Conductive Polymer Binder-Enabled SiO–SnxCoyCz Anode for High-Energy Lithium-Ion Batteries

Zhao, Hui; Fu, Yanbao; Ling, Min; Jia, Zhe; Song, Xiangyun; Chen, Zonghai; Lu, Jun; Amine, Khalil; Liu, Gao

doi:10.1021/acsami.6b00312

Title: Conductive Polymer Binder-Enabled SiO–Sn_xCo_yC_z Anode for High-Energy Lithium-Ion Batteries

Journal Article · Tue May 10 00:00:00 EDT 2016 · ACS Applied Materials and Interfaces

DOI: https://doi.org/10.1021/acsami.6b00312 · OSTI ID:1433093

Zhao, Hui ^[1]; Fu, Yanbao ^[1]; Ling, Min ^[1]; Jia, Zhe ^[1]; Song, Xiangyun ^[1]; Chen, Zonghai ^[2]; Lu, Jun ^[2]; Amine, Khalil ^[2]; Liu, Gao ^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Applied Energy Materials Group. Energy Storage and Distributed Resources Division
Argonne National Lab. (ANL), Argonne, IL (United States)

In this paper, a SiOSnCoC composite anode is assembled using a conductive polymer binder for the application in next-generation high energy density lithium-ion batteries. A specific capacity of 700 mAh/g is achieved at a 1C (900 mA/g) rate. A high active material loading anode with an areal capacity of 3.5 mAh/cm² is demonstrated by mixing SiOSnCoC with graphite. To compensate for the lithium loss in the first cycle, stabilized lithium metal powder (SLMP) is used for prelithiation; when paired with a commercial cathode, a stable full cell cycling performance with a 86% first cycle efficiency is realized. Finally, by achieving these important metrics toward a practical application, this conductive polymer binder/SiOSnCoC anode system presents great promise to enable the next generation of high-energy lithium-ion batteries.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1433093

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 21 Vol. 8; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Advanced Lithium-Ion Batteries for Practical Applications: Technology, Development, and Future Perspectives Choi, Sinho; Wang, Guoxiu Advanced Materials Technologies, Vol. 3, Issue 9 https://doi.org/10.1002/admt.201700376	journal	July 2018
In Situ Wrapping SiO with Carbon Nanotubes as Anode Material for High-Performance Li-Ion Batteries Li, Jianbin; Wang, Lei; Liu, Fangming ChemistrySelect, Vol. 4, Issue 10 https://doi.org/10.1002/slct.201900337	journal	March 2019
Electrodeposited Cu/MWCNT composite-film: a potential current collector of silicon-based negative-electrodes for Li-Ion batteries Shimizu, Masahiro; Ohnuki, Tomonari; Ogasawara, Takayuki RSC Advances, Vol. 9, Issue 38 https://doi.org/10.1039/c9ra03000j	journal	January 2019

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conductive polymer binder
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Title: Conductive Polymer Binder-Enabled SiO–SnxCoyCz Anode for High-Energy Lithium-Ion Batteries

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Title: Conductive Polymer Binder-Enabled SiO–Sn_xCo_yC_z Anode for High-Energy Lithium-Ion Batteries