Colloidal Cobalt Phosphide Nanocrystals as Trifunctional Electrocatalysts for Overall Water Splitting Powered by a Zinc–Air Battery
Abstract
Highly efficient and stable electrocatalysts, particularly those that are capable of multifunctionality in the same electrolyte, are in high demand for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). In this paper, highly monodisperse CoP and Co2P nanocrystals (NCs) are synthesized using a robust solution-phase method. The highly exposed (211) crystal plane and abundant surface phosphide atoms make the CoP NCs efficient catalysts toward ORR and HER, while metal-rich Co2P NCs show higher OER performance owing to easier formation of plentiful Co2P@COOH heterojunctions. Density functional theory calculation results indicate that the desorption of OH* from cobalt sites is the rate-limiting step for both CoP and Co2P in ORR and that the high content of phosphide can lower the reaction barrier. A water electrolyzer constructed with a CoP NC cathode and a Co2P NC anode can achieve a current density of 10 mA cm-2 at 1.56 V, comparable even to the noble metal-based Pt/C and RuO2/C pair. Finally and furthermore, the CoP NCs are employed as an air cathode in a primary zinc–air battery, exhibiting a high power density of 62 mW cm-2 and good stability.
- Authors:
-
- Wake Forest Univ., Winston-Salem, NC (United States). Dept. of Chemistry
- IBM TJ Watson Research Center, Yorktown Heights, NY (United States). Physical Science Division
- Harbin Inst. of Technology, Shenzhen (China). Shenzhen Graduate School. Dept. of Materials Science and Engineering. Shenzhen Engineering Lab. of Flexible Transparent Conductive Films
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Material Science and Technology Division
- Wake Forest Univ., Winston-Salem, NC (United States). Dept. of Physics. Center for Nanotechnology and Molecular Materials
- Soochow Univ., Suzhou (China). Inst. of Functional Nano and Soft Materials
- High Point Univ., NC (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE; Wake Forest Univ. (United States); National Science Foundation (NSF)
- OSTI Identifier:
- 1422608
- Grant/Contract Number:
- AC05-00OR22725; CHE-1531698
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 30; Journal Issue: 9; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; cobalt phosphide; density functional theory; overall water splitting; trifunctional electrocatalysts; zinc-air batteries
Citation Formats
Li, Hui, Li, Qi, Wen, Peng, Williams, Trey B., Adhikari, Shiba, Dun, Chaochao, Lu, Chang, Itanze, Dominique, Jiang, Lin, Carroll, David L., Donati, George L., Lundin, Pamela M., Qiu, Yejun, and Geyer, Scott M. Colloidal Cobalt Phosphide Nanocrystals as Trifunctional Electrocatalysts for Overall Water Splitting Powered by a Zinc–Air Battery. United States: N. p., 2018.
Web. doi:10.1002/adma.201705796.
Li, Hui, Li, Qi, Wen, Peng, Williams, Trey B., Adhikari, Shiba, Dun, Chaochao, Lu, Chang, Itanze, Dominique, Jiang, Lin, Carroll, David L., Donati, George L., Lundin, Pamela M., Qiu, Yejun, & Geyer, Scott M. Colloidal Cobalt Phosphide Nanocrystals as Trifunctional Electrocatalysts for Overall Water Splitting Powered by a Zinc–Air Battery. United States. https://doi.org/10.1002/adma.201705796
Li, Hui, Li, Qi, Wen, Peng, Williams, Trey B., Adhikari, Shiba, Dun, Chaochao, Lu, Chang, Itanze, Dominique, Jiang, Lin, Carroll, David L., Donati, George L., Lundin, Pamela M., Qiu, Yejun, and Geyer, Scott M. Mon .
"Colloidal Cobalt Phosphide Nanocrystals as Trifunctional Electrocatalysts for Overall Water Splitting Powered by a Zinc–Air Battery". United States. https://doi.org/10.1002/adma.201705796. https://www.osti.gov/servlets/purl/1422608.
@article{osti_1422608,
title = {Colloidal Cobalt Phosphide Nanocrystals as Trifunctional Electrocatalysts for Overall Water Splitting Powered by a Zinc–Air Battery},
author = {Li, Hui and Li, Qi and Wen, Peng and Williams, Trey B. and Adhikari, Shiba and Dun, Chaochao and Lu, Chang and Itanze, Dominique and Jiang, Lin and Carroll, David L. and Donati, George L. and Lundin, Pamela M. and Qiu, Yejun and Geyer, Scott M.},
abstractNote = {Highly efficient and stable electrocatalysts, particularly those that are capable of multifunctionality in the same electrolyte, are in high demand for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). In this paper, highly monodisperse CoP and Co2P nanocrystals (NCs) are synthesized using a robust solution-phase method. The highly exposed (211) crystal plane and abundant surface phosphide atoms make the CoP NCs efficient catalysts toward ORR and HER, while metal-rich Co2P NCs show higher OER performance owing to easier formation of plentiful Co2P@COOH heterojunctions. Density functional theory calculation results indicate that the desorption of OH* from cobalt sites is the rate-limiting step for both CoP and Co2P in ORR and that the high content of phosphide can lower the reaction barrier. A water electrolyzer constructed with a CoP NC cathode and a Co2P NC anode can achieve a current density of 10 mA cm-2 at 1.56 V, comparable even to the noble metal-based Pt/C and RuO2/C pair. Finally and furthermore, the CoP NCs are employed as an air cathode in a primary zinc–air battery, exhibiting a high power density of 62 mW cm-2 and good stability.},
doi = {10.1002/adma.201705796},
journal = {Advanced Materials},
number = 9,
volume = 30,
place = {United States},
year = {Mon Jan 15 00:00:00 EST 2018},
month = {Mon Jan 15 00:00:00 EST 2018}
}
Web of Science
Works referenced in this record:
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
journal, January 2017
- Suen, Nian-Tzu; Hung, Sung-Fu; Quan, Quan
- Chemical Society Reviews, Vol. 46, Issue 2
Boron-Doped Carbon Nanotubes as Metal-Free Electrocatalysts for the Oxygen Reduction Reaction
journal, June 2011
- Yang, Lijun; Jiang, Shujuan; Zhao, Yu
- Angewandte Chemie, Vol. 123, Issue 31
Janus Co/CoP Nanoparticles as Efficient Mott-Schottky Electrocatalysts for Overall Water Splitting in Wide pH Range
journal, February 2017
- Xue, Zhong-Hua; Su, Hui; Yu, Qiu-Ying
- Advanced Energy Materials, Vol. 7, Issue 12
Plasma-Assisted Synthesis of NiCoP for Efficient Overall Water Splitting
journal, November 2016
- Liang, Hanfeng; Gandi, Appala N.; Anjum, Dalaver H.
- Nano Letters, Vol. 16, Issue 12
Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications
journal, January 2014
- Faber, Matthew S.; Jin, Song
- Energy Environ. Sci., Vol. 7, Issue 11
Metal (Ni, Co)-Metal Oxides/Graphene Nanocomposites as Multifunctional Electrocatalysts
journal, August 2015
- Liu, Xien; Liu, Wen; Ko, Minseong
- Advanced Functional Materials, Vol. 25, Issue 36
Sulfur-Enriched Conjugated Polymer Nanosheet Derived Sulfur and Nitrogen co-Doped Porous Carbon Nanosheets as Electrocatalysts for Oxygen Reduction Reaction and Zinc-Air Battery
journal, June 2016
- Su, Yuezeng; Yao, Zhaoquan; Zhang, Fan
- Advanced Functional Materials, Vol. 26, Issue 32
Rapid room-temperature synthesis of nanocrystalline spinels as oxygen reduction and evolution electrocatalysts
journal, December 2010
- Cheng, Fangyi; Shen, Jian; Peng, Bo
- Nature Chemistry, Vol. 3, Issue 1
Anion and Cation Modulation in Metal Compounds for Bifunctional Overall Water Splitting
journal, September 2016
- Duan, Jingjing; Chen, Sheng; Vasileff, Anthony
- ACS Nano, Vol. 10, Issue 9
Defect Graphene as a Trifunctional Catalyst for Electrochemical Reactions
journal, September 2016
- Jia, Yi; Zhang, Longzhou; Du, Aijun
- Advanced Materials, Vol. 28, Issue 43
The Synthesis of Nanostructured Ni 5 P 4 Films and their Use as a Non-Noble Bifunctional Electrocatalyst for Full Water Splitting
journal, June 2015
- Ledendecker, Marc; Krick Calderón, Sandra; Papp, Christian
- Angewandte Chemie, Vol. 127, Issue 42
Multifunctional Carbon-Based Metal-Free Electrocatalysts for Simultaneous Oxygen Reduction, Oxygen Evolution, and Hydrogen Evolution
journal, December 2016
- Hu, Chuangang; Dai, Liming
- Advanced Materials, Vol. 29, Issue 9
Effect of Transition Metals on the Structure and Performance of the Doped Carbon Catalysts Derived From Polyaniline and Melamine for ORR Application
journal, September 2014
- Peng, Hongliang; Liu, Fangfang; Liu, Xiaojun
- ACS Catalysis, Vol. 4, Issue 10
A Graphene Oxide and Copper-Centered Metal Organic Framework Composite as a Tri-Functional Catalyst for HER, OER, and ORR
journal, May 2013
- Jahan, Maryam; Liu, Zhaolin; Loh, Kian Ping
- Advanced Functional Materials, Vol. 23, Issue 43
Self-Supported Cobalt Phosphide Mesoporous Nanorod Arrays: A Flexible and Bifunctional Electrode for Highly Active Electrocatalytic Water Reduction and Oxidation
journal, November 2015
- Zhu, Yun-Pei; Liu, Yu-Ping; Ren, Tie-Zhen
- Advanced Functional Materials, Vol. 25, Issue 47
BCN Graphene as Efficient Metal-Free Electrocatalyst for the Oxygen Reduction Reaction
journal, March 2012
- Wang, Shuangyin; Zhang, Lipeng; Xia, Zhenhai
- Angewandte Chemie International Edition, Vol. 51, Issue 17
Solar Water Splitting Cells
journal, November 2010
- Walter, Michael G.; Warren, Emily L.; McKone, James R.
- Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
Noble metal-free hydrogen evolution catalysts for water splitting
journal, January 2015
- Zou, Xiaoxin; Zhang, Yu
- Chemical Society Reviews, Vol. 44, Issue 15
Ni 2 P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni 2 P nanoparticles
journal, January 2015
- Stern, Lucas-Alexandre; Feng, Ligang; Song, Fang
- Energy & Environmental Science, Vol. 8, Issue 8
Can Boron and Nitrogen Co-doping Improve Oxygen Reduction Reaction Activity of Carbon Nanotubes?
journal, January 2013
- Zhao, Yu; Yang, Lijun; Chen, Sheng
- Journal of the American Chemical Society, Vol. 135, Issue 4
Texturing in situ: N,S-enriched hierarchically porous carbon as a highly active reversible oxygen electrocatalyst
journal, January 2017
- Pei, Zengxia; Li, Hongfei; Huang, Yan
- Energy & Environmental Science, Vol. 10, Issue 3
Urchin-like CoP Nanocrystals as Hydrogen Evolution Reaction and Oxygen Reduction Reaction Dual-Electrocatalyst with Superior Stability
journal, October 2015
- Yang, Hongchao; Zhang, Yejun; Hu, Feng
- Nano Letters, Vol. 15, Issue 11
Advanced zinc-air batteries based on high-performance hybrid electrocatalysts
journal, May 2013
- Li, Yanguang; Gong, Ming; Liang, Yongye
- Nature Communications, Vol. 4, Issue 1
Ni 3 Fe-N Doped Carbon Sheets as a Bifunctional Electrocatalyst for Air Cathodes
journal, September 2016
- Fu, Gengtao; Cui, Zhiming; Chen, Yifan
- Advanced Energy Materials, Vol. 7, Issue 1
In Situ Coupling of Strung Co 4 N and Intertwined N–C Fibers toward Free-Standing Bifunctional Cathode for Robust, Efficient, and Flexible Zn–Air Batteries
journal, August 2016
- Meng, Fanlu; Zhong, Haixia; Bao, Di
- Journal of the American Chemical Society, Vol. 138, Issue 32
A Review of Phosphide-Based Materials for Electrocatalytic Hydrogen Evolution
journal, October 2015
- Xiao, Peng; Chen, Wei; Wang, Xin
- Advanced Energy Materials, Vol. 5, Issue 24
Identification of Cobalt Oxides with Raman Scattering and Fourier Transform Infrared Spectroscopy
journal, February 2016
- Li, Yang; Qiu, Wenlan; Qin, Fan
- The Journal of Physical Chemistry C, Vol. 120, Issue 8
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
journal, February 2016
- Shao, Minhua; Chang, Qiaowan; Dodelet, Jean-Pol
- Chemical Reviews, Vol. 116, Issue 6
Earth-Abundant Heterogeneous Water Oxidation Catalysts
journal, October 2016
- Hunter, Bryan M.; Gray, Harry B.; Müller, Astrid M.
- Chemical Reviews, Vol. 116, Issue 22
Advanced Extremely Durable 3D Bifunctional Air Electrodes for Rechargeable Zinc-Air Batteries
journal, December 2013
- Lee, Dong Un; Choi, Ja-Yeon; Feng, Kun
- Advanced Energy Materials, Vol. 4, Issue 6
Materials for fuel-cell technologies
journal, November 2001
- Steele, Brian C. H.; Heinzel, Angelika
- Nature, Vol. 414, Issue 6861, p. 345-352
Hierarchical nickel–cobalt phosphide yolk–shell spheres as highly active and stable bifunctional electrocatalysts for overall water splitting
journal, January 2016
- Yin, Zhuoxun; Zhu, Chunling; Li, Chunyan
- Nanoscale, Vol. 8, Issue 45
Highly Active and Durable Core–Corona Structured Bifunctional Catalyst for Rechargeable Metal–Air Battery Application
journal, January 2012
- Chen, Zhu; Yu, Aiping; Higgins, Drew
- Nano Letters, Vol. 12, Issue 4
Design Principles for Heteroatom-Doped Carbon Nanomaterials as Highly Efficient Catalysts for Fuel Cells and Metal-Air Batteries
journal, September 2015
- Zhao, Zhenghang; Li, Mingtao; Zhang, Lipeng
- Advanced Materials, Vol. 27, Issue 43
Bifunctional Nickel Phosphide Nanocatalysts Supported on Carbon Fiber Paper for Highly Efficient and Stable Overall Water Splitting
journal, April 2016
- Wang, Xiaoguang; Li, Wei; Xiong, Dehua
- Advanced Functional Materials, Vol. 26, Issue 23
Fe–P: A New Class of Electroactive Catalyst for Oxygen Reduction Reaction
journal, February 2015
- Singh, Kiran Pal; Bae, Eun Jin; Yu, Jong-Sung
- Journal of the American Chemical Society, Vol. 137, Issue 9
High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction
journal, June 2015
- Huang, X.; Zhao, Z.; Cao, L.
- Science, Vol. 348, Issue 6240
Hollow CoP nanopaticle/N-doped graphene hybrids as highly active and stable bifunctional catalysts for full water splitting
journal, January 2016
- Yu, Xianbo; Zhang, Shen; Li, Chunyan
- Nanoscale, Vol. 8, Issue 21
A general approach to cobalt-based homobimetallic phosphide ultrathin nanosheets for highly efficient oxygen evolution in alkaline media
journal, January 2017
- Xiao, Xiaofen; He, Chun-Ting; Zhao, Shenlong
- Energy & Environmental Science, Vol. 10, Issue 4
Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions
journal, December 2016
- Chen, Pengzuo; Zhou, Tianpei; Xing, Lili
- Angewandte Chemie International Edition, Vol. 56, Issue 2
An Advanced Nitrogen-Doped Graphene/Cobalt-Embedded Porous Carbon Polyhedron Hybrid for Efficient Catalysis of Oxygen Reduction and Water Splitting
journal, December 2014
- Hou, Yang; Wen, Zhenhai; Cui, Shumao
- Advanced Functional Materials, Vol. 25, Issue 6
Nitrogen, Phosphorus, and Fluorine Tri-doped Graphene as a Multifunctional Catalyst for Self-Powered Electrochemical Water Splitting
journal, October 2016
- Zhang, Jintao; Dai, Liming
- Angewandte Chemie International Edition, Vol. 55, Issue 42
Highly efficient hydrogen evolution from seawater by a low-cost and stable CoMoP@C electrocatalyst superior to Pt/C
journal, January 2017
- Ma, Yuan-Yuan; Wu, Cai-Xia; Feng, Xiao-Jia
- Energy & Environmental Science, Vol. 10, Issue 3
Nanostructured Co 2 P Electrocatalyst for the Hydrogen Evolution Reaction and Direct Comparison with Morphologically Equivalent CoP
journal, May 2015
- Callejas, Juan F.; Read, Carlos G.; Popczun, Eric J.
- Chemistry of Materials, Vol. 27, Issue 10
Electrically Rechargeable Zinc-Air Batteries: Progress, Challenges, and Perspectives
journal, November 2016
- Fu, Jing; Cano, Zachary Paul; Park, Moon Gyu
- Advanced Materials, Vol. 29, Issue 7
Ternary Metal Phosphide with Triple-Layered Structure as a Low-Cost and Efficient Electrocatalyst for Bifunctional Water Splitting
journal, September 2016
- Yu, Jing; Li, Qianqian; Li, Yuan
- Advanced Functional Materials, Vol. 26, Issue 42
Synthesis and X-ray Characterization of Cobalt Phosphide (Co 2 P) Nanorods for the Oxygen Reduction Reaction
journal, July 2015
- Doan-Nguyen, Vicky V. T.; Zhang, Sen; Trigg, Edward B.
- ACS Nano, Vol. 9, Issue 8
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
journal, January 2015
- Hong, Wesley T.; Risch, Marcel; Stoerzinger, Kelsey A.
- Energy & Environmental Science, Vol. 8, Issue 5
Flexible High-Energy Polymer-Electrolyte-Based Rechargeable Zinc-Air Batteries
journal, August 2015
- Fu, Jing; Lee, Dong Un; Hassan, Fathy Mohamed
- Advanced Materials, Vol. 27, Issue 37
A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions
journal, April 2015
- Zhang, Jintao; Zhao, Zhenghang; Xia, Zhenhai
- Nature Nanotechnology, Vol. 10, Issue 5
Earth-Abundant Nanomaterials for Oxygen Reduction
journal, December 2015
- Xia, Wei; Mahmood, Asif; Liang, Zibin
- Angewandte Chemie International Edition, Vol. 55, Issue 8
Ternary Fe x Co 1– x P Nanowire Array as a Robust Hydrogen Evolution Reaction Electrocatalyst with Pt-like Activity: Experimental and Theoretical Insight
journal, September 2016
- Tang, Chun; Gan, Linfeng; Zhang, Rong
- Nano Letters, Vol. 16, Issue 10
Electrodeposited Cobalt-Phosphorous-Derived Films as Competent Bifunctional Catalysts for Overall Water Splitting
journal, April 2015
- Jiang, Nan; You, Bo; Sheng, Meili
- Angewandte Chemie, Vol. 127, Issue 21
Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts
journal, January 2016
- Guo, D.; Shibuya, R.; Akiba, C.
- Science, Vol. 351, Issue 6271
BCN Graphene as Efficient Metal-Free Electrocatalyst for the Oxygen Reduction Reaction
journal, March 2012
- Wang, Shuangyin; Zhang, Lipeng; Xia, Zhenhai
- Angewandte Chemie, Vol. 124, Issue 17
Electrodeposited Cobalt-Phosphorous-Derived Films as Competent Bifunctional Catalysts for Overall Water Splitting
journal, April 2015
- Jiang, Nan; You, Bo; Sheng, Meili
- Angewandte Chemie International Edition, Vol. 54, Issue 21
Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions
journal, December 2016
- Chen, Pengzuo; Zhou, Tianpei; Xing, Lili
- Angewandte Chemie, Vol. 129, Issue 2
Works referencing / citing this record:
A Review of Precious-Metal-Free Bifunctional Oxygen Electrocatalysts: Rational Design and Applications in Zn−Air Batteries
journal, August 2018
- Wang, Hao-Fan; Tang, Cheng; Zhang, Qiang
- Advanced Functional Materials, Vol. 28, Issue 46
Fully Solar-Powered Uninterrupted Overall Water-Splitting Systems
journal, January 2019
- Zhang, Qichong; He, Bing; Tang, Lei
- Advanced Functional Materials, Vol. 29, Issue 9
Graphdiyne and its Assembly Architectures: Synthesis, Functionalization, and Applications
journal, May 2019
- Yu, Huidi; Xue, Yurui; Li, Yuliang
- Advanced Materials, Vol. 31, Issue 42
Interfacial Electron Transfer of Ni 2 P-NiP 2 Polymorphs Inducing Enhanced Electrochemical Properties
journal, October 2018
- Liu, Tong; Li, Anran; Wang, Chengbo
- Advanced Materials, Vol. 30, Issue 46
Multiscale Structural Engineering of Ni-Doped CoO Nanosheets for Zinc-Air Batteries with High Power Density
journal, October 2018
- Li, Yue-Jiao; Cui, Lan; Da, Peng-Fei
- Advanced Materials, Vol. 30, Issue 46
Phosphorus‐Rich Colloidal Cobalt Diphosphide (CoP 2 ) Nanocrystals for Electrochemical and Photoelectrochemical Hydrogen Evolution
journal, May 2019
- Li, Hui; Wen, Peng; Itanze, Dominique S.
- Advanced Materials
CuCo 2 S 4 Nanosheets@N‐Doped Carbon Nanofibers by Sulfurization at Room Temperature as Bifunctional Electrocatalysts in Flexible Quasi‐Solid‐State Zn–Air Batteries
journal, July 2019
- Pan, Zhenghui; Chen, Hao; Yang, Jie
- Advanced Science, Vol. 6, Issue 17
Low Loading of Rh x P and RuP on N, P Codoped Carbon as Two Trifunctional Electrocatalysts for the Oxygen and Hydrogen Electrode Reactions
journal, August 2018
- Qin, Qing; Jang, Haeseong; Chen, Lulu
- Advanced Energy Materials, Vol. 8, Issue 29
Exploring Indium-Based Ternary Thiospinel as Conceivable High-Potential Air-Cathode for Rechargeable Zn-Air Batteries
journal, September 2018
- Fu, Gengtao; Wang, Jie; Chen, Yifan
- Advanced Energy Materials, Vol. 8, Issue 31
Densely Populated Isolated Single CoN Site for Efficient Oxygen Electrocatalysis
journal, April 2019
- Wu, Jiabin; Zhou, He; Li, Qun
- Advanced Energy Materials, Vol. 9, Issue 22
Multifunctional Transition Metal‐Based Phosphides in Energy‐Related Electrocatalysis
journal, September 2019
- Li, Yang; Dong, Zihao; Jiao, Lifang
- Advanced Energy Materials, Vol. 10, Issue 11
Layered Metal Hydroxides and Their Derivatives: Controllable Synthesis, Chemical Exfoliation, and Electrocatalytic Applications
journal, November 2019
- Chen, Gen; Wan, Hao; Ma, Wei
- Advanced Energy Materials, Vol. 10, Issue 11
Recent Progress on Transition Metal Oxides as Bifunctional Catalysts for Lithium‐Air and Zinc‐Air Batteries
journal, October 2018
- Pan, Jing; Tian, Xin Long; Zaman, Shahid
- Batteries & Supercaps, Vol. 2, Issue 4
Recent Advances in Carbon‐Based Bifunctional Oxygen Catalysts for Zinc‐Air Batteries
journal, June 2019
- Liu, Daolan; Tong, Yueyu; Yan, Xiao
- Batteries & Supercaps, Vol. 2, Issue 9
Ultrathin Two‐Dimensional Metal‐Organic‐Framework‐Derived CoO/Nitrogen and Sulfur Co‐doped Ultrathin Porous Carbon Nanoplates for Highly Efficient Water Electrolysis
journal, May 2019
- Chao, Shujun; Wu, Hongwei; Xia, Qingyun
- ChemElectroChem, Vol. 6, Issue 15
Cobalt‐Doped Tungsten Sulfides as Stable and Efficient Air Electrodes for Rechargeable Zinc‐Air Batteries
journal, October 2019
- Xu, Ruizhi; Xu, Zejun; Zhang, Xinyang
- ChemElectroChem, Vol. 7, Issue 1
MOF‐Derived Copper Nitride/Phosphide Heterostructure Coated by Multi‐Doped Carbon as Electrocatalyst for Efficient Water Splitting and Neutral‐pH Hydrogen Evolution Reaction
journal, December 2019
- Wang, Qijun; Zhang, Zheye; Zhao, Xuezhu
- ChemElectroChem, Vol. 7, Issue 1
Integrated Ultrafine Co 0.85 Se in Carbon Nanofibers: An Efficient and Robust Bifunctional Catalyst for Oxygen Electrocatalysis
journal, November 2019
- Gui, Liangqi; Huang, Ziliang; Ai, Ding
- Chemistry – A European Journal
Electrode Materials for Rechargeable Zinc-Ion and Zinc-Air Batteries: Current Status and Future Perspectives
journal, May 2019
- Yang, Dan; Tan, Huiteng; Rui, Xianhong
- Electrochemical Energy Reviews, Vol. 2, Issue 3
Colloidal silver diphosphide (AgP2) nanocrystals as low overpotential catalysts for CO2 reduction to tunable syngas
journal, December 2019
- Li, Hui; Wen, Peng; Itanze, Dominique S.
- Nature Communications, Vol. 10, Issue 1
Recent advances in hybrid sodium–air batteries
journal, January 2019
- Xu, Xiaolong; Hui, Kwan San; Dinh, Duc Anh
- Materials Horizons, Vol. 6, Issue 7
Metal–organic frameworks-based catalysts for electrochemical oxygen evolution
journal, January 2019
- Shi, Qiurong; Fu, Shaofang; Zhu, Chengzhou
- Materials Horizons, Vol. 6, Issue 4
Highly conductive and metallic cobalt–nickel selenide nanorods supported on Ni foam as an efficient electrocatalyst for alkaline water splitting
journal, January 2019
- Liu, Shu; Jiang, Yimin; Yang, Miao
- Nanoscale, Vol. 11, Issue 16
Constructing a hexagonal copper-coin-shaped NiCoSe 2 @NiO@CoNi 2 S 4 @CoS 2 hybrid nanoarray on nickel foam as a robust oxygen evolution reaction electrocatalyst
journal, January 2018
- Xu, Zhoufeng; Pan, Hailong; Lin, Yu
- Journal of Materials Chemistry A, Vol. 6, Issue 38
Recent developments of transition metal phosphides as catalysts in the energy conversion field
journal, January 2018
- Pei, Yu; Cheng, Yu; Chen, Jiyi
- Journal of Materials Chemistry A, Vol. 6, Issue 46
Cobalt nanoparticle-embedded nitrogen-doped carbon/carbon nanotube frameworks derived from a metal–organic framework for tri-functional ORR, OER and HER electrocatalysis
journal, January 2019
- Guo, Hele; Feng, Qichun; Zhu, Jixin
- Journal of Materials Chemistry A, Vol. 7, Issue 8
The oxygen evolution reaction enabled by transition metal phosphide and chalcogenide pre-catalysts with dynamic changes
journal, January 2019
- Li, Wei; Xiong, Dehua; Gao, Xuefei
- Chemical Communications, Vol. 55, Issue 60
Design strategies for developing non-precious metal based bi-functional catalysts for alkaline electrolyte based zinc–air batteries
journal, January 2019
- Han, Chao; Li, Weijie; Liu, Hua-Kun
- Materials Horizons, Vol. 6, Issue 9
Ultrasmall Co 2 P 2 O 7 nanocrystals anchored on nitrogen-doped graphene as efficient electrocatalysts for the oxygen reduction reaction
journal, January 2019
- Li, Kaidi; Guo, Mingjing; Yan, Ya
- New Journal of Chemistry, Vol. 43, Issue 17
A novel core–double shell heterostructure derived from a metal–organic framework for efficient HER, OER and ORR electrocatalysis
journal, January 2020
- Li, Jing; Li, Guangshe; Wang, Jianghao
- Inorganic Chemistry Frontiers, Vol. 7, Issue 1
Nearly spherical CoP nanoparticle/carbon nanosheet hybrids: a high-performance trifunctional electrocatalyst for oxygen reduction and water splitting
journal, January 2019
- Zou, Wenjian; Dou, Kunpeng; Jiang, Qi
- RSC Advances, Vol. 9, Issue 68
Ni 2 P 2 O 7 microsheets as efficient Bi-functional electrocatalysts for water splitting application
journal, January 2019
- Surendran, Subramani; Sivanantham, Arumugam; Shanmugam, Sangaraju
- Sustainable Energy & Fuels, Vol. 3, Issue 9
Scalable and energy-efficient synthesis of Co x P for overall water splitting in alkaline media by high energy ball milling
journal, January 2020
- Xue, Hongyao; Zhang, Haiqin; Fricke, Sebastian
- Sustainable Energy & Fuels, Vol. 4, Issue 4
Coupled nanocomposite Co 5.47 N–Co 3 Fe 7 inlaid in a tremella-like carbon framework as a highly efficient multifunctional electrocatalyst for oxygen transformation and overall water splitting
journal, January 2019
- Kong, Fantao; Zhang, Chaoqi; Qiao, Yu
- Sustainable Energy & Fuels, Vol. 3, Issue 12
Hierarchical tri-functional electrocatalysts derived from bimetallic–imidazolate framework for overall water splitting and rechargeable zinc–air batteries
journal, January 2019
- Ahn, Sung Hoon; Manthiram, Arumugam
- Journal of Materials Chemistry A, Vol. 7, Issue 14
Iron doped cobalt phosphide ultrathin nanosheets on nickel foam for overall water splitting
journal, January 2019
- Li, Ying; Li, Fumin; Zhao, Yue
- Journal of Materials Chemistry A, Vol. 7, Issue 36
Electronic structure modulation of bifunctional oxygen catalysts for rechargeable Zn–air batteries
journal, January 2020
- Yang, Jian; Chang, Le; Guo, Heng
- Journal of Materials Chemistry A, Vol. 8, Issue 3
Tunable Synthesis of CoP and CoP 2 Decorated 3D Carbon Nanohybrids and the Application of CoP 2 Decorated One in Electrochemical Detection of Chloramphenicol in Milk and Honey
journal, January 2018
- Wu, Xingxing; Lao, Chunfeng; Li, Yingchun
- Journal of The Electrochemical Society, Vol. 165, Issue 16