Impacts of Methane on Carbon Dioxide Storage in Brine Formations
Abstract
In the context of geological carbon sequestration (GCS), carbon dioxide (CO2) is often injected into deep formations saturated with a brine that may contain dissolved light hydrocarbons, such as methane (CH4). In this multicomponent multiphase displacement process, CO2 competes with CH4 in terms of dissolution, and CH4 tends to exsolve from the aqueous into a gaseous phase. Because CH4 has a lower viscosity than injected CO2, CH4 is swept up into a ‘bank’ of CH4–rich gas ahead of the CO2 displacement front. On the one hand, this may provide a useful tracer signal of an approaching CO2 front. On the other hand, the emergence of gaseous CH4 is undesirable because it poses a leakage risk of a far more potent greenhouse gas than CO2 if the cap rock is compromised. Open fractures or faults and wells could result in CH4 contamination of overlying groundwater aquifers as well as surface emissions. We investigate this process through detailed numerical simulations for a large–scale GCS pilot project (near Cranfield, Mississippi) for which a rich set of field data is available. An accurate cubic–plus–association equation–of–state is used to describe the non–linear phase behavior of multiphase brine–CH4–CO2 mixtures, and breakthrough curves in two observation wellsmore »
- Authors:
-
- The Ohio State Univ., Columbus, OH (United States); Univ. of Cincinnati, Cincinnati, OH (United States)
- The Ohio State Univ., Columbus, OH (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- The Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Southern States Energy Board, Norcross, GA (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 1479685
- Alternate Identifier(s):
- OSTI ID: 1417124
- Report Number(s):
- DOE-SSEB-42590-8
Journal ID: ISSN 0017-467X
- Grant/Contract Number:
- FC26-05NT42590; AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Ground Water
- Additional Journal Information:
- Journal Volume: 56; Journal Issue: 2; Journal ID: ISSN 0017-467X
- Publisher:
- Wiley - NGWA
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES
Citation Formats
Soltanian, Mohamad R., Amooie, Mohammad A., Cole, David R., Darrah, Thomas H., Graham, David E., Pfiffner, Susan M., Phelps, Tommy J., and Moortgat, Joachim. Impacts of Methane on Carbon Dioxide Storage in Brine Formations. United States: N. p., 2018.
Web. doi:10.1111/gwat.12633.
Soltanian, Mohamad R., Amooie, Mohammad A., Cole, David R., Darrah, Thomas H., Graham, David E., Pfiffner, Susan M., Phelps, Tommy J., & Moortgat, Joachim. Impacts of Methane on Carbon Dioxide Storage in Brine Formations. United States. https://doi.org/10.1111/gwat.12633
Soltanian, Mohamad R., Amooie, Mohammad A., Cole, David R., Darrah, Thomas H., Graham, David E., Pfiffner, Susan M., Phelps, Tommy J., and Moortgat, Joachim. Tue .
"Impacts of Methane on Carbon Dioxide Storage in Brine Formations". United States. https://doi.org/10.1111/gwat.12633. https://www.osti.gov/servlets/purl/1479685.
@article{osti_1479685,
title = {Impacts of Methane on Carbon Dioxide Storage in Brine Formations},
author = {Soltanian, Mohamad R. and Amooie, Mohammad A. and Cole, David R. and Darrah, Thomas H. and Graham, David E. and Pfiffner, Susan M. and Phelps, Tommy J. and Moortgat, Joachim},
abstractNote = {In the context of geological carbon sequestration (GCS), carbon dioxide (CO2) is often injected into deep formations saturated with a brine that may contain dissolved light hydrocarbons, such as methane (CH4). In this multicomponent multiphase displacement process, CO2 competes with CH4 in terms of dissolution, and CH4 tends to exsolve from the aqueous into a gaseous phase. Because CH4 has a lower viscosity than injected CO2, CH4 is swept up into a ‘bank’ of CH4–rich gas ahead of the CO2 displacement front. On the one hand, this may provide a useful tracer signal of an approaching CO2 front. On the other hand, the emergence of gaseous CH4 is undesirable because it poses a leakage risk of a far more potent greenhouse gas than CO2 if the cap rock is compromised. Open fractures or faults and wells could result in CH4 contamination of overlying groundwater aquifers as well as surface emissions. We investigate this process through detailed numerical simulations for a large–scale GCS pilot project (near Cranfield, Mississippi) for which a rich set of field data is available. An accurate cubic–plus–association equation–of–state is used to describe the non–linear phase behavior of multiphase brine–CH4–CO2 mixtures, and breakthrough curves in two observation wells are used to constrain transport processes. Furthermore, both field data and simulations indeed show the development of an extensive plume of CH4–rich (up to 90 mol%) gas as a consequence of CO2 injection, with important implications for the risk assessment of future GCS projects.},
doi = {10.1111/gwat.12633},
journal = {Ground Water},
number = 2,
volume = 56,
place = {United States},
year = {Tue Jan 16 00:00:00 EST 2018},
month = {Tue Jan 16 00:00:00 EST 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
The Sim-SEQ Project: Comparison of Selected Flow Models for the S-3 Site
journal, July 2014
- Mukhopadhyay, Sumit; Doughty, Christine; Bacon, Diana
- Transport in Porous Media, Vol. 108, Issue 1
Analytical Model for CO2 Injection into Brine Aquifers-Containing Residual CH4
journal, June 2012
- Hosseini, Seyyed Abolfazl; Mathias, Simon A.; Javadpour, Farzam
- Transport in Porous Media, Vol. 94, Issue 3
Extraction of Dissolved Methane in Brines by CO2 Injection: Implication for CO2 Sequestration
journal, October 2010
- Taggart, Ian J.
- SPE Reservoir Evaluation & Engineering, Vol. 13, Issue 05
Noble gases identify the mechanisms of fugitive gas contamination in drinking-water wells overlying the Marcellus and Barnett Shales
journal, September 2014
- Darrah, Thomas H.; Vengosh, Avner; Jackson, Robert B.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 39
Fickian Diffusion in Discrete-Fractured Media from Chemical Potential Gradients and Comparison to Experiment
journal, September 2013
- Moortgat, Joachim; Firoozabadi, Abbas
- Energy & Fuels, Vol. 27, Issue 10
Mixing and spreading of multiphase fluids in heterogeneous bimodal porous media
journal, April 2017
- Amooie, Mohammad Amin; Soltanian, Mohamad Reza; Xiong, Fengyang
- Geomechanics and Geophysics for Geo-Energy and Geo-Resources, Vol. 3, Issue 3
Monitoring a large volume CO2 injection: Year two results from SECARB project at Denbury’s Cranfield, Mississippi, USA
journal, January 2011
- Hovorka, Susan D.; Meckel, Timothy A.; Trevino, Ramon H.
- Energy Procedia, Vol. 4
Capillary Behavior in Porous Solids
journal, December 1941
- Leverett, M. C.
- Transactions of the AIME, Vol. 142, Issue 01
Cubic-plus-association equation of state for water-containing mixtures: Is “cross association” necessary?
journal, July 2009
- Li, Zhidong; Firoozabadi, Abbas
- AIChE Journal, Vol. 55, Issue 7
Investigation of Small-Scale Preferential Flow with a Forced-Gradient Tracer Test
journal, August 2010
- Bianchi, Marco; Zheng, Chunmiao; Tick, Geoffrey R.
- Ground Water, Vol. 49, Issue 4
Understanding the impact of open-framework conglomerates on water–oil displacements: the Victor interval of the Ivishak Reservoir, Prudhoe Bay Field, Alaska
journal, December 2014
- Gershenzon, Naum I.; Soltanian, Mohamadreza; Ritzi, Robert W.
- Petroleum Geoscience, Vol. 21, Issue 1
Three-phase compositional modeling of CO 2 injection by higher-order finite element methods with CPA equation of state for aqueous phase : THREE-PHASE MODELING WITH CPA EOS
journal, December 2012
- Moortgat, Joachim; Li, Zhidong; Firoozabadi, Abbas
- Water Resources Research, Vol. 48, Issue 12
Viscous and gravitational fingering in multiphase compositional and compressible flow
journal, March 2016
- Moortgat, Joachim
- Advances in Water Resources, Vol. 89
Phase equilibria of oil, gas and water/brine mixtures from a cubic equation of state and henry's law
journal, June 1986
- Li, Yau-Kun; Nghiem, Long X.
- The Canadian Journal of Chemical Engineering, Vol. 64, Issue 3
Static and dynamic reservoir modeling for geological CO2 sequestration at Cranfield, Mississippi, U.S.A.
journal, October 2013
- Hosseini, Seyyed Abolfazl; Lashgari, Hamidreza; Choi, Jong W.
- International Journal of Greenhouse Gas Control, Vol. 18
Numerical Modeling of Methane Leakage from a Faulty Natural Gas Well into Fractured Tight Formations
journal, January 2018
- Moortgat, Joachim; Schwartz, Franklin W.; Darrah, Thomas H.
- Groundwater, Vol. 56, Issue 2
General Strategy for Stability Testing and Phase-Split Calculation in Two and Three Phases
journal, December 2012
- Li, Zhidong; Firoozabadi, Abbas
- SPE Journal, Vol. 17, Issue 04
Hydrothermodynamic mixing of fluids across phases in porous media: HYDROTHERMODYNAMIC MIXING
journal, April 2017
- Amooie, Mohammad Amin; Soltanian, Mohamad Reza; Moortgat, Joachim
- Geophysical Research Letters, Vol. 44, Issue 8
Reservoir Fluid Monitoring in Carbon Dioxide Sequestration at Cranfield
journal, January 2013
- Verma, S.; Oakes, C. S.; Chugunov, N.
- Energy Procedia, Vol. 37
Implicit finite volume and discontinuous Galerkin methods for multicomponent flow in unstructured 3D fractured porous media
journal, October 2016
- Moortgat, Joachim; Amooie, Mohammad Amin; Soltanian, Mohamad Reza
- Advances in Water Resources, Vol. 96
Solute transport through preferential pathways in municipal solid waste
journal, November 2000
- Rosqvist, Håkan; Destouni, Georgia
- Journal of Contaminant Hydrology, Vol. 46, Issue 1-2
Geological storage of carbon dioxide
journal, January 2004
- Baines, Shelagh J.; Worden, Richard H.
- Geological Society, London, Special Publications, Vol. 233, Issue 1
Dissolution Trapping of Carbon Dioxide in Heterogeneous Aquifers
journal, June 2017
- Soltanian, Mohamad Reza; Amooie, Mohammad Amin; Gershenzon, Naum
- Environmental Science & Technology, Vol. 51, Issue 13
Modeling CO 2 injection at Cranfield, Mississippi: Investigation of methane and temperature effects : Modeling and Analysis: Modeling CO
journal, August 2013
- Doughty, Christine; Freifeld, Barry M.
- Greenhouse Gases: Science and Technology, Vol. 3, Issue 6
Using noble gas fingerprints at the Kerr Farm to assess CO 2 leakage allegations linked to the Weyburn-Midale CO 2 monitoring and storage project
journal, August 2017
- Gilfillan, Stuart M. V.; Sherk, George William; Poreda, Robert J.
- International Journal of Greenhouse Gas Control, Vol. 63
Sequestration of CO2 in geological media: criteria and approach for site selection in response to climate change
journal, June 2000
- Bachu, Stefan
- Energy Conversion and Management, Vol. 41, Issue 9
Monitoring a large-volume injection at Cranfield, Mississippi—Project design and recommendations
journal, October 2013
- Hovorka, Susan D.; Meckel, Timothy A.; Treviño, Ramón H.
- International Journal of Greenhouse Gas Control, Vol. 18
Optimum design of CO2 storage and oil recovery under geological uncertainty
journal, June 2017
- Ampomah, W.; Balch, R. S.; Cather, M.
- Applied Energy, Vol. 195
Gas source attribution techniques for assessing leakage at geologic CO2 storage sites: Evaluating a CO2 and CH4 soil gas anomaly at the Cranfield CO2-EOR site
journal, April 2017
- Anderson, Jacob S.; Romanak, Katherine D.; Yang, Changbing
- Chemical Geology, Vol. 454
CO2–rock–brine interactions in Lower Tuscaloosa Formation at Cranfield CO2 sequestration site, Mississippi, U.S.A.
journal, January 2012
- Lu, Jiemin; Kharaka, Yousif K.; Thordsen, James J.
- Chemical Geology, Vol. 291
Compositional modeling of three-phase flow with gravity using higher-order finite element methods: COMPOSITIONAL MODELING OF 3-PHASE FLOW
journal, May 2011
- Moortgat, Joachim; Sun, Shuyu; Firoozabadi, Abbas
- Water Resources Research, Vol. 47, Issue 5
How does the connectivity of open-framework conglomerates within multi-scale hierarchical fluvial architecture affect oil-sweep efficiency in waterflooding?
journal, October 2015
- Gershenzon, Naum I.; Soltanian, Mohamad Reza; Ritzi, Robert W.
- Geosphere, Vol. 11, Issue 6
Critical Dynamics of Gravito-Convective Mixing in Geological Carbon Sequestration
journal, November 2016
- Soltanian, Mohamad Reza; Amooie, Mohammad Amin; Dai, Zhenxue
- Scientific Reports, Vol. 6, Issue 1
Analysis of convergent flow tracer tests in a heterogeneous sandy box with connected gravel channels
journal, July 2015
- Molinari, Antonio; Pedretti, D.; Fallico, C.
- Water Resources Research, Vol. 51, Issue 7
The geochemistry of naturally occurring methane and saline groundwater in an area of unconventional shale gas development
journal, July 2017
- Harkness, Jennifer S.; Darrah, Thomas H.; Warner, Nathaniel R.
- Geochimica et Cosmochimica Acta, Vol. 208
Complex fluid flow revealed by monitoring CO 2 injection in a fluvial formation : MONITOR FLUID FLOW IN FLUVIAL RESERVOIR
journal, March 2012
- Lu, Jiemin; Cook, Paul J.; Hosseini, Seyyed A.
- Journal of Geophysical Research: Solid Earth, Vol. 117, Issue B3
The evolution of Devonian hydrocarbon gases in shallow aquifers of the northern Appalachian Basin: Insights from integrating noble gas and hydrocarbon geochemistry
journal, December 2015
- Darrah, Thomas H.; Jackson, Robert B.; Vengosh, Avner
- Geochimica et Cosmochimica Acta, Vol. 170
The Influence of Streambed Heterogeneity on Hyporheic Flow in Gravelly Rivers: Y. Zhou etal. Ground Water XX, no. X: XXXX
journal, April 2013
- Zhou, YaoQuan; Ritzi, Robert W.; Soltanian, Mohamad Reza
- Groundwater, Vol. 52, Issue 2
Identification and characterization of high methane-emitting abandoned oil and gas wells
journal, November 2016
- Kang, Mary; Christian, Shanna; Celia, Michael A.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 48
CO 2 Accounting and Risk Analysis for CO 2 Sequestration at Enhanced Oil Recovery Sites
journal, June 2016
- Dai, Zhenxue; Viswanathan, Hari; Middleton, Richard
- Environmental Science & Technology, Vol. 50, Issue 14
Modeling and simulation of carbon sequestration at Cranfield incorporating new physical models
journal, October 2013
- Delshad, Mojdeh; Kong, Xianhui; Tavakoli, Reza
- International Journal of Greenhouse Gas Control, Vol. 18
Simulating the Cranfield geological carbon sequestration project with high-resolution static models and an accurate equation of state
journal, November 2016
- Soltanian, Mohamad Reza; Amooie, Mohammad Amin; Cole, David R.
- International Journal of Greenhouse Gas Control, Vol. 54
Extraction of Dissolved Methane in brines by CO2 Injection: Implication for CO2 Sequestration
conference, October 2009
- Taggart, Ian James
- SPE Annual Technical Conference and Exhibition, All Days
CO2-rock-brine interactions in Lower Tuscaloosa Formation at Cranfield CO2 sequestration site, Mississippi, U.S.A.
text, January 2012
- Lu, J.; Kharaka, Y. K.; Thordsen, J. J.
- The University of Texas at Austin
Viscous and Gravitational Fingering in Multiphase Compositional and Compressible Flow
text, January 2016
- Moortgat, Joachim
- arXiv
Implicit Finite Volume and Discontinuous Galerkin Methods for Multicomponent Flow in Unstructured 3D Fractured Porous Media
text, January 2016
- Moortgat, Joachim; Amooie, Mohammad Amin; Soltanian, Mohamad Reza
- arXiv
Phase equilibria of oil, gas and water/brine mixtures from a cubic equation of state and henry's law
journal, June 1986
- Li, Yau-Kun; Nghiem, Long X.
- The Canadian Journal of Chemical Engineering, Vol. 64, Issue 3
Viscous and gravitational fingering in multiphase compositional and compressible flow
journal, March 2016
- Moortgat, Joachim
- Advances in Water Resources, Vol. 89
Monitoring a large volume CO2 injection: Year two results from SECARB project at Denbury’s Cranfield, Mississippi, USA
journal, January 2011
- Hovorka, Susan D.; Meckel, Timothy A.; Trevino, Ramon H.
- Energy Procedia, Vol. 4
The geochemistry of naturally occurring methane and saline groundwater in an area of unconventional shale gas development
journal, July 2017
- Harkness, Jennifer S.; Darrah, Thomas H.; Warner, Nathaniel R.
- Geochimica et Cosmochimica Acta, Vol. 208
Monitoring a large-volume injection at Cranfield, Mississippi—Project design and recommendations
journal, October 2013
- Hovorka, Susan D.; Meckel, Timothy A.; Treviño, Ramón H.
- International Journal of Greenhouse Gas Control, Vol. 18
Fickian Diffusion in Discrete-Fractured Media from Chemical Potential Gradients and Comparison to Experiment
journal, September 2013
- Moortgat, Joachim; Firoozabadi, Abbas
- Energy & Fuels, Vol. 27, Issue 10
Interfacial tension of nonassociating pure substances and binary mixtures by density functional theory combined with Peng–Robinson equation of state
journal, April 2009
- Li, Zhidong; Firoozabadi, Abbas
- The Journal of Chemical Physics, Vol. 130, Issue 15
Noble gases identify the mechanisms of fugitive gas contamination in drinking-water wells overlying the Marcellus and Barnett Shales
journal, September 2014
- Darrah, Thomas H.; Vengosh, Avner; Jackson, Robert B.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 39
CO2-rock-brine interactions in Lower Tuscaloosa Formation at Cranfield CO2 sequestration site, Mississippi, U.S.A.
text, January 2012
- Lu, J.; Kharaka, Y. K.; Thordsen, J. J.
- The University of Texas at Austin
Works referencing / citing this record:
Convective Dissolution of Carbon Dioxide in Deep Saline Aquifers: Insights from Engineering a High-Pressure Porous Visual Cell
journal, September 2019
- Mahmoodpour, Saeed; Rostami, Behzad; Soltanian, Mohamad Reza
- Physical Review Applied, Vol. 12, Issue 3
Numerical Investigation of a Methane Leakage from a Geothermal Well into a Shallow Aquifer
journal, November 2019
- D'Aniello, Andrea; Fabbricino, Massimiliano; Ducci, Daniela
- Groundwater, Vol. 58, Issue 4
Transport of perfluorocarbon tracers in the Cranfield Geological Carbon Sequestration Project: Modeling and Analysis: Transport of perfluorocarbon tracers in the Cranfield Geological Carbon Sequestration Project
journal, June 2018
- Soltanian, Mohamad Reza; Amooie, Mohammad Amin; Cole, David
- Greenhouse Gases: Science and Technology, Vol. 8, Issue 4
An Intelligent IoT-Based Food Quality Monitoring Approach Using Low-Cost Sensors
journal, March 2019
- Popa, Alexandru; Hnatiuc, Mihaela; Paun, Mirel
- Symmetry, Vol. 11, Issue 3
Convective dissolution of carbon dioxide in deep saline aquifers: Insights from engineering a high-pressure porous Hele-Shaw cell
text, January 2018
- Mahmoodpour, Saeed; Rostami, Behzad; Soltanian, Mohamad Reza
- Unpublished
An Intelligent IoT-Based Food Quality Monitoring Approach Using Low-Cost Sensors
journal, March 2019
- Popa, Alexandru; Hnatiuc, Mihaela; Paun, Mirel
- Symmetry, Vol. 11, Issue 3
Figures / Tables found in this record: