Dendritic core-shell nickel-iron-copper metal/metal oxide electrode for efficient electrocatalytic water oxidation

Zhang, Peili; Li, Lin; Nordlund, Dennis; Chen, Hong; Fan, Lizhou; Zhang, Biaobiao; Sheng, Xia; Daniel, Quentin; Sun, Licheng

doi:10.1038/s41467-017-02429-9

Title: Dendritic core-shell nickel-iron-copper metal/metal oxide electrode for efficient electrocatalytic water oxidation

Journal Article · Thu Jan 25 23:00:00 EST 2018 · Nature Communications

DOI: https://doi.org/10.1038/s41467-017-02429-9 · OSTI ID:1426183

Zhang, Peili ^[1]; Li, Lin ^[2]; Nordlund, Dennis ^[3]; Chen, Hong ^[1]; Fan, Lizhou ^[1]; Zhang, Biaobiao ^[1]; Sheng, Xia ^[1]; Daniel, Quentin ^[1];

^[4]

KTH Royal Inst. of Technology, Stockholm (Sweden). Dept. of Chemistry
SLAC National Accelerator Lab., Menlo Park, CA (United States). Photon Ultrafast Laser Science and Engineering Inst. (PULSE)
SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
KTH Royal Inst. of Technology, Stockholm (Sweden). Dept. of Chemistry; Dalian Univ. of Technology, Dalian (China). State Key Lab. of Fine Chemicals, Inst. of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices

Electrochemical water splitting requires efficient water oxidation catalysts to accelerate the sluggish kinetics of water oxidation reaction. Here in this paper, we report a promisingly dendritic core-shell nickel-iron-copper metal/metal oxide electrode, prepared via dealloying with an electrodeposited nickel-iron-copper alloy as a precursor, as the catalyst for water oxidation. The as-prepared core-shell nickel-iron-copper electrode is characterized with porous oxide shells and metallic cores. This tri-metal-based core-shell nickel-iron-copper electrode exhibits a remarkable activity toward water oxidation in alkaline medium with an overpotential of only 180 mV at a current density of 10 mA cm^-2. The core-shell NiFeCu electrode exhibits pH-dependent oxygen evolution reaction activity on the reversible hydrogen electrode scale, suggesting that non-concerted proton-electron transfers participate in catalyzing the oxygen evolution reaction. To the best of our knowledge, the as-fabricated core-shell nickel-iron-copper is one of the most promising oxygen evolution catalysts.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Natural Science Foundation of China (NNSF); Swedish Energy Agency; Knut & Alice Wallenberg Foundation; Swedish Research Council (SRC)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1426183

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 9; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (50)

Seamlessly Conductive 3D Nanoarchitecture of Core-Shell Ni-Co Nanowire Network for Highly Efficient Oxygen Evolution Bae, Seok-Hu; Kim, Ji-Eun; Randriamahazaka, Hyacinthe Advanced Energy Materials, Vol. 7, Issue 1 https://doi.org/10.1002/aenm.201601492	journal	September 2016
A Strongly Coupled Graphene and FeNi Double Hydroxide Hybrid as an Excellent Electrocatalyst for the Oxygen Evolution Reaction Long, Xia; Li, Jinkai; Xiao, Shuang Angewandte Chemie, Vol. 126, Issue 29 https://doi.org/10.1002/ange.201402822	journal	June 2014
A Strongly Coupled Graphene and FeNi Double Hydroxide Hybrid as an Excellent Electrocatalyst for the Oxygen Evolution Reaction Long, Xia; Li, Jinkai; Xiao, Shuang Angewandte Chemie International Edition, Vol. 53, Issue 29 https://doi.org/10.1002/anie.201402822	journal	June 2014
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis Dau, Holger; Limberg, Christian; Reier, Tobias ChemCatChem, Vol. 2, Issue 7 https://doi.org/10.1002/cctc.201000126	journal	June 2010
Water Oxidation at Electrodes Modified with Earth-Abundant Transition-Metal Catalysts Galán-Mascarós, José Ramón ChemElectroChem, Vol. 2, Issue 1 https://doi.org/10.1002/celc.201402268	journal	October 2014
Efficient Water Splitting Catalyzed by Cobalt Phosphide-Based Nanoneedle Arrays Supported on Carbon Cloth Wang, Peng; Song, Fang; Amal, Rose ChemSusChem, Vol. 9, Issue 5 https://doi.org/10.1002/cssc.201501599	journal	January 2016
The mechanism of oxidation of copper in alkaline solutions De Chialvo, M. R. Gennero; Marchiano, S. L.; Arvía, A. J. Journal of Applied Electrochemistry, Vol. 14, Issue 2 https://doi.org/10.1007/BF00618735	journal	March 1984
A mini review of NiFe-based materials as highly active oxygen evolution reaction electrocatalysts Gong, Ming; Dai, Hongjie Nano Research, Vol. 8, Issue 1 https://doi.org/10.1007/s12274-014-0591-z	journal	November 2014
Ligand hole induced symmetry mixing of d8 states in LixNi1−xO, as observed in Ni 2p x-ray absorption spectroscopy van Elp, J.; Searle, B. G.; Sawatzky, G. A. Solid State Communications, Vol. 80, Issue 1 https://doi.org/10.1016/0038-1098(91)90600-Z	journal	October 1991
Structural comparison of nickel electrodes and precursor phases Cornilsen, Bahne C.; Shan, Xiaoyin; Loyselle, Patricia L. Journal of Power Sources, Vol. 29, Issue 3-4 https://doi.org/10.1016/0378-7753(90)85018-8	journal	February 1990
Electrochemical corrosion of unalloyed copper in chloride media––a critical review Kear, G.; Barker, B. D.; Walsh, F. C. Corrosion Science, Vol. 46, Issue 1 https://doi.org/10.1016/S0010-938X(02)00257-3	journal	January 2004
A NEXAFS investigation of the formation and decomposition of CuO and Cu2O thin films on Cu(100) Gurevich, Alejandra B.; Bent, Brian E.; Teplyakov, Andrew V. Surface Science, Vol. 442, Issue 1 https://doi.org/10.1016/S0039-6028(99)00913-9	journal	November 1999
pH dependence of OER activity of oxides: Current and future perspectives Giordano, Livia; Han, Binghong; Risch, Marcel Catalysis Today, Vol. 262 https://doi.org/10.1016/j.cattod.2015.10.006	journal	March 2016
Water oxidation catalysts based on abundant 1st row transition metals Singh, Archana; Spiccia, Leone Coordination Chemistry Reviews, Vol. 257, Issue 17-18 https://doi.org/10.1016/j.ccr.2013.02.027	journal	September 2013
Copper oxidation state in chalcopyrite: Mixed Cu d9 and d10 characteristics Pearce, C. I.; Pattrick, R. A. D.; Vaughan, D. J. Geochimica et Cosmochimica Acta, Vol. 70, Issue 18 https://doi.org/10.1016/j.gca.2006.05.017	journal	September 2006
Comparison of Ni–Cu alloy films electrodeposited at low and high pH levels Alper, Mürsel; Kockar, Hakan; Safak, Mürside Journal of Alloys and Compounds, Vol. 453, Issue 1-2 https://doi.org/10.1016/j.jallcom.2006.11.066	journal	April 2008
On tuning the morphology of nanoporous gold Detsi, E.; van de Schootbrugge, M.; Punzhin, S. Scripta Materialia, Vol. 64, Issue 4 https://doi.org/10.1016/j.scriptamat.2010.10.023	journal	February 2011
Electrodeposition and characterization of Ni–Cu alloys Goranova, Desislava; Avdeev, Georgi; Rashkov, Rashko Surface and Coatings Technology, Vol. 240 https://doi.org/10.1016/j.surfcoat.2013.12.014	journal	February 2014
Self-Supported Copper Oxide Electrocatalyst for Water Oxidation at Low Overpotential and Confirmation of Its Robustness by Cu K-Edge X-ray Absorption Spectroscopy Liu, Xiang; Cui, Shengsheng; Sun, Zijun The Journal of Physical Chemistry C, Vol. 120, Issue 2 https://doi.org/10.1021/acs.jpcc.5b09818	journal	January 2016
In Situ Transformation of Hydrogen-Evolving CoP Nanoparticles: Toward Efficient Oxygen Evolution Catalysts Bearing Dispersed Morphologies with Co-oxo/hydroxo Molecular Units Ryu, Jaeyune; Jung, Namgee; Jang, Jong Hyun ACS Catalysis, Vol. 5, Issue 7 https://doi.org/10.1021/acscatal.5b00349	journal	June 2015
In Situ Electrochemical Oxidation Tuning of Transition Metal Disulfides to Oxides for Enhanced Water Oxidation Chen, Wei; Wang, Haotian; Li, Yuzhang ACS Central Science, Vol. 1, Issue 5 https://doi.org/10.1021/acscentsci.5b00227	journal	July 2015
Fabrication of Nanoporous Nickel by Electrochemical Dealloying Sun, Li; Chien, Chia-Ling; Searson, Peter C. Chemistry of Materials, Vol. 16, Issue 16 https://doi.org/10.1021/cm0497881	journal	August 2004
An Advanced Ni–Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation Gong, Ming; Li, Yanguang; Wang, Hailiang Journal of the American Chemical Society, Vol. 135, Issue 23 https://doi.org/10.1021/ja4027715	journal	May 2013
An Investigation of Thin-Film Ni–Fe Oxide Catalysts for the Electrochemical Evolution of Oxygen Louie, Mary W.; Bell, Alexis T. Journal of the American Chemical Society, Vol. 135, Issue 33 https://doi.org/10.1021/ja405351s	journal	August 2013
Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation Trotochaud, Lena; Young, Samantha L.; Ranney, James K. Journal of the American Chemical Society, Vol. 136, Issue 18 https://doi.org/10.1021/ja502379c	journal	April 2014
Highly Active Mixed-Metal Nanosheet Water Oxidation Catalysts Made by Pulsed-Laser Ablation in Liquids Hunter, Bryan M.; Blakemore, James D.; Deimund, Mark Journal of the American Chemical Society, Vol. 136, Issue 38 https://doi.org/10.1021/ja506087h	journal	September 2014
In Situ Raman Study of Nickel Oxide and Gold-Supported Nickel Oxide Catalysts for the Electrochemical Evolution of Oxygen Yeo, Boon Siang; Bell, Alexis T. The Journal of Physical Chemistry C, Vol. 116, Issue 15 https://doi.org/10.1021/jp3007415	journal	April 2012
Enhanced Strain in Functional Nanoporous Gold with a Dual Microscopic Length Scale Structure Detsi, Eric; Punzhin, Sergey; Rao, Jiancun ACS Nano, Vol. 6, Issue 5 https://doi.org/10.1021/nn300179n	journal	April 2012
A Superlattice of Alternately Stacked Ni–Fe Hydroxide Nanosheets and Graphene for Efficient Splitting of Water Ma, Wei; Ma, Renzhi; Wang, Chengxiang ACS Nano, Vol. 9, Issue 2 https://doi.org/10.1021/nn5069836	journal	January 2015
Evolution of nanoporosity in dealloying Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain Nature, Vol. 410, Issue 6827, p. 450-453 https://doi.org/10.1038/35068529	journal	March 2001
Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution Grimaud, Alexis; Diaz-Morales, Oscar; Han, Binghong Nature Chemistry, Vol. 9, Issue 5 https://doi.org/10.1038/nchem.2695	journal	January 2017
Nickel–vanadium monolayer double hydroxide for efficient electrochemical water oxidation Fan, Ke; Chen, Hong; Ji, Yongfei Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11981	journal	June 2016
A nickel iron diselenide-derived efficient oxygen-evolution catalyst Xu, Xiang; Song, Fang; Hu, Xile Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12324	journal	August 2016
Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities Lu, Xunyu; Zhao, Chuan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7616	journal	March 2015
Three-dimensional NiFe layered double hydroxide film for high-efficiency oxygen evolution reaction Lu, Zhiyi; Xu, Wenwen; Zhu, Wei Chem. Commun., Vol. 50, Issue 49 https://doi.org/10.1039/C4CC01625D	journal	January 2014
A survey of diverse earth abundant oxygen evolution electrocatalysts showing enhanced activity from Ni–Fe oxides containing a third metal Gerken, James B.; Shaner, Sarah E.; Massé, Robert C. Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00436A	journal	January 2014
Ni ₂ P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni ₂ P nanoparticles Stern, Lucas-Alexandre; Feng, Ligang; Song, Fang Energy & Environmental Science, Vol. 8, Issue 8 https://doi.org/10.1039/C5EE01155H	journal	January 2015
Mesoporous Ni ₆₀ Fe ₃₀ Mn ₁₀ -alloy based metal/metal oxide composite thick films as highly active and robust oxygen evolution catalysts Detsi, Eric; Cook, John B.; Lesel, Benjamin K. Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE02509E	journal	January 2016
Vertically oriented cobalt selenide/NiFe layered-double-hydroxide nanosheets supported on exfoliated graphene foil: an efficient 3D electrode for overall water splitting Hou, Yang; Lohe, Martin R.; Zhang, Jian Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE03440J	journal	January 2016
Fast electrosynthesis of Fe-containing layered double hydroxide arrays toward highly efficient electrocatalytic oxidation reactions Li, Zhenhua; Shao, Mingfei; An, Hongli Chemical Science, Vol. 6, Issue 11 https://doi.org/10.1039/C5SC02417J	journal	January 2015
In situ generated highly active copper oxide catalysts for the oxygen evolution reaction at low overpotential in alkaline solutions Liu, Xiang; Cui, Shengsheng; Qian, Manman Chemical Communications, Vol. 52, Issue 32 https://doi.org/10.1039/C6CC00526H	journal	January 2016
Preparation of dendritic NiFe films by electrodeposition for oxygen evolution Kim, Kyung Ho; Zheng, Jin You; Shin, Woonsup RSC Advances, Vol. 2, Issue 11 https://doi.org/10.1039/c2ra20241g	journal	January 2012
Theory of multiple proton–electron transfer reactions and its implications for electrocatalysis Koper, Marc T. M. Chemical Science, Vol. 4, Issue 7 https://doi.org/10.1039/c3sc50205h	journal	January 2013
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Oxygen 1 s x-ray-absorption edges of transition-metal oxides de Groot, F. M. F.; Grioni, M.; Fuggle, J. C. Physical Review B, Vol. 40, Issue 8 https://doi.org/10.1103/PhysRevB.40.5715	journal	September 1989
Interface electronic structures of BaTiO 3 @ X nanoparticles ( X = γ -Fe 2 O 3 , Fe 3 O 4 , α -Fe 2 O 3 , and Fe) investigated by XAS and XMCD Kim, D. H.; Lee, H. J.; Kim, G. Physical Review B, Vol. 79, Issue 3 https://doi.org/10.1103/PhysRevB.79.033402	journal	January 2009
Homogeneously dispersed multimetal oxygen-evolving catalysts Zhang, B.; Zheng, X.; Voznyy, O. Science, Vol. 352, Issue 6283 https://doi.org/10.1126/science.aaf1525	journal	March 2016
An Investigation of the Anodic Behavior of Copper and Its Anodically Produced Oxides in Aqueous Solutions of High pH Burke, L. D. Journal of The Electrochemical Society, Vol. 137, Issue 2 https://doi.org/10.1149/1.2086496	journal	January 1990
Oxygen Evolution on La[sub 1−x]Sr[sub x]CoO[sub 3] Electrodes in Alkaline Solutions Matsumoto, Y. Journal of The Electrochemical Society, Vol. 127, Issue 4 https://doi.org/10.1149/1.2129762	journal	January 1980
Evolution of Nanoporosity in Dealloying Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain arXiv https://doi.org/10.48550/arxiv.cond-mat/0103615	text	January 2001

Cited By (50)

Epitaxial Heterogeneous Interfaces on N-NiMoO ₄ /NiS ₂ Nanowires/Nanosheets to Boost Hydrogen and Oxygen Production for Overall Water Splitting An, Li; Feng, Jianrui; Zhang, Yu Advanced Functional Materials, Vol. 29, Issue 1 https://doi.org/10.1002/adfm.201805298	journal	November 2018
Recent Advances in Metallic Glass Nanostructures: Synthesis Strategies and Electrocatalytic Applications Li, Jinyang; Doubek, Gustavo; McMillon-Brown, Lyndsey Advanced Materials, Vol. 31, Issue 7 https://doi.org/10.1002/adma.201802120	journal	December 2018
Identification of Facet‐Governing Reactivity in Hematite for Oxygen Evolution Wu, Hao; Yang, Tong; Du, Yonghua Advanced Materials, Vol. 30, Issue 52 https://doi.org/10.1002/adma.201804341	journal	November 2018
Copper–Nickel Nitride Nanosheets as Efficient Bifunctional Catalysts for Hydrazine‐Assisted Electrolytic Hydrogen Production Wang, Zhaoyang; Xu, Lin; Huang, Fuzhi Advanced Energy Materials, Vol. 9, Issue 21 https://doi.org/10.1002/aenm.201900390	journal	April 2019
Single Atoms and Clusters Based Nanomaterials for Hydrogen Evolution, Oxygen Evolution Reactions, and Full Water Splitting Sultan, Siraj; Tiwari, Jitendra N.; Singh, Aditya Narayan Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900624	journal	May 2019
Amorphous Nanocages of Cu‐Ni‐Fe Hydr(oxy)oxide Prepared by Photocorrosion For Highly Efficient Oxygen Evolution Cai, Zhi; Li, Lidong; Zhang, Youwei Angewandte Chemie, Vol. 131, Issue 13 https://doi.org/10.1002/ange.201812601	journal	February 2019
Amorphous Nanocages of Cu‐Ni‐Fe Hydr(oxy)oxide Prepared by Photocorrosion For Highly Efficient Oxygen Evolution Cai, Zhi; Li, Lidong; Zhang, Youwei Angewandte Chemie International Edition, Vol. 58, Issue 13 https://doi.org/10.1002/anie.201812601	journal	March 2019
Two novel Co (II)‐coordination polymers as bifunctional materials for efficient photocatalytic degradation of dyes and electrocatalytic water oxidation Wang, Lulu; Wang, Jinmiao; Fan, Chuanbin Applied Organometallic Chemistry https://doi.org/10.1002/aoc.5767	journal	June 2020
Current Status of Self‐Supported Catalysts for Robust and Efficient Water Splitting for Commercial Electrolyzer Kwon, Jiseok; Han, HyukSu; Choi, Seungun ChemCatChem, Vol. 11, Issue 24 https://doi.org/10.1002/cctc.201901638	journal	October 2019
Improved Electrocatalytic Performance in Overall Water Splitting with Rational Design of Hierarchical Co ₃ O ₄ @NiFe Layered Double Hydroxide Core-Shell Nanostructure Wang, Shanpeng; Wu, Jian; Yin, Junwen ChemElectroChem, Vol. 5, Issue 10 https://doi.org/10.1002/celc.201800194	journal	March 2018
Improved Electrocatalytic Performance in Overall Water Splitting with Rational Design of Hierarchical Co ₃ O ₄ @NiFe Layered Double Hydroxide Core-Shell Nanostructure Wang, Shanpeng; Wu, Jian; Yin, Junwen ChemElectroChem, Vol. 5, Issue 10 https://doi.org/10.1002/celc.201800392	journal	April 2018
Enhanced Water Oxidation Activity by Introducing Gallium into Cobalt‐Iron Oxide System Zhang, Qiaoqiao; Fan, Yong; Wang, Wei ChemElectroChem, Vol. 7, Issue 1 https://doi.org/10.1002/celc.201901598	journal	November 2019
Nickel Foam‐Supported Amorphous FeCo(Mn)−O Nanoclusters with Abundant Oxygen Vacancies through Selective Dealloying for Efficient Electrocatalytic Oxygen Evolution Wu, Shuai‐Na; Qi, Yu‐Feng; Wang, Qian ChemElectroChem, Vol. 7, Issue 3 https://doi.org/10.1002/celc.201902070	journal	February 2020
Two-Step Synthesis of Cobalt Iron Alloy Nanoparticles Embedded in Nitrogen-Doped Carbon Nanosheets/Carbon Nanotubes for the Oxygen Evolution Reaction Liu, Yang; Li, Feng; Yang, Haidong ChemSusChem, Vol. 11, Issue 14 https://doi.org/10.1002/cssc.201800961	journal	June 2018
Recent Advances in the Development of Molecular Catalyst‐Based Anodes for Water Oxidation toward Artificial Photosynthesis Zahran, Zaki N.; Tsubonouchi, Yuta; Mohamed, Eman A. ChemSusChem, Vol. 12, Issue 9 https://doi.org/10.1002/cssc.201802795	journal	November 2018
Smart Control of Composition for Double Perovskite Electrocatalysts toward Enhanced Oxygen Evolution Reaction Sun, Hainan; Xu, Xiaomin; Chen, Gao ChemSusChem, Vol. 12, Issue 23 https://doi.org/10.1002/cssc.201902138	journal	October 2019
Reversible ternary nickel‐cobalt‐iron catalysts for intermittent water electrolysis Lu, Xunyu; Zhang, Qingran; Ng, Yun Hau EcoMat, Vol. 2, Issue 1 https://doi.org/10.1002/eom2.12012	journal	January 2020
One‐dimensional and two‐dimensional synergized nanostructures for high‐performing energy storage and conversion Li, Xin; Wang, John InfoMat, Vol. 2, Issue 1 https://doi.org/10.1002/inf2.12040	journal	November 2019
Noble-Metal-Free Electrocatalysts for Oxygen Evolution Lyu, Fenglei; Wang, Qingfa; Choi, Sung Mook Small, Vol. 15, Issue 1 https://doi.org/10.1002/smll.201804201	journal	November 2018
Ultrafine Metallic Nickel Domains and Reduced Molybdenum States Improve Oxygen Evolution Reaction of NiFeMo Electrocatalysts Moon, Byeong Cheul; Choi, Won Ho; Kim, Keon‐Han Small, Vol. 15, Issue 19 https://doi.org/10.1002/smll.201804764	journal	March 2019
A Robust Nonprecious CuFe Composite as a Highly Efficient Bifunctional Catalyst for Overall Electrochemical Water Splitting Inamdar, Akbar I.; Chavan, Harish S.; Hou, Bo Small, Vol. 16, Issue 2 https://doi.org/10.1002/smll.201905884	journal	November 2019
Evaluation of Antimicrobial and Antidiabetic Activities of Ag@SiO2 Core–Shell Nanoparticles Synthesized with Diverse Shell Thicknesses Selvan, Dominic Savio Arumai; Shobana, Sugumar; Thiruvasagam, Ponnusamy Journal of Cluster Science, Vol. 31, Issue 4 https://doi.org/10.1007/s10876-019-01682-w	journal	September 2019
Nitrogen-Doped Sponge Ni Fibers as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction Zhang, Kaili; Xia, Xinhui; Deng, Shengjue Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0253-5	journal	March 2019
Three dimensional carbon substrate materials for electrolysis of water Zhang, Xinglin; Shao, Jinjun; Huang, Wei Science China Materials, Vol. 61, Issue 9 https://doi.org/10.1007/s40843-018-9295-8	journal	June 2018
A surface-modified antiperovskite as an electrocatalyst for water oxidation Zhu, Yanping; Chen, Gao; Zhong, Yijun Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04682-y	journal	June 2018
Single atom tungsten doped ultrathin α-Ni(OH)2 for enhanced electrocatalytic water oxidation Yan, Junqing; Kong, Lingqiao; Ji, Yujin Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09845-z	journal	May 2019
Superb water splitting activity of the electrocatalyst Fe3Co(PO4)4 designed with computation aid Sultan, Siraj; Ha, Miran; Kim, Dong Yeon Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13050-3	journal	November 2019
Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts Huang, Zhen-Feng; Song, Jiajia; Du, Yonghua Nature Energy, Vol. 4, Issue 4 https://doi.org/10.1038/s41560-019-0355-9	journal	March 2019
Concentrated-acid triggered superfast generation of porous amorphous cobalt oxide toward efficient water oxidation catalysis in alkaline solution Ji, Xuqiang; He, Yujia; Liu, Jingquan Chemical Communications, Vol. 55, Issue 12 https://doi.org/10.1039/c8cc10229e	journal	January 2019
Artificial photosynthesis: opportunities and challenges of molecular catalysts Zhang, Biaobiao; Sun, Licheng Chemical Society Reviews, Vol. 48, Issue 7 https://doi.org/10.1039/c8cs00897c	journal	January 2019
Ni-Doped CuS as an efficient electrocatalyst for the oxygen evolution reaction Kundu, Joyjit; Khilari, Santimoy; Bhunia, Kousik Catalysis Science & Technology, Vol. 9, Issue 2 https://doi.org/10.1039/c8cy02181c	journal	January 2019
Flexible vanadium-doped Ni ₂ P nanosheet arrays grown on carbon cloth for an efficient hydrogen evolution reaction Wen, Lulu; Yu, Jie; Xing, Changchang Nanoscale, Vol. 11, Issue 10 https://doi.org/10.1039/c8nr10167a	journal	January 2019
Hierarchically structured CoN/Cu ₃ N nanotube array supported on copper foam as an efficient bifunctional electrocatalyst for overall water splitting Li, Jiali; Kong, Xianggui; Jiang, Meihong Inorganic Chemistry Frontiers, Vol. 5, Issue 11 https://doi.org/10.1039/c8qi00860d	journal	January 2018
Binary Ni ₂ FeO _x anchored on modified graphite for efficient and durable oxygen evolution electrocatalysis Bai, Lu; Guan, Jingqi Sustainable Energy & Fuels, Vol. 2, Issue 10 https://doi.org/10.1039/c8se00307f	journal	January 2018
NiS ₂ nanodotted carnation-like CoS ₂ for enhanced electrocatalytic water splitting Xin, Weili; Jiang, Wen-Jie; Lian, Yajuan Chemical Communications, Vol. 55, Issue 26 https://doi.org/10.1039/c9cc01235d	journal	January 2019
Controllable electrodeposition of binary metal films from deep eutectic solvent as an efficient and durable catalyst for the oxygen evolution reaction Vo, Truong-Giang; Hidalgo, Sebastian Dario Suarez; Chiang, Chia-Ying Dalton Transactions, Vol. 48, Issue 39 https://doi.org/10.1039/c9dt03028j	journal	January 2019
Optimization of gold–palladium core–shell nanowires towards H ₂ O ₂ reduction by adjusting shell thickness Dong, Yongdi; Chen, Qiaoli; Cheng, Xiqing Nanoscale Advances, Vol. 2, Issue 2 https://doi.org/10.1039/c9na00726a	journal	January 2020
Self-supported Co-doped FeNi carbonate hydroxide nanosheet array as a highly efficient electrocatalyst towards the oxygen evolution reaction in an alkaline solution Qi, Yu-Feng; Wang, Qian; Wang, Xiu-Guang Nanoscale, Vol. 11, Issue 22 https://doi.org/10.1039/c9nr01735f	journal	January 2019
A facile sequential ion exchange strategy to synthesize CoSe ₂ /FeSe ₂ double-shelled hollow nanocuboids for the highly active and stable oxygen evolution reaction Xu, Chunyang; Li, Qinghao; Shen, Junling Nanoscale, Vol. 11, Issue 22 https://doi.org/10.1039/c9nr02599e	journal	January 2019
Inception of molybdate as a “pore forming additive” to enhance the bifunctional electrocatalytic activity of nickel and cobalt based mixed hydroxides for overall water splitting Ganguli, Sagar; Ghosh, Sourav; Das, Soumik Nanoscale, Vol. 11, Issue 36 https://doi.org/10.1039/c9nr05142b	journal	January 2019
Dispersing transition metal vacancies in layered double hydroxides by ionic reductive complexation extraction for efficient water oxidation Xie, Yang-Shan; Wang, Zheng; Ju, Min Chemical Science, Vol. 10, Issue 36 https://doi.org/10.1039/c9sc02723h	journal	January 2019
Pulsed laser rusted stainless steel: a robust electrode material applied for energy storage and generation applications Karthik, Namachivayam; Tian, Tian; Edison, Thomas Nesakumar Jebakumar Immanuel Sustainable Energy & Fuels, Vol. 4, Issue 3 https://doi.org/10.1039/c9se00676a	journal	January 2020
Accelerative oxygen evolution by Cu-doping into Fe-Co oxides Zhang, Qiaoqiao; Liu, Ning; Guan, Jingqi Sustainable Energy & Fuels, Vol. 4, Issue 1 https://doi.org/10.1039/c9se00928k	journal	January 2020
Temperature and doping-tuned coordination environments around electroactive centers in Fe-doped α(β)-Ni(OH) ₂ for excellent water splitting Cao, Qinghe; Luo, Mi; Huang, Yutian Sustainable Energy & Fuels, Vol. 4, Issue 3 https://doi.org/10.1039/c9se01172b	journal	January 2020
Identifying high-efficiency oxygen evolution electrocatalysts from Co–Ni–Cu based selenides through combinatorial electrodeposition Cao, Xi; Johnson, Emily; Nath, Manashi Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta00863b	journal	January 2019
Surface dual-oxidation induced metallic copper doping into NiFe electrodes for electrocatalytic water oxidation Ma, Yaming; Wang, Ke; Liu, Dongyu Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/c9ta08797d	journal	January 2019
A Setaria-inflorescence-structured catalyst based on nickel–cobalt wrapped silver nanowire conductive networks for highly efficient hydrogen evolution Zhou, Kailing; Zhang, Qianqian; Wang, Zelin Journal of Materials Chemistry A, Vol. 7, Issue 46 https://doi.org/10.1039/c9ta10413e	journal	January 2019
Pressure-promoted irregular CoMoP ₂ nanoparticles activated by surface reconstruction for oxygen evolution reaction electrocatalysts Xu, Shishuai; Gao, Xiang; Deshmukh, Amol Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta11775j	journal	January 2020
Amorphous FeO _x ( x = 1, 1.5) coated Cu ₃ P nanosheets with bamboo leaves-like morphology induced by solvent molecule adsorption for highly active HER catalysts Tong, Cheng; Xiang, Rui; Peng, Lishan Journal of Materials Chemistry A, Vol. 8, Issue 6 https://doi.org/10.1039/c9ta11779b	journal	January 2020
Modern developments in electrodes for electrochemical technology and the role of surface finishing Walsh, F. C. Transactions of the IMF, Vol. 97, Issue 1 https://doi.org/10.1080/00202967.2019.1551277	journal	December 2018

Similar Records

Benchmarking nanoparticulate metal oxide electrocatalysts for the alkaline water oxidation reaction

Journal Article · Sat Nov 26 23:00:00 EST 2016 · Journal of Materials Chemistry. A · OSTI ID:1436119

Jung, Suho; McCrory, Charles C. L.; Ferrer, Ivonne M.; +2 more

Universal Surface Engineering of Transition Metals for Superior Electrocatalytic Hydrogen Evolution in Neutral Water

Journal Article · Tue Aug 22 00:00:00 EDT 2017 · Journal of the American Chemical Society · OSTI ID:1465415

You, Bo; Liu, Xuan; Hu, Guoxiang; +4 more

The catalysis of the oxygen evolution reaction by iron impurities in thin film nickel oxide electrodes

Journal Article · Sat Jan 31 23:00:00 EST 1987 · J. Electrochem. Soc.; (United States) · OSTI ID:6610493

Corrigan, D A

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Electrocatalysis
Electronic devices
Energy
Heterogeneous catalysis

Title: Dendritic core-shell nickel-iron-copper metal/metal oxide electrode for efficient electrocatalytic water oxidation

Citation Formats

References (50)

Cited By (50)

Similar Records

Related Subjects