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Title: Using lead chalcogenide nanocrystals as spin mixers: a perspective on near-infrared-to-visible upconversion

Abstract

This perspective highlights recent advances in the field of PbS NC-sensitized near-infrared-to-visible upconversion based on triplet–triplet annihilation in rubrene.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [1]
  1. Massachusetts Institute of Technology, Cambridge, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1434079
Grant/Contract Number:  
SC0001088
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 26; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Nienhaus, Lea, Wu, Mengfei, Bulović, Vladimir, Baldo, Marc A., and Bawendi, Moungi G. Using lead chalcogenide nanocrystals as spin mixers: a perspective on near-infrared-to-visible upconversion. United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT00419F.
Nienhaus, Lea, Wu, Mengfei, Bulović, Vladimir, Baldo, Marc A., & Bawendi, Moungi G. Using lead chalcogenide nanocrystals as spin mixers: a perspective on near-infrared-to-visible upconversion. United Kingdom. doi:10.1039/C8DT00419F.
Nienhaus, Lea, Wu, Mengfei, Bulović, Vladimir, Baldo, Marc A., and Bawendi, Moungi G. Mon . "Using lead chalcogenide nanocrystals as spin mixers: a perspective on near-infrared-to-visible upconversion". United Kingdom. doi:10.1039/C8DT00419F.
@article{osti_1434079,
title = {Using lead chalcogenide nanocrystals as spin mixers: a perspective on near-infrared-to-visible upconversion},
author = {Nienhaus, Lea and Wu, Mengfei and Bulović, Vladimir and Baldo, Marc A. and Bawendi, Moungi G.},
abstractNote = {This perspective highlights recent advances in the field of PbS NC-sensitized near-infrared-to-visible upconversion based on triplet–triplet annihilation in rubrene.},
doi = {10.1039/C8DT00419F},
journal = {Dalton Transactions},
number = 26,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8DT00419F

Citation Metrics:
Cited by: 7 works
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Works referenced in this record:

PbSe Nanocrystal Solids for n- and p-Channel Thin Film Field-Effect Transistors
journal, October 2005


Delayed Molecular Triplet Generation from Energized Lead Sulfide Quantum Dots
journal, March 2017

  • Garakyaraghi, Sofia; Mongin, Cédric; Granger, Devin B.
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 7
  • DOI: 10.1021/acs.jpclett.7b00546

Photon upconversion based on sensitized triplet–triplet annihilation
journal, November 2010

  • Singh-Rachford, Tanya N.; Castellano, Felix N.
  • Coordination Chemistry Reviews, Vol. 254, Issue 21-22
  • DOI: 10.1016/j.ccr.2010.01.003

Excitons in nanoscale systems
journal, September 2006

  • Scholes, Gregory D.; Rumbles, Garry
  • Nature Materials, Vol. 5, Issue 9
  • DOI: 10.1038/nmat1710

Photochemical Stability of Pentacene and a Substituted Pentacene in Solution and in Thin Films
journal, November 2004

  • Maliakal, Ashok; Raghavachari, Krishnan; Katz, Howard
  • Chemistry of Materials, Vol. 16, Issue 24
  • DOI: 10.1021/cm049060k

Temporal full-colour tuning through non-steady-state upconversion
journal, January 2015


Upconversion nanoparticles in biological labeling, imaging, and therapy
journal, January 2010

  • Wang, Feng; Banerjee, Debapriya; Liu, Yongsheng
  • The Analyst, Vol. 135, Issue 8
  • DOI: 10.1039/c0an00144a

Encapsulated Triplet–Triplet Annihilation-Based Upconversion in the Aqueous Phase for Sub-Band-Gap Semiconductor Photocatalysis
journal, October 2012

  • Kim, Jae-Hyuk; Kim, Jae-Hong
  • Journal of the American Chemical Society, Vol. 134, Issue 42
  • DOI: 10.1021/ja308789u

Photochemical upconversion: present status and prospects for its application to solar energy conversion
journal, January 2015

  • Schulze, Tim F.; Schmidt, Timothy W.
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE02481H

Colloidal atomic layer deposition growth of PbS/CdS core/shell quantum dots
journal, January 2017

  • Nasilowski, Michel; Nienhaus, Lea; Bertram, Sophie N.
  • Chemical Communications, Vol. 53, Issue 5
  • DOI: 10.1039/C6CC07403K

High Tolerance to Iron Contamination in Lead Halide Perovskite Solar Cells
journal, July 2017


Resonant energy transfer of triplet excitons from pentacene to PbSe nanocrystals
journal, October 2014

  • Tabachnyk, Maxim; Ehrler, Bruno; Gélinas, Simon
  • Nature Materials, Vol. 13, Issue 11
  • DOI: 10.1038/nmat4093

L ONG -R ANGE R ESONANCE E NERGY T RANSFER IN M OLECULAR S YSTEMS
journal, October 2003


Efficient Infrared-to-Visible Upconversion with Subsolar Irradiance
journal, October 2016


Solid-state infrared-to-visible upconversion sensitized by colloidal nanocrystals
journal, November 2015


Designing Transmitter Ligands That Mediate Energy Transfer between Semiconductor Nanocrystals and Molecules
journal, June 2017

  • Huang, Zhiyuan; Tang, Ming L.
  • Journal of the American Chemical Society, Vol. 139, Issue 28
  • DOI: 10.1021/jacs.6b08783

High resolution fluorescence bio-imaging upconversion nanoparticles in insects
journal, January 2017

  • Alkahtani, Masfer; Chen, Yunyun; Pedraza, Julie J.
  • Optics Express, Vol. 25, Issue 2
  • DOI: 10.1364/OE.25.001030

Generation of Optical Harmonics
journal, August 1961


Energy harvesting of non-emissive triplet excitons in tetracene by emissive PbS nanocrystals
journal, October 2014

  • Thompson, Nicholas J.; Wilson, Mark W. B.; Congreve, Daniel N.
  • Nature Materials, Vol. 13, Issue 11
  • DOI: 10.1038/nmat4097

Improving solar cell efficiencies by up-conversion of sub-band-gap light
journal, October 2002

  • Trupke, T.; Green, M. A.; Würfel, P.
  • Journal of Applied Physics, Vol. 92, Issue 7
  • DOI: 10.1063/1.1505677

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

  • Stranks, S. D.; Eperon, G. E.; Grancini, G.
  • Science, Vol. 342, Issue 6156, p. 341-344
  • DOI: 10.1126/science.1243982

Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells
journal, January 2014

  • Eperon, Giles E.; Stranks, Samuel D.; Menelaou, Christopher
  • Energy & Environmental Science, Vol. 7, Issue 3
  • DOI: 10.1039/c3ee43822h

Upconversion Luminescent Materials: Advances and Applications
journal, November 2014

  • Zhou, Jing; Liu, Qian; Feng, Wei
  • Chemical Reviews, Vol. 115, Issue 1
  • DOI: 10.1021/cr400478f

Broadband dye-sensitized upconversion of near-infrared light
journal, July 2012


Size-Dependent Optical Properties of Colloidal PbS Quantum Dots
journal, September 2009

  • Moreels, Iwan; Lambert, Karel; Smeets, Dries
  • ACS Nano, Vol. 3, Issue 10
  • DOI: 10.1021/nn900863a

Relationships between Lead Halide Perovskite Thin-Film Fabrication, Morphology, and Performance in Solar Cells
journal, November 2015

  • Sharenko, Alexander; Toney, Michael F.
  • Journal of the American Chemical Society, Vol. 138, Issue 2
  • DOI: 10.1021/jacs.5b10723

A Theory of Sensitized Luminescence in Solids
journal, May 1953

  • Dexter, D. L.
  • The Journal of Chemical Physics, Vol. 21, Issue 5, p. 836-850
  • DOI: 10.1063/1.1699044

Absolute quantum yield measurements of colloidal NaYF4: Er3+, Yb3+ upconverting nanoparticles
journal, January 2010

  • Boyer, John-Christopher; van Veggel, Frank C. J. M.
  • Nanoscale, Vol. 2, Issue 8
  • DOI: 10.1039/c0nr00253d

Speed Limit for Triplet-Exciton Transfer in Solid-State PbS Nanocrystal-Sensitized Photon Upconversion
journal, July 2017


Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells
journal, March 1961

  • Shockley, William; Queisser, Hans J.
  • Journal of Applied Physics, Vol. 32, Issue 3, p. 510-519
  • DOI: 10.1063/1.1736034

Exciton Fine Structure and Spin Relaxation in Semiconductor Colloidal Quantum Dots
journal, August 2009

  • Kim, Jeongho; Wong, Cathy Y.; Scholes, Gregory D.
  • Accounts of Chemical Research, Vol. 42, Issue 8
  • DOI: 10.1021/ar8002046

Multicomponent Polymeric Film for Red to Green Low Power Sensitized Up-Conversion
journal, February 2009

  • Monguzzi, Angelo; Tubino, Riccardo; Meinardi, Francesco
  • The Journal of Physical Chemistry A, Vol. 113, Issue 7
  • DOI: 10.1021/jp809971u

The triplet state energies of rubrene and diphenylisobenzofuran
journal, August 1981


Utilizing the Lability of Lead Selenide to Produce Heterostructured Nanocrystals with Bright, Stable Infrared Emission
journal, April 2008

  • Pietryga, Jeffrey M.; Werder, Donald J.; Williams, Darrick J.
  • Journal of the American Chemical Society, Vol. 130, Issue 14
  • DOI: 10.1021/ja710437r

Interference-enhanced infrared-to-visible upconversion in solid-state thin films sensitized by colloidal nanocrystals
journal, May 2017

  • Wu, Mengfei; Jean, Joel; Bulović, Vladimir
  • Applied Physics Letters, Vol. 110, Issue 21
  • DOI: 10.1063/1.4984136

Efficient UV–Vis-NIR Responsive Upconversion and Plasmonic-Enhanced Photocatalyst Based on Lanthanide-Doped NaYF 4 /SnO 2 /Ag
journal, October 2017


Upconversion and Anti-Stokes Processes with f and d Ions in Solids
journal, January 2004


Hybrid Molecule–Nanocrystal Photon Upconversion Across the Visible and Near-Infrared
journal, July 2015


Highly Efficient LiYF 4 :Yb 3+ , Er 3+ Upconversion Single Crystal under Solar Cell Spectrum Excitation and Photovoltaic Application
journal, April 2016

  • Chen, Xu; Xu, Wen; Song, Hongwei
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 14
  • DOI: 10.1021/acsami.5b12528

PbS/CdS Core-Shell Quantum Dots Suppress Charge Transfer and Enhance Triplet Transfer
journal, December 2017

  • Huang, Zhiyuan; Xu, Zihao; Mahboub, Melika
  • Angewandte Chemie, Vol. 129, Issue 52
  • DOI: 10.1002/ange.201710224

The nature of quantum dot capping ligands
journal, January 2010


Room-temperature sub-band gap optoelectronic response of hyperdoped silicon
journal, January 2014

  • Mailoa, Jonathan P.; Akey, Austin J.; Simmons, Christie B.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4011

Taking advantage of luminescent lanthanide ions
journal, January 2005

  • Bünzli, Jean-Claude G.; Piguet, Claude
  • Chemical Society Reviews, Vol. 34, Issue 12
  • DOI: 10.1039/b406082m

Triplet annihilation exceeding spin statistical limit in highly efficient fluorescent organic light-emitting diodes
journal, December 2009

  • Kondakov, D. Y.; Pawlik, T. D.; Hatwar, T. K.
  • Journal of Applied Physics, Vol. 106, Issue 12
  • DOI: 10.1063/1.3273407

Ligand enhanced upconversion of near-infrared photons with nanocrystal light absorbers
journal, January 2016

  • Huang, Zhiyuan; Simpson, Duane E.; Mahboub, Melika
  • Chemical Science, Vol. 7, Issue 7
  • DOI: 10.1039/C6SC00257A

Near-Infrared-to-Visible Photon Upconversion Sensitized by a Metal Complex with Spin-Forbidden yet Strong S 0 –T 1 Absorption
journal, July 2016

  • Amemori, Shogo; Sasaki, Yoichi; Yanai, Nobuhiro
  • Journal of the American Chemical Society, Vol. 138, Issue 28
  • DOI: 10.1021/jacs.6b04692