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This content will become publicly available on December 18, 2018

Title: Synthesis and characterization of the heavy-fermion compound CePtAl 4Ge 2

Here, we report the synthesis of the Ce-based quaternary compound CePtAl 4Ge 2 that crystallizes in the trigonal structure (space group R 3¯m, 166) with unit cell parameters, a = 4.1995(5) Å, c = 31.851(7) Å, and γ = 120°. Powder X-ray diffraction and energy dispersive X-ray spectroscopy show that CePtAl 4Ge 2 (LaPtAl 4Ge 2) is in a single, homogeneous phase. Magnetic susceptibility, electrical resistivity, and heat capacity measurements of CePtAl 4Ge 2 show that it exhibits antiferromagnetic behavior below 2.3 K. The magnetic susceptibility for the magnetic field applied perpendicular (χ ab) and parallel (χ c) to the crystalline c-axis is very anisotropic, and the susceptibility ratio (χ abc) reaches a maximum value of 10, indicating that the spin easy axis is within the Ce plane. The entropy recovered at T N is consistent with the doublet ground state of the crystal field split J = 5/2 multiplet of Ce 3+ ions.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [2] ; ORCiD logo [2] ; ORCiD logo [2] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ; ORCiD logo [2] ;  [1]
  1. Sungkyunkwan Univ., Suwon (South Korea)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Report Number(s):
LA-UR-17-28376
Journal ID: ISSN 0925-8388; TRN: US1800815
Grant/Contract Number:
AC52-06NA25396
Type:
Accepted Manuscript
Journal Name:
Journal of Alloys and Compounds
Additional Journal Information:
Journal Volume: 738; Journal Issue: C; Journal ID: ISSN 0925-8388
Publisher:
Elsevier
Research Org:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org:
USDOE Office of Science (SC). Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Material Science
OSTI Identifier:
1415422