Direct 17O dynamic nuclear polarization of single-site heterogeneous catalysts

Perras, Frédéric A.; Boteju, Kasuni C.; Slowing, Igor I.; Sadow, Aaron D.; Pruski, Marek

doi:10.1039/C8CC00293B

Title: Direct ¹⁷O dynamic nuclear polarization of single-site heterogeneous catalysts

Journal Article · Tue Mar 13 00:00:00 EDT 2018 · ChemComm

DOI: https://doi.org/10.1039/C8CC00293B · OSTI ID:1427737

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Ames Lab., Ames, IA (United States)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States). Department of Chemistry

In this work, we utilize direct ¹⁷O DNP for the characterization of non-protonated oxygens in heterogeneous catalysts. The optimal sample preparation and population transfer approach for ¹⁷O direct DNP experiments performed on silica surfaces is determined and applied to the characterization of Zr- and Y-based mesoporous silica-supported single-site catalysts.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1427737

Report Number(s):: IS-J--593

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 28 Vol. 54; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Shedding light on the atomic-scale structure of amorphous silica–alumina and its Brønsted acid sites Perras, Frédéric A.; Wang, Zichun; Kobayashi, Takeshi Physical Chemistry Chemical Physics, Vol. 21, Issue 35 https://doi.org/10.1039/c9cp04099d	journal	January 2019
Optimizing nitroxide biradicals for cross-effect MAS-DNP: the role of g -tensors’ distance Mentink-Vigier, Frédéric Physical Chemistry Chemical Physics, Vol. 22, Issue 6 https://doi.org/10.1039/c9cp06201g	journal	January 2020
Shedding light on the atomic-scale structure of amorphous silica-alumina and its Brønsted acid sites Perras, Frédéric A.; Wang, Zichun; Kobayashi, Takeshi ETH Zurich https://doi.org/10.3929/ethz-b-000364135	text	January 2019

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