Crystallization Mechanism and Charge Carrier Transport in MAPLE-Deposited Conjugated Polymer Thin Films

Dong, Ban Xuan; Strzalka, Joseph; Jiang, Zhang; Li, Huanghe; Stein, Gila E.; Green, Peter F.

doi:10.1021/acsami.7b13609

Title: Crystallization Mechanism and Charge Carrier Transport in MAPLE-Deposited Conjugated Polymer Thin Films

Journal Article · Thu Nov 23 04:00:00 UTC 2017 · ACS Applied Materials and Interfaces

DOI: https://doi.org/10.1021/acsami.7b13609 · OSTI ID:1415483

^[1]; Strzalka, Joseph ^[2]; Jiang, Zhang ^[2]; Li, Huanghe ^[3]; Stein, Gila E. ^[4];

^[5]

Univ. of Michigan, Ann Arbor, MI (United States); The Univ. of Chicago, Chicago, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of Michigan, Ann Arbor, MI (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Michigan, Ann Arbor, MI (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)

Although spin casting and chemical surface reactions are the most common methods used for fabricating functional polymer films onto substrates, they are limited with regard to producing films of certain morphological characteristics on different wetting and nonwetting substrates. The matrix-assisted pulsed laser evaporation (MAPLE) technique offers advantages with regard to producing films of different morphologies on different types of substrates. Here, we provide a quantitative characterization, using X-ray diffraction and optical methods, to elucidate the additive growth mechanism of MAPLE-deposited poly(3-hexylthiophene) (P3HT) films on substrates that have undergone different surface treatments, enabling them to possess different wettabilities. We show that MAPLE-deposited films are composed of crystalline phases, wherein the overall P3HT aggregate size and crystallite coherence length increase with deposition time. A complete pole figure constructed from X-ray diffraction measurements reveals that in these MAPLE-deposited films, there exist two distinct crystallite populations: (i) highly oriented crystals that grow from the flat dielectric substrate and (ii) misoriented crystals that preferentially grow on top of the existing polymer layers. The growth of the highly oriented crystals is highly sensitive to the chemistry of the substrate, whereas the effect of substrate chemistry on misoriented crystal growth is weaker. The use of a self-assembled monolayer to treat the substrate greatly enhances the population and crystallite coherence length at the buried interfaces, particularly during the early stage of deposition. Furthermore, the evolution of the in-plane carrier mobilities during the course of deposition is consistent with the development of highly oriented crystals at the buried interface, suggesting that this interface plays a key role toward determining carrier transport in organic thin-film transistors.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF), Directorate for Mathematical and Physical Sciences Division of Materials Research (MPS-DMR); Vietnam Education Foundation; University of Michigan; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1415483

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 51 Vol. 9; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (61)

Mechanism of Crystallization and Implications for Charge Transport in Poly(3-ethylhexylthiophene) Thin Films Duong, Duc T.; Ho, Victor; Shang, Zhengrong Advanced Functional Materials, Vol. 24, Issue 28 https://doi.org/10.1002/adfm.201304247	journal	April 2014
Solvent Effects on Chain Orientation and Interchain π-Interaction in Conjugated Polymer Thin Films: Direct Measurements of the Air and Substrate Interfaces by Near-Edge X-ray Absorption Spectroscopy Ho, P. K. -H.; Chua, L. -L.; Dipankar, M. Advanced Materials, Vol. 19, Issue 2 https://doi.org/10.1002/adma.200601285	journal	January 2007
25th Anniversary Article: Organic Field-Effect Transistors: The Path Beyond Amorphous Silicon Sirringhaus, Henning Advanced Materials, Vol. 26, Issue 9 https://doi.org/10.1002/adma.201304346	journal	January 2014
Solar Cells: Morphological Degradation in Low Bandgap Polymer Solar Cells - An In Operando Study (Adv. Energy Mater. 19/2016) Schaffer, Christoph J.; Palumbiny, Claudia M.; Niedermeier, Martin A. Advanced Energy Materials, Vol. 6, Issue 19 https://doi.org/10.1002/aenm.201670115	journal	October 2016
MAPLE Deposition of Macromolecules Shepard, Kimberly B.; Priestley, Rodney D. Macromolecular Chemistry and Physics, Vol. 214, Issue 8 https://doi.org/10.1002/macp.201200621	journal	February 2013
Organic light-emitting diode (OLED) technology: materials, devices and display technologies Geffroy, Bernard; le Roy, Philippe; Prat, Christophe Polymer International, Vol. 55, Issue 6 https://doi.org/10.1002/pi.1974	journal	January 2006
Vertical confinement and interface effects on the microstructure and charge transport of P3HT thin films Jimison, Leslie H.; Himmelberger, Scott; Duong, Duc T. Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 7 https://doi.org/10.1002/polb.23265	journal	February 2013
Radiation damage in polymer films from grazing-incidence X-ray scattering measurements Vaselabadi, Saeed Ahmadi; Shakarisaz, David; Ruchhoeft, Paul Journal of Polymer Science Part B: Polymer Physics, Vol. 54, Issue 11 https://doi.org/10.1002/polb.24006	journal	February 2016
Molecular organization in MAPLE-deposited conjugated polymer thin films and the implications for carrier transport characteristics Dong, Ban Xuan; Li, Anton; Strzalka, Joseph Journal of Polymer Science Part B: Polymer Physics, Vol. 55, Issue 1 https://doi.org/10.1002/polb.24237	journal	September 2016
Growth of polymer–metal nanocomposites by pulsed laser deposition Röder, Johanna; Faupel, Jörg; Krebs, Hans-Ulrich Applied Physics A, Vol. 93, Issue 4 https://doi.org/10.1007/s00339-008-4740-7	journal	December 2008
Absorption in regio-regular poly(3-hexyl)thiophene thin films: Fermi resonances, interband coupling and disorder Spano, Frank C. Chemical Physics, Vol. 325, Issue 1 https://doi.org/10.1016/j.chemphys.2005.08.019	journal	June 2006
Depth-resolved molecular structure and orientation of polymer thin films by synchrotron X-ray diffraction Porzio, W.; Scavia, G.; Barba, L. European Polymer Journal, Vol. 47, Issue 3 https://doi.org/10.1016/j.eurpolymj.2010.12.007	journal	March 2011
Growth of polyalkylthiophene films by matrix assisted pulsed laser evaporation Gutierrezllorente, A. Organic Electronics, Vol. 5, Issue 1-3 https://doi.org/10.1016/j.orgel.2003.11.003	journal	March 2004
Hybrid nanocomposite thin films deposited by emulsion-based resonant infrared matrix-assisted pulsed laser evaporation for photovoltaic applications Ge, Wangyao; Atewologun, Ayomide; Stiff-Roberts, Adrienne D. Organic Electronics, Vol. 22 https://doi.org/10.1016/j.orgel.2015.03.043	journal	July 2015
Growth of organic thin films by the matrix assisted pulsed laser evaporation (MAPLE) technique Piqué, A.; McGill, R. A.; Chrisey, D. B. Thin Solid Films, Vol. 355-356 https://doi.org/10.1016/s0257-8972(99)00376-x	journal	November 1999
Additive Growth and Crystallization of Polymer Films Jeong, Hyuncheol; Shepard, Kimberly B.; Purdum, Geoffrey E. Macromolecules, Vol. 49, Issue 7 https://doi.org/10.1021/acs.macromol.5b02675	journal	March 2016
Emulsion-Based RIR-MAPLE Deposition of Conjugated Polymers: Primary Solvent Effect and Its Implications on Organic Solar Cell Performance Ge, Wangyao; Li, Nan K.; McCormick, Ryan D. ACS Applied Materials & Interfaces, Vol. 8, Issue 30 https://doi.org/10.1021/acsami.6b05596	journal	July 2016
Enhancing Carrier Mobilities in Organic Thin-Film Transistors Through Morphological Changes at the Semiconductor/Dielectric Interface Using Supercritical Carbon Dioxide Processing Dong, Ban Xuan; Amonoo, Jojo A.; Purdum, Geoffrey E. ACS Applied Materials & Interfaces, Vol. 8, Issue 45 https://doi.org/10.1021/acsami.6b08248	journal	November 2016
Efficient Solvent-Assisted Post-Treatment for Molecular Rearrangement of Sprayed Polymer Field-Effect Transistors Park, Hye-Yun; Yang, Hoichang; Choi, Si-Kyung ACS Applied Materials & Interfaces, Vol. 4, Issue 1 https://doi.org/10.1021/am201274s	journal	December 2011
Introduction to Organic Thin Film Transistors and Design of n-Channel Organic Semiconductors Newman, Christopher R.; Frisbie, C. Daniel; da Silva Filho, Demetrio A. Chemistry of Materials, Vol. 16, Issue 23, p. 4436-4451 https://doi.org/10.1021/cm049391x	journal	August 2004
Laser Deposition of Polymer and Biomaterial Films Chrisey, D. B.; Piqué, A.; McGill, R. A. Chemical Reviews, Vol. 103, Issue 2 https://doi.org/10.1021/cr010428w	journal	February 2003
Conjugated Polymer-Based Organic Solar Cells Günes, Serap; Neugebauer, Helmut; Sariciftci, Niyazi Serdar Chemical Reviews, Vol. 107, Issue 4, p. 1324-1338 https://doi.org/10.1021/cr050149z	journal	April 2007
High-Performance Semiconducting Polythiophenes for Organic Thin-Film Transistors Ong, Beng S.; Wu, Yiliang; Liu, Ping Journal of the American Chemical Society, Vol. 126, Issue 11, p. 3378-3379 https://doi.org/10.1021/ja039772w	journal	March 2004
Lamination Method for the Study of Interfaces in Polymeric Thin Film Transistors Chabinyc, Michael L.; Salleo, Alberto; Wu, Yiliang Journal of the American Chemical Society, Vol. 126, Issue 43 https://doi.org/10.1021/ja044884o	journal	November 2004
X-ray Scattering Study of Thin Films of Poly(2,5-bis(3-alkylthiophen-2-yl)thieno[3,2- b ]thiophene) Chabinyc, Michael L.; Toney, Michael F.; Kline, R. Joseph Journal of the American Chemical Society, Vol. 129, Issue 11 https://doi.org/10.1021/ja0670714	journal	March 2007
Nanoscale Orientation Effects on Carrier Transport in a Low-Band-Gap Polymer Dong, Ban Xuan; Huang, Bingyuan; Tan, Aaron The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp506374m	journal	July 2014
Phase Diagram of P3HT/PCBM Blends and Its Implication for the Stability of Morphology Zhao, Jun; Swinnen, Ann; Van Assche, Guy The Journal of Physical Chemistry B, Vol. 113, Issue 6, p. 1587-1591 https://doi.org/10.1021/jp804151a	journal	February 2009
Quantification of Thin Film Crystallographic Orientation Using X-ray Diffraction with an Area Detector Baker, Jessy L.; Jimison, Leslie H.; Mannsfeld, Stefan Langmuir, Vol. 26, Issue 11 https://doi.org/10.1021/la904840q	journal	June 2010
Layering Transitions in Thin Films of Spherical-Domain Block Copolymers Stein, Gila E.; Kramer, Edward J.; Li, Xuefa Macromolecules, Vol. 40, Issue 7 https://doi.org/10.1021/ma0625509	journal	April 2007
Thickness Dependence of the Crystalline Structure and Hole Mobility in Thin Films of Low Molecular Weight Poly(3-hexylthiophene) Joshi, Siddharth; Grigorian, Souren; Pietsch, Ullrich Macromolecules, Vol. 41, Issue 18 https://doi.org/10.1021/ma702802x	journal	September 2008
Printing Highly Efficient Organic Solar Cells Hoth, Claudia N.; Schilinsky, Pavel; Choulis, Stelios A. Nano Letters, Vol. 8, Issue 9 https://doi.org/10.1021/nl801365k	journal	September 2008
Molecular Order in High-Efficiency Polymer/Fullerene Bulk Heterojunction Solar Cells Hammond, Matthew R.; Kline, R. Joseph; Herzing, Andrew A. ACS Nano, Vol. 5, Issue 10 https://doi.org/10.1021/nn202951e	journal	September 2011
Two-dimensional charge transport in self-organized, high-mobility conjugated polymers Sirringhaus, H.; Brown, P. J.; Friend, R. H. Nature, Vol. 401, Issue 6754, p. 685-688 https://doi.org/10.1038/44359	journal	October 1999
Highly oriented crystals at the buried interface in polythiophene thin-film transistors Joseph Kline, R.; McGehee, Michael D.; Toney, Michael F. Nature Materials, Vol. 5, Issue 3 https://doi.org/10.1038/nmat1590	journal	February 2006
White multi-layered polymer light emitting diode through matrix assisted pulsed laser evaporation Mariano, F.; Caricato, A. P.; Accorsi, G. Journal of Materials Chemistry C, Vol. 4, Issue 32 https://doi.org/10.1039/c6tc01826b	journal	January 2016
Band bending in conjugated polymer films: role of morphology and implications for bulk charge transport characteristics Wenderott, J. K.; Dong, Ban Xuan; Green, Peter F. Journal of Materials Chemistry C, Vol. 5, Issue 30 https://doi.org/10.1039/c7tc02302b	journal	January 2017
Polymer thin-film transistors with chemically modified dielectric interfaces Salleo, A.; Chabinyc, M. L.; Yang, M. S. Applied Physics Letters, Vol. 81, Issue 23 https://doi.org/10.1063/1.1527691	journal	December 2002
Increased mobility from regioregular poly(3-hexylthiophene) field-effect transistors Wang, Guangming; Swensen, James; Moses, Daniel Journal of Applied Physics, Vol. 93, Issue 10 https://doi.org/10.1063/1.1568526	journal	May 2003
Modeling disorder in polymer aggregates: The optical spectroscopy of regioregular poly(3-hexylthiophene) thin films Spano, Frank C. The Journal of Chemical Physics, Vol. 122, Issue 23 https://doi.org/10.1063/1.1914768	journal	June 2005
Molecular dynamics simulation study of the ejection and transport of polymer molecules in matrix-assisted pulsed laser evaporation Leveugle, Elodie; Zhigilei, Leonid V. Journal of Applied Physics, Vol. 102, Issue 7 https://doi.org/10.1063/1.2783898	journal	October 2007
Excitonic versus electronic couplings in molecular assemblies: The importance of non-nearest neighbor interactions Gierschner, Johannes; Huang, Ya-Shih; Van Averbeke, Bernard The Journal of Chemical Physics, Vol. 130, Issue 4 https://doi.org/10.1063/1.3065267	journal	January 2009
High performance airbrushed organic thin film transistors Chan, Calvin K.; Richter, Lee J.; Dinardo, Brad Applied Physics Letters, Vol. 96, Issue 13 https://doi.org/10.1063/1.3360230	journal	March 2010
Dependence of persistent photocurrent on gate bias in inkjet printed organic thin-film transistor Kim, Chang Hyun; Choi, Min Hee; Lee, Sun Hee Applied Physics Letters, Vol. 96, Issue 12 https://doi.org/10.1063/1.3372619	journal	March 2010
Poly-(3-hexylthiophene)/[6,6]-phenyl-C ₆₁ -butyric-acid-methyl-ester bilayer deposition by matrix-assisted pulsed laser evaporation for organic photovoltaic applications Caricato, A. P.; Cesaria, M.; Gigli, G. Applied Physics Letters, Vol. 100, Issue 7 https://doi.org/10.1063/1.3685702	journal	February 2012
Origins of nanostructure in amorphous polymer coatings via matrix assisted pulsed laser evaporation Shepard, Kimberly B.; Arnold, Craig B.; Priestley, Rodney D. Applied Physics Letters, Vol. 103, Issue 12 https://doi.org/10.1063/1.4821366	journal	September 2013
Bulk heterojunction PCPDTBT:PC ₇₁ BM organic solar cells deposited by emulsion-based, resonant infrared matrix-assisted pulsed laser evaporation McCormick, Ryan D.; Nyikayaramba, Gift; Stiff-Roberts, Adrienne D. Applied Physics Letters, Vol. 104, Issue 22 https://doi.org/10.1063/1.4881058	journal	June 2014
Patchy Janus particles with tunable roughness and composition via vapor-assisted deposition of macromolecules Shepard, Kimberly B.; Christie, Dane A.; Sosa, Chris L. Applied Physics Letters, Vol. 106, Issue 9 https://doi.org/10.1063/1.4913913	journal	March 2015
Small Bandgap Polymers for Organic Solar Cells (Polymer Material Development in the Last 5 Years) Kroon, Renee; Lenes, Martijn; Hummelen, Jan C. Polymer Reviews, Vol. 48, Issue 3 https://doi.org/10.1080/15583720802231833	journal	August 2008
Quantum efficiency roll-off at high brightness in fluorescent and phosphorescent organic light emitting diodes Giebink, N. C.; Forrest, S. R. Physical Review B, Vol. 77, Issue 23 https://doi.org/10.1103/physrevb.77.235215	journal	June 2008
Correlating the microstructure of thin films of poly[5,5-bis(3-dodecyl-2-thienyl)-2,2-bithiophene] with charge transport: Effect of dielectric surface energy and thermal annealing Jimison, Leslie H.; Salleo, Alberto; Chabinyc, Michael L. Physical Review B, Vol. 78, Issue 12 https://doi.org/10.1103/physrevb.78.125319	journal	September 2008
Quantitative analysis of lattice disorder and crystallite size in organic semiconductor thin films Rivnay, Jonathan; Noriega, Rodrigo; Kline, R. Joseph Physical Review B, Vol. 84, Issue 4 https://doi.org/10.1103/physrevb.84.045203	journal	July 2011
Role of Intermolecular Coupling in the Photophysics of Disordered Organic Semiconductors: Aggregate Emission in Regioregular Polythiophene Clark, Jenny; Silva, Carlos; Friend, Richard H. Physical Review Letters, Vol. 98, Issue 20 https://doi.org/10.1103/physrevlett.98.206406	journal	May 2007
Scherrer grain-size analysis adapted to grazing-incidence scattering with area detectors Smilgies, Detlef-M. Journal of Applied Crystallography, Vol. 42, Issue 6 https://doi.org/10.1107/s0021889809040126	journal	October 2009
The dedicated high-resolution grazing-incidence X-ray scattering beamline 8-ID-E at the Advanced Photon Source Jiang, Zhang; Li, Xuefa; Strzalka, Joseph Journal of Synchrotron Radiation, Vol. 19, Issue 4 https://doi.org/10.1107/s0909049512022017	journal	June 2012
GIXSGUI : a MATLAB toolbox for grazing-incidence X-ray scattering data visualization and reduction, and indexing of buried three-dimensional periodic nanostructured films Jiang, Zhang Journal of Applied Crystallography, Vol. 48, Issue 3 https://doi.org/10.1107/s1600576715004434	journal	April 2015
Tabletop Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation of Light-Emitting Organic Thin Films Pate, Ryan; Lantz, Kevin R.; Stiff-Roberts, Adrienne D. IEEE Journal of Selected Topics in Quantum Electronics, Vol. 14, Issue 4 https://doi.org/10.1109/jstqe.2008.915625	journal	January 2008
High-Resolution Inkjet Printing of All-Polymer Transistor Circuits Sirringhaus, H.; Kawase, T.; Friend, R. H. Science, Vol. 290, Issue 5499, p. 2123-2126 https://doi.org/10.1126/science.290.5499.2123	journal	December 2000
H- and J-Aggregate Behavior in Polymeric Semiconductors Spano, Frank C.; Silva, Carlos Annual Review of Physical Chemistry, Vol. 65, Issue 1 https://doi.org/10.1146/annurev-physchem-040513-103639	journal	April 2014
Surface induced orientation and vertically layered morphology in thin films of poly(3-hexylthiophene) crystallized from the melt Balko, Jens; Portale, Guiseppe; Lohwasser, Ruth H. Journal of Materials Research, Vol. 32, Issue 10 https://doi.org/10.1557/jmr.2017.107	journal	April 2017
Influence of morphological disorder on in- and out-of-plane charge transport in conjugated polymer films Li, Anton; Dong, Ban Xuan; Green, Peter F. MRS Communications, Vol. 5, Issue 4 https://doi.org/10.1557/mrc.2015.72	journal	November 2015
Effects of Emulsion-Based Resonant Infrared Matrix Assisted Pulsed Laser Evaporation (RIR-MAPLE) on the Molecular Weight of Polymers McCormick, Ryan D.; Lenhardt, Jeremy; Stiff-Roberts, Adrienne D. Polymers, Vol. 4, Issue 1 https://doi.org/10.3390/polym4010341	journal	February 2012

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36 MATERIALS SCIENCE
MAPLE
X-Ray diffraction
conjugated polymers
crystallization
structure-transport relationship

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