Type I antiferromagnetic order in Ba2LuReO6: Exploring the role of structural distortions in double perovskites containing 5d2 ions

Xiong, Jie; Yan, Jiaqiang; Aczel, Adam A.; Woodward, Patrick M.

doi:10.1016/j.jssc.2017.11.040

Title: Type I antiferromagnetic order in Ba₂LuReO₆: Exploring the role of structural distortions in double perovskites containing 5d² ions

Abstract

The structural, electrical, and magnetic properties of the double perovskite Ba₂LuReO₆ have been examined in this paper. It is an insulator whose temperature dependent conductivity is consistent with variable range hopping electrical transport. A transition to an antiferromagnet state with type I order occurs below T_N = 31 K. High resolution time-of-flight neutron powder diffraction measurements show that it retains the cubic double perovskite structure down to 10 K. High intensity, low resolution neutron powder diffraction measurements confirm the antiferromagnetic order and indicate that cubic symmetry is still observed at 1.5 K. The small ordered moment of 0.34(4)μ_B per Re is comparable to estimates of moments on 5d² ions in other antiferromagnetically ordered cubic double perovskites. Finally, comparisons with related double perovskites containing 5d² ions, such as Os⁶⁺ and Re⁵⁺, reveal that subtle changes in structure or electron configuration of the diamagnetic octahedral cations can have a large impact on the magnetic ground state, the size of the ordered moment, and the Néel temperature.

Authors:

Xiong, Jie ^[1]; Yan, Jiaqiang ^[2]; Aczel, Adam A. ^[3]; Woodward, Patrick M. ^[1]

The Ohio State Univ., Columbus, OH (United States). Dept. of Chemistry and Biochemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Materials Science and Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Division

Publication Date:: 2017-12-02

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); The Ohio State Univ., Columbus, OH (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

OSTI Identifier:: 1423055

Alternate Identifier(s):: OSTI ID: 1505861

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357; DMR-1420451

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Solid State Chemistry

Additional Journal Information:: Journal Volume: 258; Journal ID: ISSN 0022-4596

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; double perovskite; 5d transition metal oxide; antiferromagnetism; magnetic material

Citation Formats


                    Xiong, Jie, Yan, Jiaqiang, Aczel, Adam A., and Woodward, Patrick M. Type I antiferromagnetic order in Ba2LuReO6: Exploring the role of structural distortions in double perovskites containing 5d2 ions.  United States: N. p., 2017. 
Web.  doi:10.1016/j.jssc.2017.11.040.

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                    Xiong, Jie, Yan, Jiaqiang, Aczel, Adam A., & Woodward, Patrick M. Type I antiferromagnetic order in Ba2LuReO6: Exploring the role of structural distortions in double perovskites containing 5d2 ions.  United States.  https://doi.org/10.1016/j.jssc.2017.11.040

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                    Xiong, Jie, Yan, Jiaqiang, Aczel, Adam A., and Woodward, Patrick M. Sat .  
"Type I antiferromagnetic order in Ba2LuReO6: Exploring the role of structural distortions in double perovskites containing 5d2 ions".  United States.  https://doi.org/10.1016/j.jssc.2017.11.040.  https://www.osti.gov/servlets/purl/1423055.

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@article{osti_1423055,

  title        = {Type I antiferromagnetic order in Ba2LuReO6: Exploring the role of structural distortions in double perovskites containing 5d2 ions},

  author       = {Xiong, Jie and Yan, Jiaqiang and Aczel, Adam A. and Woodward, Patrick M.},

  abstractNote = {The structural, electrical, and magnetic properties of the double perovskite Ba2LuReO6 have been examined in this paper. It is an insulator whose temperature dependent conductivity is consistent with variable range hopping electrical transport. A transition to an antiferromagnet state with type I order occurs below TN = 31 K. High resolution time-of-flight neutron powder diffraction measurements show that it retains the cubic double perovskite structure down to 10 K. High intensity, low resolution neutron powder diffraction measurements confirm the antiferromagnetic order and indicate that cubic symmetry is still observed at 1.5 K. The small ordered moment of 0.34(4)μB per Re is comparable to estimates of moments on 5d2 ions in other antiferromagnetically ordered cubic double perovskites. Finally, comparisons with related double perovskites containing 5d2 ions, such as Os6+ and Re5+, reveal that subtle changes in structure or electron configuration of the diamagnetic octahedral cations can have a large impact on the magnetic ground state, the size of the ordered moment, and the Néel temperature.},

  doi          = {10.1016/j.jssc.2017.11.040},

  journal      = {Journal of Solid State Chemistry},

  number       = ,

  volume       = 258,

  place        = {United States},

  year         = {2017},

  month        = {12}

}

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Works referencing / citing this record:

Octupolar versus Néel Order in Cubic $5 d^{2}$ Double Perovskites
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Structural and electronic properties of the ordered double perovskites $A_{2} M {ReO}_{6}$ $(A$ =Sr,Ca; $M$ =Mg,Sc,Cr,Mn,Fe,Co,Ni,Zn)
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Magnetic order and electronic structure of the $5 d^{3}$ double perovskite ${Sr}_{2} {ScOsO}_{6}$
journal, March 2015

Radial integrals for the magnetic form factor of 5 d transition elements
journal, August 2011

Matrix elements of four-quark operators relevant to life time difference $\Delta \Gamma _{B_s}$ from QCD sum rules
journal, June 2001

The role of nonmagnetic d0 vs. d10 B-type cations on the magnetic exchange interactions in osmium double perovskites
journal, November 2016

Magnetically Frustrated Double Perovskites: Synthesis, Structural Properties, and Magnetic Order of Sr ₂ B OsO ₆ ( B = Y, In, Sc) : Magnetically Frustrated Double Perovskites Sr
journal, February 2015

Active role of nonmagnetic cations in magnetic interactions for double-perovskite $S r_{2} B Os O_{6} (B = Y, In, Sc)$
journal, April 2016

Octupolar versus Néel Order in Cubic $5 d^{2}$ Double Perovskites
journal, February 2020

Revisiting the Kitaev material candidacy of ${Ir}^{4 +}$ double perovskite iridates
journal, April 2019