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Title: Measurement of O and Ti atom displacements in TiO 2 during flash sintering experiments

Abstract

In-situ flash experiments on rutile TiO2 were performed at the synchrotron at the Brookhaven National Laboratory. Pair distribution function analysis of total X-ray scattering measurements yielded mean-square atomic displacements of oxygen and titanium atoms during the progression of the 3 stages of flash. The displacements are measured to be far greater for oxygen atoms than for titanium atoms. Thus, these large displacements may signal an “elastic softening” of the lattice, which, recently, has been predicted as a precursor to the onset of flash.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [2];  [3]; ORCiD logo [4]
+ Show Author Affiliations
  1. Univ. of Colorado, Boulder, CO (United States). Materials Science and Engineering Program and Dept. of Mechanical Engineering
  2. Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II). Energy Sciences Directorate/Photon Science Division
  3. Oklahoma State Univ., Tulsa, OK (United States). School of Materials Science and Engineering
  4. Univ. of Illinois, Urbana, IL (United States). Dept. of Materials Science and Engineering
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); US Dept. of the Navy, Office of Naval Research (ONR); US Army Research Office (ARO)
OSTI Identifier:
1426460
Alternate Identifier(s):
OSTI ID: 1415153
Report Number(s):
BNL-203349-2018-JAAM
Journal ID: ISSN 0002-7820; TRN: US1802288
Grant/Contract Number:  
SC0012704; N00014‐15‐1‐2505; W911NF‐17‐1‐0142; AC02-98CH10886
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Ceramic Society
Additional Journal Information:
Journal Volume: 101; Journal Issue: 5; Journal ID: ISSN 0002-7820
Publisher:
American Ceramic Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; sinter; sintering; spark plasma sintering; X-ray methods

Citation Formats

Yoon, Bola, Yadav, Devinder, Raj, Rishi, Sortino, Emanuele P., Ghose, Sanjit, Sarin, Pankaj, and Shoemaker, Daniel. Measurement of O and Ti atom displacements in TiO 2 during flash sintering experiments. United States: N. p., 2017. Web. doi:10.1111/jace.15375.
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Yoon, Bola, Yadav, Devinder, Raj, Rishi, Sortino, Emanuele P., Ghose, Sanjit, Sarin, Pankaj, & Shoemaker, Daniel. Measurement of O and Ti atom displacements in TiO 2 during flash sintering experiments. United States. https://doi.org/10.1111/jace.15375
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Yoon, Bola, Yadav, Devinder, Raj, Rishi, Sortino, Emanuele P., Ghose, Sanjit, Sarin, Pankaj, and Shoemaker, Daniel. Fri . "Measurement of O and Ti atom displacements in TiO 2 during flash sintering experiments". United States. https://doi.org/10.1111/jace.15375. https://www.osti.gov/servlets/purl/1426460.
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@article{osti_1426460,
title = {Measurement of O and Ti atom displacements in TiO 2 during flash sintering experiments},
author = {Yoon, Bola and Yadav, Devinder and Raj, Rishi and Sortino, Emanuele P. and Ghose, Sanjit and Sarin, Pankaj and Shoemaker, Daniel},
abstractNote = {In-situ flash experiments on rutile TiO2 were performed at the synchrotron at the Brookhaven National Laboratory. Pair distribution function analysis of total X-ray scattering measurements yielded mean-square atomic displacements of oxygen and titanium atoms during the progression of the 3 stages of flash. The displacements are measured to be far greater for oxygen atoms than for titanium atoms. Thus, these large displacements may signal an “elastic softening” of the lattice, which, recently, has been predicted as a precursor to the onset of flash.},
doi = {10.1111/jace.15375},
journal = {Journal of the American Ceramic Society},
number = 5,
volume = 101,
place = {United States},
year = {Fri Dec 29 00:00:00 EST 2017},
month = {Fri Dec 29 00:00:00 EST 2017}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1111/jace.15375
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Citation Metrics:
Cited by: 51 works
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Figures / Tables:

Figure 1: Figure 1:: Experimental set-up for in-situ flash experiments at NSLS-II.
All figures and tables (4 total)
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Works referenced in this record:

PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals
journal, July 2007

Flash Sintering of Nanograin Zirconia in <5 s at 850°C
journal, September 2010

Analysis of the Power Density at the Onset of Flash Sintering
journal, June 2016

  • Raj, Rishi
  • Journal of the American Ceramic Society, Vol. 99, Issue 10
  • DOI: 10.1111/jace.14178

Interstitialcy theory of simple condensed matter
journal, January 2014

Two unique measurements related to flash experiments with yttria-stabilized zirconia
journal, August 2017

  • Yadav, Devinder; Raj, Rishi
  • Journal of the American Ceramic Society, Vol. 100, Issue 12
  • DOI: 10.1111/jace.15114

Emergence and Extinction of a New Phase During On–Off Experiments Related to Flash Sintering of 3 YSZ
journal, January 2015

  • Lebrun, Jean‐Marie; Morrissey, Timothy G.; Francis, John S. C.
  • Journal of the American Ceramic Society, Vol. 98, Issue 5
  • DOI: 10.1111/jace.13476

Calibration and correction of distortions in two‐dimensional detector systems a)
journal, March 1995

  • Hammersley, A. P.; Svensson, S. O.; Thompson, A.
  • Review of Scientific Instruments, Vol. 66, Issue 3
  • DOI: 10.1063/1.1145618

Flash sintering as a nucleation phenomenon and a model thereof
journal, December 2014

Influence of the Field and the Current Limit on Flash Sintering at Isothermal Furnace Temperatures
journal, July 2013

  • Francis, John S. C.; Raj, Rishi
  • Journal of the American Ceramic Society, Vol. 96, Issue 9
  • DOI: 10.1111/jace.12472

In‐situ measurements of lattice expansion related to defect generation during flash sintering
journal, July 2017

  • Lebrun, J. ‐M.; Hellberg, C. S.; Jha, S. K.
  • Journal of the American Ceramic Society, Vol. 100, Issue 11
  • DOI: 10.1111/jace.15071

PDFFIT , a program for full profile structural refinement of the atomic pair distribution function
journal, June 1999

Atomic Dispacement Parameter Nomenclature. Report of a Subcommittee on Atomic Displacement Parameter Nomenclature
journal, September 1996

  • Trueblood, K. N.; Bürgi, H. B.; Burzlaff, H.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 52, Issue 5
  • DOI: 10.1107/S0108767396005697

Flash sintering of a three‐phase alumina, spinel, and yttria‐stabilized zirconia composite
journal, April 2017

  • Kok, David; Jha, Shikhar Krishn; Raj, Rishi
  • Journal of the American Ceramic Society, Vol. 100, Issue 7
  • DOI: 10.1111/jace.14818

Evidence of Distributed Interstitialcy-Like Relaxation of the Shear Modulus due to Structural Relaxation of Metallic Glasses
journal, February 2008

On Pre-Breakdown Phenomena in Insulators and Electronic Semi-Conductors
journal, October 1938

Phase transformation in the alumina–titania system during flash sintering experiments
journal, February 2016

Electroluminescence and the measurement of temperature during Stage III of flash sintering experiments
journal, October 2015

Interstitialcy model for condensed matter states of face-centered-cubic metals
journal, February 1992

Electric field induced texture in titania during experiments related to flash sintering
journal, January 2016

Broadening of Diffraction Peak Widths and Temperature Nonuniformity During Flash Experiments
journal, June 2016

  • Lebrun, Jean‐Marie; Jha, Shikhar K.; McCormack, Scott J.
  • Journal of the American Ceramic Society, Vol. 99, Issue 10
  • DOI: 10.1111/jace.14326

Melting Mechanisms at the Limit of Superheating
journal, July 2001

Influence of Externally Imposed and Internally Generated Electrical Fields on Grain Growth, Diffusional Creep, Sintering and Related Phenomena in Ceramics
journal, July 2011

The crystal structure of rutile as a function of temperature up to 1600°C
journal, January 1991

  • Sugiyama, Kazumasa; Takéuchi, Yoshio
  • Zeitschrift für Kristallographie - Crystalline Materials, Vol. 194, Issue 3-4
  • DOI: 10.1524/zkri.1991.194.3-4.305
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    Works referencing / citing this record:

    Defect‐Mediated Anisotropic Lattice Expansion in Ceramics as Evidence for Nonthermal Coupling between Electromagnetic Fields and Matter
    journal, September 2019

    • Jha, Shikhar Krishn; Nakamura, Nathan; Zhang, Shuyan
    • Advanced Engineering Materials, Vol. 21, Issue 12
    • DOI: 10.1002/adem.201900762

    Reactive flash sintering: MgO and α‐Al 2 O 3 transform and sinter into single‐phase polycrystals of MgAl 2 O 4
    journal, October 2018

    • Yoon, Bola; Yadav, Devinder; Ghose, Sanjit
    • Journal of the American Ceramic Society
    • DOI: 10.1111/jace.15974

    The effects of external fields in ceramic sintering
    journal, September 2018

    • Jha, Shikhar K.; Phuah, Xin Li; Luo, Jian
    • Journal of the American Ceramic Society
    • DOI: 10.1111/jace.16061

    On the synchronicity of flash sintering and phase transformation
    journal, February 2019

    • Yoon, Bola; Yadav, Devinder; Ghose, Sanjit
    • Journal of the American Ceramic Society, Vol. 102, Issue 6
    • DOI: 10.1111/jace.16335

    Element‐specific displacements in defect‐enriched TiO 2 : Indication of a flash sintering mechanism
    journal, July 2019

    • Jongmanns, Malte; Wolf, Dietrich E.
    • Journal of the American Ceramic Society, Vol. 103, Issue 1
    • DOI: 10.1111/jace.16696
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      Figures / Tables found in this record:

      Figure 1: (p. 6)figure
      Figure 2: (p. 7)figure
      Figure 3(a): (p. 8)figure
      Figure 4: (p. 9)figure
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