Improved stability and efficiency of perovskite solar cells with submicron flexible barrier films deposited in air
Abstract
We report on submicron organosilicate barrier films produced rapidly in air by a scalable spray plasma process that improves both the stability and efficiency of perovskite solar cells.
- Authors:
-
- Stanford Univ., CA (United States). Dept. of Applied Physics
- Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1423463
- Alternate Identifier(s):
- OSTI ID: 1491403
- Grant/Contract Number:
- DGE-1656518; EECS-1542152; AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 44; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Rolston, Nicholas, Printz, Adam D., Hilt, Florian, Hovish, Michael Q., Brüning, Karsten, Tassone, Christopher J., and Dauskardt, Reinhold H. Improved stability and efficiency of perovskite solar cells with submicron flexible barrier films deposited in air. United States: N. p., 2017.
Web. doi:10.1039/c7ta09178h.
Rolston, Nicholas, Printz, Adam D., Hilt, Florian, Hovish, Michael Q., Brüning, Karsten, Tassone, Christopher J., & Dauskardt, Reinhold H. Improved stability and efficiency of perovskite solar cells with submicron flexible barrier films deposited in air. United States. https://doi.org/10.1039/c7ta09178h
Rolston, Nicholas, Printz, Adam D., Hilt, Florian, Hovish, Michael Q., Brüning, Karsten, Tassone, Christopher J., and Dauskardt, Reinhold H. Fri .
"Improved stability and efficiency of perovskite solar cells with submicron flexible barrier films deposited in air". United States. https://doi.org/10.1039/c7ta09178h. https://www.osti.gov/servlets/purl/1423463.
@article{osti_1423463,
title = {Improved stability and efficiency of perovskite solar cells with submicron flexible barrier films deposited in air},
author = {Rolston, Nicholas and Printz, Adam D. and Hilt, Florian and Hovish, Michael Q. and Brüning, Karsten and Tassone, Christopher J. and Dauskardt, Reinhold H.},
abstractNote = {We report on submicron organosilicate barrier films produced rapidly in air by a scalable spray plasma process that improves both the stability and efficiency of perovskite solar cells.},
doi = {10.1039/c7ta09178h},
journal = {Journal of Materials Chemistry. A},
number = 44,
volume = 5,
place = {United States},
year = {2017},
month = {10}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 6 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:

All figures and tables
(6 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Scaffold-reinforced perovskite compound solar cells
journal, January 2017
- Watson, Brian L.; Rolston, Nicholas; Printz, Adam D.
- Energy & Environmental Science, Vol. 10, Issue 12
Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells
journal, January 2016
- Bryant, Daniel; Aristidou, Nicholas; Pont, Sebastian
- Energy & Environmental Science, Vol. 9, Issue 5
A large area (70 cm 2 ) monolithic perovskite solar module with a high efficiency and stability
journal, January 2016
- Priyadarshi, Anish; Haur, Lew Jia; Murray, Paul
- Energy & Environmental Science, Vol. 9, Issue 12
One-Year stable perovskite solar cells by 2D/3D interface engineering
journal, June 2017
- Grancini, G.; Roldán-Carmona, C.; Zimmermann, I.
- Nature Communications, Vol. 8, Issue 1
23.6%-efficient monolithic perovskite/silicon tandem solar cells with improved stability
journal, February 2017
- Bush, Kevin A.; Palmstrom, Axel F.; Yu, Zhengshan J.
- Nature Energy, Vol. 2, Issue 4
The emergence of perovskite solar cells
journal, July 2014
- Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
- Nature Photonics, Vol. 8, Issue 7, p. 506-514
High-efficiency robust perovskite solar cells on ultrathin flexible substrates
journal, January 2016
- Li, Yaowen; Meng, Lei; Yang, Yang
- Nature Communications, Vol. 7, Issue 1
Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells
journal, June 2017
- Yang, Woon Seok; Park, Byung-Wook; Jung, Eui Hyuk
- Science, Vol. 356, Issue 6345
Thermal and Environmental Stability of Semi-Transparent Perovskite Solar Cells for Tandems Enabled by a Solution-Processed Nanoparticle Buffer Layer and Sputtered ITO Electrode
journal, February 2016
- Bush, Kevin A.; Bailie, Colin D.; Chen, Ye
- Advanced Materials, Vol. 28, Issue 20
Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology
journal, October 2005
- Ma, W.; Yang, C.; Gong, X.
- Advanced Functional Materials, Vol. 15, Issue 10, p. 1617-1622
In situ vapor-deposited parylene substrates for ultra-thin, lightweight organic solar cells
journal, April 2016
- Jean, Joel; Wang, Annie; Bulović, Vladimir
- Organic Electronics, Vol. 31
GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013
- Toby, Brian H.; Von Dreele, Robert B.
- Journal of Applied Crystallography, Vol. 46, Issue 2
Towards enabling stable lead halide perovskite solar cells; interplay between structural, environmental, and thermal stability
journal, January 2017
- Leijtens, Tomas; Bush, Kevin; Cheacharoen, Rongrong
- Journal of Materials Chemistry A, Vol. 5, Issue 23
Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016
- Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn
- Energy & Environmental Science, Vol. 9, Issue 6
Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells
journal, January 2014
- Eperon, Giles E.; Stranks, Samuel D.; Menelaou, Christopher
- Energy & Environmental Science, Vol. 7, Issue 3
Role of Carbon Bridge Length of Organosilicate Precursors on the Atmospheric Plasma Deposition of Transparent Bilayer Protective Coatings on Plastics: Role of Carbon Bridge Length of Organosilicate …
journal, July 2016
- Dong, Siming; Han, Jiahao; Zhao, Zhenlin
- Plasma Processes and Polymers, Vol. 13, Issue 11
Mechanical integrity of solution-processed perovskite solar cells
journal, December 2016
- Rolston, Nicholas; Watson, Brian L.; Bailie, Colin D.
- Extreme Mechanics Letters, Vol. 9
Superflexible, high-efficiency perovskite solar cells utilizing graphene electrodes: towards future foldable power sources
journal, January 2017
- Yoon, Jungjin; Sung, Hyangki; Lee, Gunhee
- Energy & Environmental Science, Vol. 10, Issue 1
Synthesis and use of a hyper-connecting cross-linking agent in the hole-transporting layer of perovskite solar cells
journal, January 2017
- Watson, Brian L.; Rolston, Nicholas; Bush, Kevin A.
- Journal of Materials Chemistry A, Vol. 5, Issue 36
A technoeconomic analysis of perovskite solar module manufacturing with low-cost materials and techniques
journal, January 2017
- Song, Zhaoning; McElvany, Chad L.; Phillips, Adam B.
- Energy & Environmental Science, Vol. 10, Issue 6
A manufacturing cost estimation method with uncertainty analysis and its application to perovskite on glass photovoltaic modules: A manufacturing cost estimation method
journal, February 2017
- Chang, Nathan L.; Yi Ho-Baillie, Anita Wing; Basore, Paul A.
- Progress in Photovoltaics: Research and Applications, Vol. 25, Issue 5
Improving efficiency and stability of perovskite solar cells with photocurable fluoropolymers
journal, September 2016
- Bella, F.; Griffini, G.; Correa-Baena, J. -P.
- Science, Vol. 354, Issue 6309
Toward Large Scale Roll-to-Roll Production of Fully Printed Perovskite Solar Cells
journal, January 2015
- Hwang, Kyeongil; Jung, Yen-Sook; Heo, Youn-Jung
- Advanced Materials, Vol. 27, Issue 7
Perovskite solar cells and large area modules (100 cm 2 ) based on an air flow-assisted PbI 2 blade coating deposition process
journal, March 2015
- Razza, Stefano; Di Giacomo, Francesco; Matteocci, Fabio
- Journal of Power Sources, Vol. 277
Organometal halide perovskite solar cells: degradation and stability
journal, January 2016
- Berhe, Taame Abraha; Su, Wei-Nien; Chen, Ching-Hsiang
- Energy & Environmental Science, Vol. 9, Issue 2
From Nano- to Micrometer Scale: The Role of Antisolvent Treatment on High Performance Perovskite Solar Cells
journal, April 2017
- Paek, S.; Schouwink, P.; Athanasopoulou, E. Nefeli
- Chemistry of Materials, Vol. 29, Issue 8
Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance
journal, May 2014
- Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa
- Advanced Materials, Vol. 26, Issue 27
A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells
journal, January 2016
- McMeekin, D. P.; Sadoughi, G.; Rehman, W.
- Science, Vol. 351, Issue 6269
Degradation observations of encapsulated planar CH 3 NH 3 PbI 3 perovskite solar cells at high temperatures and humidity
journal, January 2015
- Han, Yu; Meyer, Steffen; Dkhissi, Yasmina
- Journal of Materials Chemistry A, Vol. 3, Issue 15
Self-Assembled Molecular Films of Aminosilanes and Their Immobilization Capacities
journal, March 2004
- Zhang, Fengxiang; Srinivasan, M. P.
- Langmuir, Vol. 20, Issue 6
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
journal, July 2016
- Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe
- Nature, Vol. 536, Issue 7616
Cost-Performance Analysis of Perovskite Solar Modules
journal, September 2016
- Cai, Molang; Wu, Yongzhen; Chen, Han
- Advanced Science, Vol. 4, Issue 1
Stabilizing the Efficiency Beyond 20% with a Mixed Cation Perovskite Solar Cell Fabricated in Ambient Air under Controlled Humidity
journal, September 2017
- Singh, Trilok; Miyasaka, Tsutomu
- Advanced Energy Materials, Vol. 8, Issue 3
Overcoming ultraviolet light instability of sensitized TiO2 with meso-superstructured organometal tri-halide perovskite solar cells
journal, December 2013
- Leijtens, Tomas; Eperon, Giles E.; Pathak, Sandeep
- Nature Communications, Vol. 4, Issue 1
Engineering interface structures between lead halide perovskite and copper phthalocyanine for efficient and stable perovskite solar cells
journal, January 2017
- Kim, Y. C.; Yang, T. -Y.; Jeon, N. J.
- Energy Environ. Sci., Vol. 10, Issue 10
Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates
journal, November 2013
- Docampo, Pablo; Ball, James M.; Darwich, Mariam
- Nature Communications, Vol. 4, Article No. 2761
Suppressed decomposition of organometal halide perovskites by impermeable electron-extraction layers in inverted solar cells
journal, January 2017
- Brinkmann, K. O.; Zhao, J.; Pourdavoud, N.
- Nature Communications, Vol. 8, Issue 1
Enhancing the Hole-Conductivity of Spiro-OMeTAD without Oxygen or Lithium Salts by Using Spiro(TFSI) 2 in Perovskite and Dye-Sensitized Solar Cells
journal, July 2014
- Nguyen, William H.; Bailie, Colin D.; Unger, Eva L.
- Journal of the American Chemical Society, Vol. 136, Issue 31
Superhydrophobic surfaces: from structural control to functional application
journal, January 2008
- Zhang, Xi; Shi, Feng; Niu, Jia
- J. Mater. Chem., Vol. 18, Issue 6
Works referencing / citing this record:
Toward Perovskite Solar Cell Commercialization: A Perspective and Research Roadmap Based on Interfacial Engineering
journal, June 2018
- Rajagopal, Adharsh; Yao, Kai; Jen, Alex K. -Y.
- Advanced Materials, Vol. 30, Issue 32
Application of Perovskite‐Structured Materials in Field‐Effect Transistors
journal, September 2019
- Wu, Tingjun; Pisula, Wojciech; Rashid, Mohd Yusoff Abd
- Advanced Electronic Materials, Vol. 5, Issue 12
Engineering Stress in Perovskite Solar Cells to Improve Stability
journal, September 2018
- Rolston, Nicholas; Bush, Kevin A.; Printz, Adam D.
- Advanced Energy Materials, Vol. 8, Issue 29
Caesium for Perovskite Solar Cells: An Overview
journal, June 2018
- Bella, Federico; Renzi, Polyssena; Cavallo, Carmen
- Chemistry - A European Journal, Vol. 24, Issue 47
Rapid route to efficient, scalable, and robust perovskite photovoltaics in air
journal, January 2018
- Hilt, Florian; Hovish, Michael Q.; Rolston, Nicholas
- Energy & Environmental Science, Vol. 11, Issue 8
Crystallization kinetics of rapid spray plasma processed multiple cation perovskites in open air
journal, January 2020
- Hovish, Michael Q.; Rolston, Nicholas; Brüning, Karsten
- Journal of Materials Chemistry A, Vol. 8, Issue 1
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.