Monoclinic 122-Type BaIr2Ge2 with a Channel Framework: A Structural Connection between Clathrate and Layered Compounds

Gui, Xin; Chang, Tay-Rong; Kong, Tai; Pan, Max T.; Cava, Robert J.; Xie, Weiwei

doi:10.3390/ma10070818

Title: Monoclinic 122-Type BaIr2Ge2 with a Channel Framework: A Structural Connection between Clathrate and Layered Compounds

Journal Article · Tue Jul 18 00:00:00 EDT 2017 · Materials

DOI: https://doi.org/10.3390/ma10070818 · OSTI ID:1425741

^[1]; Chang, Tay-Rong ^[2]; Kong, Tai ^[3]; Pan, Max T. ^[4]; Cava, Robert J. ^[3]; Xie, Weiwei ^[4]

Louisiana State Univ., Baton Rouge, LA (United States). Dept. of Chemistry; Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803
National Cheng Kung Univ., Tainan City (Taiwan). Dept. of Physics
Princeton Univ., NJ (United States). Dept. of Chemistry
Louisiana State Univ., Baton Rouge, LA (United States). Dept. of Chemistry

A new 122-type phase, monoclinic BaIr2Ge2 is successfully synthesized by arc melting; X-ray diffraction and scanning electron microscopy are used to purify the phase and determine its crystal structure. BaIr2Ge2 adopts a clathrate-like channel framework structure of the monoclinic BaRh2Si2-type, with space group P21/c. Structural comparisons of clathrate, ThCr2Si2, CaBe2Ge2, and BaRh2Si2 structure types indicate that BaIr2Ge2 can be considered as an intermediate between clathrate and layered compounds. Magnetic measurements show it to be diamagnetic and non-superconducting down to 1.8 K. Different from many layered or clathrate compounds, monoclinic BaIr2Ge2 displays a metallic resistivity. Electronic structure calculations performed for BaIr2Ge2 support its observed structural stability and physical properties.

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Research Organization:: Princeton Univ., NJ (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Louisiana State Univ., Baton Rouge, LA (United States); Ministry of Science and Technology (MOST) (Taiwan); National Cheng Kung Univ., Tainan City (Taiwan)

Grant/Contract Number:: FG02-98ER45706

OSTI ID:: 1425741

Journal Information:: Materials, Journal Name: Materials Journal Issue: 7 Vol. 10; ISSN 1996-1944; ISSN MATEG9

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

36 MATERIALS SCIENCE
BaIr2Ge2
metal-insulator transition (MIT)
new 122-phase

Title: Monoclinic 122-Type BaIr2Ge2 with a Channel Framework: A Structural Connection between Clathrate and Layered Compounds

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