Rapid Assessment of the Ce-Co-Fe-Cu System for Permanent Magnetic Applications

Meng, F.; Chaudhary, R. P.; Gandha, K.; Nlebedim, I. C.; Palasyuk, A.; Simsek, E.; Kramer, M. J.; Ott, R. T.

doi:10.1007/s11837-018-2862-8

Title: Rapid Assessment of the Ce-Co-Fe-Cu System for Permanent Magnetic Applications

Abstract

Here, this work focuses on the rapid synthesis and characterization of quaternary Ce(CoFeCu)₅ alloy libraries to assess their potential viability as permanent magnets. Arrays of bulk specimens with controlled compositions were synthesized via laser engineered net shaping (LENS) by feeding different ratios of alloy powders into a melt pool created by a laser. Based on the assessment of the magnetic properties of the LENS printed samples, arc-melted and cast ingots were prepared with varying Fe (5–20 at.%) and Co (60–45 at.%) compositions while maintaining constant Ce (16 at.%) and Cu (19 at.%) content. The evolution of the microstructure and phases with varying chemical compositions and their dependence on magnetic properties are analyzed in as-cast and heat-treated samples. In both the LENS printed and cast samples, we find the best magnetic properties correspond to a predominantly single-phase Ce(CoFeCu)₅ microstructure in which high coercivity (H_c > 10 kOe) can be achieved without any microstructural refinement.

Authors:

Meng, F. ^[1]; Chaudhary, R. P. ^[1]; Gandha, K. ^[1]; Nlebedim, I. C. ^[1]; Palasyuk, A. ^[1]; Simsek, E. ^[1]; Kramer, M. J. ^[1]; Ott, R. T. ^[1]

Ames Lab., Ames, IA (United States)

Publication Date:: Mon Apr 23 00:00:00 EDT 2018

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1435745

Report Number(s):: IS-J-9649
Journal ID: ISSN 1047-4838; PII: 2862

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: JOM. Journal of the Minerals, Metals & Materials Society

Additional Journal Information:: Journal Volume: 70; Journal Issue: 6; Journal ID: ISSN 1047-4838

Publisher:: Springer

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Meng, F., Chaudhary, R. P., Gandha, K., Nlebedim, I. C., Palasyuk, A., Simsek, E., Kramer, M. J., and Ott, R. T. Rapid Assessment of the Ce-Co-Fe-Cu System for Permanent Magnetic Applications.  United States: N. p., 2018. 
Web.  doi:10.1007/s11837-018-2862-8.

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                    Meng, F., Chaudhary, R. P., Gandha, K., Nlebedim, I. C., Palasyuk, A., Simsek, E., Kramer, M. J., & Ott, R. T. Rapid Assessment of the Ce-Co-Fe-Cu System for Permanent Magnetic Applications.  United States.  https://doi.org/10.1007/s11837-018-2862-8

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                    Meng, F., Chaudhary, R. P., Gandha, K., Nlebedim, I. C., Palasyuk, A., Simsek, E., Kramer, M. J., and Ott, R. T. Mon .  
"Rapid Assessment of the Ce-Co-Fe-Cu System for Permanent Magnetic Applications".  United States.  https://doi.org/10.1007/s11837-018-2862-8.  https://www.osti.gov/servlets/purl/1435745.

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@article{osti_1435745,

  title        = {Rapid Assessment of the Ce-Co-Fe-Cu System for Permanent Magnetic Applications},

  author       = {Meng, F. and Chaudhary, R. P. and Gandha, K. and Nlebedim, I. C. and Palasyuk, A. and Simsek, E. and Kramer, M. J. and Ott, R. T.},

  abstractNote = {Here, this work focuses on the rapid synthesis and characterization of quaternary Ce(CoFeCu)5 alloy libraries to assess their potential viability as permanent magnets. Arrays of bulk specimens with controlled compositions were synthesized via laser engineered net shaping (LENS) by feeding different ratios of alloy powders into a melt pool created by a laser. Based on the assessment of the magnetic properties of the LENS printed samples, arc-melted and cast ingots were prepared with varying Fe (5–20 at.%) and Co (60–45 at.%) compositions while maintaining constant Ce (16 at.%) and Cu (19 at.%) content. The evolution of the microstructure and phases with varying chemical compositions and their dependence on magnetic properties are analyzed in as-cast and heat-treated samples. In both the LENS printed and cast samples, we find the best magnetic properties correspond to a predominantly single-phase Ce(CoFeCu)5 microstructure in which high coercivity (Hc > 10 kOe) can be achieved without any microstructural refinement.},

  doi          = {10.1007/s11837-018-2862-8},

  journal      = {JOM. Journal of the Minerals, Metals & Materials Society},

  number       = 6,

  volume       = 70,

  place        = {United States},

  year         = {Mon Apr 23 00:00:00 EDT 2018},

  month        = {Mon Apr 23 00:00:00 EDT 2018}

}

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Works referenced in this record:

Preparation and properties of sintered CoCuFeCe permanent magnets
journal, May 1972

Sherwood, R. C.; Nesbitt, E. A.; Chin, G. Y.
Materials Research Bulletin, Vol. 7, Issue 5
DOI: 10.1016/0025-5408(72)90151-1

Magnetic properties of in-situ synthesized FeNi3 by selective laser melting Fe-80%Ni powders
journal, June 2013

Zhang, Baicheng; Fenineche, Nour-Eddine; Liao, Hanlin
Journal of Magnetism and Magnetic Materials, Vol. 336
DOI: 10.1016/j.jmmm.2013.02.014

Laser additive processing of functionally-graded Fe–Si–B–Cu–Nb soft magnetic materials
journal, October 2016

Borkar, T.; Conteri, R.; Chen, X.
Materials and Manufacturing Processes, Vol. 32, Issue 14
DOI: 10.1080/10426914.2016.1244849

Hard Magnetic Materials: A Perspective
journal, December 2011

Coey, J. M. D.
IEEE Transactions on Magnetics, Vol. 47, Issue 12
DOI: 10.1109/TMAG.2011.2166975

Combinatorial Materials Sciences: Experimental Strategies for Accelerated Knowledge Discovery
journal, August 2008

Rajan, Krishna
Annual Review of Materials Research, Vol. 38, Issue 1
DOI: 10.1146/annurev.matsci.38.060407.130217

Applications of high throughput (combinatorial) methodologies to electronic, magnetic, optical, and energy-related materials
journal, June 2013

Green, Martin L.; Takeuchi, Ichiro; Hattrick-Simpers, Jason R.
Journal of Applied Physics, Vol. 113, Issue 23
DOI: 10.1063/1.4803530

Prospects for Non-Rare Earth Permanent Magnets for Traction Motors and Generators
journal, June 2012

Kramer, M. J.; McCallum, R. W.; Anderson, I. A.
JOM, Vol. 64, Issue 7
DOI: 10.1007/s11837-012-0351-z

Cast Permanent Magnets of the Co ₅ RE Type with Mixtures of Cerium and Samarium
journal, March 1971

Nesbitt, E. A.; Chin, G. Y.; Gallagher, P. K.
Journal of Applied Physics, Vol. 42, Issue 4
DOI: 10.1063/1.1660325

The structure of Co-Cu-Fe-Ce permanent magnets
journal, September 1973

Leamy, H.; Green, M.
IEEE Transactions on Magnetics, Vol. 9, Issue 3
DOI: 10.1109/TMAG.1973.1067642

A Family of New Cobalt‐Base Permanent Magnet Materials
journal, March 1967

Strnat, K.; Hoffer, G.; Olson, J.
Journal of Applied Physics, Vol. 38, Issue 3
DOI: 10.1063/1.1709459

Cerium, Cobalt and Copper Alloy as a Permanent Magnet Material
journal, August 1968

Tawara, Yoshio; Senno, Harufumi
Japanese Journal of Applied Physics, Vol. 7, Issue 8
DOI: 10.1143/JJAP.7.966

New Permanent Magnet Materials Containing Rare‐Earth Metals
journal, March 1969

Nesbitt, E. A.
Journal of Applied Physics, Vol. 40, Issue 3
DOI: 10.1063/1.1657619

CAST PERMANENT MAGNETS OF THE CO ₅ RE TYPE WITH A ( BH ) _M EXCEEDING 12 MILLION G‐Oe
journal, April 1970

Nesbitt, E. A.; Chin, G. Y.; Sherwood, R. C.
Applied Physics Letters, Vol. 16, Issue 8
DOI: 10.1063/1.1653207

High Energy Product Developed from Cobalt Nanowires
journal, June 2014

Gandha, Kinjal; Elkins, Kevin; Poudyal, Narayan
Scientific Reports, Vol. 4, Issue 1
DOI: 10.1038/srep05345

Magnetic Materials and Devices for the 21st Century: Stronger, Lighter, and More Energy Efficient
journal, December 2010

Gutfleisch, Oliver; Willard, Matthew A.; Brück, Ekkes
Advanced Materials, Vol. 23, Issue 7
DOI: 10.1002/adma.201002180

Laser Additive Manufacturing of Magnetic Materials
journal, January 2017

Mikler, C. V.; Chaudhary, V.; Borkar, T.
JOM, Vol. 69, Issue 3
DOI: 10.1007/s11837-017-2257-2

Bulk Combinatorial Synthesis and High Throughput Characterization for Rapid Assessment of Magnetic Materials: Application of Laser Engineered Net Shaping (LENS™)
journal, April 2016

Geng, J.; Nlebedim, I. C.; Besser, M. F.
JOM, Vol. 68, Issue 7
DOI: 10.1007/s11837-016-1918-x

RETM ₅ and RE ₂ TM ₁ ₇ permanent magnets development
journal, March 1988

Kumar, Kaplesh
Journal of Applied Physics, Vol. 63, Issue 6
DOI: 10.1063/1.341084

Net Shape Processing of Alnico Magnets by Additive Manufacturing
journal, November 2017

White, Emma Marie Hamilton; Kassen, Aaron Gregory; Simsek, Emrah
IEEE Transactions on Magnetics, Vol. 53, Issue 11
DOI: 10.1109/TMAG.2017.2711965

Current Status of Combinatorial and High-Throughput Methods for Discovering New Materials and Catalysts
journal, February 2005

Woo, Seong Ihl; Kim, Ki Woong; Cho, Hyun Yong
QSAR & Combinatorial Science, Vol. 24, Issue 1
DOI: 10.1002/qsar.200420061

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Title: Rapid Assessment of the Ce-Co-Fe-Cu System for Permanent Magnetic Applications

Abstract

Citation Formats

Preparation and properties of sintered CoCuFeCe permanent magnets journal, May 1972

Magnetic properties of in-situ synthesized FeNi3 by selective laser melting Fe-80%Ni powders journal, June 2013

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The structure of Co-Cu-Fe-Ce permanent magnets journal, September 1973

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Hard Magnetic Materials: A Perspective
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Prospects for Non-Rare Earth Permanent Magnets for Traction Motors and Generators
journal, June 2012

Cast Permanent Magnets of the Co ₅ RE Type with Mixtures of Cerium and Samarium
journal, March 1971

The structure of Co-Cu-Fe-Ce permanent magnets
journal, September 1973

A Family of New Cobalt‐Base Permanent Magnet Materials
journal, March 1967

Cerium, Cobalt and Copper Alloy as a Permanent Magnet Material
journal, August 1968

New Permanent Magnet Materials Containing Rare‐Earth Metals
journal, March 1969

CAST PERMANENT MAGNETS OF THE CO ₅ RE TYPE WITH A ( BH ) _M EXCEEDING 12 MILLION G‐Oe
journal, April 1970

High Energy Product Developed from Cobalt Nanowires
journal, June 2014

Magnetic Materials and Devices for the 21st Century: Stronger, Lighter, and More Energy Efficient
journal, December 2010

Laser Additive Manufacturing of Magnetic Materials
journal, January 2017

Bulk Combinatorial Synthesis and High Throughput Characterization for Rapid Assessment of Magnetic Materials: Application of Laser Engineered Net Shaping (LENS™)
journal, April 2016

RETM ₅ and RE ₂ TM ₁ ₇ permanent magnets development
journal, March 1988

Net Shape Processing of Alnico Magnets by Additive Manufacturing
journal, November 2017

Current Status of Combinatorial and High-Throughput Methods for Discovering New Materials and Catalysts
journal, February 2005