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Title: Nanostructured cerium oxide: preparation, characterization, and application in energy and environmental catalysis

Abstract

Nanostructured cerium oxide (CeO2) with outstanding physical and chemical properties has attracted extensive interests over the past few decades in environment and energy-related applications. With controllable synthesis of nanostructured CeO2, much more features were technologically brought out from defect chemistry to structure-derived effects. This paper highlights recent progress on the synthesis and characterization of nanostructured ceria-based materials as well as the traditional and new applications. Specifically, several typical applications based on the desired ceria nanostructures are focused to showcase the importance of nanostructure-derived effects. Moreover, some challenges and perspectives on the nanostructured ceria are presented, such as defects controlling and retainment, scale-up fabrication, and monolithic devices. Hopefully, this paper can provide an improved understanding of nanostructured CeO2 and offer new opportunities to promote the further research and applications in the future.

Authors:
 [1];  [1]
  1. Univ. of Connecticut, Storrs, CT (United States). Nanomaterials Science Lab. Dept. of Materials Science and Engineering. Inst. of Materials Science
Publication Date:
Research Org.:
Univ. of Connecticut, Storrs, CT (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Fossil Energy (FE); National Science Foundation (NSF)
OSTI Identifier:
1430259
Grant/Contract Number:  
EE0006854; FE0011577; CBET-1344792
Resource Type:
Accepted Manuscript
Journal Name:
MRS Communications
Additional Journal Information:
Journal Volume: 6; Journal Issue: 4; Journal ID: ISSN 2159-6859
Publisher:
Materials Research Society - Cambridge University Press
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; cerium oxide; nanostructure; preparation; energy harvesting; environmental catalysis; chemical sensors

Citation Formats

Tang, Wen-Xiang, and Gao, Pu-Xian. Nanostructured cerium oxide: preparation, characterization, and application in energy and environmental catalysis. United States: N. p., 2016. Web. doi:10.1557/mrc.2016.52.
Tang, Wen-Xiang, & Gao, Pu-Xian. Nanostructured cerium oxide: preparation, characterization, and application in energy and environmental catalysis. United States. https://doi.org/10.1557/mrc.2016.52
Tang, Wen-Xiang, and Gao, Pu-Xian. Thu . "Nanostructured cerium oxide: preparation, characterization, and application in energy and environmental catalysis". United States. https://doi.org/10.1557/mrc.2016.52. https://www.osti.gov/servlets/purl/1430259.
@article{osti_1430259,
title = {Nanostructured cerium oxide: preparation, characterization, and application in energy and environmental catalysis},
author = {Tang, Wen-Xiang and Gao, Pu-Xian},
abstractNote = {Nanostructured cerium oxide (CeO2) with outstanding physical and chemical properties has attracted extensive interests over the past few decades in environment and energy-related applications. With controllable synthesis of nanostructured CeO2, much more features were technologically brought out from defect chemistry to structure-derived effects. This paper highlights recent progress on the synthesis and characterization of nanostructured ceria-based materials as well as the traditional and new applications. Specifically, several typical applications based on the desired ceria nanostructures are focused to showcase the importance of nanostructure-derived effects. Moreover, some challenges and perspectives on the nanostructured ceria are presented, such as defects controlling and retainment, scale-up fabrication, and monolithic devices. Hopefully, this paper can provide an improved understanding of nanostructured CeO2 and offer new opportunities to promote the further research and applications in the future.},
doi = {10.1557/mrc.2016.52},
journal = {MRS Communications},
number = 4,
volume = 6,
place = {United States},
year = {Thu Nov 10 00:00:00 EST 2016},
month = {Thu Nov 10 00:00:00 EST 2016}
}

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Works referenced in this record:

Synthesis, characterization, and magnetic properties of monodisperse CeO2 nanospheres prepared by PVP-assisted hydrothermal method
journal, January 2012

  • Phokha, Sumalin; Pinitsoontorn, Supree; Chirawatkul, Prae
  • Nanoscale Research Letters, Vol. 7, Issue 1
  • DOI: 10.1186/1556-276X-7-425

Toward the Innovative Synthesis of Columnar CeO 2 Nanostructures
journal, October 2006

  • Barreca, Davide; Gasparotto, Alberto; Maccato, Chiara
  • Langmuir, Vol. 22, Issue 21
  • DOI: 10.1021/la061052q

Effect of Ceria Crystal Plane on the Physicochemical and Catalytic Properties of Pd/Ceria for CO and Propane Oxidation
journal, March 2016


Insights into the Surface-Defect Dependence of Photoreactivity over CeO 2 Nanocrystals with Well-Defined Crystal Facets
journal, July 2015


Enhanced CO Oxidation Rates at the Interface of Mesoporous Oxides and Pt Nanoparticles
journal, October 2013

  • An, Kwangjin; Alayoglu, Selim; Musselwhite, Nathan
  • Journal of the American Chemical Society, Vol. 135, Issue 44
  • DOI: 10.1021/ja4088743

Catalytic oxidation of toluene on Ce–Co and La–Co mixed oxides synthesized by exotemplating and evaporation methods
journal, April 2015


Raman Analysis of Mode Softening in Nanoparticle CeO 2−δ and Au-CeO 2−δ during CO Oxidation
journal, August 2011

  • Lee, Youjin; He, Guanghui; Akey, Austin J.
  • Journal of the American Chemical Society, Vol. 133, Issue 33
  • DOI: 10.1021/ja204479j

Enhanced catalytic activity of ceria nanorods from well-defined reactive crystal planes
journal, January 2005


CO Oxidation Mechanism on CeO 2 -Supported Au Nanoparticles
journal, January 2012

  • Kim, Hyun You; Lee, Hyuck Mo; Henkelman, Graeme
  • Journal of the American Chemical Society, Vol. 134, Issue 3
  • DOI: 10.1021/ja207510v

Doped CeO 2 –LaFeO 3 Composite Oxide as an Active Anode for Direct Hydrocarbon-Type Solid Oxide Fuel Cells
journal, December 2011

  • Shin, Tae Ho; Ida, Shintaro; Ishihara, Tatsumi
  • Journal of the American Chemical Society, Vol. 133, Issue 48
  • DOI: 10.1021/ja206278f

Oxidation of benzene over bimetallic Cu–Ce incorporated rice husk silica catalysts
journal, May 2010


Anchoring High-Concentration Oxygen Vacancies at Interfaces of CeO 2– x /Cu toward Enhanced Activity for Preferential CO Oxidation
journal, October 2015

  • Chen, Shaoqing; Li, Liping; Hu, Wanbiao
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 41
  • DOI: 10.1021/acsami.5b06302

Facile fabrication of porous hollow CeO2 microspheres using polystyrene spheres as templates
journal, May 2011


Controlled Synthesis of CeO 2 Flower-Like and Well-Aligned Nanorod Hierarchical Architectures by a Phosphate-Assisted Hydrothermal Route
journal, November 2008

  • Yu, Ranbo; Yan, Lai; Zheng, Peng
  • The Journal of Physical Chemistry C, Vol. 112, Issue 50
  • DOI: 10.1021/jp806092q

Exceptional Activity for Methane Combustion over Modular Pd@CeO2 Subunits on Functionalized Al2O3
journal, August 2012


A facile synthesis for hierarchical porous CeO 2 nanobundles and their superior catalytic performance for CO oxidation
journal, January 2015

  • Rao, Richuan; Yang, Ming; Li, Changshun
  • Journal of Materials Chemistry A, Vol. 3, Issue 2
  • DOI: 10.1039/C4TA03875D

Catalytic Properties of Ceria and CeO 2 -Containing Materials
journal, November 1996


Structure–Activity Relationships of NiO on CeO 2 Nanorods for the Selective Catalytic Reduction of NO with NH 3 : Experimental and DFT Studies
journal, April 2014

  • Maitarad, Phornphimon; Han, Jin; Zhang, Dengsong
  • The Journal of Physical Chemistry C, Vol. 118, Issue 18
  • DOI: 10.1021/jp5024845

NO reduction by CO over CuO–CeO2 catalysts: effect of preparation methods
journal, January 2013

  • Yao, Xiaojiang; Gao, Fei; Yu, Qiang
  • Catalysis Science & Technology, Vol. 3, Issue 5
  • DOI: 10.1039/c3cy20805b

Metal oxides for solid-state gas sensors: What determines our choice?
journal, April 2007


Adsorption and Reaction of Acetaldehyde on Shape-Controlled CeO 2 Nanocrystals: Elucidation of Structure–Function Relationships
journal, June 2014

  • Mann, Amanda K. P.; Wu, Zili; Calaza, Florencia C.
  • ACS Catalysis, Vol. 4, Issue 8
  • DOI: 10.1021/cs500611g

Catalytic oxidation of toluene over nanorod-structured Mn–Ce mixed oxides
journal, November 2013


Anin SituElectrical Conductivity Study of a CeO2Aerogel Supported Palladium Catalyst in Correlation with the Total Oxidation of Propane
journal, April 1996

  • Herrmann, Jean-Marie; Hoang-Van, Can; Dibansa, Lucie
  • Journal of Catalysis, Vol. 159, Issue 2
  • DOI: 10.1006/jcat.1996.0098

Reaction Mechanisms for the CO Oxidation on Au/CeO 2 Catalysts: Activity of Substitutional Au 3+ /Au + Cations and Deactivation of Supported Au + Adatoms
journal, August 2009

  • Camellone, Matteo Farnesi; Fabris, Stefano
  • Journal of the American Chemical Society, Vol. 131, Issue 30
  • DOI: 10.1021/ja902109k

Solid oxide fuel cells
journal, November 2002

  • Ormerod, R. Mark
  • Chemical Society Reviews, Vol. 32, Issue 1, p. 17-28
  • DOI: 10.1039/b105764m

Preferential oxidation of carbon monoxide on Co/CeO2 nanoparticles
journal, June 2010


Probing the Surface Sites of CeO 2 Nanocrystals with Well-Defined Surface Planes via Methanol Adsorption and Desorption
journal, September 2012

  • Wu, Zili; Li, Meijun; Mullins, David R.
  • ACS Catalysis, Vol. 2, Issue 11
  • DOI: 10.1021/cs300467p

Preparation of hierarchical layer-stacking Mn-Ce composite oxide for catalytic total oxidation of VOCs
journal, January 2015


CeO2 catalysed soot oxidation
journal, July 2004


Surface reactivity of prereduced rare earth oxides with nitric oxide: New approach for NO decomposition
journal, May 2002

  • Haneda, Masaaki; Kintaichi, Yoshiaki; Hamada, Hideaki
  • Physical Chemistry Chemical Physics, Vol. 4, Issue 13
  • DOI: 10.1039/b201340a

Removal of oxygenated volatile organic compounds by catalytic oxidation over Zr–Ce–Mn catalysts
journal, April 2011


Controlled synthesis of double-shelled CeO2 hollow spheres and enzyme-free electrochemical bio-sensing properties for uric acid
journal, January 2012

  • Han, Lijun; Liu, Rongji; Li, Chunshan
  • Journal of Materials Chemistry, Vol. 22, Issue 33
  • DOI: 10.1039/c2jm32804f

The formation of nanodomains of Ce6O11 in ceria catalyzed soot combustion
journal, April 2014


Facile synthesis of core–shell Au@CeO2 nanocomposites with remarkably enhanced catalytic activity for CO oxidation
journal, January 2012

  • Qi, Jian; Chen, Jie; Li, Guodong
  • Energy & Environmental Science, Vol. 5, Issue 10
  • DOI: 10.1039/c2ee22600f

Study of Catalytic Activity at the CuO−CeO 2 Interface for CO Oxidation
journal, November 2010

  • Jia, Ai-Ping; Jiang, Shi-Yu; Lu, Ji-Qing
  • The Journal of Physical Chemistry C, Vol. 114, Issue 49
  • DOI: 10.1021/jp108556u

Hollow Microporous Cerium Oxide Spheres Templated By Colloidal Silica
journal, October 2009

  • Strandwitz, Nicholas C.; Stucky, Galen D.
  • Chemistry of Materials, Vol. 21, Issue 19
  • DOI: 10.1021/cm901516b

Ceria-based catalysts for soot oxidation: a review
journal, June 2015


Synthesis of doped ceria with mesoporous flowerlike morphology and its catalytic performance for CO oxidation
journal, April 2009


Tuning the surface oxygen concentration of {111} surrounded ceria nanocrystals for enhanced photocatalytic activities
journal, January 2016

  • Younis, Adnan; Chu, Dewei; Kaneti, Yusuf Valentino
  • Nanoscale, Vol. 8, Issue 1
  • DOI: 10.1039/C5NR06588G

Synthesis and Oxygen Storage Capacity of Two-Dimensional Ceria Nanocrystals
journal, April 2011

  • Wang, Dianyuan; Kang, Yijin; Doan-Nguyen, Vicky
  • Angewandte Chemie International Edition, Vol. 50, Issue 19
  • DOI: 10.1002/anie.201101043

Hexahedron Prism-Anchored Octahedronal CeO 2 : Crystal Facet-Based Homojunction Promoting Efficient Solar Fuel Synthesis
journal, July 2015

  • Li, Ping; Zhou, Yong; Zhao, Zongyan
  • Journal of the American Chemical Society, Vol. 137, Issue 30
  • DOI: 10.1021/jacs.5b05926

Highly Sulfur Tolerant Cu-Ceria Anodes for SOFCs
journal, January 2005

  • He, Hongpeng; Gorte, Raymond J.; Vohs, John M.
  • Electrochemical and Solid-State Letters, Vol. 8, Issue 6
  • DOI: 10.1149/1.1896469

Catalytically Stable and Active CeO 2 Mesoporous Spheres
journal, September 2010

  • Liang, Xin; Xiao, Junjia; Chen, Biaohua
  • Inorganic Chemistry, Vol. 49, Issue 18
  • DOI: 10.1021/ic100795p

One-step synthesis of nanostructured Pd-doped mixed oxides MOx-CeO2 (M=Mn, Fe, Co, Ni, Cu) for efficient CO and C3H8 total oxidation
journal, March 2009


Synthesis and Stability of Pd@CeO 2 Core–Shell Catalyst Films in Solid Oxide Fuel Cell Anodes
journal, July 2013

  • Adijanto, Lawrence; Sampath, Anirudh; Yu, Anthony S.
  • ACS Catalysis, Vol. 3, Issue 8
  • DOI: 10.1021/cs4004112

Porous Ni–Mn oxide nanosheets in situ formed on nickel foam as 3D hierarchical monolith de-NO x catalysts
journal, January 2014

  • Cai, Sixiang; Zhang, Dengsong; Shi, Liyi
  • Nanoscale, Vol. 6, Issue 13
  • DOI: 10.1039/c4nr00475b

Evidence of a lacunar mechanism for deNOx activity in ceria-based catalysts
journal, January 2001

  • Daturi, M.; Bion, N.; Saussey, J.
  • Physical Chemistry Chemical Physics, Vol. 3, Issue 2
  • DOI: 10.1039/b007818m

Three-Dimensional Ordered CeO2 Hollow Spheres (3DOHSs-CeO2) from Polymethylmethacrylate/CeO2 Core/Shell Microsphere Colloidal Crystals
journal, September 2015

  • Chen, Ailian; Chen, Yang; Chen, Zhigang
  • Journal of Inorganic and Organometallic Polymers and Materials, Vol. 26, Issue 1
  • DOI: 10.1007/s10904-015-0282-6

Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes
journal, October 2004


Morphology-controlled synthesis of cage-bell Pd@CeO2 structured nanoparticle aggregates as catalysts for the low-temperature oxidation of CO
journal, January 2013

  • Guo, Hong; He, Yunbo; Wang, Yapeng
  • Journal of Materials Chemistry A, Vol. 1, Issue 25
  • DOI: 10.1039/c3ta10643h

Alkali Metal Poisoning of a CeO 2 –WO 3 Catalyst Used in the Selective Catalytic Reduction of NO x with NH 3 : an Experimental and Theoretical Study
journal, February 2012

  • Peng, Yue; Li, Junhua; Chen, Liang
  • Environmental Science & Technology, Vol. 46, Issue 5
  • DOI: 10.1021/es203619w

Pt@CeO 2 Multicore@Shell Self-Assembled Nanospheres: Clean Synthesis, Structure Optimization, and Catalytic Applications
journal, October 2013

  • Wang, Xiao; Liu, Dapeng; Song, Shuyan
  • Journal of the American Chemical Society, Vol. 135, Issue 42
  • DOI: 10.1021/ja4069134

Colloidal Solution Combustion Synthesis: Toward Mass Production of a Crystalline Uniform Mesoporous CeO 2 Catalyst with Tunable Porosity
journal, April 2016


Nanocrystalline undoped ceria oxygen sensor
journal, October 2003


Low-Temperature CO Oxidation over a Ternary Oxide Catalyst with High Resistance to Hydrocarbon Inhibition
journal, September 2015

  • Binder, Andrew J.; Toops, Todd J.; Unocic, Raymond R.
  • Angewandte Chemie International Edition, Vol. 54, Issue 45
  • DOI: 10.1002/anie.201506093

Catalytic oxidation of benzene over CuO/Ce1−xMnxO2 catalysts
journal, March 2011


Converting Ceria Polyhedral Nanoparticles into Single-Crystal Nanospheres
journal, June 2006


Synthesis and characterization of low amount tin-doped ceria (CeXSn1−XO2−δ) for catalytic CO oxidation
journal, May 2014

  • Ayastuy, J. L.; Iglesias-González, A.; Gutiérrez-Ortiz, M. A.
  • Chemical Engineering Journal, Vol. 244
  • DOI: 10.1016/j.cej.2014.01.077

The Impact of Aerosols on Solar Ultraviolet Radiation and Photochemical Smog
journal, October 1997


Hydrothermal Synthesis of CeO 2 Nanocrystals: Ostwald Ripening or Oriented Attachment?
journal, May 2012

  • Lin, Ming; Fu, Zi Yuan; Tan, Hui Ru
  • Crystal Growth & Design, Vol. 12, Issue 6
  • DOI: 10.1021/cg300421x

Porous CeO2 nanowires/nanowire arrays: electrochemical synthesis and application in water treatment
journal, January 2010

  • Lu, Xi-hong; Zheng, De-zhou; Gan, Jia-yong
  • Journal of Materials Chemistry, Vol. 20, Issue 34
  • DOI: 10.1039/c0jm00487a

Synthesis and characterization of mesoporous CeO2 nanotube arrays
journal, May 2013


VOC oxidation over CuO–CeO2 catalysts prepared by a combustion method
journal, July 2009


Morphology-dependent redox and catalytic properties of CeO2 nanostructures: Nanowires, nanorods and nanoparticles
journal, October 2009


Extra-Low-Temperature Oxygen Storage Capacity of CeO 2 Nanocrystals with Cubic Facets
journal, February 2011

  • Zhang, Jing; Kumagai, Hitoshi; Yamamura, Kae
  • Nano Letters, Vol. 11, Issue 2
  • DOI: 10.1021/nl102738n

Efficient low-temperature catalytic combustion of trichloroethylene over flower-like mesoporous Mn-doped CeO2 microspheres
journal, February 2011


Mesoporous-shelled CeO2 hollow nanospheres synthesized by a one-pot hydrothermal route and their catalytic performance
journal, January 2013

  • Liu, Xiufang; Yang, Hongxiao; Han, Lu
  • CrystEngComm, Vol. 15, Issue 38
  • DOI: 10.1039/c3ce40959g

Computer modeling of surfaces and defects on cerium dioxide
journal, October 1995


CO Oxidation Activity at Room Temperature over Au/CeO 2 Catalysts: Disclosure of Induction Period and Humidity Effect
journal, September 2014

  • Zhang, Shuo; Li, Xiao-Song; Chen, Bingbing
  • ACS Catalysis, Vol. 4, Issue 10
  • DOI: 10.1021/cs500614f

Defect Engineering in Cubic Cerium Oxide Nanostructures for Catalytic Oxidation
journal, July 2011

  • Lawrence, Neil J.; Brewer, Joseph R.; Wang, Lu
  • Nano Letters, Vol. 11, Issue 7
  • DOI: 10.1021/nl200722z

Heterogeneous production of nitrous acid on soot in polluted air masses
journal, September 1998

  • Ammann, M.; Kalberer, M.; Jost, D. T.
  • Nature, Vol. 395, Issue 6698
  • DOI: 10.1038/25965

Synthesis, characterization and CO oxidation of TiO2/(La,Sr)MnO3 composite nanorod array
journal, April 2012


Manganese Oxide Nanoarray-Based Monolithic Catalysts: Tunable Morphology and High Efficiency for CO Oxidation
journal, March 2016

  • Chen, Sheng-Yu; Song, Wenqiao; Lin, Hui-Jan
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 12
  • DOI: 10.1021/acsami.6b00578

Alcohol induced ultra-fine dispersion of Pt on tuned morphologies of CeO2 for CO oxidation
journal, February 2013

  • Meher, Sumanta Kumar; Cargnello, Matteo; Troiani, Horacio
  • Applied Catalysis B: Environmental, Vol. 130-131
  • DOI: 10.1016/j.apcatb.2012.10.022

N 2 Selectivity of NO Reduction by NH 3 over MnO x –CeO 2 : Mechanism and Key Factors
journal, September 2014

  • Yang, Shijian; Liao, Yong; Xiong, Shangchao
  • The Journal of Physical Chemistry C, Vol. 118, Issue 37
  • DOI: 10.1021/jp5062489

Preparing an active cerium oxide catalyst for the catalytic incineration of aromatic hydrocarbons
journal, August 2004


On the structure dependence of CO oxidation over CeO2 nanocrystals with well-defined surface planes
journal, January 2012


Elucidating the Nature of the Active Phase in Copper/Ceria Catalysts for CO Oxidation
journal, February 2016


Highly efficient mesoporous Pd/CeO2 catalyst for low temperature CO oxidation especially under moisture condition
journal, October 2014


Highly dispersed CeO 2 on carbon nanotubes for selective catalytic reduction of NO with NH 3
journal, January 2013

  • Fang, Cheng; Zhang, Dengsong; Shi, Liyi
  • Catal. Sci. Technol., Vol. 3, Issue 3
  • DOI: 10.1039/C2CY20670F

DRIFT Study of CuO–CeO 2 –TiO 2 Mixed Oxides for NO x Reduction with NH 3 at Low Temperatures
journal, May 2014

  • Chen, Lei; Si, Zhichun; Wu, Xiaodong
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 11
  • DOI: 10.1021/am5004969

Columnar CeO 2 nanostructures for sensor application
journal, February 2007


Catalytic removal of benzene over CeO2–MnOx composite oxides prepared by hydrothermal method
journal, July 2013


Tailored Mesostructured Copper/Ceria Catalysts with Enhanced Performance for Preferential Oxidation of CO at Low Temperature
journal, October 2012

  • Yen, Hoang; Seo, Yongbeom; Kaliaguine, Serge
  • Angewandte Chemie International Edition, Vol. 51, Issue 48
  • DOI: 10.1002/anie.201206505

Layer-by-layer synthesis of hollow spherical CeO2 templated by carbon spheres
journal, May 2009


Uniform and Porous Ce 1– x Zn x O 2−δ Solid Solution Nanodisks: Preparation and Their CO Oxidation Activity
journal, June 2012

  • Zhong, Sheng-Liang; Zhang, Lin-Fei; Wang, Lei
  • The Journal of Physical Chemistry C, Vol. 116, Issue 24
  • DOI: 10.1021/jp3017826

Multi-shelled CeO 2 hollow microspheres as superior photocatalysts for water oxidation
journal, January 2014


Hierarchical nanoscale multi-shell Au/CeO 2 hollow spheres
journal, January 2014


Supported Co3O4-CeO2 catalysts on modified activated carbon for CO preferential oxidation in H2-rich gases
journal, May 2012


Mechanical-Agitation-Assisted Growth of Large-Scale and Uniform ZnO Nanorod Arrays within 3D Multichannel Monolithic Substrates
journal, July 2013

  • Xiao, Wen; Guo, Yanbing; Ren, Zheng
  • Crystal Growth & Design, Vol. 13, Issue 8
  • DOI: 10.1021/cg400672z

Shape-Selective Synthesis and Oxygen Storage Behavior of Ceria Nanopolyhedra, Nanorods, and Nanocubes
journal, December 2005

  • Mai, Hao-Xin; Sun, Ling-Dong; Zhang, Ya-Wen
  • The Journal of Physical Chemistry B, Vol. 109, Issue 51
  • DOI: 10.1021/jp055584b

Fabrication of three dimensional CeO2 hierarchical structures: Precursor template synthesis, formation mechanism and properties
journal, January 2011

  • Wei, Jingjing; Yang, Zhijie; Yang, Yanzhao
  • CrystEngComm, Vol. 13, Issue 7
  • DOI: 10.1039/c0ce00635a

Low temperature propane oxidation over Co3O4 based nano-array catalysts: Ni dopant effect, reaction mechanism and structural stability
journal, January 2016


Nanostructured manganese doped ceria solid solutions for CO oxidation at lower temperatures
journal, January 2015

  • Venkataswamy, Perala; Rao, Komateedi N.; Jampaiah, Deshetti
  • Applied Catalysis B: Environmental, Vol. 162
  • DOI: 10.1016/j.apcatb.2014.06.038

Morphology-dependent nanocatalysts: Rod-shaped oxides
journal, January 2014


Ceria Hollow Nanospheres Produced by a Template-Free Microwave-Assisted Hydrothermal Method for Heavy Metal Ion Removal and Catalysis
journal, May 2010

  • Cao, Chang-Yan; Cui, Zhi-Min; Chen, Chao-Qiu
  • The Journal of Physical Chemistry C, Vol. 114, Issue 21
  • DOI: 10.1021/jp101553x

Forty years of catalysis by ceria: A success story
journal, November 2016


Enhanced Sensitivity and Stability of Room-Temperature NH 3 Sensors Using Core–Shell CeO 2 Nanoparticles@Cross-linked PANI with p–n Heterojunctions
journal, July 2014

  • Wang, Lingling; Huang, Hui; Xiao, Songhua
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 16
  • DOI: 10.1021/am503286h

Shape-Dependent Activity of Ceria in Soot Combustion
journal, December 2013

  • Aneggi, Eleonora; Wiater, Dawid; de Leitenburg, Carla
  • ACS Catalysis, Vol. 4, Issue 1
  • DOI: 10.1021/cs400850r

Diesel soot combustion ceria catalysts
journal, March 2014


Pd/CeO 2− x Nanorod Catalysts for CO Oxidation: Insights into the Origin of Their Regenerative Ability at Room Temperature
journal, August 2014


Ordered Mesoporous CeO 2 Synthesized by Nanocasting from Cubic Ia3d Mesoporous MCM-48 Silica: Formation, Characterization and Photocatalytic Activity
journal, October 2008

  • Ji, Pengfei; Zhang, Jinlong; Chen, Feng
  • The Journal of Physical Chemistry C, Vol. 112, Issue 46
  • DOI: 10.1021/jp8054087

Facile synthesis of 3D flowerlike CeO2 microspheres under mild condition with high catalytic performance for CO oxidation
journal, August 2011

  • Li, Junfeng; Lu, Guanzhong; Li, Hongfeng
  • Journal of Colloid and Interface Science, Vol. 360, Issue 1
  • DOI: 10.1016/j.jcis.2011.04.052

Fast humidity sensors based on CeO 2 nanowires
journal, March 2007


Temperature-programmed reduction and CO oxidation studies over Ce–Sn mixed oxides
journal, January 2001

  • Sasikala, R.; Gupta, N. M.; Kulshreshtha, S. K.
  • Catalysis Letters, Vol. 71, Issue 1/2, p. 69-73
  • DOI: 10.1023/A:1016656408728

Studies of the Catalytic Oxidation of CO Over Ag/CeO2 Catalyst
journal, September 2012


MnOx–CeO2 mixed oxide catalysts for complete oxidation of formaldehyde: Effect of preparation method and calcination temperature
journal, February 2006

  • Tang, Xingfu; Li, Yonggang; Huang, Xiumin
  • Applied Catalysis B: Environmental, Vol. 62, Issue 3-4, p. 265-273
  • DOI: 10.1016/j.apcatb.2005.08.004

In situ TPR removal: a generic method for fabricating tubular array devices with mechanical and structural soundness, and functional robustness on various substrates
journal, January 2012

  • Zhang, Zhonghua; Gao, Haiyong; Cai, Wenjie
  • Journal of Materials Chemistry, Vol. 22, Issue 43, p. 23098-23105
  • DOI: 10.1039/c2jm34606k

Redox properties of nanostructured lanthanide-doped ceria spheres prepared by microwave assisted hydrothermal homogeneous co-precipitation
journal, January 2015

  • Muñoz, F. F.; Acuña, L. M.; Albornoz, C. A.
  • Nanoscale, Vol. 7, Issue 1
  • DOI: 10.1039/C4NR05630B

Polyhedral Shapes of CeO 2 Nanoparticles
journal, December 2003

  • Wang, Zhong Lin; Feng, Xiangdong
  • The Journal of Physical Chemistry B, Vol. 107, Issue 49
  • DOI: 10.1021/jp036815m

Synthesis of porous CuO–CeO2 nanospheres with an enhanced low-temperature CO oxidation activity
journal, January 2010

  • Qin, Jinwen; Lu, Junfeng; Cao, Minhua
  • Nanoscale, Vol. 2, Issue 12
  • DOI: 10.1039/c0nr00446d

Catalytic soot combustion over CeO2-based oxides
journal, August 2010


One-Pot Synthesis of Mn-Doped CeO 2 Nanospheres for CO Oxidation
journal, July 2013

  • Zhang, Xueying; Wei, Jingjing; Yang, Hongxiao
  • European Journal of Inorganic Chemistry, Vol. 2013, Issue 25
  • DOI: 10.1002/ejic.201300370

Origin of Active Oxygen in a Ternary CuO x /Co 3 O 4 –CeO 2 Catalyst for CO Oxidation
journal, November 2014

  • Liu, Zhigang; Wu, Zili; Peng, Xihong
  • The Journal of Physical Chemistry C, Vol. 118, Issue 48
  • DOI: 10.1021/jp508487x

Size-Dependent Reaction Pathways of Low-Temperature CO Oxidation on Au/CeO 2 Catalysts
journal, February 2015

  • Chen, Shilong; Luo, Liangfeng; Jiang, Zhiquan
  • ACS Catalysis, Vol. 5, Issue 3
  • DOI: 10.1021/cs502067x

Controlled Synthesis and Self-Assembly of CeO 2 Nanocubes
journal, July 2006

  • Yang, Songwang; Gao, Lian
  • Journal of the American Chemical Society, Vol. 128, Issue 29
  • DOI: 10.1021/ja063359h

Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment
journal, December 2012

  • Paier, Joachim; Penschke, Christopher; Sauer, Joachim
  • Chemical Reviews, Vol. 113, Issue 6
  • DOI: 10.1021/cr3004949

Sintering-resistant Pt@CeO 2 nanoparticles for high-temperature oxidation catalysis
journal, January 2016

  • Lee, Siwon; Seo, Jongsu; Jung, WooChul
  • Nanoscale, Vol. 8, Issue 19
  • DOI: 10.1039/C6NR00170J

Samarium-Doped Ceria Nanowires: Novel Synthesis and Application in Low-Temperature Solid Oxide Fuel Cells
journal, January 2010


High activity mesoporous copper doped cerium oxide catalysts for the total oxidation of polyaromatic hydrocarbon pollutants
journal, January 2012

  • Aranda, Asunción; Aylón, Elvira; Solsona, Benjamín
  • Chemical Communications, Vol. 48, Issue 39
  • DOI: 10.1039/c2cc31206a

Template-free synthesis of hierarchical layer-stacking CeO2 nanostructure with enhanced catalytic oxidation activity
journal, February 2015


Kinetics of Carbon Monoxide Oxidation over CuO Supported on Nanosized CeO 2
journal, June 2009

  • Ayastuy, Jose L.; Gurbani, Anita; González-Marcos, María P.
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 12
  • DOI: 10.1021/ie9001603

Effect of hydrothermal reaction time and calcination temperature on properties of Au@CeO2 core–shell catalyst for CO oxidation at low temperature
journal, June 2015


Novel Effect of H 2 O on the Low Temperature Selective Catalytic Reduction of NO with NH 3 over MnO x —CeO 2 : Mechanism and Kinetic Study
journal, February 2015

  • Xiong, Shangchao; Liao, Yong; Xiao, Xin
  • The Journal of Physical Chemistry C, Vol. 119, Issue 8
  • DOI: 10.1021/jp512407k

Direct oxidation of hydrocarbons in a solid-oxide fuel cell
journal, March 2000

  • Park, Seungdoo; Vohs, John M.; Gorte, Raymond J.
  • Nature, Vol. 404, Issue 6775
  • DOI: 10.1038/35005040

The stability of ionic crystal surfaces
journal, November 1979


Oxygen gas sensors based on CeO2 thick and thin films
journal, June 1991


Fundamentals and Catalytic Applications of CeO 2 -Based Materials
journal, April 2016


Structural and Morphological Characterization of Cerium Oxide Nanocrystals Prepared by Hydrothermal Synthesis
journal, February 2007

  • Kaneko, Kenji; Inoke, Koji; Freitag, Bert
  • Nano Letters, Vol. 7, Issue 2
  • DOI: 10.1021/nl062677b

Fabrication of Monodisperse CeO 2 Hollow Spheres Assembled by Nano-octahedra
journal, January 2010

  • Yang, Zhijie; Han, Dongqing; Ma, Donglin
  • Crystal Growth & Design, Vol. 10, Issue 1
  • DOI: 10.1021/cg900898r

CeO 2 Spherical Crystallites:  Synthesis, Formation Mechanism, Size Control, and Electrochemical Property Study
journal, February 2007

  • Zhou, Fu; Zhao, Xuemei; Xu, Hai
  • The Journal of Physical Chemistry C, Vol. 111, Issue 4
  • DOI: 10.1021/jp0660435

Facile Preparation of Well-Dispersed CeO 2 –ZnO Composite Hollow Microspheres with Enhanced Catalytic Activity for CO Oxidation
journal, December 2013

  • Xie, Qingshui; Zhao, Yue; Guo, Huizhang
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 1
  • DOI: 10.1021/am404487b

A novel method to synthesize homogeneous and mono-dispersible CeO2 nanospheres: two-step hydrothermal process
journal, July 2011


Synthesis and Oxygen Storage Capacity of Two-Dimensional Ceria Nanocrystals
journal, April 2011

  • Wang, Dianyuan; Kang, Yijin; Doan-Nguyen, Vicky
  • Angewandte Chemie, Vol. 123, Issue 19
  • DOI: 10.1002/ange.201101043

Tailored Mesostructured Copper/Ceria Catalysts with Enhanced Performance for Preferential Oxidation of CO at Low Temperature
journal, October 2012

  • Yen, Hoang; Seo, Yongbeom; Kaliaguine, Serge
  • Angewandte Chemie, Vol. 124, Issue 48
  • DOI: 10.1002/ange.201206505

Low‐Temperature CO Oxidation over a Ternary Oxide Catalyst with High Resistance to Hydrocarbon Inhibition
journal, September 2015

  • Binder, Andrew J.; Toops, Todd J.; Unocic, Raymond R.
  • Angewandte Chemie, Vol. 127, Issue 45
  • DOI: 10.1002/ange.201506093

Solid Oxide Fuel Cells
journal, April 2003


Works referencing / citing this record:

Size, shape, and orientation dependence of the field-induced behavior in ferroelectric nanoparticles
journal, April 2019

  • Zhu, Daopei; Mangeri, John; Wang, Ruolin
  • Journal of Applied Physics, Vol. 125, Issue 13
  • DOI: 10.1063/1.5088864

The Effect of CeO2 Preparation Method on the Carbon Pathways in the Dry Reforming of Methane on Ni/CeO2 Studied by Transient Techniques
journal, July 2019

  • Damaskinos, Constantinos M.; Vasiliades, Michalis A.; Stathopoulos, Vassilis N.
  • Catalysts, Vol. 9, Issue 7
  • DOI: 10.3390/catal9070621

Synthesis, design and sensing applications of nanostructured ceria-based materials
journal, January 2018

  • Raza Naqvi, Sayed Tayyab; Shirinfar, Bahareh; Majeed, Saadat
  • The Analyst, Vol. 143, Issue 23
  • DOI: 10.1039/c8an01268g

Approaches to Exploring Spatio-Temporal Surface Dynamics in Nanoparticles with In Situ Transmission Electron Microscopy
journal, December 2019

  • Lawrence, Ethan L.; Levin, Barnaby D. A.; Miller, Benjamin K.
  • Microscopy and Microanalysis, Vol. 26, Issue 1
  • DOI: 10.1017/s1431927619015228

The Role of Gold‐Alumina Template in the Electrochemical Deposition of CeO 2 Nanotubes
journal, August 2019

  • González‐Souto, Lorena; González‐Rovira, Leandro; Botana, Francisco Javier
  • Particle & Particle Systems Characterization, Vol. 36, Issue 10
  • DOI: 10.1002/ppsc.201900168

Facet-Dependent Reactivity of Fe2O3/CeO2 Nanocomposites: Effect of Ceria Morphology on CO Oxidation
journal, April 2019

  • Lykaki, Maria; Stefa, Sofia; Carabineiro, Sόnia
  • Catalysts, Vol. 9, Issue 4
  • DOI: 10.3390/catal9040371

Novel Fe 2 O 3 @CeO 2 Coreshell‐based Electrochemical Nanosensor for the Voltammetric Determination of Norepinephrine
journal, October 2019

  • Mazloum‐Ardakani, Mohammad; Alizadeh, Zahra; Sabaghian, Fariba
  • Electroanalysis, Vol. 32, Issue 3
  • DOI: 10.1002/elan.201900454

Metastable vortex-like polarization textures in ferroelectric nanoparticles of different shapes and sizes
journal, August 2018

  • Pitike, Krishna Chaitanya; Mangeri, John; Whitelock, Hope
  • Journal of Applied Physics, Vol. 124, Issue 6
  • DOI: 10.1063/1.5037163

Electromechanical control of polarization vortex ordering in an interacting ferroelectric-dielectric composite dimer
journal, August 2018

  • Mangeri, John; Alpay, S. Pamir; Nakhmanson, Serge
  • Applied Physics Letters, Vol. 113, Issue 9
  • DOI: 10.1063/1.5046080

Monolithic Au/CeO 2 nanorod framework catalyst prepared by dealloying for low-temperature CO oxidation
journal, January 2018


Synthesis of mesoporous Fe/h-CeO 2 hollow micro-spheres with enhanced visible light photocatalytic activity
journal, July 2019