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Title: Uncovering the Origin of Divergence in the CsM(CrO 4 ) 2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis

Authors:
 [1];  [1];  [2];  [2]; ORCiD logo [3];  [1];  [1];  [1];  [4];  [5];  [5];  [6]; ORCiD logo [1]; ORCiD logo [7];  [6]
  1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, United States
  2. Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08856-8019, United States
  3. Department of Physics and Astronomy, and Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, Iowa 50011, United States
  4. Department of Physics, Florida State University, Tallahassee, Florida 32306, United States, National High Magnetic Field Laboratory, Tallahassee, Florida 32310, United States
  5. National High Magnetic Field Laboratory, Tallahassee, Florida 32310, United States, Department of Chemical Engineering, Florida State University, Tallahassee, Florida 32310, United States
  6. National High Magnetic Field Laboratory, Tallahassee, Florida 32310, United States
  7. School of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, United Kingdom
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Actinide Science & Technology (CAST)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1434561
Alternate Identifier(s):
OSTI ID: 1427725; OSTI ID: 1508589
Report Number(s):
IS-J-9584
Journal ID: ISSN 0002-7863
Grant/Contract Number:  
SC0016568; AC02-07CH11358
Resource Type:
Published Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Name: Journal of the American Chemical Society Journal Volume: 140 Journal Issue: 5; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY

Citation Formats

Galley, Shane S., Arico, Alexandra A., Lee, Tsung-Han, Deng, Xiaoyu, Yao, Yong-Xin, Sperling, Joseph M., Proust, Vanessa, Storbeck, Julia S., Dobrosavljevic, Vladimir, Neu, Jennifer N., Siegrist, Theo, Baumbach, Ryan E., Albrecht-Schmitt, Thomas E., Kaltsoyannis, Nikolas, and Lanatà, Nicola. Uncovering the Origin of Divergence in the CsM(CrO 4 ) 2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis. United States: N. p., 2018. Web. doi:10.1021/jacs.7b09474.
Galley, Shane S., Arico, Alexandra A., Lee, Tsung-Han, Deng, Xiaoyu, Yao, Yong-Xin, Sperling, Joseph M., Proust, Vanessa, Storbeck, Julia S., Dobrosavljevic, Vladimir, Neu, Jennifer N., Siegrist, Theo, Baumbach, Ryan E., Albrecht-Schmitt, Thomas E., Kaltsoyannis, Nikolas, & Lanatà, Nicola. Uncovering the Origin of Divergence in the CsM(CrO 4 ) 2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis. United States. doi:10.1021/jacs.7b09474.
Galley, Shane S., Arico, Alexandra A., Lee, Tsung-Han, Deng, Xiaoyu, Yao, Yong-Xin, Sperling, Joseph M., Proust, Vanessa, Storbeck, Julia S., Dobrosavljevic, Vladimir, Neu, Jennifer N., Siegrist, Theo, Baumbach, Ryan E., Albrecht-Schmitt, Thomas E., Kaltsoyannis, Nikolas, and Lanatà, Nicola. Wed . "Uncovering the Origin of Divergence in the CsM(CrO 4 ) 2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis". United States. doi:10.1021/jacs.7b09474.
@article{osti_1434561,
title = {Uncovering the Origin of Divergence in the CsM(CrO 4 ) 2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis},
author = {Galley, Shane S. and Arico, Alexandra A. and Lee, Tsung-Han and Deng, Xiaoyu and Yao, Yong-Xin and Sperling, Joseph M. and Proust, Vanessa and Storbeck, Julia S. and Dobrosavljevic, Vladimir and Neu, Jennifer N. and Siegrist, Theo and Baumbach, Ryan E. and Albrecht-Schmitt, Thomas E. and Kaltsoyannis, Nikolas and Lanatà, Nicola},
abstractNote = {},
doi = {10.1021/jacs.7b09474},
journal = {Journal of the American Chemical Society},
number = 5,
volume = 140,
place = {United States},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/jacs.7b09474

Citation Metrics:
Cited by: 3 works
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Figures / Tables:

Figure 1 Figure 1: Polyhedral representations of CsLn(CrO4)2 (Ln = La, Pr). (a) View along the c axis showing stacking of the lanthanum chromate layers with Cs+ cations in the interlayer space. (b) Depiction of part of a single [Ln(CrO4)2] 1− layer. LnIII is represented as blue polyhedra, CrO4 2− as orangemore » tetrahedra, and Cs+ as tan spheres.« less

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Works referencing / citing this record:

Synthesis and Utility of Neptunium(III) Hydrocarbyl Complex
journal, September 2019

  • Myers, Alexander J.; Tarlton, Michael L.; Kelley, Steven P.
  • Angewandte Chemie International Edition, Vol. 58, Issue 42
  • DOI: 10.1002/anie.201906324

Origins of the odd optical observables in plutonium and americium tungstates
journal, January 2019

  • Cross, Justin N.; Lee, Tsung-Han; Kang, Chang-Jong
  • Chemical Science, Vol. 10, Issue 26
  • DOI: 10.1039/c9sc01174a

Synthesis and Utility of Neptunium(III) Hydrocarbyl Complex
journal, September 2019

  • Myers, Alexander J.; Tarlton, Michael L.; Kelley, Steven P.
  • Angewandte Chemie International Edition, Vol. 58, Issue 42
  • DOI: 10.1002/anie.201906324

Origins of the odd optical observables in plutonium and americium tungstates
journal, January 2019

  • Cross, Justin N.; Lee, Tsung-Han; Kang, Chang-Jong
  • Chemical Science, Vol. 10, Issue 26
  • DOI: 10.1039/c9sc01174a