Type I antiferromagnetic order in Ba2LuReO6: Exploring the role of structural distortions in double perovskites containing 5d2 ions

Xiong, Jie; Yan, Jiaqiang; Aczel, Adam A.; Woodward, Patrick M.

doi:10.1016/j.jssc.2017.11.040

Title: Type I antiferromagnetic order in Ba₂LuReO₆: Exploring the role of structural distortions in double perovskites containing 5d² ions

Journal Article · Sat Dec 02 04:00:00 UTC 2017 · Journal of Solid State Chemistry

DOI: https://doi.org/10.1016/j.jssc.2017.11.040 · OSTI ID:1423055

Xiong, Jie ^[1]; Yan, Jiaqiang ^[2]; Aczel, Adam A. ^[3]; Woodward, Patrick M. ^[1]

The Ohio State Univ., Columbus, OH (United States). Dept. of Chemistry and Biochemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Materials Science and Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Division

The structural, electrical, and magnetic properties of the double perovskite Ba₂LuReO₆ have been examined in this paper. It is an insulator whose temperature dependent conductivity is consistent with variable range hopping electrical transport. A transition to an antiferromagnet state with type I order occurs below T_N = 31 K. High resolution time-of-flight neutron powder diffraction measurements show that it retains the cubic double perovskite structure down to 10 K. High intensity, low resolution neutron powder diffraction measurements confirm the antiferromagnetic order and indicate that cubic symmetry is still observed at 1.5 K. The small ordered moment of 0.34(4)μ_B per Re is comparable to estimates of moments on 5d² ions in other antiferromagnetically ordered cubic double perovskites. Finally, comparisons with related double perovskites containing 5d² ions, such as Os⁶⁺ and Re⁵⁺, reveal that subtle changes in structure or electron configuration of the diamagnetic octahedral cations can have a large impact on the magnetic ground state, the size of the ordered moment, and the Néel temperature.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); The Ohio State Univ., Columbus, OH (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF) (United States)

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

OSTI ID:: 1423055

Journal Information:: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Vol. 258; ISSN 0022-4596

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Revisiting the Kitaev material candidacy of Ir 4 + double perovskite iridates Aczel, A. A.; Clancy, J. P.; Chen, Q. Physical Review B, Vol. 99, Issue 13 https://doi.org/10.1103/physrevb.99.134417	journal	April 2019
Octupolar versus Néel Order in Cubic 5 d 2 Double Perovskites Maharaj, D. D.; Sala, G.; Stone, M. B. Physical Review Letters, Vol. 124, Issue 8 https://doi.org/10.1103/physrevlett.124.087206	journal	February 2020

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Title: Type I antiferromagnetic order in Ba2LuReO6: Exploring the role of structural distortions in double perovskites containing 5d2 ions

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Title: Type I antiferromagnetic order in Ba₂LuReO₆: Exploring the role of structural distortions in double perovskites containing 5d² ions