Highly porous CO2 hydrate generation aided by silica nanoparticles for potential secure storage of CO2 and desalination

Kim, Ijung; Nole, Michael; Jang, Sunghyun; Ko, Saebom; Daigle, Hugh; Pope, Gary A.; Huh, Chun

doi:10.1039/c6ra26366f

Title: Highly porous CO₂ hydrate generation aided by silica nanoparticles for potential secure storage of CO₂ and desalination

Abstract

Here in this paper, we report a new way of storing CO₂ in a highly porous hydrate structure, stabilized by silica nanoparticles (NPs). Such a porous CO₂ hydrate structure was generated either by cooling down NP-stabilized CO₂-in-seawater foams, or by gently mixing CO₂ and seawater that contains silica NPs under CO₂ hydrate-generating conditions. With the highly porous structure, enhanced desalination was also achievable when the partial meltdown of CO₂ hydrate was allowed.

Authors:

^[1]; Nole, Michael ^[2]; Jang, Sunghyun ^[2]; Ko, Saebom ^[2]; Daigle, Hugh ^[2]; Pope, Gary A. ^[2]; Huh, Chun ^[2]

Western New England Univ., Springfield, MA (United States). Dept. of Civil and Environmental Engineering
Univ. of Texas, Austin, TX (United States). Dept. of Petroleum and Geosystems Engineering

Publication Date:: Tue Jan 31 00:00:00 EST 2017

Research Org.:: Univ. of Texas, Austin, TX (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1426174

Grant/Contract Number:: SC0001114

Resource Type:: Accepted Manuscript

Journal Name:: RSC Advances

Additional Journal Information:: Journal Volume: 7; Journal Issue: 16; Journal ID: ISSN 2046-2069

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats


                    Kim, Ijung, Nole, Michael, Jang, Sunghyun, Ko, Saebom, Daigle, Hugh, Pope, Gary A., and Huh, Chun. Highly porous CO2 hydrate generation aided by silica nanoparticles for potential secure storage of CO2 and desalination.  United States: N. p., 2017. 
Web.  doi:10.1039/c6ra26366f.

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                    Kim, Ijung, Nole, Michael, Jang, Sunghyun, Ko, Saebom, Daigle, Hugh, Pope, Gary A., & Huh, Chun. Highly porous CO2 hydrate generation aided by silica nanoparticles for potential secure storage of CO2 and desalination.  United States.  https://doi.org/10.1039/c6ra26366f

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                    Kim, Ijung, Nole, Michael, Jang, Sunghyun, Ko, Saebom, Daigle, Hugh, Pope, Gary A., and Huh, Chun. Tue .  
"Highly porous CO2 hydrate generation aided by silica nanoparticles for potential secure storage of CO2 and desalination".  United States.  https://doi.org/10.1039/c6ra26366f.  https://www.osti.gov/servlets/purl/1426174.

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@article{osti_1426174,

  title        = {Highly porous CO2 hydrate generation aided by silica nanoparticles for potential secure storage of CO2 and desalination},

  author       = {Kim, Ijung and Nole, Michael and Jang, Sunghyun and Ko, Saebom and Daigle, Hugh and Pope, Gary A. and Huh, Chun},

  abstractNote = {Here in this paper, we report a new way of storing CO2 in a highly porous hydrate structure, stabilized by silica nanoparticles (NPs). Such a porous CO2 hydrate structure was generated either by cooling down NP-stabilized CO2-in-seawater foams, or by gently mixing CO2 and seawater that contains silica NPs under CO2 hydrate-generating conditions. With the highly porous structure, enhanced desalination was also achievable when the partial meltdown of CO2 hydrate was allowed.},

  doi          = {10.1039/c6ra26366f},

  journal      = {RSC Advances},

  number       = 16,

  volume       = 7,

  place        = {United States},

  year         = {Tue Jan 31 00:00:00 EST 2017},

  month        = {Tue Jan 31 00:00:00 EST 2017}

}

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https://doi.org/10.1039/c6ra26366f

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Title: Highly porous CO2 hydrate generation aided by silica nanoparticles for potential secure storage of CO2 and desalination

Abstract

Citation Formats

The Carbon Dioxide−Water Interface at Conditions of Gas Hydrate Formation journal, January 2009

Experimental study and thermodynamic modeling of CO 2 gas hydrate formation in presence of zinc oxide nanoparticles journal, May 2016

Phase inversion of particle-stabilized materials from foams to dry water journal, October 2006

Scaled-Up Ocean Injection of CO 2 –Hydrate Composite Particles † journal, November 2007

Improved Oil Recovery by Low-Salinity Waterflooding journal, May 2011

The drainage of a foam lamella journal, May 2002

CO 2 Hydrates Could Provide Secondary Safety Factor in Subsurface Sequestration of CO 2 journal, February 2010

Fundamental Investigation of the Effects of Hydrophobic Fumed Silica on the Formation of Carbon Dioxide Gas Hydrates journal, October 2014

CO 2 Hydrate Composite for Ocean Carbon Sequestration journal, August 2003

Size-dependent properties of silica nanoparticles for Pickering stabilization of emulsions and foams journal, March 2016

Nucleation of the CO 2 Hydrate from Three-Phase Contact Lines journal, May 2012

Permanent carbon dioxide storage in deep-sea sediments journal, August 2006

Nanoparticle-stabilized carbon dioxide-in-water foams with fine texture journal, February 2013

The clathrate hydrate process for post and pre-combustion capture of carbon dioxide journal, November 2007

Investigation of Nanoparticle Adsorption During Transport in Porous Media journal, August 2015

Influence of Sodium Halides on the Kinetics of CO 2 Hydrate Formation journal, January 2014

Effect of Graphite Nanoparticles on Promoting CO 2 Hydrate Formation journal, May 2014

Ultradry Carbon Dioxide-in-Water Foams with Viscoelastic Aqueous Phases journal, December 2015

Atrazine removal by covalent bonding to piperazine functionalized PolyHIPEs journal, November 2007

New method for ocean disposal of CO2 by a submerged kenics-type static mixer journal, January 2004

Emulsion-templated porous materials (PolyHIPEs) for selective ion and molecular recognition and transport: applications in electrochemical sensing journal, January 2007

CO 2 Hydrate Nucleation Kinetics Enhanced by an Organo-Mineral Complex Formed at the Montmorillonite–Water Interface journal, January 2015

A new apparatus for seawater desalination by gas hydrate process and removal characteristics of dissolved minerals (Na+, Mg2+, Ca2+, K+, B3+) journal, July 2011

Colloidal Particles at Liquid Interfaces book, August 2006

Formation of CO2 Hydrate in Pure and Sea Waters. journal, January 1993

Field Studies on the Formation of Sinking CO2 Particles for Ocean Carbon Sequestration: Effects of Injector Geometry on Particle Density and Dissolution Rate and Model Simulation of Plume Behavior journal, August 2005

Gas Storage in “Dry Water” and “Dry Gel” Clathrates journal, March 2010

Gravity-induced sea ice desalination under low temperature journal, February 2013

Controlled Foaming of Polymer Films through Restricted Surface Diffusion and the Addition of Nanosilica Particles or CO 2 -philic Surfactants journal, March 2005

Title: Highly porous CO₂ hydrate generation aided by silica nanoparticles for potential secure storage of CO₂ and desalination

The Carbon Dioxide−Water Interface at Conditions of Gas Hydrate Formation
journal, January 2009

Experimental study and thermodynamic modeling of CO 2 gas hydrate formation in presence of zinc oxide nanoparticles
journal, May 2016

Phase inversion of particle-stabilized materials from foams to dry water
journal, October 2006

Scaled-Up Ocean Injection of CO ₂ –Hydrate Composite Particles ^†
journal, November 2007

Improved Oil Recovery by Low-Salinity Waterflooding
journal, May 2011

The drainage of a foam lamella
journal, May 2002

CO ₂ Hydrates Could Provide Secondary Safety Factor in Subsurface Sequestration of CO ₂
journal, February 2010

Fundamental Investigation of the Effects of Hydrophobic Fumed Silica on the Formation of Carbon Dioxide Gas Hydrates
journal, October 2014

CO ₂ Hydrate Composite for Ocean Carbon Sequestration
journal, August 2003

Size-dependent properties of silica nanoparticles for Pickering stabilization of emulsions and foams
journal, March 2016

Nucleation of the CO ₂ Hydrate from Three-Phase Contact Lines
journal, May 2012

Permanent carbon dioxide storage in deep-sea sediments
journal, August 2006

Nanoparticle-stabilized carbon dioxide-in-water foams with fine texture
journal, February 2013

The clathrate hydrate process for post and pre-combustion capture of carbon dioxide
journal, November 2007

Investigation of Nanoparticle Adsorption During Transport in Porous Media
journal, August 2015

Influence of Sodium Halides on the Kinetics of CO ₂ Hydrate Formation
journal, January 2014

Effect of Graphite Nanoparticles on Promoting CO ₂ Hydrate Formation
journal, May 2014

Ultradry Carbon Dioxide-in-Water Foams with Viscoelastic Aqueous Phases
journal, December 2015

Atrazine removal by covalent bonding to piperazine functionalized PolyHIPEs
journal, November 2007

New method for ocean disposal of CO2 by a submerged kenics-type static mixer
journal, January 2004

Emulsion-templated porous materials (PolyHIPEs) for selective ion and molecular recognition and transport: applications in electrochemical sensing
journal, January 2007

CO ₂ Hydrate Nucleation Kinetics Enhanced by an Organo-Mineral Complex Formed at the Montmorillonite–Water Interface
journal, January 2015

A new apparatus for seawater desalination by gas hydrate process and removal characteristics of dissolved minerals (Na+, Mg2+, Ca2+, K+, B3+)
journal, July 2011

Colloidal Particles at Liquid Interfaces
book, August 2006

Formation of CO2 Hydrate in Pure and Sea Waters.
journal, January 1993

Field Studies on the Formation of Sinking CO₂ Particles for Ocean Carbon Sequestration: Effects of Injector Geometry on Particle Density and Dissolution Rate and Model Simulation of Plume Behavior
journal, August 2005

Gas Storage in “Dry Water” and “Dry Gel” Clathrates
journal, March 2010

Gravity-induced sea ice desalination under low temperature
journal, February 2013

Controlled Foaming of Polymer Films through Restricted Surface Diffusion and the Addition of Nanosilica Particles or CO ₂ -philic Surfactants
journal, March 2005