Exceptional Lithium Storage in a Co(OH)2 Anode: Hydride Formation
Abstract
Current lithium ion battery technology is tied in with conventional reaction mechanisms such as insertion, conversion, and alloying reactions even though most future applications like EVs demand much higher energy densities than current ones. Exploring the exceptional reaction mechanism and related electrode materials can be critical for pushing current battery technology to a next level. Here, we introduce an exceptional reaction with a Co(OH)2 material which exhibits an initial charge capacity of 1112 mAh g–1, about twice its theoretical value based on known conventional conversion reaction, and retains its first cycle capacity after 30 cycles. The combined results of synchrotron X-ray diffraction and X-ray absorption spectroscopy indicate that nanosized Co metal particles and LiOH are generated by conversion reaction at high voltages, and CoxHy, Li2O, and LiH are subsequently formed by hydride reaction between Co metal, LiOH, and other lithium species at low voltages, resulting in a anomalously high capacity beyond the theoretical capacity of Co(OH)2. This is further corroborated by AIMD simulations, localized STEM, and XPS. Furthermore, these findings will provide not only further understanding of exceptional lithium storage of recent nanostructured materials but also valuable guidance to develop advanced electrode materials with high energy density for next-generation batteries.
- Authors:
-
[2];
[1];
[1];
[1]
- Sungkyunkwan Univ., Suwon (South Korea)
- Samsung Advanced Institute of Technology, Suwon (South Korea)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1434329
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Nano
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 3; Journal ID: ISSN 1936-0851
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; colloidal silica-assisted Co(OH)2; high capacity; hydride formation; lithium ion batteries; reaction mechanism
Citation Formats
Kim, Hyunchul, Choi, Woon Ih, Jang, Yoonjung, Balasubramanian, Mahalingam, Lee, Wontae, Park, Gwi Ok, Park, Su Bin, Yoo, Jaeseung, Hong, Jin Seok, Choi, Youn -Suk, Lee, Hyo Sug, Bae, In Tae, Kim, Ji Man, and Yoon, Won -Sub. Exceptional Lithium Storage in a Co(OH)2 Anode: Hydride Formation. United States: N. p., 2018.
Web. doi:10.1021/acsnano.8b00435.
Kim, Hyunchul, Choi, Woon Ih, Jang, Yoonjung, Balasubramanian, Mahalingam, Lee, Wontae, Park, Gwi Ok, Park, Su Bin, Yoo, Jaeseung, Hong, Jin Seok, Choi, Youn -Suk, Lee, Hyo Sug, Bae, In Tae, Kim, Ji Man, & Yoon, Won -Sub. Exceptional Lithium Storage in a Co(OH)2 Anode: Hydride Formation. United States. https://doi.org/10.1021/acsnano.8b00435
Kim, Hyunchul, Choi, Woon Ih, Jang, Yoonjung, Balasubramanian, Mahalingam, Lee, Wontae, Park, Gwi Ok, Park, Su Bin, Yoo, Jaeseung, Hong, Jin Seok, Choi, Youn -Suk, Lee, Hyo Sug, Bae, In Tae, Kim, Ji Man, and Yoon, Won -Sub. Mon .
"Exceptional Lithium Storage in a Co(OH)2 Anode: Hydride Formation". United States. https://doi.org/10.1021/acsnano.8b00435. https://www.osti.gov/servlets/purl/1434329.
@article{osti_1434329,
title = {Exceptional Lithium Storage in a Co(OH)2 Anode: Hydride Formation},
author = {Kim, Hyunchul and Choi, Woon Ih and Jang, Yoonjung and Balasubramanian, Mahalingam and Lee, Wontae and Park, Gwi Ok and Park, Su Bin and Yoo, Jaeseung and Hong, Jin Seok and Choi, Youn -Suk and Lee, Hyo Sug and Bae, In Tae and Kim, Ji Man and Yoon, Won -Sub},
abstractNote = {Current lithium ion battery technology is tied in with conventional reaction mechanisms such as insertion, conversion, and alloying reactions even though most future applications like EVs demand much higher energy densities than current ones. Exploring the exceptional reaction mechanism and related electrode materials can be critical for pushing current battery technology to a next level. Here, we introduce an exceptional reaction with a Co(OH)2 material which exhibits an initial charge capacity of 1112 mAh g–1, about twice its theoretical value based on known conventional conversion reaction, and retains its first cycle capacity after 30 cycles. The combined results of synchrotron X-ray diffraction and X-ray absorption spectroscopy indicate that nanosized Co metal particles and LiOH are generated by conversion reaction at high voltages, and CoxHy, Li2O, and LiH are subsequently formed by hydride reaction between Co metal, LiOH, and other lithium species at low voltages, resulting in a anomalously high capacity beyond the theoretical capacity of Co(OH)2. This is further corroborated by AIMD simulations, localized STEM, and XPS. Furthermore, these findings will provide not only further understanding of exceptional lithium storage of recent nanostructured materials but also valuable guidance to develop advanced electrode materials with high energy density for next-generation batteries.},
doi = {10.1021/acsnano.8b00435},
journal = {ACS Nano},
number = 3,
volume = 12,
place = {United States},
year = {Mon Feb 26 00:00:00 EST 2018},
month = {Mon Feb 26 00:00:00 EST 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 51 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013
- Sathiya, M.; Rousse, G.; Ramesha, K.
- Nature Materials, Vol. 12, Issue 9
Intercalation compounds of graphite
journal, January 2002
- Dresselhaus, M. S.; Dresselhaus, G.
- Advances in Physics, Vol. 51, Issue 1
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000
- Poizot, P.; Laruelle, S.; Grugeon, S.
- Nature, Vol. 407, Issue 6803, p. 496-499
Reversible Lithium-Ion Insertion in Molybdenum Oxide Nanoparticles
journal, October 2008
- Lee, Se-Hee; Kim, Yong-Hyun; Deshpande, Rohit
- Advanced Materials, Vol. 20, Issue 19
A review of the electrochemical performance of alloy anodes for lithium-ion batteries
journal, January 2011
- Zhang, Wei-Jun
- Journal of Power Sources, Vol. 196, Issue 1
Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes
journal, November 2011
- Wang, Feng; Robert, Rosa; Chernova, Natasha A.
- Journal of the American Chemical Society, Vol. 133, Issue 46
Porous Co3O4 Nanotubes Derived From Co4(CO)12 Clusters on Carbon Nanotube Templates: A Highly Efficient Material For Li-Battery Applications
journal, December 2007
- Du, N.; Zhang, H.; Chen, B. D.
- Advanced Materials, Vol. 19, Issue 24
Layered vanadium and molybdenum oxides: batteries and electrochromics
journal, January 2009
- Chernova, Natasha A.; Roppolo, Megan; Dillon, Anne C.
- Journal of Materials Chemistry, Vol. 19, Issue 17
α-Fe2O3 Nanoflakes as an Anode Material for Li-Ion Batteries
journal, October 2007
- Reddy, M. V.; Yu, T.; Sow, C. H.
- Advanced Functional Materials, Vol. 17, Issue 15
Crystalline-Amorphous Core−Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes
journal, January 2009
- Cui, Li-Feng; Ruffo, Riccardo; Chan, Candace K.
- Nano Letters, Vol. 9, Issue 1, p. 491-495
Fe3O4 nanoparticle-integrated graphene sheets for high-performance half and full lithium ion cells
journal, January 2011
- Ji, Liwen; Tan, Zhongkui; Kuykendall, Tevye R.
- Physical Chemistry Chemical Physics, Vol. 13, Issue 15
Interactions of Copper and Iron in Conversion Reactions of Nanosized Oxides with Large Variations in Iron-Copper Ratio
journal, January 2011
- Gruner, W.; Thomas, J.; Giebeler, L.
- Journal of The Electrochemical Society, Vol. 158, Issue 12
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions (Adv. Mater. 35/2010)
journal, September 2010
- Cabana, Jordi; Monconduit, Laure; Larcher, Dominique
- Advanced Materials, Vol. 22, Issue 35
Nanoionics: ion transport and electrochemical storage in confined systems
journal, November 2005
- Maier, J.
- Nature Materials, Vol. 4, Issue 11, p. 805-815
Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005
- Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
- Nature Materials, Vol. 4, Issue 5, p. 366-377
High capacity and excellent cycling stability of branched cobalt oxide nanowires as Li-insertion materials
journal, July 2010
- Li, Cheng Chao; Yin, Xiao Ming; Chen, Li Bao
- Applied Physics Letters, Vol. 97, Issue 4
High Capacity MoO 2 /Graphite Oxide Composite Anode for Lithium-Ion Batteries
journal, January 2012
- Xu, Yun; Yi, Ran; Yuan, Bin
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 3
Porous SnO2 nanowire bundles for photocatalyst and Li ion battery applications
journal, January 2011
- Han, Yutao; Wu, Xiang; Ma, Yulin
- CrystEngComm, Vol. 13, Issue 10
Ordered mesoporous SnO2 with a highly crystalline state as an anode material for lithium ion batteries with enhanced electrochemical performance
journal, January 2013
- Wang, Xuekun; Li, Zhaoqiang; Li, Qun
- CrystEngComm, Vol. 15, Issue 18
Origin of additional capacities in metal oxide lithium-ion battery electrodes
journal, November 2013
- Hu, Yan-Yan; Liu, Zigeng; Nam, Kyung-Wan
- Nature Materials, Vol. 12, Issue 12
New Insight into the Reaction Mechanism for Exceptional Capacity of Ordered Mesoporous SnO 2 Electrodes via Synchrotron-Based X-ray Analysis
journal, November 2014
- Kim, Hyunchul; Park, Gwi Ok; Kim, Yunok
- Chemistry of Materials, Vol. 26, Issue 22
Probing the Additional Capacity and Reaction Mechanism of the RuO 2 Anode in Lithium Rechargeable Batteries
journal, June 2015
- Kim, Yunok; Muhammad, Shoaib; Kim, Hyunchul
- ChemSusChem, Vol. 8, Issue 14
Discovery of abnormal lithium-storage sites in molybdenum dioxide electrodes
journal, March 2016
- Shon, Jeong Kuk; Lee, Hyo Sug; Park, Gwi Ok
- Nature Communications, Vol. 7, Issue 1
Nanocrystallinity effects in lithium battery materials
journal, January 2003
- Jamnik, Janez; Maier, Joachim
- Physical Chemistry Chemical Physics, Vol. 5, Issue 23
Fully Reversible Homogeneous and Heterogeneous Li Storage in RuO2 with High Capacity
journal, August 2003
- Balaya, P.; Li, H.; Kienle, L.
- Advanced Functional Materials, Vol. 13, Issue 8
Improved performances of β-Ni(OH)2@reduced-graphene-oxide in Ni-MH and Li-ion batteries
journal, January 2011
- Li, Baojun; Cao, Huaqiang; Shao, Jin
- Chemical Communications, Vol. 47, Issue 11
A Co(OH)2−graphene nanosheets composite as a high performance anode material for rechargeable lithium batteries
journal, April 2010
- He, Yu-Shi; Bai, Da-Wei; Yang, Xiaowei
- Electrochemistry Communications, Vol. 12, Issue 4
Preparation and electrochemical performances of doughnut-like Ni(OH)2–Co(OH)2 composites as pseudocapacitor materials
journal, January 2012
- Li, Jinxiu; Yang, Mei; Wei, Jinping
- Nanoscale, Vol. 4, Issue 15
Electrochemically-deposited nanostructured Co(OH) 2 flakes on three-dimensional ordered nickel/silicon microchannel plates for miniature supercapacitors
journal, January 2013
- Li, Mai; Xu, Shaohui; Liu, Tao
- J. Mater. Chem. A, Vol. 1, Issue 3
Preparation of the Novel Nanocomposite Co(OH)2/ Ultra-Stable Y Zeolite and Its Application as a Supercapacitor with High Energy Density
journal, October 2004
- Cao, L.; Xu, F.; Liang, Y. -Y.
- Advanced Materials, Vol. 16, Issue 20
Synthesis and electrochemical characterization of mesoporous CoxNi1−x layered double hydroxides as electrode materials for supercapacitors
journal, April 2009
- Hu, Zhong-Ai; Xie, Yu-Long; Wang, Yao-Xian
- Electrochimica Acta, Vol. 54, Issue 10
Three-Dimentional Porous Nano-Ni/Co(OH) 2 Nanoflake Composite Film: A Pseudocapacitive Material with Superior Performance
journal, October 2011
- Xia, X. H.; Tu, J. P.; Zhang, Y. Q.
- The Journal of Physical Chemistry C, Vol. 115, Issue 45
Potentiostatically deposited nanostructured α-Co(OH)2: A high performance electrode material for redox-capacitors
journal, September 2007
- Gupta, Vinay; Kusahara, Teruki; Toyama, Hiroshi
- Electrochemistry Communications, Vol. 9, Issue 9
Assessment of Liquid Crystal Template Deposited Porous Nickel as a Supercapacitor Electrode Material
journal, January 2005
- Ganesh, V.; Lakshminarayanan, V.; Pitchumani, S.
- Electrochemical and Solid-State Letters, Vol. 8, Issue 6
Facile and controllable one-pot synthesis of an ordered nanostructure of Co(OH)2 nanosheets and their modification by oxidation for high-performance lithium-ion batteries
journal, January 2012
- Huang, Xiao-lei; Zhao, Xue; Wang, Zhong-li
- Journal of Materials Chemistry, Vol. 22, Issue 9
Self-assembled large-area Co(OH)2 nanosheets/ionic liquid modified graphene heterostructures toward enhanced energy storage
journal, January 2012
- Huang, Xiao-lei; Chai, Jia; Jiang, Tao
- Journal of Materials Chemistry, Vol. 22, Issue 8
Effect of Colloidal Silica on the Porous Structure Parameters of Microspheres Prepared from Urea Formaldehyde Resin and Silica Gel
journal, July 2004
- Hayrapetyan, S. S.; Khachatryan, H. G.
- Colloid Journal, Vol. 66, Issue 4
Effect of colloidal silica on the mechanical properties of fiber–cement reinforced with cellulosic fibers
journal, July 2014
- Santos, Sergio Francisco; Rodrigues, José de Anchieta; Tonoli, Gustavo Henrique Denzin
- Journal of Materials Science, Vol. 49, Issue 21
Crystal structure of brucite-type cobalt hydroxide β-Co{O(H,D)}2 — neutron diffraction, IR and Raman spectroscopy
journal, February 1998
- Mockenhaupt, Ch.; Zeiske, Th.; Lutz, H. D.
- Journal of Molecular Structure, Vol. 443, Issue 1-3
Selective and Controlled Synthesis of α- and β-Cobalt Hydroxides in Highly Developed Hexagonal Platelets
journal, October 2005
- Liu, Zhaoping; Ma, Renzhi; Osada, Minoru
- Journal of the American Chemical Society, Vol. 127, Issue 40
Topochemical Synthesis of Monometallic (Co2+–Co3+) Layered Double Hydroxide and Its Exfoliation into Positively Charged Co(OH)2 Nanosheets
journal, January 2008
- Ma, Renzhi; Takada, Kazunori; Fukuda, Katsutoshi
- Angewandte Chemie International Edition, Vol. 47, Issue 1
TiO2-(B) Nanotubes as Anodes for Lithium Batteries: Origin and Mitigation of Irreversible Capacity
journal, January 2012
- Brutti, Sergio; Gentili, Valentina; Menard, Hervé
- Advanced Energy Materials, Vol. 2, Issue 3
High Capacity Li Ion Battery Anodes Using Ge Nanowires
journal, January 2008
- Chan, Candace K.; Zhang, Xiao Feng; Cui, Yi
- Nano Letters, Vol. 8, Issue 1, p. 307-309
Synthesis, Characterization, and Li-Electrochemical Performance of Highly Porous Co 3 O 4 Powders
journal, June 2007
- Binotto, G.; Larcher, D.; Prakash, A. S.
- Chemistry of Materials, Vol. 19, Issue 12
On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential
journal, January 2002
- Laruelle, S.; Grugeon, S.; Poizot, P.
- Journal of The Electrochemical Society, Vol. 149, Issue 5, p. A627-A634
Elucidation of the reaction mechanism upon lithiation and delithiation of Cu 0.5 TiOPO 4
journal, January 2014
- Bleith, Peter; Valla, Maxence; Novák, Petr
- J. Mater. Chem. A, Vol. 2, Issue 31
Electrochemical behavior of [{Mn(Bpy)}(VO3)2]≈(H2O)1.24 and [{Mn(Bpy)0.5}(VO3)2]≈(H2O)0.62 inorganic–organic Brannerites in lithium and sodium cells
journal, April 2014
- Fernández de Luis, Roberto; Ponrouch, Alexandre; Rosa Palacín, M.
- Journal of Solid State Chemistry, Vol. 212
Intercalation and conversion reactions in Ni0.5TiOPO4 Li-ion battery anode materials
journal, May 2013
- Lasri, Karima; Dahbi, Mohammed; Liivat, Anti
- Journal of Power Sources, Vol. 229
The Origin of Capacity Fading in NiFe 2 O 4 Conversion Electrodes for Lithium Ion Batteries Unfolded by 57 Fe Mössbauer Spectroscopy
journal, June 2010
- Vidal-Abarca, C.; Lavela, P.; Tirado, J. L.
- The Journal of Physical Chemistry C, Vol. 114, Issue 29
Electrochemical and In Situ X-Ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites
journal, January 1997
- Courtney, Ian A.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 144, Issue 6, p. 2045-2052
Doped tin oxides as potential lithium ion battery negative electrodes
journal, September 1999
- Belliard, F.; Connor, P. A.; Irvine, J. T. S.
- Ionics, Vol. 5, Issue 5-6
Anodes based on oxide materials for lithium rechargeable batteries
journal, August 1999
- Li, H.
- Solid State Ionics, Vol. 123, Issue 1-4
Electrochemical Reaction Between Lithium and β-Quartz GeO[sub 2]
journal, January 2004
- Peña, Jesús Santos; Sandu, Izabela; Joubert, Olivier
- Electrochemical and Solid-State Letters, Vol. 7, Issue 9
Effects of alloying elements on the electronic structure and ductility of NiAl compounds investigated by X-ray absorption fine structure
journal, June 2013
- Tian, J. S.; Han, G. M.; Wei, H.
- Philosophical Magazine, Vol. 93, Issue 17
The Co-Li (Cobalt-Lithium) system
journal, October 1990
- Sangster, J.; Pelton, A. D.
- Journal of Phase Equilibria, Vol. 11, Issue 5
Relation between the Allotropic Transformation of Cobalt and Some Additional Elements [コバルトの同素變態と附加元素との關係に就て]
journal, January 1937
- Haschimoto, Uichi
- The Journal of the Japan Institute of Metals, Vol. 1, Issue 5
Enthalpies of mixing of liquid ternary Co–Li–Sn alloys
journal, September 2014
- Yakymovych, Andriy; Fürtauer, Siegfried; Flandorfer, Hans
- Monatshefte für Chemie - Chemical Monthly, Vol. 145, Issue 11
Algebraic Representation of Thermodynamic Properties and the Classification of Solutions
journal, February 1948
- Redlich, Otto; Kister, A. T.
- Industrial & Engineering Chemistry, Vol. 40, Issue 2
Enthalpies de formation des alliages liquides bismuth-étain-gallium à 723 k. Choix d’une représentation analytique des grandeurs d’excès intégrales et partielles de mélange
journal, January 1975
- Muggianu, Yves-Marie; Gambino, Michèle; Bros, Jean-Pierre
- Journal de Chimie Physique, Vol. 72
Amorphous FePO4 as 3 V cathode material for lithium secondary batteries
journal, April 2002
- Hong, Young-Sik; Ryu, Kwang Sun; Park, Yong Joon
- Journal of Materials Chemistry, Vol. 12, Issue 6
Amorphous Hierarchical Porous GeO x as High-Capacity Anodes for Li Ion Batteries with Very Long Cycling Life
journal, December 2011
- Wang, Xiao-Liang; Han, Wei-Qiang; Chen, Haiyan
- Journal of the American Chemical Society, Vol. 133, Issue 51
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 49, Issue 20, p. 14251-14269
Nanoscale Chemical and Electrical Stabilities of Graphene-covered Silver Nanowire Networks for Transparent Conducting Electrodes
journal, September 2016
- Kim, Seong Heon; Choi, Woon Ih; Kim, Kwang Hee
- Scientific Reports, Vol. 6, Issue 1
Hydrogen-Bond Dynamics of Water at the Interface with InP/GaP(001) and the Implications for Photoelectrochemistry
journal, October 2013
- Wood, Brandon C.; Schwegler, Eric; Choi, Woon Ih
- Journal of the American Chemical Society, Vol. 135, Issue 42
A fast and robust algorithm for Bader decomposition of charge density
journal, June 2006
- Henkelman, Graeme; Arnaldsson, Andri; Jónsson, Hannes
- Computational Materials Science, Vol. 36, Issue 3
Atoms in molecules
journal, January 1985
- Bader, R. F. W.
- Accounts of Chemical Research, Vol. 18, Issue 1
Improved grid-based algorithm for Bader charge allocation
journal, January 2007
- Sanville, Edward; Kenny, Steven D.; Smith, Roger
- Journal of Computational Chemistry, Vol. 28, Issue 5
Mössbauer and TEM study of Fe–Cr powders elaborated by mechanical alloying
journal, August 1999
- Lemoine, C.; Fnidiki, A.; Lemarchand, D.
- Journal of Magnetism and Magnetic Materials, Vol. 203, Issue 1-3
Influence of boron content on the amorphization rate of Co–B mixtures by mechanical alloying
journal, June 1993
- Corrias, A.; Ennas, G.; Marongiu, G.
- Journal of Materials Research, Vol. 8, Issue 6
Study on mechanical alloying and subsequent heat treatment of the Ti–Si system
journal, May 2000
- Yang, Junyou; Wu, Jiansheng; Hua, Wei
- Physica B: Condensed Matter, Vol. 279, Issue 4
Mechanical stability of Sn–Co alloy anodes for lithium secondary batteries
journal, May 2004
- Tamura, N.; Fujimoto, M.; Kamino, M.
- Electrochimica Acta, Vol. 49, Issue 12
The electronic structure of alkali metal oxides
journal, February 2010
- Zhuravlev, Yu. N.; Kravchenko, N. G.; Obolonskaya, O. S.
- Russian Journal of Physical Chemistry B, Vol. 4, Issue 1
XPS and UPS studies on electronic structure of Li2O
journal, December 2000
- Tanaka, Satoru; Taniguchi, Masaki; Tanigawa, Hisashi
- Journal of Nuclear Materials, Vol. 283-287
Formation of a linear LiOH compound on Cu(001): reaction of H2O with Li adatoms at low coverages
journal, March 1992
- Mizuno, S.; Tochihara, H.; Kadowaki, T.
- Surface Science, Vol. 264, Issue 1-2
XPS investigations of electrolyte/electrode interactions for various Li-ion battery materials
journal, January 2011
- Oswald, S.; Mikhailova, D.; Scheiba, F.
- Analytical and Bioanalytical Chemistry, Vol. 400, Issue 3
Thermal Stability of Li 2 O 2 and Li 2 O for Li-Air Batteries: In Situ XRD and XPS Studies
journal, January 2013
- Yao, Koffi P. C.; Kwabi, David G.; Quinlan, Ronald A.
- Journal of The Electrochemical Society, Vol. 160, Issue 6
Probing the Origin of Enhanced Stability of “AlPO4” Nanoparticle Coated LiCoO2 during Cycling to High Voltages: Combined XRD and XPS Studies
journal, October 2009
- Lu, Yi-Chun; Mansour, Azzam N.; Yabuuchi, Naoaki
- Chemistry of Materials, Vol. 21, Issue 19, p. 4408-4424
X-ray photoelectron studies on some oxides and hydroxides of cobalt, nickel, and copper
journal, November 1975
- McIntyre, N. S.; Cook, M. G.
- Analytical Chemistry, Vol. 47, Issue 13
Surface analysis and the adsorption of Co(II) on goethite
journal, October 1983
- Schenck, C. V.; Dillard, J. G.; Murray, J. W.
- Journal of Colloid and Interface Science, Vol. 95, Issue 2
Synthesis and Characterization of Cobalt Hydroxide, Cobalt Oxyhydroxide, and Cobalt Oxide Nanodiscs
journal, November 2009
- Yang, Jing; Liu, Hongwei; Martens, Wayde N.
- The Journal of Physical Chemistry C, Vol. 114, Issue 1
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni
journal, January 2011
- Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P.
- Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730
ELECTROOXIDATION OF 2,4,6-TRICHLOROPHENOL ON GLASSY CARBON ELECTRODES MODIFIED WITH COMPOSITE Ni(OH)2-Co(OH)2 FILMS
journal, January 2013
- GonzÁLez, ThaÍS; Salazar, Ricardo; Marco, JosÉ F.
- Journal of the Chilean Chemical Society, Vol. 58, Issue 4
EXPGUI , a graphical user interface for GSAS
journal, April 2001
- Toby, Brian H.
- Journal of Applied Crystallography, Vol. 34, Issue 2
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Effect of the damping function in dispersion corrected density functional theory
journal, March 2011
- Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars
- Journal of Computational Chemistry, Vol. 32, Issue 7
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010
- Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
- The Journal of Chemical Physics, Vol. 132, Issue 15
Works referencing / citing this record:
A Robust Route to Co 2 (OH) 2 CO 3 Ultrathin Nanosheets with Superior Lithium Storage Capability Templated by Aspartic Acid‐Functionalized Graphene Oxide
journal, May 2019
- Zhao, Shiqiang; Wang, Zewei; He, Yanjie
- Advanced Energy Materials
Discovery of a new intercalation-type anode for high-performance sodium ion batteries
journal, January 2019
- Zhao, Yajun; Sun, Tao; Yin, Qing
- Journal of Materials Chemistry A, Vol. 7, Issue 25