2. Chemistry Division, Los Alamos National Laboratory, Los Alamos, USA
  3. H. C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, USA
  4. Materials and Physics Applications Division, Los Alamos National Laboratory, Los Alamos, USA
Publication Date:
Grant/Contract Number:
AC52-06NA25396; SC0008479
Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 54 Journal Issue: 48; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1436357

Pattenaude, Scott A., Anderson, Nickolas H., Bart, Suzanne C., Gaunt, Andrew J., and Scott, Brian L.. Non-aqueous neptunium and plutonium redox behaviour in THF – access to a rare Np( iii ) synthetic precursor. United Kingdom: N. p., Web. doi:10.1039/C8CC02611D.
Pattenaude, Scott A., Anderson, Nickolas H., Bart, Suzanne C., Gaunt, Andrew J., & Scott, Brian L.. Non-aqueous neptunium and plutonium redox behaviour in THF – access to a rare Np( iii ) synthetic precursor. United Kingdom. doi:10.1039/C8CC02611D.
Pattenaude, Scott A., Anderson, Nickolas H., Bart, Suzanne C., Gaunt, Andrew J., and Scott, Brian L.. 2018. "Non-aqueous neptunium and plutonium redox behaviour in THF – access to a rare Np( iii ) synthetic precursor". United Kingdom. doi:10.1039/C8CC02611D.
@article{osti_1436357,
title = {Non-aqueous neptunium and plutonium redox behaviour in THF – access to a rare Np( iii ) synthetic precursor},
author = {Pattenaude, Scott A. and Anderson, Nickolas H. and Bart, Suzanne C. and Gaunt, Andrew J. and Scott, Brian L.},
abstractNote = {Redox stability of tetravalent Np and Pu in THF is explored, leading to facile access routes into anhydrous Np( iii ) chemistry.},
doi = {10.1039/C8CC02611D},
journal = {Chemical Communications},
number = 48,
volume = 54,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976