Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms

Chernyy, Sergey; Kirkensgaard, Jacob Judas Kain; Mahalik, Jyoti P.; Kim, Hyeyoung; Arras, Matthias M.  L.; Kumar, Rajeev; Sumpter, Bobby G.; Smith, Gregory S.; Mortensen, Kell; Russell, Thomas P.; Almdal, Kristoffer

doi:10.1021/acs.macromol.7b02485

Title: Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms

Abstract

DIM miktoarm star copolymers, composed of polydimethylsiloxane [D], poly(1,4-isoprene) [I], and poly(methyl methacrylate) [M], were synthesized using a newly developed linking methodology with 4-allyl-1,1-diphenylethylene as a linking agent. The equilibrium bulk morphologies of the DIM stars were found to range from [6.6.6] tiling patterns to alternating lamellar and alternating cylindrical morphologies, as determined experimentally by small-angle X-ray scattering and transmission electron microscopy and confirmed by dissipative particle dynamics and self-consistent field theory based arguments. The thin film morphologies, which differ from those found in the bulk, were identified by scanning electron microscopy, coupled with oxygen plasma etching. Finally, square arrays of the PDMS nanodots and empty core cylinders were formed on silica after oxygen plasma removal of the poly(1,4-isoprene) and poly(methyl methacrylate) which generated nanostructured substrates decorated with these features readily observable.

Authors:

^[1];

^[2];

^[3]; Kim, Hyeyoung ^[4];

^[5];

^[3];

^[3]; Smith, Gregory S. ^[5];

^[2];

^[4]; Almdal, Kristoffer ^[6]

Technical Univ. of Denmark, Lyngby (Denmark). DTU Nanotech
Univ. of Copenhagen (Denmark). The Niels Bohr Inst.
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Computational Sciences and Engineering Division
Univ. of Massachusetts, Amherst, MA (United States). Dept. of Polymer Science and Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Division
Technical Univ. of Denmark, Lyngby (Denmark). DTU Nanotech

Publication Date:: Fri Feb 02 00:00:00 EST 2018

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1430603

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Macromolecules

Additional Journal Information:: Journal Volume: 51; Journal Issue: 3; Journal ID: ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats


                    Chernyy, Sergey, Kirkensgaard, Jacob Judas Kain, Mahalik, Jyoti P., Kim, Hyeyoung, Arras, Matthias M.  L., Kumar, Rajeev, Sumpter, Bobby G., Smith, Gregory S., Mortensen, Kell, Russell, Thomas P., and Almdal, Kristoffer. Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms.  United States: N. p., 2018. 
Web.  doi:10.1021/acs.macromol.7b02485.

Copy to clipboard


                    Chernyy, Sergey, Kirkensgaard, Jacob Judas Kain, Mahalik, Jyoti P., Kim, Hyeyoung, Arras, Matthias M.  L., Kumar, Rajeev, Sumpter, Bobby G., Smith, Gregory S., Mortensen, Kell, Russell, Thomas P., & Almdal, Kristoffer. Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms.  United States.  https://doi.org/10.1021/acs.macromol.7b02485

Copy to clipboard


                    Chernyy, Sergey, Kirkensgaard, Jacob Judas Kain, Mahalik, Jyoti P., Kim, Hyeyoung, Arras, Matthias M.  L., Kumar, Rajeev, Sumpter, Bobby G., Smith, Gregory S., Mortensen, Kell, Russell, Thomas P., and Almdal, Kristoffer. Fri .  
"Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms".  United States.  https://doi.org/10.1021/acs.macromol.7b02485.  https://www.osti.gov/servlets/purl/1430603.

Copy to clipboard


                    
@article{osti_1430603,

  title        = {Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms},

  author       = {Chernyy, Sergey and Kirkensgaard, Jacob Judas Kain and Mahalik, Jyoti P. and Kim, Hyeyoung and Arras, Matthias M.  L. and Kumar, Rajeev and Sumpter, Bobby G. and Smith, Gregory S. and Mortensen, Kell and Russell, Thomas P. and Almdal, Kristoffer},

  abstractNote = {DIM miktoarm star copolymers, composed of polydimethylsiloxane [D], poly(1,4-isoprene) [I], and poly(methyl methacrylate) [M], were synthesized using a newly developed linking methodology with 4-allyl-1,1-diphenylethylene as a linking agent. The equilibrium bulk morphologies of the DIM stars were found to range from [6.6.6] tiling patterns to alternating lamellar and alternating cylindrical morphologies, as determined experimentally by small-angle X-ray scattering and transmission electron microscopy and confirmed by dissipative particle dynamics and self-consistent field theory based arguments. The thin film morphologies, which differ from those found in the bulk, were identified by scanning electron microscopy, coupled with oxygen plasma etching. Finally, square arrays of the PDMS nanodots and empty core cylinders were formed on silica after oxygen plasma removal of the poly(1,4-isoprene) and poly(methyl methacrylate) which generated nanostructured substrates decorated with these features readily observable.},

  doi          = {10.1021/acs.macromol.7b02485},

  journal      = {Macromolecules},

  number       = 3,

  volume       = 51,

  place        = {United States},

  year         = {Fri Feb 02 00:00:00 EST 2018},

  month        = {Fri Feb 02 00:00:00 EST 2018}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1021/acs.macromol.7b02485

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 13 works

Citation information provided by
Web of Science

Figures / Tables:

Figure 1: Generic phase diagram based on simulation predictions under the constraint of two arms (green A and blue B) having equal volumes while the third arm (red C) is varied.^20-23,44 The parameter x is the fractional length of C relative to A. The tiling patterns are labeled by amore »

All figures and tables (10 total)

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst
journal, October 2015

Chen, Chi; Hecht, Maxwell B.; Kavara, Aydin
Journal of the American Chemical Society, Vol. 137, Issue 41
DOI: 10.1021/jacs.5b08611

Block Copolymer Lithography
journal, November 2013

Bates, Christopher M.; Maher, Michael J.; Janes, Dustin W.
Macromolecules, Vol. 47, Issue 1, p. 2-12
DOI: 10.1021/ma401762n

Novel network morphologies and compositionally robust 3-colored perforated lamellar phase in A(BC)2 mikto-arm star copolymer melts
journal, January 2010

Kirkensgaard, Jacob Judas Kain
Soft Matter, Vol. 6, Issue 24
DOI: 10.1039/c0sm00358a

Weak segregation theory and non-conventional morphologies in the ternary ABC triblock copolymers
journal, December 2005

Erukhimovich, I. Y.
The European Physical Journal E, Vol. 18, Issue 4
DOI: 10.1140/epje/e2005-00054-5

Precise Synthesis of New Exactly Defined Graft Copolymers Made up of Poly(alkyl methacrylate)s by Iterative Methodology Using Living Anionic Polymerization
journal, October 2015

Ito, Shotaro; Ishizone, Takashi; Hirao, Akira
Macromolecules, Vol. 48, Issue 22
DOI: 10.1021/acs.macromol.5b01908

SCFT Study of Nonfrustrated ABC Triblock Copolymer Melts
journal, June 2007

Tyler, Christopher A.; Qin, Jian; Bates, Frank S.
Macromolecules, Vol. 40, Issue 13
DOI: 10.1021/ma062778w

Multiblock Polymers: Panacea or Pandora's Box?
journal, April 2012

Bates, F. S.; Hillmyer, M. A.; Lodge, T. P.
Science, Vol. 336, Issue 6080
DOI: 10.1126/science.1215368

Thin Film Knitting Pattern Morphology from a Miktoarm Star Terpolymer
journal, January 2014

Choi, Hong Kyoon; Nunns, Adam; Sun, Xue Yin
Advanced Materials, Vol. 26, Issue 16
DOI: 10.1002/adma.201305243

Laboratory‐scale setup for anionic polymerization under inert atmosphere
journal, February 1995

Ndoni, Sokol; Papadakis, Christine M.; Bates, Frank S.
Review of Scientific Instruments, Vol. 66, Issue 2
DOI: 10.1063/1.1146052

Photocatalytic Nanostructuring of Graphene Guided by Block Copolymer Self-Assembly
journal, March 2016

Wang, Zhongli; Li, Tao; Schulte, Lars
ACS Applied Materials & Interfaces, Vol. 8, Issue 13
DOI: 10.1021/acsami.6b01021

Ordered Nanoscale Archimedean Tilings of a Templated 3-Miktoarm Star Terpolymer
journal, January 2013

Aissou, Karim; Choi, Hong Kyoon; Nunns, Adam
Nano Letters, Vol. 13, Issue 2
DOI: 10.1021/nl400006c

Ordering in thin films of block copolymers: Fundamentals to potential applications
journal, November 2009

Hamley, I. W.
Progress in Polymer Science, Vol. 34, Issue 11
DOI: 10.1016/j.progpolymsci.2009.06.003

Self-assembly of block copolymer thin films
journal, June 2010

Albert, Julie N. L.; Epps, Thomas H.
Materials Today, Vol. 13, Issue 6, p. 24-33
DOI: 10.1016/S1369-7021(10)70106-1

Orientation-Controlled Self-Assembled Nanolithography Using a Polystyrene−Polydimethylsiloxane Block Copolymer
journal, July 2007

Jung, Yeon Sik; Ross, C. A.
Nano Letters, Vol. 7, Issue 7
DOI: 10.1021/nl070924l

Photonic band structure calculations of two-dimensional Archimedean tiling patterns
journal, May 2007

Ueda, Kazunari; Dotera, Tomonari; Gemma, Tohru
Physical Review B, Vol. 75, Issue 19
DOI: 10.1103/PhysRevB.75.195122

Donor−Acceptor Poly(thiophene- block -perylene diimide) Copolymers: Synthesis and Solar Cell Fabrication
journal, February 2009

Zhang, Qingling; Cirpan, Ali; Russell, Thomas P.
Macromolecules, Vol. 42, Issue 4
DOI: 10.1021/ma801504e

Parallel algorithm for numerical self-consistent field theory simulations of block copolymer structure
journal, September 2003

Sides, Scott W.; Fredrickson, Glenn H.
Polymer, Vol. 44, Issue 19
DOI: 10.1016/S0032-3861(03)00606-2

Phase Behavior of Nonfrustrated ABC Triblock Copolymers: Weak and Intermediate Segregation
journal, June 2010

Qin, Jian; Bates, Frank S.; Morse, David C.
Macromolecules, Vol. 43, Issue 11
DOI: 10.1021/ma100400q

Morphology and phase diagram of complex block copolymers: ABC linear triblock copolymers
journal, March 2004

Tang, Ping; Qiu, Feng; Zhang, Hongdong
Physical Review E, Vol. 69, Issue 3
DOI: 10.1103/PhysRevE.69.031803

Self-Consistent Field Theory of Multiply-Branched Block Copolymer Melts
text, January 2005

Grason, Gregory M.; Kamien, Randall D.
arXiv
DOI: 10.48550/arxiv.cond-mat/0501404

Design of ABC Triblock Copolymers near the ODT with the Random Phase Approximation
journal, February 2003

Cochran, Eric W.; Morse, David C.; Bates, Frank S.
Macromolecules, Vol. 36, Issue 3
DOI: 10.1021/ma020651a

Controlled Anionic Polymerization of Hexamethylcyclotrisiloxane. Model Linear and Miktoarm Star Co- and Terpolymers of Dimethylsiloxane with Styrene and Isoprene
journal, September 2000

Bellas, Vasilios; Iatrou, Hermis; Hadjichristidis, Nikos
Macromolecules, Vol. 33, Issue 19
DOI: 10.1021/ma000635i

Metal-Catalyzed Hydrosilylation of Alkenes and Alkynes Using Dimethyl(pyridyl)silane
journal, April 2002

Itami, Kenichiro; Mitsudo, Koichi; Nishino, Akira
The Journal of Organic Chemistry, Vol. 67, Issue 8
DOI: 10.1021/jo0163389

Systematic Transitions of Tiling Patterns Formed by ABC Star-Shaped Terpolymers
journal, December 2006

Hayashida, Kenichi; Takano, Atsushi; Arai, Shigeo
Macromolecules, Vol. 39, Issue 26
DOI: 10.1021/ma0618474

Systematic progressions of core-shell polygon containing tiling patterns in melts of 2nd generation dendritic miktoarm star copolymers
journal, January 2011

Kirkensgaard, Jacob Judas Kain
Soft Matter, Vol. 7, Issue 22
DOI: 10.1039/c1sm06115a

Block Copolymer Thin Films: Physics and Applications
journal, August 2001

Fasolka, Michael J.; Mayes, Anne M.
Annual Review of Materials Research, Vol. 31, Issue 1, p. 323-355
DOI: 10.1146/annurev.matsci.31.1.323

Block copolymer patterns and templates
journal, September 2006

Li, Mingqi; Ober, Christopher K.
Materials Today, Vol. 9, Issue 9, p. 30-39
DOI: 10.1016/S1369-7021(06)71620-0

Supramolecular Polymeric Materials with Hierarchical Structure-Within-Structure Morphologies
journal, June 1999

Ruokolainen, Janne; Brinke, Gerrit ten; Ikkala, Olli
Advanced Materials, Vol. 11, Issue 9
DOI: 10.1002/(SICI)1521-4095(199906)11:9<777::AID-ADMA777>3.0.CO;2-M

Orthorhombic $F d d d$ Network in Triblock and Diblock Copolymer Melts
journal, May 2005

Tyler, Christopher A.; Morse, David C.
Physical Review Letters, Vol. 94, Issue 20
DOI: 10.1103/PhysRevLett.94.208302

Striped networks and other hierarchical structures in $A_{m} B_{m} C_{n}$ ( $2 m + n$ )-miktoarm star terpolymer melts
journal, March 2012

Kirkensgaard, Jacob Judas Kain
Physical Review E, Vol. 85, Issue 3
DOI: 10.1103/PhysRevE.85.031802

Microdomain Morphology in an ABC 3-Miktoarm Star Terpolymer: A Study by Energy-Filtering TEM and 3D Electron Tomography
journal, September 2003

Yamauchi, Kazuhiro; Takahashi, Keiko; Hasegawa, Hirokazu
Macromolecules, Vol. 36, Issue 19
DOI: 10.1021/ma034840k

Discovering New Ordered Phases of Block Copolymers
journal, October 2000

Bohbot-Raviv, Yardena; Wang, Zhen-Gang
Physical Review Letters, Vol. 85, Issue 16
DOI: 10.1103/physrevlett.85.3428

Emergence and Stability of Helical Superstructures in ABC Triblock Copolymers
journal, December 2011

Li, Weihua; Qiu, Feng; Shi, An-Chang
Macromolecules, Vol. 45, Issue 1
DOI: 10.1021/ma2023952

Orienting Block Copolymer Thin Films via Entropy
journal, January 2016

Lo, Ting-Ya; Dehghan, Ashkan; Georgopanos, Prokopios
Macromolecules, Vol. 49, Issue 2
DOI: 10.1021/acs.macromol.5b02685

Solubility parameter of poly(dimethyl siloxane) as a function of temperature and chain length
journal, December 1990

Roth, Michal
Journal of Polymer Science Part B: Polymer Physics, Vol. 28, Issue 13
DOI: 10.1002/polb.1990.090281317

Monte Carlo Simulations of the Morphology of ABC Star Polymers Using the Diagonal Bond Method
journal, April 2002

Gemma, Tohru; Hatano, Akira; Dotera, Tomonari
Macromolecules, Vol. 35, Issue 8
DOI: 10.1021/ma001040q

Preparation and characterization of novel star-shaped copolymers having three different branches
journal, January 1992

Fujimoto, Teruo; Zhang, Hongmin; Kazama, Takeo
Polymer, Vol. 33, Issue 10
DOI: 10.1016/0032-3861(92)90890-9

Polymer Interfaces: Synthetic Strategies Enabling Functionality, Adaptivity, and Spatial Control
journal, June 2016

Barner-Kowollik, Christopher; Goldmann, Anja S.; Schacher, Felix H.
Macromolecules, Vol. 49, Issue 14
DOI: 10.1021/acs.macromol.6b00650

Morphology of model three-component three-arm star-shaped copolymers
journal, October 1997

Okamoto, Shigeru; Hasegawa, Hirokazu; Hashimoto, Takeji
Polymer, Vol. 38, Issue 21
DOI: 10.1016/S0032-3861(97)00089-X

A fast Fourier transform compiler
journal, May 1999

Frigo, Matteo
ACM SIGPLAN Notices, Vol. 34, Issue 5
DOI: 10.1145/301631.301661

Theoretical Study of Phase Behavior of Frustrated ABC Linear Triblock Copolymers
journal, November 2012

Liu, Meijiao; Li, Weihua; Qiu, Feng
Macromolecules, Vol. 45, Issue 23
DOI: 10.1021/ma302060m

Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films
journal, March 2016

Aissou, Karim; Kwon, Wonsang; Mumtaz, Muhammad
ACS Nano, Vol. 10, Issue 4
DOI: 10.1021/acsnano.5b06728

Kaleidoscopic morphologies from ABC star-shaped terpolymers
journal, June 2011

Matsushita, Yushu; Hayashida, Kenichi; Dotera, Tomonari
Journal of Physics: Condensed Matter, Vol. 23, Issue 28
DOI: 10.1088/0953-8984/23/28/284111

A Strategy to Explore Stable and Metastable Ordered Phases of Block Copolymers
journal, April 2013

Xu, Weiquan; Jiang, Kai; Zhang, Pingwen
The Journal of Physical Chemistry B, Vol. 117, Issue 17
DOI: 10.1021/jp309862b

Polyisoprene-Polystyrene Diblock Copolymer Phase Diagram near the Order-Disorder Transition
journal, December 1995

Khandpur, Ashish K.; Foerster, Stephan; Bates, Frank S.
Macromolecules, Vol. 28, Issue 26
DOI: 10.1021/ma00130a012

Poly(dimethylsiloxane- b -methyl methacrylate): A Promising Candidate for Sub-10 nm Patterning
journal, May 2015

Luo, Yingdong; Montarnal, Damien; Kim, Sangwon
Macromolecules, Vol. 48, Issue 11
DOI: 10.1021/acs.macromol.5b00518

Morphology of ABC Triblock Copolymers
journal, October 1995

Zheng, Wei; Wang, Zhen-Gang
Macromolecules, Vol. 28, Issue 21
DOI: 10.1021/ma00125a026

Morphologies of ABC Triblock Terpolymer Melts Containing Poly(Cyclohexadiene): Effects of Conformational Asymmetry
journal, January 2013

Kumar, Rajeev; Sides, Scott W.; Goswami, Monojoy
Langmuir, Vol. 29, Issue 6
DOI: 10.1021/la304576c

Phase Behavior of Polystyrene−Poly(2-vinylpyridine) Diblock Copolymers
journal, January 1996

Schulz, Mark F.; Khandpur, Ashish K.; Bates, Frank S.
Macromolecules, Vol. 29, Issue 8
DOI: 10.1021/ma951714a

Hierarchical self-assembly of a striped gyroid formed by threaded chiral mesoscale networks
journal, January 2014

Kirkensgaard, J. J. K.; Evans, M. E.; de Campo, L.
Proceedings of the National Academy of Sciences, Vol. 111, Issue 4
DOI: 10.1073/pnas.1316348111

Metal-Catalyzed Hydrosilylation of Alkenes and Alkynes Using Dimethyl(pyridyl)silane
journal, April 2002

Itami, Kenichiro; Mitsudo, Koichi; Nishino, Akira
The Journal of Organic Chemistry, Vol. 67, Issue 8
DOI: 10.1021/jo0163389

Hierarchical self-assembly of a striped gyroid formed by threaded chiral mesoscale networks
journal, January 2014

Kirkensgaard, J. J. K.; Evans, M. E.; de Campo, L.
Proceedings of the National Academy of Sciences, Vol. 111, Issue 4
DOI: 10.1073/pnas.1316348111

Kaleidoscopic tilings, networks and hierarchical structures in blends of 3-miktoarm star terpolymers
journal, January 2012

Kirkensgaard, Jacob Judas Kain
Interface Focus, Vol. 2, Issue 5
DOI: 10.1098/rsfs.2011.0093

Systematic progressions of core-shell polygon containing tiling patterns in melts of 2nd generation dendritic miktoarm star copolymers
journal, January 2011

Kirkensgaard, Jacob Judas Kain
Soft Matter, Vol. 7, Issue 22
DOI: 10.1039/c1sm06115a

Kaleidoscopic tilings, networks and hierarchical structures in blends of 3-miktoarm star terpolymers
journal, January 2012

Kirkensgaard, Jacob Judas Kain
Interface Focus, Vol. 2, Issue 5
DOI: 10.1098/rsfs.2011.0093

The packing of soft materials: Molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts
journal, October 2006

Grason, G.
Physics Reports, Vol. 433, Issue 1
DOI: 10.1016/j.physrep.2006.08.001

Morphologies of poly(cyclohexadiene) diblock copolymers: Effect of conformational asymmetry
journal, October 2012

Mays, Jimmy W.; Kumar, Rajeev; Sides, Scott W.
Polymer, Vol. 53, Issue 22
DOI: 10.1016/j.polymer.2012.08.047

Synthesis and characterization of a model saturated hydrocarbon diblock copolymer
journal, November 1989

Bates, Frank S.; Rosedale, Jeffrey H.; Bair, Harvey E.
Macromolecules, Vol. 22, Issue 6
DOI: 10.1021/ma00196a002

Block Copolymer Nanolithography: Translation of Molecular Level Control to Nanoscale Patterns
journal, July 2009

Bang, Joona; Jeong, Unyong; Ryu, Du Yeol
Advanced Materials, Vol. 21, Issue 47, p. 4769-4792
DOI: 10.1002/adma.200803302

Self-Assembly of Asymmetrically Interacting ABC Star Triblock Copolymer Melts
journal, November 2015

Jiang, Kai; Zhang, Juan; Liang, Qin
The Journal of Physical Chemistry B, Vol. 119, Issue 45
DOI: 10.1021/acs.jpcb.5b08187

Controlled Anionic Polymerization of Hexamethylcyclotrisiloxane. Model Linear and Miktoarm Star Co- and Terpolymers of Dimethylsiloxane with Styrene and Isoprene
journal, September 2000

Bellas, Vasilios; Iatrou, Hermis; Hadjichristidis, Nikos
Macromolecules, Vol. 33, Issue 19
DOI: 10.1021/ma000635i

Synthesis and Bulk Self-Assembly of ABC Star Terpolymers with a Polyferrocenylsilane Metalloblock
journal, March 2013

Nunns, Adam; Ross, Caroline A.; Manners, Ian
Macromolecules, Vol. 46, Issue 7
DOI: 10.1021/ma302602u

Archimedean Tiling Patterns of ABC Star-Shaped Terpolymers Studied by Microbeam Small-Angle X-ray Scattering
journal, July 2006

Hayashida, Kenichi; Kawashima, Wataru; Takano, Atsushi
Macromolecules, Vol. 39, Issue 14
DOI: 10.1021/ma060647p

Kaleidoscopic morphologies from ABC star-shaped terpolymers
journal, June 2011

Matsushita, Yushu; Hayashida, Kenichi; Dotera, Tomonari
Journal of Physics: Condensed Matter, Vol. 23, Issue 28
DOI: 10.1088/0953-8984/23/28/284111

Efficient computation of the structural phase behavior of block copolymers
journal, April 2002

Tzeremes, G.; Rasmussen, K. Ø.; Lookman, T.
Physical Review E, Vol. 65, Issue 4
DOI: 10.1103/physreve.65.041806

Nanomanufacturing: A Perspective
journal, February 2016

Liddle, J. Alexander; Gallatin, Gregg M.
ACS Nano, Vol. 10, Issue 3
DOI: 10.1021/acsnano.5b03299

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view
journal, July 2011

Troegel, Dennis; Stohrer, Jürgen
Coordination Chemistry Reviews, Vol. 255, Issue 13-14
DOI: 10.1016/j.ccr.2010.12.025

Creation of Hierarchically Ordered Nanophase Structures in Block Polymers Having Various Competing Interactions
journal, February 2007

Matsushita, Yushu
Macromolecules, Vol. 40, Issue 4
DOI: 10.1021/ma062266h

A Particle Tracking Velocimetric Study of Interfacial Slip at Polymer–Polymer Interfaces
journal, December 2011

Zartman, Gregory D.; Wang, Shi-Qing
Macromolecules, Vol. 44, Issue 24
DOI: 10.1021/ma201929q

Photopatterning of Block Copolymer Thin Films
journal, March 2016

Lane, Austin P.; Maher, Michael J.; Willson, C. Grant
ACS Macro Letters, Vol. 5, Issue 4
DOI: 10.1021/acsmacrolett.6b00075

Real-space self-consistent mean-field theory study of ABC star triblock copolymers
journal, August 2010

Li, Weihua; Xu, Yuci; Zhang, Guojie
The Journal of Chemical Physics, Vol. 133, Issue 6
DOI: 10.1063/1.3469857

Morphology and phase diagram of $A B C$ linear triblock copolymers: Parallel real-space self-consistent-field-theory simulation
journal, January 2008

Sun, Mingzhu; Wang, Peng; Qiu, Feng
Physical Review E, Vol. 77, Issue 1
DOI: 10.1103/PhysRevE.77.016701

Self-consistent field theory of multiply branched block copolymer melts
journal, May 2005

Grason, Gregory M.; Kamien, Randall D.
Physical Review E, Vol. 71, Issue 5
DOI: 10.1103/PhysRevE.71.051801

Broadly Accessible Self-Consistent Field Theory for Block Polymer Materials Discovery
journal, June 2016

Arora, Akash; Qin, Jian; Morse, David C.
Macromolecules, Vol. 49, Issue 13
DOI: 10.1021/acs.macromol.6b00107

SCFT Study of Tiling Patterns in ABC Star Terpolymers
journal, March 2010

Zhang, Guojie; Qiu, Feng; Zhang, Hongdong
Macromolecules, Vol. 43, Issue 6
DOI: 10.1021/ma902735t

On the properties of poly(isoprene-b-ferrocenylmethyl methacrylate) block copolymers
journal, December 2017

Chernyy, Sergey; Kirkensgaard, Jacob Judas Kain; Bakke, Anders
Polymer, Vol. 133
DOI: 10.1016/j.polymer.2017.11.036

Anionic polymerization of (meth)acrylic monomers. 4. Effect of lithium salts as ligands on the "living" polymerization of methyl methacrylate using monofunctional initiators
journal, May 1990

Varshney, S. K.; Hautekeer, J. P.; Fayt, R.
Macromolecules, Vol. 23, Issue 10
DOI: 10.1021/ma00212a004

The packing of soft materials: Molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts
journal, October 2006

Grason, G.
Physics Reports, Vol. 433, Issue 1
DOI: 10.1016/j.physrep.2006.08.001

Microphase separation of ABC-type triblock copolymers
journal, September 1993

Nakazawa, Hatsumi; Ohta, Takao
Macromolecules, Vol. 26, Issue 20
DOI: 10.1021/ma00072a031

Tiling patterns from ABC star molecules: 3-colored foams?
journal, January 2014

Kirkensgaard, Jacob J. K.; Pedersen, Martin C.; Hyde, Stephen T.
Soft Matter, Vol. 10, Issue 37
DOI: 10.1039/C4SM01052C

Effect of Partial Hydrogenation on the Phase Behavior of Poly(isoprene- b -styrene- b -methyl methacrylate) Triblock Copolymers
journal, October 2012

Tureau, Maëva S.; Epps, Thomas H.
Macromolecules, Vol. 45, Issue 20
DOI: 10.1021/ma301739j

Direct Energy Transfer Studies of the Domain−Boundary Interface in Polyisoprene−Poly(methyl methacrylate) Block Copolymer Films
journal, January 1996

Tcherkasskaya, Olga; Ni, Shaoru; Winnik, Mitchell A.
Macromolecules, Vol. 29, Issue 2
DOI: 10.1021/ma950840b

Self-Assembled Block Copolymer Thin Films as Water Filtration Membranes
journal, February 2010

Phillip, William A.; O’Neill, Brandon; Rodwogin, Marc
ACS Applied Materials & Interfaces, Vol. 2, Issue 3
DOI: 10.1021/am900882t

Comprehensive Phase Behavior of Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers
journal, April 2007

Chatterjee, Joon; Jain, Sumeet; Bates, Frank S.
Macromolecules, Vol. 40, Issue 8
DOI: 10.1021/ma062249s

Morphological transition behavior of $A B C$ star copolymers by varying the interaction parameters
journal, March 2008

Huang, Ching-I; Fang, Hsin-Kai; Lin, Chih-Hao
Physical Review E, Vol. 77, Issue 3
DOI: 10.1103/PhysRevE.77.031804

Hierarchical Morphologies Formed by ABC Star-Shaped Terpolymers
journal, May 2007

Hayashida, Kenichi; Saito, Noriyuki; Arai, Shigeo
Macromolecules, Vol. 40, Issue 10
DOI: 10.1021/ma062972i

Weak segregation theory and non-conventional morphologies in the ternary ABC triblock copolymers
journal, December 2005

Erukhimovich, I. Y.
The European Physical Journal E, Vol. 18, Issue 4
DOI: 10.1140/epje/e2005-00054-5

Observation of Cylinder-Based Microphase-Separated Structures from ABC Star-Shaped Terpolymers Investigated by Electron Computerized Tomography
journal, December 2004

Takano, A.; Wada, S.; Sato, S.
Macromolecules, Vol. 37, Issue 26
DOI: 10.1021/ma048893t

A fast Fourier transform compiler
conference, January 1999

Frigo, Matteo
Proceedings of the ACM SIGPLAN 1999 conference on Programming language design and implementation - PLDI '99
DOI: 10.1145/301618.301661

Works referencing / citing this record:

Dendrons and Dendritic Terpolymers: Synthesis, Characterization and Self-Assembly Comparison
journal, December 2020

Rangou, Sofia; Moschovas, Dimitrios; Moutsios, Ioannis
Molecules, Vol. 25, Issue 24
DOI: 10.3390/molecules25246030

Star‐shaped siloxane polymers with various cyclic cores: Synthesis and properties
journal, April 2019

Vysochinskaya, Yulia S.; Anisimov, Anton A.; Peregudov, Alexander S.
Journal of Polymer Science Part A: Polymer Chemistry, Vol. 57, Issue 11
DOI: 10.1002/pola.29380

Tunable helical structures formed by ABC triblock copolymers under cylindrical confinement
journal, January 2019

Liu, Meijiao; Chen, Ka; Li, Weihua
Physical Chemistry Chemical Physics, Vol. 21, Issue 48
DOI: 10.1039/c9cp04978a

On the morphological behavior of ABC miktoarm stars containing poly(cis 1,4-isoprene), poly(styrene), and poly(2-vinylpyridine): On the Morphological Behavior of ABC Miktoarm Stars Containing Poly(cis 1,4-isoprene), Poly(styrene), and Poly(2-vinylpyridine)
journal, October 2018

Chernyy, Sergey; Mahalik, Jyoti P.; Kumar, Rajeev
Journal of Polymer Science Part B: Polymer Physics, Vol. 56, Issue 22
DOI: 10.1002/polb.24733

Figures / Tables found in this record:

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

Similar Records in DOE PAGES and OSTI.GOV collections:

On the morphological behavior of ABC miktoarm stars containing poly(cis 1,4-isoprene), poly(styrene), and poly(2-vinylpyridine)

Journal Article Chernyy, Sergey ; Mahalik, Jyoti P. ; Kumar, Rajeev ; ... - Journal of Polymer Science. Part B, Polymer Physics

Fundamental understanding of microphase separation in ABC miktoarm copolymers is vital to access a plethora of nonconventional morphologies. Miktoarm stars based on poly(cis 1,4-isoprene) (I), poly(styrene) (S), and poly(2-vinylpyridine) (V) are model systems, which allow systematic studies of the effects of composition, chemical microstructure, and temperature on the thermodynamics of microphase separation. Eleven ISV-x (I:S:V = 1:1:x, v:v:v) miktoarm copolymers were synthesized by anionic polymerization affording well-defined copolymers with a variable V arm. Equilibrium bulk morphologies of all samples, as evidenced by small-angle X-ray scattering, transmission electron microscopy (TEM), and self-consistent field theory, showed a systematic transition from lamellae (xmore »« less
Cited by 4
https://doi.org/10.1002/polb.24733

Full Text Available
Studies on the 3-Lamellar Morphology of Miktoarm Terpolymers

Journal Article Kim, Hyeyoung ; Arras, Matthias M. L. ; Mahalik, Jyoti P. ; ... - Macromolecules

The morphologies of ABC miktoarm star terpolymer consisting of polystyrene (PS), polyisoprene (PI), and poly(2-vinylpyridine) (P2VP) were studied by combining small-angle neutron and X-ray scattering (SANS and SAXS) and transmission electron microscopy. Here we find that this system displays a rich morphological behavior including an alternate lamellar (ALT.LAM), cylinder in undulated lamellar (CYLULAM), and 3-lamellar (LAM-3) phase. While the SAXS data alone were insufficient to conclusively differentiate between possible phases, we show that the use of selective deuteration and SANS is essential to unambiguously identify the morphology. In particular, the primary peak in SANS for the miktoarm polymer containing deuteratedmore »« less
Cited by 11
https://doi.org/10.1021/acs.macromol.8b01548

Full Text Available
Effects of Asymmetric Molecular Architecture on Chain Stretching and Dynamics in Miktoarm Star Copolymers

Journal Article Kinsey, Thomas ; Mapesa, Emmanuel Urandu ; Wang, Weiyu ; ... - Macromolecules

We use broad-band dielectric spectroscopy (BDS) and small-angle X-ray scattering (SAXS) to investigate the impact of architectural asymmetry in the miktoarm star copolymer on the dielectric polymer relaxations. The miktoarm copolymers studied contain one or two polystyrene (PS) chains of constant molecular weight and two identical poly(cis-1,4-isoprene) (PI) chains with varied molecular weights. Using the chains in the PI block as dielectric probes, we find that the architecturally asymmetric miktoarm star copolymer systems (PSPI₂) feature distributions in chain relaxation times and dielectric relaxation strengths that are not dependent on molecular weight or morphology, in stark contrast to the effects ofmore »« less
https://doi.org/10.1021/acs.macromol.0c01858

Full Text Available
Synthesis and characterization of an ABC miktoarm star terpolymer of cyclohexadiene, styrene, and 2-vinylpyridine

Journal Article Uhrig, David ; Hong, Kunlun ; Mays, Jimmy W. ; ... - Macromolecules

Several research groups have expended great effort toward the preparation of miktoarm (mixed-arm) star copolymers and terpolymers.^1-9 In this study, we describe a novel synthesis, using anionic polymerization, of a poly(cyclohexadiene) [PCHD]-polystyrene [PS]-poly(2-vinylpyridine) [P2VP] miktoarm star terpolymer.
https://doi.org/10.1021/ma801852t
Synthesis and Morphological Behavior of Model 6-Miktoarm Star Copolymers, PS(P2MP)5, of Styrene (S) and 2-Methyl-1,3-Pentadiene (P2MP)

Journal Article Mavroudis, A ; Avgeropoulos, A ; Hadjichristidis, N ; ... - Chem. Mater.

Three 6-miktoarm star (6{mu}-star) copolymers [PS(P2MP){sub 5}] of styrene (S) and 2-methyl-1,3-pentadiene (2MP) were synthesized by anionic polymerization and controlled chlorosilane chemistry, using high vacuum techniques. In all cases [M{sub w} = 103 kg/mol, [S] = 44% (v/v); M{sub w} = 91.1 kg/mol, [S] = 53% (v/v); M{sub w} = 224 kg/mol, [S] = 92% (v/v)] the P2MP exhibited high 1,4-microstructure ({approx}99%). Molecular characterization (size-exclusion chromatography, membrane osmometry, low-angle laser light scattering, and NMR) revealed high molecular weight/composition homogeneity, and structural analysis (differential scanning calorimetry, transmission electron microscopy, and small-angle X-ray scattering) showed highly ordered patterns. The deviations from predictionsmore »« less
https://doi.org/10.1021/cm052477l

Similar Records

Title: Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms

Abstract

Citation Formats

Figures / Tables:

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst journal, October 2015

Block Copolymer Lithography journal, November 2013

Novel network morphologies and compositionally robust 3-colored perforated lamellar phase in A(BC)2 mikto-arm star copolymer melts journal, January 2010

Weak segregation theory and non-conventional morphologies in the ternary ABC triblock copolymers journal, December 2005

Precise Synthesis of New Exactly Defined Graft Copolymers Made up of Poly(alkyl methacrylate)s by Iterative Methodology Using Living Anionic Polymerization journal, October 2015

SCFT Study of Nonfrustrated ABC Triblock Copolymer Melts journal, June 2007

Multiblock Polymers: Panacea or Pandora's Box? journal, April 2012

Thin Film Knitting Pattern Morphology from a Miktoarm Star Terpolymer journal, January 2014

Laboratory‐scale setup for anionic polymerization under inert atmosphere journal, February 1995

Photocatalytic Nanostructuring of Graphene Guided by Block Copolymer Self-Assembly journal, March 2016

Ordered Nanoscale Archimedean Tilings of a Templated 3-Miktoarm Star Terpolymer journal, January 2013

Ordering in thin films of block copolymers: Fundamentals to potential applications journal, November 2009

Self-assembly of block copolymer thin films journal, June 2010

Orientation-Controlled Self-Assembled Nanolithography Using a Polystyrene−Polydimethylsiloxane Block Copolymer journal, July 2007

Photonic band structure calculations of two-dimensional Archimedean tiling patterns journal, May 2007

Donor−Acceptor Poly(thiophene- block -perylene diimide) Copolymers: Synthesis and Solar Cell Fabrication journal, February 2009

Parallel algorithm for numerical self-consistent field theory simulations of block copolymer structure journal, September 2003

Phase Behavior of Nonfrustrated ABC Triblock Copolymers: Weak and Intermediate Segregation journal, June 2010

Morphology and phase diagram of complex block copolymers: ABC linear triblock copolymers journal, March 2004

Self-Consistent Field Theory of Multiply-Branched Block Copolymer Melts text, January 2005

Design of ABC Triblock Copolymers near the ODT with the Random Phase Approximation journal, February 2003

Controlled Anionic Polymerization of Hexamethylcyclotrisiloxane. Model Linear and Miktoarm Star Co- and Terpolymers of Dimethylsiloxane with Styrene and Isoprene journal, September 2000

Metal-Catalyzed Hydrosilylation of Alkenes and Alkynes Using Dimethyl(pyridyl)silane journal, April 2002

Systematic Transitions of Tiling Patterns Formed by ABC Star-Shaped Terpolymers journal, December 2006

Systematic progressions of core-shell polygon containing tiling patterns in melts of 2nd generation dendritic miktoarm star copolymers journal, January 2011

Block Copolymer Thin Films: Physics and Applications journal, August 2001

Block copolymer patterns and templates journal, September 2006

Supramolecular Polymeric Materials with Hierarchical Structure-Within-Structure Morphologies journal, June 1999

Orthorhombic F d d d Network in Triblock and Diblock Copolymer Melts journal, May 2005

Striped networks and other hierarchical structures in A m B m C n ( 2 m + n )-miktoarm star terpolymer melts journal, March 2012

Microdomain Morphology in an ABC 3-Miktoarm Star Terpolymer: A Study by Energy-Filtering TEM and 3D Electron Tomography journal, September 2003

Discovering New Ordered Phases of Block Copolymers journal, October 2000

Emergence and Stability of Helical Superstructures in ABC Triblock Copolymers journal, December 2011

Orienting Block Copolymer Thin Films via Entropy journal, January 2016

Solubility parameter of poly(dimethyl siloxane) as a function of temperature and chain length journal, December 1990

Monte Carlo Simulations of the Morphology of ABC Star Polymers Using the Diagonal Bond Method journal, April 2002

Preparation and characterization of novel star-shaped copolymers having three different branches journal, January 1992

Polymer Interfaces: Synthetic Strategies Enabling Functionality, Adaptivity, and Spatial Control journal, June 2016

Morphology of model three-component three-arm star-shaped copolymers journal, October 1997

A fast Fourier transform compiler journal, May 1999

Theoretical Study of Phase Behavior of Frustrated ABC Linear Triblock Copolymers journal, November 2012

Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films journal, March 2016

Kaleidoscopic morphologies from ABC star-shaped terpolymers journal, June 2011

A Strategy to Explore Stable and Metastable Ordered Phases of Block Copolymers journal, April 2013

Polyisoprene-Polystyrene Diblock Copolymer Phase Diagram near the Order-Disorder Transition journal, December 1995

Poly(dimethylsiloxane- b -methyl methacrylate): A Promising Candidate for Sub-10 nm Patterning journal, May 2015

Morphology of ABC Triblock Copolymers journal, October 1995

Morphologies of ABC Triblock Terpolymer Melts Containing Poly(Cyclohexadiene): Effects of Conformational Asymmetry journal, January 2013

Phase Behavior of Polystyrene−Poly(2-vinylpyridine) Diblock Copolymers journal, January 1996

Hierarchical self-assembly of a striped gyroid formed by threaded chiral mesoscale networks journal, January 2014

Metal-Catalyzed Hydrosilylation of Alkenes and Alkynes Using Dimethyl(pyridyl)silane journal, April 2002

Hierarchical self-assembly of a striped gyroid formed by threaded chiral mesoscale networks journal, January 2014

Kaleidoscopic tilings, networks and hierarchical structures in blends of 3-miktoarm star terpolymers journal, January 2012

Systematic progressions of core-shell polygon containing tiling patterns in melts of 2nd generation dendritic miktoarm star copolymers journal, January 2011

Kaleidoscopic tilings, networks and hierarchical structures in blends of 3-miktoarm star terpolymers journal, January 2012

The packing of soft materials: Molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts journal, October 2006

Morphologies of poly(cyclohexadiene) diblock copolymers: Effect of conformational asymmetry journal, October 2012

Synthesis and characterization of a model saturated hydrocarbon diblock copolymer journal, November 1989

Block Copolymer Nanolithography: Translation of Molecular Level Control to Nanoscale Patterns journal, July 2009

Self-Assembly of Asymmetrically Interacting ABC Star Triblock Copolymer Melts journal, November 2015

Controlled Anionic Polymerization of Hexamethylcyclotrisiloxane. Model Linear and Miktoarm Star Co- and Terpolymers of Dimethylsiloxane with Styrene and Isoprene journal, September 2000

Synthesis and Bulk Self-Assembly of ABC Star Terpolymers with a Polyferrocenylsilane Metalloblock journal, March 2013

Archimedean Tiling Patterns of ABC Star-Shaped Terpolymers Studied by Microbeam Small-Angle X-ray Scattering journal, July 2006

Kaleidoscopic morphologies from ABC star-shaped terpolymers journal, June 2011

Efficient computation of the structural phase behavior of block copolymers journal, April 2002

Nanomanufacturing: A Perspective journal, February 2016

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view journal, July 2011

Creation of Hierarchically Ordered Nanophase Structures in Block Polymers Having Various Competing Interactions journal, February 2007

A Particle Tracking Velocimetric Study of Interfacial Slip at Polymer–Polymer Interfaces journal, December 2011

Photopatterning of Block Copolymer Thin Films journal, March 2016

Real-space self-consistent mean-field theory study of ABC star triblock copolymers journal, August 2010

Morphology and phase diagram of A B C linear triblock copolymers: Parallel real-space self-consistent-field-theory simulation journal, January 2008

Self-consistent field theory of multiply branched block copolymer melts journal, May 2005

Broadly Accessible Self-Consistent Field Theory for Block Polymer Materials Discovery journal, June 2016

SCFT Study of Tiling Patterns in ABC Star Terpolymers journal, March 2010

On the properties of poly(isoprene-b-ferrocenylmethyl methacrylate) block copolymers journal, December 2017

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst
journal, October 2015

Block Copolymer Lithography
journal, November 2013

Novel network morphologies and compositionally robust 3-colored perforated lamellar phase in A(BC)2 mikto-arm star copolymer melts
journal, January 2010

Weak segregation theory and non-conventional morphologies in the ternary ABC triblock copolymers
journal, December 2005

Precise Synthesis of New Exactly Defined Graft Copolymers Made up of Poly(alkyl methacrylate)s by Iterative Methodology Using Living Anionic Polymerization
journal, October 2015

SCFT Study of Nonfrustrated ABC Triblock Copolymer Melts
journal, June 2007

Multiblock Polymers: Panacea or Pandora's Box?
journal, April 2012

Thin Film Knitting Pattern Morphology from a Miktoarm Star Terpolymer
journal, January 2014

Laboratory‐scale setup for anionic polymerization under inert atmosphere
journal, February 1995

Photocatalytic Nanostructuring of Graphene Guided by Block Copolymer Self-Assembly
journal, March 2016

Ordered Nanoscale Archimedean Tilings of a Templated 3-Miktoarm Star Terpolymer
journal, January 2013

Ordering in thin films of block copolymers: Fundamentals to potential applications
journal, November 2009

Self-assembly of block copolymer thin films
journal, June 2010

Orientation-Controlled Self-Assembled Nanolithography Using a Polystyrene−Polydimethylsiloxane Block Copolymer
journal, July 2007

Photonic band structure calculations of two-dimensional Archimedean tiling patterns
journal, May 2007

Donor−Acceptor Poly(thiophene- block -perylene diimide) Copolymers: Synthesis and Solar Cell Fabrication
journal, February 2009

Parallel algorithm for numerical self-consistent field theory simulations of block copolymer structure
journal, September 2003

Phase Behavior of Nonfrustrated ABC Triblock Copolymers: Weak and Intermediate Segregation
journal, June 2010

Morphology and phase diagram of complex block copolymers: ABC linear triblock copolymers
journal, March 2004

Self-Consistent Field Theory of Multiply-Branched Block Copolymer Melts
text, January 2005

Design of ABC Triblock Copolymers near the ODT with the Random Phase Approximation
journal, February 2003

Controlled Anionic Polymerization of Hexamethylcyclotrisiloxane. Model Linear and Miktoarm Star Co- and Terpolymers of Dimethylsiloxane with Styrene and Isoprene
journal, September 2000

Metal-Catalyzed Hydrosilylation of Alkenes and Alkynes Using Dimethyl(pyridyl)silane
journal, April 2002

Systematic Transitions of Tiling Patterns Formed by ABC Star-Shaped Terpolymers
journal, December 2006

Systematic progressions of core-shell polygon containing tiling patterns in melts of 2nd generation dendritic miktoarm star copolymers
journal, January 2011

Block Copolymer Thin Films: Physics and Applications
journal, August 2001

Block copolymer patterns and templates
journal, September 2006

Supramolecular Polymeric Materials with Hierarchical Structure-Within-Structure Morphologies
journal, June 1999

Orthorhombic $F d d d$ Network in Triblock and Diblock Copolymer Melts
journal, May 2005

Striped networks and other hierarchical structures in $A_{m} B_{m} C_{n}$ ( $2 m + n$ )-miktoarm star terpolymer melts
journal, March 2012

Microdomain Morphology in an ABC 3-Miktoarm Star Terpolymer: A Study by Energy-Filtering TEM and 3D Electron Tomography
journal, September 2003

Discovering New Ordered Phases of Block Copolymers
journal, October 2000

Emergence and Stability of Helical Superstructures in ABC Triblock Copolymers
journal, December 2011

Orienting Block Copolymer Thin Films via Entropy
journal, January 2016

Solubility parameter of poly(dimethyl siloxane) as a function of temperature and chain length
journal, December 1990

Monte Carlo Simulations of the Morphology of ABC Star Polymers Using the Diagonal Bond Method
journal, April 2002

Preparation and characterization of novel star-shaped copolymers having three different branches
journal, January 1992

Polymer Interfaces: Synthetic Strategies Enabling Functionality, Adaptivity, and Spatial Control
journal, June 2016

Morphology of model three-component three-arm star-shaped copolymers
journal, October 1997

A fast Fourier transform compiler
journal, May 1999

Theoretical Study of Phase Behavior of Frustrated ABC Linear Triblock Copolymers
journal, November 2012

Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films
journal, March 2016

Kaleidoscopic morphologies from ABC star-shaped terpolymers
journal, June 2011

A Strategy to Explore Stable and Metastable Ordered Phases of Block Copolymers
journal, April 2013

Polyisoprene-Polystyrene Diblock Copolymer Phase Diagram near the Order-Disorder Transition
journal, December 1995

Poly(dimethylsiloxane- b -methyl methacrylate): A Promising Candidate for Sub-10 nm Patterning
journal, May 2015

Morphology of ABC Triblock Copolymers
journal, October 1995

Morphologies of ABC Triblock Terpolymer Melts Containing Poly(Cyclohexadiene): Effects of Conformational Asymmetry
journal, January 2013

Phase Behavior of Polystyrene−Poly(2-vinylpyridine) Diblock Copolymers
journal, January 1996

Hierarchical self-assembly of a striped gyroid formed by threaded chiral mesoscale networks
journal, January 2014

Metal-Catalyzed Hydrosilylation of Alkenes and Alkynes Using Dimethyl(pyridyl)silane
journal, April 2002

Hierarchical self-assembly of a striped gyroid formed by threaded chiral mesoscale networks
journal, January 2014

Kaleidoscopic tilings, networks and hierarchical structures in blends of 3-miktoarm star terpolymers
journal, January 2012

Systematic progressions of core-shell polygon containing tiling patterns in melts of 2nd generation dendritic miktoarm star copolymers
journal, January 2011

Kaleidoscopic tilings, networks and hierarchical structures in blends of 3-miktoarm star terpolymers
journal, January 2012

The packing of soft materials: Molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts
journal, October 2006

Morphologies of poly(cyclohexadiene) diblock copolymers: Effect of conformational asymmetry
journal, October 2012

Synthesis and characterization of a model saturated hydrocarbon diblock copolymer
journal, November 1989

Block Copolymer Nanolithography: Translation of Molecular Level Control to Nanoscale Patterns
journal, July 2009

Self-Assembly of Asymmetrically Interacting ABC Star Triblock Copolymer Melts
journal, November 2015

Controlled Anionic Polymerization of Hexamethylcyclotrisiloxane. Model Linear and Miktoarm Star Co- and Terpolymers of Dimethylsiloxane with Styrene and Isoprene
journal, September 2000

Synthesis and Bulk Self-Assembly of ABC Star Terpolymers with a Polyferrocenylsilane Metalloblock
journal, March 2013

Archimedean Tiling Patterns of ABC Star-Shaped Terpolymers Studied by Microbeam Small-Angle X-ray Scattering
journal, July 2006

Kaleidoscopic morphologies from ABC star-shaped terpolymers
journal, June 2011

Efficient computation of the structural phase behavior of block copolymers
journal, April 2002

Nanomanufacturing: A Perspective
journal, February 2016

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view
journal, July 2011

Creation of Hierarchically Ordered Nanophase Structures in Block Polymers Having Various Competing Interactions
journal, February 2007

A Particle Tracking Velocimetric Study of Interfacial Slip at Polymer–Polymer Interfaces
journal, December 2011

Photopatterning of Block Copolymer Thin Films
journal, March 2016

Real-space self-consistent mean-field theory study of ABC star triblock copolymers
journal, August 2010

Morphology and phase diagram of $A B C$ linear triblock copolymers: Parallel real-space self-consistent-field-theory simulation
journal, January 2008

Self-consistent field theory of multiply branched block copolymer melts
journal, May 2005

Broadly Accessible Self-Consistent Field Theory for Block Polymer Materials Discovery
journal, June 2016

SCFT Study of Tiling Patterns in ABC Star Terpolymers
journal, March 2010

On the properties of poly(isoprene-b-ferrocenylmethyl methacrylate) block copolymers
journal, December 2017

Anionic polymerization of (meth)acrylic monomers. 4. Effect of lithium salts as ligands on the "living" polymerization of methyl methacrylate using monofunctional initiators
journal, May 1990

The packing of soft materials: Molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts
journal, October 2006

Microphase separation of ABC-type triblock copolymers
journal, September 1993

Tiling patterns from ABC star molecules: 3-colored foams?
journal, January 2014