Insertion, protonolysis and photolysis reactivity of a thorium monoalkyl amidinate complex

Settineri, Nicholas S.; Arnold, John

doi:10.1039/C7SC05328B

Title: Insertion, protonolysis and photolysis reactivity of a thorium monoalkyl amidinate complex

Journal Article · Mon Jan 01 04:00:00 UTC 2018 · Chemical Science

DOI: https://doi.org/10.1039/C7SC05328B · OSTI ID:1421572

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Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division

A tris-amidinate thorium monoalkyl complex facilitates new small molecule reactivity and eliminates SiMe ₄ under photolytic conditions to generate a mixed amidinate dimer.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1421572

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 10 Vol. 9; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2 and ThCl4(THF)3.5 using commercially available and inexpensive starting materials Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L. Chemical Communications, Vol. 46, Issue 6 https://doi.org/10.1039/b923558b	journal	January 2010
Thorium-mediated ring-opening of tetrahydrofuran and the development of a new thorium starting material: preparation and chemistry of ThI4(DME)2 Travia, Nicholas E.; Monreal, Marisa J.; Scott, Brian L. Dalton Transactions, Vol. 41, Issue 48 https://doi.org/10.1039/c2dt31676e	journal	January 2012
Recent developments in actinide–ligand multiple bonding Hayton, Trevor W. Chemical Communications, Vol. 49, Issue 29 https://doi.org/10.1039/c3cc39053e	journal	January 2013
Synthesizing Multidentate Ferrocenylphosphines: A Powerful Route to Dissymmetrically Tri-Substituted Ferrocenes. X-ray Structure and ¹³ C NMR of a Diaryl–Alkyl-phosphino Ferrocene Hierso, Jean-Cyrille; Ivanov, Vladimir V.; Amardeil, Régine Chemistry Letters, Vol. 33, Issue 10 https://doi.org/10.1246/cl.2004.1296	journal	October 2004

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