Chemical states of surface oxygen during CO oxidation on Pt(1 1 0) surface revealed by ambient pressure XPS

Yu, Youngseok; Koh, Yoobin Esther; Lim, Hojoon; Jeong, Beomgyun; Isegawa, Kazuhisa; Kim, Daehyun; Ueda, Kohei; Kondoh, Hiroshi; Mase, Kazuhiko; Crumlin, Ethan J.; Ross, Philip N.; Gallet, Jean-Jacques; Bournel, Fabrice; Mun, Bongjin Simon

doi:10.1088/1361-648x/aa889e

Title: Chemical states of surface oxygen during CO oxidation on Pt(1 1 0) surface revealed by ambient pressure XPS

Abstract

Here, the study of CO oxidation on Pt(110) surface is revisited using ambient pressure x-ray photoemission spectroscopy. When the surface temperature reaches the activation temperature for CO oxidation under elevated pressure conditions, both the α-phase of PtO₂ oxide and chemisorbed oxygen are formed simultaneously on the surface. Due to the exothermic nature of CO oxidation, the temperature of the Pt surface increases as CO oxidation takes place. As the CO/O₂ ratio increases, the production of CO₂ increases continuously and the surface temperature also increases. Interestingly, within the diffusion limited regions, the amount of surface oxide changes little while the chemisorbed oxygen is reduced.

Authors:

Yu, Youngseok ^[1]; Koh, Yoobin Esther ^[1]; Lim, Hojoon ^[1]; Jeong, Beomgyun ^[2]; Isegawa, Kazuhisa ^[3]; Kim, Daehyun ^[3]; Ueda, Kohei ^[3]; Kondoh, Hiroshi ^[3]; Mase, Kazuhiko ^[4]; Crumlin, Ethan J. ^[5]; Ross, Philip N. ^[5]; Gallet, Jean-Jacques ^[6]; Bournel, Fabrice ^[6]; Mun, Bongjin Simon ^[1]

Gwangju Inst. of Science and Technology (Korea, Republic of). Dept. of Physics and Photon Science
Korea Basic Science Inst., Daejeon (Korea, Republic of). Advanced Nan-Surface Research Group
Keio Univ., Kanagawa (Japan). Dept. of Chemistry
Highg Energy Accelerator Research Organization, Tsukuba (Japan). Inst. of Materials Structure Science
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Sorbonne Univ., Paris (France). Lab. of Chemical Physics

Publication Date:: Fri Oct 20 00:00:00 EDT 2017

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Research Foundation of Korea (NRF)

OSTI Identifier:: 1418308

Grant/Contract Number:: AC02-05CH11231; E36800

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physics. Condensed Matter

Additional Journal Information:: Journal Volume: 29; Journal Issue: 46; Journal ID: ISSN 0953-8984

Publisher:: IOP Publishing

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; CO oxidation; ambient pressure XPS; Pt(1 1 0); surface oxide

Citation Formats


                    Yu, Youngseok, Koh, Yoobin Esther, Lim, Hojoon, Jeong, Beomgyun, Isegawa, Kazuhisa, Kim, Daehyun, Ueda, Kohei, Kondoh, Hiroshi, Mase, Kazuhiko, Crumlin, Ethan J., Ross, Philip N., Gallet, Jean-Jacques, Bournel, Fabrice, and Mun, Bongjin Simon. Chemical states of surface oxygen during CO oxidation on Pt(1 1 0) surface revealed by ambient pressure XPS.  United States: N. p., 2017. 
Web.  doi:10.1088/1361-648x/aa889e.

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                    Yu, Youngseok, Koh, Yoobin Esther, Lim, Hojoon, Jeong, Beomgyun, Isegawa, Kazuhisa, Kim, Daehyun, Ueda, Kohei, Kondoh, Hiroshi, Mase, Kazuhiko, Crumlin, Ethan J., Ross, Philip N., Gallet, Jean-Jacques, Bournel, Fabrice, & Mun, Bongjin Simon. Chemical states of surface oxygen during CO oxidation on Pt(1 1 0) surface revealed by ambient pressure XPS.  United States.  https://doi.org/10.1088/1361-648x/aa889e

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                    Yu, Youngseok, Koh, Yoobin Esther, Lim, Hojoon, Jeong, Beomgyun, Isegawa, Kazuhisa, Kim, Daehyun, Ueda, Kohei, Kondoh, Hiroshi, Mase, Kazuhiko, Crumlin, Ethan J., Ross, Philip N., Gallet, Jean-Jacques, Bournel, Fabrice, and Mun, Bongjin Simon. Fri .  
"Chemical states of surface oxygen during CO oxidation on Pt(1 1 0) surface revealed by ambient pressure XPS".  United States.  https://doi.org/10.1088/1361-648x/aa889e.  https://www.osti.gov/servlets/purl/1418308.

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@article{osti_1418308,

  title        = {Chemical states of surface oxygen during CO oxidation on Pt(1 1 0) surface revealed by ambient pressure XPS},

  author       = {Yu, Youngseok and Koh, Yoobin Esther and Lim, Hojoon and Jeong, Beomgyun and Isegawa, Kazuhisa and Kim, Daehyun and Ueda, Kohei and Kondoh, Hiroshi and Mase, Kazuhiko and Crumlin, Ethan J. and Ross, Philip N. and Gallet, Jean-Jacques and Bournel, Fabrice and Mun, Bongjin Simon},

  abstractNote = {Here, the study of CO oxidation on Pt(110) surface is revisited using ambient pressure x-ray photoemission spectroscopy. When the surface temperature reaches the activation temperature for CO oxidation under elevated pressure conditions, both the α-phase of PtO2 oxide and chemisorbed oxygen are formed simultaneously on the surface. Due to the exothermic nature of CO oxidation, the temperature of the Pt surface increases as CO oxidation takes place. As the CO/O2 ratio increases, the production of CO2 increases continuously and the surface temperature also increases. Interestingly, within the diffusion limited regions, the amount of surface oxide changes little while the chemisorbed oxygen is reduced.},

  doi          = {10.1088/1361-648x/aa889e},

  journal      = {Journal of Physics. Condensed Matter},

  number       = 46,

  volume       = 29,

  place        = {United States},

  year         = {Fri Oct 20 00:00:00 EDT 2017},

  month        = {Fri Oct 20 00:00:00 EDT 2017}

}

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Works referencing / citing this record:

Operando study of Pd(100) surface during CO oxidation using ambient pressure x-ray photoemission spectroscopy
journal, January 2019

Yu, Youngseok; Kim, Dongwoo; Lim, Hojoon
AIP Advances, Vol. 9, Issue 1
DOI: 10.1063/1.5081066

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Similar Records

Title: Chemical states of surface oxygen during CO oxidation on Pt(1 1 0) surface revealed by ambient pressure XPS

Abstract

Citation Formats

Bridging the "Pressure Gap" between Ultrahigh-Vacuum Surface Physics and High-Pressure Catalysis journal, November 1985

CO Oxidation on Pt(110): Scanning Tunneling Microscopy Inside a High-Pressure Flow Reactor journal, July 2002

Polarization Modulation Infrared Reflection Absorption Spectroscopy at Elevated Pressures: CO Adsorption on Pd(111) at Atmospheric Pressures journal, September 2002

The role of steps in surface catalysis and reaction oscillations journal, July 2010

Structure and Reactivity of Surface Oxides on Pt (110) during Catalytic CO Oxidation journal, December 2005

Oxidation of Pt(110) journal, September 2004

Bridging the pressure gap in model systems for heterogeneous catalysis with high-pressure scanning tunneling microscopy journal, January 2007

CO Oxidation on Pt-Group Metals from Ultrahigh Vacuum to Near Atmospheric Pressures. 2. Palladium and Platinum journal, December 2008

Kinetic Oscillations in the Platinum-Catalyzed Oxidation of Co journal, July 1982

Spatiotemporal concentration patterns in a surface reaction: Propagating and standing waves, rotating spirals, and turbulence journal, December 1990

Oscillatory CO oxidation on Pt(110): Modeling of temporal self‐organization journal, June 1992

Reactions at well-defined surfaces journal, January 1994

Imaging Pattern Formation in Surface Reactions from Ultrahigh Vacuum up to Atmospheric Pressures journal, October 1995

Subsurface oxygen formation on the Pt(110) surface: experiment and mathematical modeling journal, April 1996

Oscillatory Kinetics and Spatio-Temporal Self-Organization in Reactions at Solid Surfaces journal, December 1991

A molecular beam study of the catalytic oxidation of CO on a Pt(111) surface journal, December 1980

In Situ Oxidation Study of Pt(110) and Its Interaction with CO journal, December 2011

In Situ Ambient Pressure XPS Study of CO Oxidation Reaction on Pd(111) Surfaces journal, August 2012

New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2 journal, May 2010

Mechanism of CO oxidation reaction on O-covered Pd(111) surfaces studied with fast x-ray photoelectron spectroscopy: Change of reaction path accompanying phase transition of O domains journal, June 2006

In Situ X-Ray Photoelectron Spectroscopy of Model Catalysts: At the Edge of the Gap journal, March 2013

Operando study of Pd(100) surface during CO oxidation using ambient pressure x-ray photoemission spectroscopy journal, January 2019

Bridging the "Pressure Gap" between Ultrahigh-Vacuum Surface Physics and High-Pressure Catalysis
journal, November 1985

CO Oxidation on Pt(110): Scanning Tunneling Microscopy Inside a High-Pressure Flow Reactor
journal, July 2002

Polarization Modulation Infrared Reflection Absorption Spectroscopy at Elevated Pressures: CO Adsorption on Pd(111) at Atmospheric Pressures
journal, September 2002

The role of steps in surface catalysis and reaction oscillations
journal, July 2010

Structure and Reactivity of Surface Oxides on Pt (110) during Catalytic CO Oxidation
journal, December 2005

Oxidation of Pt(110)
journal, September 2004

Bridging the pressure gap in model systems for heterogeneous catalysis with high-pressure scanning tunneling microscopy
journal, January 2007

CO Oxidation on Pt-Group Metals from Ultrahigh Vacuum to Near Atmospheric Pressures. 2. Palladium and Platinum
journal, December 2008

Kinetic Oscillations in the Platinum-Catalyzed Oxidation of Co
journal, July 1982

Spatiotemporal concentration patterns in a surface reaction: Propagating and standing waves, rotating spirals, and turbulence
journal, December 1990

Oscillatory CO oxidation on Pt(110): Modeling of temporal self‐organization
journal, June 1992

Reactions at well-defined surfaces
journal, January 1994

Imaging Pattern Formation in Surface Reactions from Ultrahigh Vacuum up to Atmospheric Pressures
journal, October 1995

Subsurface oxygen formation on the Pt(110) surface: experiment and mathematical modeling
journal, April 1996

Oscillatory Kinetics and Spatio-Temporal Self-Organization in Reactions at Solid Surfaces
journal, December 1991

A molecular beam study of the catalytic oxidation of CO on a Pt(111) surface
journal, December 1980

In Situ Oxidation Study of Pt(110) and Its Interaction with CO
journal, December 2011

In Situ Ambient Pressure XPS Study of CO Oxidation Reaction on Pd(111) Surfaces
journal, August 2012

New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2
journal, May 2010

Mechanism of CO oxidation reaction on O-covered Pd(111) surfaces studied with fast x-ray photoelectron spectroscopy: Change of reaction path accompanying phase transition of O domains
journal, June 2006

In Situ X-Ray Photoelectron Spectroscopy of Model Catalysts: At the Edge of the Gap
journal, March 2013

Operando study of Pd(100) surface during CO oxidation using ambient pressure x-ray photoemission spectroscopy
journal, January 2019