Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry
Abstract
In this paper we provide a summary of the recent development of ambient pressure X-ray photoelectron spectroscopy (AP-XPS) and its application to catalytic surface chemistry. The methodology as well as significant advantages and challenges associated with this novel technique are described. Details about specific examples of using AP-XPS to probe surface chemistry under working reaction conditions for a number of reactions are explained: CO oxidation, water-gas shift (WGS), CO2 hydrogenation, dry reforming of methane (DRM) and ethanol steam reforming (ESR). In conclusion, we discuss insights into the future development of the AP-XPS technique and its applications.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
- Stony Brook Univ., NY (United States). Dept. of Chemistry
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Stony Brook Univ., NY (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1425096
- Alternate Identifier(s):
- OSTI ID: 1495732
- Report Number(s):
- BNL-203312-2018-JAAM
Journal ID: ISSN 0368-2048
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Electron Spectroscopy and Related Phenomena
- Additional Journal Information:
- Journal Volume: 221; Journal ID: ISSN 0368-2048
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Palomino, Robert M., Hamlyn, Rebecca, Liu, Zongyuan, Grinter, David C., Waluyo, Iradwikanari, Rodriguez, Jose A., and Senanayake, Sanjaya D. Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry. United States: N. p., 2017.
Web. doi:10.1016/j.elspec.2017.04.006.
Palomino, Robert M., Hamlyn, Rebecca, Liu, Zongyuan, Grinter, David C., Waluyo, Iradwikanari, Rodriguez, Jose A., & Senanayake, Sanjaya D. Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry. United States. https://doi.org/10.1016/j.elspec.2017.04.006
Palomino, Robert M., Hamlyn, Rebecca, Liu, Zongyuan, Grinter, David C., Waluyo, Iradwikanari, Rodriguez, Jose A., and Senanayake, Sanjaya D. Thu .
"Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry". United States. https://doi.org/10.1016/j.elspec.2017.04.006. https://www.osti.gov/servlets/purl/1425096.
@article{osti_1425096,
title = {Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry},
author = {Palomino, Robert M. and Hamlyn, Rebecca and Liu, Zongyuan and Grinter, David C. and Waluyo, Iradwikanari and Rodriguez, Jose A. and Senanayake, Sanjaya D.},
abstractNote = {In this paper we provide a summary of the recent development of ambient pressure X-ray photoelectron spectroscopy (AP-XPS) and its application to catalytic surface chemistry. The methodology as well as significant advantages and challenges associated with this novel technique are described. Details about specific examples of using AP-XPS to probe surface chemistry under working reaction conditions for a number of reactions are explained: CO oxidation, water-gas shift (WGS), CO2 hydrogenation, dry reforming of methane (DRM) and ethanol steam reforming (ESR). In conclusion, we discuss insights into the future development of the AP-XPS technique and its applications.},
doi = {10.1016/j.elspec.2017.04.006},
journal = {Journal of Electron Spectroscopy and Related Phenomena},
number = ,
volume = 221,
place = {United States},
year = {Thu Apr 27 00:00:00 EDT 2017},
month = {Thu Apr 27 00:00:00 EDT 2017}
}
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Works referencing / citing this record:
A mini review of in situ near-ambient pressure XPS studies on non-noble, late transition metal catalysts
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