Direct observation of supramolecular binding of light hydrocarbons in vanadium(iii) and (iv) metal–organic framework materials

Lu, Zhenzhong; Godfrey, Harry G. W.; da Silva, Ivan; Cheng, Yongqiang; Savage, Mathew; Manuel, Pascal; Rudić, Svemir; Ramirez-Cuesta, Anibal J.; Yang, Sihai; Schröder, Martin

doi:10.1039/C8SC00330K

Title: Direct observation of supramolecular binding of light hydrocarbons in vanadium(iii) and (iv) metal–organic framework materials

Abstract

Binding of C₂H₂ in MFM-300(V^III) showing interactions to O–H, carboxylate O-centres and intermolecular packing.

Authors:

Lu, Zhenzhong ^[1];

^[2];

^[3]; Cheng, Yongqiang ^[4];

^[2]; Manuel, Pascal ^[3];

^[3]; Ramirez-Cuesta, Anibal J. ^[4]; Yang, Sihai ^[2];

^[2]

School of Chemistry, University of Manchester, Manchester, UK, Institute of Advanced Materials (IAM)
School of Chemistry, University of Manchester, Manchester, UK
ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, UK
The Chemical and Engineering Materials Division (CEMD), Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, USA

Publication Date:: Mon Jan 01 00:00:00 EST 2018

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

OSTI Identifier:: 1424807

Alternate Identifier(s):: OSTI ID: 1624961; OSTI ID: 1761789

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Published Article

Journal Name:: Chemical Science

Additional Journal Information:: Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 13; Journal ID: ISSN 2041-6520

Publisher:: Royal Society of Chemistry

Country of Publication:: United Kingdom

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry

Citation Formats


                    Lu, Zhenzhong, Godfrey, Harry G. W., da Silva, Ivan, Cheng, Yongqiang, Savage, Mathew, Manuel, Pascal, Rudić, Svemir, Ramirez-Cuesta, Anibal J., Yang, Sihai, and Schröder, Martin. Direct observation of supramolecular binding of light hydrocarbons in vanadium(iii) and (iv) metal–organic framework materials.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C8SC00330K.

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                    Lu, Zhenzhong, Godfrey, Harry G. W., da Silva, Ivan, Cheng, Yongqiang, Savage, Mathew, Manuel, Pascal, Rudić, Svemir, Ramirez-Cuesta, Anibal J., Yang, Sihai, & Schröder, Martin. Direct observation of supramolecular binding of light hydrocarbons in vanadium(iii) and (iv) metal–organic framework materials.  United Kingdom.  https://doi.org/10.1039/C8SC00330K

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                    Lu, Zhenzhong, Godfrey, Harry G. W., da Silva, Ivan, Cheng, Yongqiang, Savage, Mathew, Manuel, Pascal, Rudić, Svemir, Ramirez-Cuesta, Anibal J., Yang, Sihai, and Schröder, Martin. Mon .  
"Direct observation of supramolecular binding of light hydrocarbons in vanadium(iii) and (iv) metal–organic framework materials".  United Kingdom.  https://doi.org/10.1039/C8SC00330K.

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@article{osti_1424807,

  title        = {Direct observation of supramolecular binding of light hydrocarbons in vanadium(iii) and (iv) metal–organic framework materials},

  author       = {Lu, Zhenzhong and Godfrey, Harry G. W. and da Silva, Ivan and Cheng, Yongqiang and Savage, Mathew and Manuel, Pascal and Rudić, Svemir and Ramirez-Cuesta, Anibal J. and Yang, Sihai and Schröder, Martin},

  abstractNote = {Binding of C2H2 in MFM-300(VIII) showing interactions to O–H, carboxylate O-centres and intermolecular packing.},

  doi          = {10.1039/C8SC00330K},

  journal      = {Chemical Science},

  number       = 13,

  volume       = 9,

  place        = {United Kingdom},

  year         = {Mon Jan 01 00:00:00 EST 2018},

  month        = {Mon Jan 01 00:00:00 EST 2018}

}

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Title: Direct observation of supramolecular binding of light hydrocarbons in vanadium(iii) and (iv) metal–organic framework materials

Abstract

Citation Formats

Pore Space Partition in Metal–Organic Frameworks journal, January 2017

Potential of microporous metal–organic frameworks for separation of hydrocarbon mixtures journal, January 2016

Highly controlled acetylene accommodation in a metal–organic microporous material journal, July 2005

Introduction to Metal–Organic Frameworks journal, September 2011

Exceptionally High Acetylene Uptake in a Microporous Metal−Organic Framework with Open Metal Sites journal, September 2009

A robust doubly interpenetrated metal–organic framework constructed from a novel aromatic tricarboxylate for highly selective separation of small hydrocarbons journal, January 2012

Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene journal, May 2016

Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework journal, February 2017

Influence of the Oxidation State of the Metal Center on the Flexibility and Adsorption Properties of a Porous Metal Organic Framework: MIL-47(V) journal, September 2011

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites journal, March 2012

Storage and Sorption Properties of Acetylene in Jungle-Gym-Like Open Frameworks journal, September 2008

Structures of cubic and orthorhombic phases of acetylene by single-crystal neutron diffraction journal, October 1992

Selectivity and direct visualization of carbon dioxide and sulfur dioxide in a decorated porous host journal, September 2012

Supramolecular binding and separation of hydrocarbons within a functionalized porous metal–organic framework journal, December 2014

Hydrocarbon Separations in Metal–Organic Frameworks journal, September 2013

Absolute Molecular Sieve Separation of Ethylene/Ethane Mixtures with Silver Zeolite A journal, August 2012

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A microporous metal–organic framework with both open metal and Lewis basic pyridyl sites for highly selective C 2 H 2 /CH 4 and C 2 H 2 /CO 2 gas separation at room temperature journal, January 2013

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journal, January 2016

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