Block copolymer derived 3-D interpenetrating multifunctional gyroidal nanohybrids for electrical energy storage
Abstract
All necessary battery components are synthesized within a three-dimensionally periodic, co-continuous nanostructure and the first reversible charge–discharge characteristics are demonstrated.
- Authors:
-
- Department of Materials Science and Engineering, Cornell University, Ithaca, USA, Department of Chemistry and Chemical Biology, Cornell University, Ithaca
- Department of Chemistry and Chemical Biology, Cornell University, Ithaca, USA
- Department of Materials Science and Engineering, Cornell University, Ithaca, USA
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1434081
- Grant/Contract Number:
- DE SC0001086
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Name: Energy & Environmental Science Journal Volume: 11 Journal Issue: 5; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Werner, J. G., Rodríguez-Calero, G. G., Abruña, H. D., and Wiesner, U. Block copolymer derived 3-D interpenetrating multifunctional gyroidal nanohybrids for electrical energy storage. United Kingdom: N. p., 2018.
Web. doi:10.1039/C7EE03571C.
Werner, J. G., Rodríguez-Calero, G. G., Abruña, H. D., & Wiesner, U. Block copolymer derived 3-D interpenetrating multifunctional gyroidal nanohybrids for electrical energy storage. United Kingdom. https://doi.org/10.1039/C7EE03571C
Werner, J. G., Rodríguez-Calero, G. G., Abruña, H. D., and Wiesner, U. Mon .
"Block copolymer derived 3-D interpenetrating multifunctional gyroidal nanohybrids for electrical energy storage". United Kingdom. https://doi.org/10.1039/C7EE03571C.
@article{osti_1434081,
title = {Block copolymer derived 3-D interpenetrating multifunctional gyroidal nanohybrids for electrical energy storage},
author = {Werner, J. G. and Rodríguez-Calero, G. G. and Abruña, H. D. and Wiesner, U.},
abstractNote = {All necessary battery components are synthesized within a three-dimensionally periodic, co-continuous nanostructure and the first reversible charge–discharge characteristics are demonstrated.},
doi = {10.1039/C7EE03571C},
journal = {Energy & Environmental Science},
number = 5,
volume = 11,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
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https://doi.org/10.1039/C7EE03571C
https://doi.org/10.1039/C7EE03571C
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Works referenced in this record:
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Three-dimensional integrated circuits
journal, July 2006
- Topol, A. W.; Tulipe, D. C. La; Shi, L.
- IBM Journal of Research and Development, Vol. 50, Issue 4.5
High-power lithium ion microbatteries from interdigitated three-dimensional bicontinuous nanoporous electrodes
journal, April 2013
- Pikul, James H.; Gang Zhang, Hui; Cho, Jiung
- Nature Communications, Vol. 4, Article No. 1732
Tunable near-infrared and visible-light transmittance in nanocrystal-in-glass composites
journal, August 2013
- Llordés, Anna; Garcia, Guillermo; Gazquez, Jaume
- Nature, Vol. 500, Issue 7462
Architectural integration of the components necessary for electrical energy storage on the nanoscale and in 3D
journal, January 2011
- Rhodes, Christopher P.; Long, Jeffrey W.; Pettigrew, Katherine A.
- Nanoscale, Vol. 3, Issue 4
Porphyrin-Sensitized Solar Cells with Cobalt (II/III)-Based Redox Electrolyte Exceed 12 Percent Efficiency
journal, November 2011
- Yella, A.; Lee, H. -W.; Tsao, H. N.
- Science, Vol. 334, Issue 6056
Three-dimensional holey-graphene/niobia composite architectures for ultrahigh-rate energy storage
journal, May 2017
- Sun, Hongtao; Mei, Lin; Liang, Junfei
- Science, Vol. 356, Issue 6338
Optimizing Areal Capacities through Understanding the Limitations of Lithium-Ion Electrodes
journal, November 2015
- Gallagher, Kevin G.; Trask, Stephen E.; Bauer, Christoph
- Journal of The Electrochemical Society, Vol. 163, Issue 2
Multifunctional 3D nanoarchitectures for energy storage and conversion
journal, January 2009
- Rolison, Debra R.; Long, Jeffrey W.; Lytle, Justin C.
- Chemical Society Reviews, Vol. 38, Issue 1, p. 226-252
Where Do Batteries End and Supercapacitors Begin?
journal, March 2014
- Simon, P.; Gogotsi, Y.; Dunn, B.
- Science, Vol. 343, Issue 6176
3D Printing of Interdigitated Li-Ion Microbattery Architectures
journal, June 2013
- Sun, Ke; Wei, Teng-Sing; Ahn, Bok Yeop
- Advanced Materials, Vol. 25, Issue 33, p. 4539-4543
Fabrication of a Fully Infiltrated Three-Dimensional Solid-State Interpenetrating Electrochemical Cell
journal, January 2007
- Ergang, Nicholas S.; Fierke, Melissa A.; Wang, Zhiyong
- Journal of The Electrochemical Society, Vol. 154, Issue 12
Direct access to thermally stable and highly crystalline mesoporous transition-metal oxides with uniform pores
journal, January 2008
- Lee, Jinwoo; Christopher Orilall, M.; Warren, Scott C.
- Nature Materials, Vol. 7, Issue 3
Promises and challenges of nanomaterials for lithium-based rechargeable batteries
journal, June 2016
- Sun, Yongming; Liu, Nian; Cui, Yi
- Nature Energy, Vol. 1, Issue 7
The Gyroid: A New Equilibrium Morphology in Weakly Segregated Diblock Copolymers
journal, July 1994
- Hajduk, Damian A.; Harper, Paul E.; Gruner, Sol M.
- Macromolecules, Vol. 27, Issue 15
Nanomaterials for Rechargeable Lithium Batteries
journal, April 2008
- Bruce, Peter G.; Scrosati, Bruno; Tarascon, Jean-Marie
- Angewandte Chemie International Edition, Vol. 47, Issue 16, p. 2930-2946
Pushing the limits of lithography
journal, August 2000
- Ito, Takashi; Okazaki, Shinji
- Nature, Vol. 406, Issue 6799
Self-Assembly at All Scales
journal, March 2002
- Whitesides, George M.; Grzybowski, Bartosz
- Science, Vol. 295, Issue 5564, p. 2418-2421
Solid-state thin-film rechargeable batteries
journal, February 2005
- Dudney, N.J.
- Materials Science and Engineering: B, Vol. 116, Issue 3, p. 245-249
Synthesis and Characterization of Poly-3,4-ethylenedioxythiophene/2,5-Dimercapto-1,3,4-thiadiazole (PEDOT-DMcT) Hybrids
journal, June 2015
- Rodríguez-Calero, Gabriel G.; Conte, Sean; Lowe, Michael A.
- Electrochimica Acta, Vol. 167
Block Copolymers—Designer Soft Materials
journal, February 1999
- Bates, Frank S.; Fredrickson, Glenn H.
- Physics Today, Vol. 52, Issue 2
Theoretical and Electrochemical Analysis of Poly(3,4-alkylenedioxythiophenes): Electron-Donating Effects and Onset of p-Doped Conductivity
journal, September 2010
- Burkhardt, Stephen E.; Rodríguez-Calero, Gabriel G.; Lowe, Michael A.
- The Journal of Physical Chemistry C, Vol. 114, Issue 39
Ordered Network Phases in Linear Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers
journal, November 2004
- Epps, Thomas H.; Cochran, Eric W.; Bailey, Travis S.
- Macromolecules, Vol. 37, Issue 22
Butterfly gyroid nanostructures as a time-frozen glimpse of intracellular membrane development
journal, April 2017
- Wilts, Bodo D.; Apeleo Zubiri, Benjamin; Klatt, Michael A.
- Science Advances, Vol. 3, Issue 4
A Bicontinuous Double Gyroid Hybrid Solar Cell
journal, August 2009
- Crossland, Edward J. W.; Kamperman, Marleen; Nedelcu, Mihaela
- Nano Letters, Vol. 9, Issue 8
A Noncubic Triply Periodic Network Morphology in Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers
journal, August 2002
- Bailey, Travis S.; Hardy, Cordell M.; Epps, Thomas H.
- Macromolecules, Vol. 35, Issue 18
Highly Improved Rate Capability for a Lithium-Ion Battery Nano-Li4Ti5O12 Negative Electrode via Carbon-Coated Mesoporous Uniform Pores with a Simple Self-Assembly Method
journal, September 2011
- Kang, Eunae; Jung, Yoon Seok; Kim, Gi-Heon
- Advanced Functional Materials, Vol. 21, Issue 22
Permeant molecular sieving with electrochemically prepared 6-nm films of poly(phenylene oxide)
journal, March 1991
- McCarley, Robin L.; Irene, Eugene A.; Murray, Royce W.
- The Journal of Physical Chemistry, Vol. 95, Issue 6
Nanofabrication
journal, September 2003
- Marrian, Christie R. K.; Tennant, Donald M.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 21, Issue 5
Block copolymer based composition and morphology control in nanostructured hybrid materials for energy conversion and storage: solar cells, batteries, and fuel cells
journal, January 2011
- Orilall, M. Christopher; Wiesner, Ulrich
- Chem. Soc. Rev., Vol. 40, Issue 2
True Performance Metrics in Electrochemical Energy Storage
journal, November 2011
- Gogotsi, Y.; Simon, P.
- Science, Vol. 334, Issue 6058
Nanomaterials in transistors: From high-performance to thin-film applications
journal, August 2015
- Franklin, A. D.
- Science, Vol. 349, Issue 6249
A Family of Highly Ordered Mesoporous Polymer Resin and Carbon Structures from Organic−Organic Self-Assembly
journal, September 2006
- Meng, Yan; Gu, Dong; Zhang, Fuqiang
- Chemistry of Materials, Vol. 18, Issue 18
Gyroidal mesoporous multifunctional nanocomposites via atomic layer deposition
journal, January 2014
- Werner, Jörg G.; Scherer, Maik R. J.; Steiner, Ullrich
- Nanoscale, Vol. 6, Issue 15
Synthesis and Characterization of Gyroidal Mesoporous Carbons and Carbon Monoliths with Tunable Ultralarge Pore Size
journal, December 2013
- Werner, Jörg G.; Hoheisel, Tobias N.; Wiesner, Ulrich
- ACS Nano, Vol. 8, Issue 1
The chiral structure of porous chitin within the wing-scales of Callophrys rubi
journal, May 2011
- Schröder-Turk, G. E.; Wickham, S.; Averdunk, H.
- Journal of Structural Biology, Vol. 174, Issue 2
Three-Dimensional Battery Architectures
journal, October 2004
- Long, Jeffrey W.; Dunn, Bruce; Rolison, Debra R.
- Chemical Reviews, Vol. 104, Issue 10, p. 4463-4492
Mesophase Structure-Mechanical and Ionic Transport Correlations in Extended Amphiphilic Dendrons
journal, September 2004
- Cho, B. -K.
- Science, Vol. 305, Issue 5690
Moore's law: the future of Si microelectronics
journal, June 2006
- Thompson, Scott E.; Parthasarathy, Srivatsan
- Materials Today, Vol. 9, Issue 6
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy
journal, September 2013
- Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 19
MATERIALS SCIENCE: Electrochemical Capacitors for Energy Management
journal, August 2008
- Miller, J. R.; Simon, P.
- Science, Vol. 321, Issue 5889
Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles
journal, July 2001
- Joo, Sang Hoon; Choi, Seong Jae; Oh, Ilwhan
- Nature, Vol. 412, Issue 6843
Nanoscale Polymer Electrolytes: Ultrathin Electrodeposited Poly(Phenylene Oxide) with Solid-State Ionic Conductivity
journal, September 2004
- Rhodes, Christopher P.; Long, Jeffrey W.; Doescher, Michael S.
- The Journal of Physical Chemistry B, Vol. 108, Issue 35
Hybrid Organic Electrodes: The Rational Design and Synthesis of High-Energy Redox-Active Pendant Functionalized Polypyrroles for Electrochemical Energy Storage
journal, January 2017
- Shen, Luxi; Mizutani, Masato; Rodríguez-Calero, Gabriel G.
- Journal of The Electrochemical Society, Vol. 164, Issue 9
Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005
- Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
- Nature Materials, Vol. 4, Issue 5, p. 366-377
Preparation and properties of electrically conducting textiles byin situ polymerization of poly(3,4-ethylenedioxythiophene)
journal, January 2005
- Hong, Kyung Hwa; Oh, Kyung Wha; Kang, Tae Jin
- Journal of Applied Polymer Science, Vol. 97, Issue 3
3D lithium ion batteries—from fundamentals to fabrication
journal, January 2011
- Roberts, Matthew; Johns, Phil; Owen, John
- Journal of Materials Chemistry, Vol. 21, Issue 27
Fabrication and properties of a carbon/polypyrrole three-dimensional microbattery
journal, April 2008
- Min, Hong-Seok; Park, Benjamin Y.; Taherabadi, Lili
- Journal of Power Sources, Vol. 178, Issue 2
Polymorphism of Lipids
journal, August 1967
- Luzzati, Vittorio; Spegt, P. A.
- Nature, Vol. 215, Issue 5102
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009
- Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
- Nature Materials, Vol. 8, Issue 6, p. 500-506
Template-Synthesized LiCoO 2 , LiMn 2 O 4 , and LiNi 0.8 Co 0.2 O 2 Nanotubes as the Cathode Materials of Lithium Ion Batteries
journal, July 2005
- Li, Xiaoxia; Cheng, Fangyi; Guo, Bing
- The Journal of Physical Chemistry B, Vol. 109, Issue 29