Uncovering the Origin of Divergence in the CsM(CrO 4 ) 2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis

Galley, Shane S.; Arico, Alexandra A.; Lee, Tsung-Han; Deng, Xiaoyu; Yao, Yong-Xin; Sperling, Joseph M.; Proust, Vanessa; Storbeck, Julia S.; Dobrosavljevic, Vladimir; Neu, Jennifer N.; Siegrist, Theo; Baumbach, Ryan E.; Albrecht-Schmitt, Thomas E.; Kaltsoyannis, Nikolas; Lanatà, Nicola

doi:10.1021/jacs.7b09474

Title: Uncovering the Origin of Divergence in the CsM(CrO ₄ ) ₂ (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis

Journal Article · Tue Jan 09 23:00:00 EST 2018 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.7b09474 · OSTI ID:1434561

Galley, Shane S. ^[1]; Arico, Alexandra A. ^[1]; Lee, Tsung-Han ^[2]; Deng, Xiaoyu ^[2];

^[3]; Sperling, Joseph M. ^[1]; Proust, Vanessa ^[1]; Storbeck, Julia S. ^[1]; Dobrosavljevic, Vladimir ^[4]; Neu, Jennifer N. ^[5]; Siegrist, Theo ^[5]; Baumbach, Ryan E. ^[6];

^[1];

^[7]; Lanatà, Nicola ^[6]

Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, United States
Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08856-8019, United States
Department of Physics and Astronomy, and Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, Iowa 50011, United States
Department of Physics, Florida State University, Tallahassee, Florida 32306, United States, National High Magnetic Field Laboratory, Tallahassee, Florida 32310, United States
National High Magnetic Field Laboratory, Tallahassee, Florida 32310, United States, Department of Chemical Engineering, Florida State University, Tallahassee, Florida 32310, United States
National High Magnetic Field Laboratory, Tallahassee, Florida 32310, United States
School of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, United Kingdom

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016568

OSTI ID:: 1434561

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 5 Vol. 140; ISSN 0002-7863

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Uncovering the Origin of Divergence in the CsM(CrO ₄ ) ₂ (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis