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Title: Chemical structure and bonding in a thorium( iii )–aluminum heterobimetallic complex

We describe the syntheses of [Th( iii )]–[Al] and [U( iii )]–[Al] bimetallics that demonstrate An→Al interactions where the actinide behaves as an electron donor.
Authors:
 [1] ;  [2] ; ORCiD logo [3] ; ORCiD logo [1] ; ORCiD logo [3] ;  [4] ; ORCiD logo [5] ; ORCiD logo [5] ; ORCiD logo [1]
  1. Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
  2. Department of Chemistry, University of California, Berkeley, USA
  3. Department of Chemistry, University of California, Davis, USA
  4. LPCNO, Université de Toulouse, INAS Toulouse, Toulouse, France
  5. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
Publication Date:
Grant/Contract Number:
AC02-05CH11231; NA0003180; NA0000979
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 18; Related Information: CHORUS Timestamp: 2018-05-09 08:14:11; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE National Nuclear Security Administration (NNSA)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1434399