Electroless Deposition of Palladium on Macroscopic 3D-Printed Polymers with Dense Microlattice Architectures for Development of Multifunctional Composite Materials
Abstract
A simple procedure has been developed to create palladium (Pd) films on the surface of several common polymers used in commercial fused deposition modeling (FDM) and stereolithography (SLA) based three-dimensional (3D) printing by an electroless deposition process. The procedure can be performed at room temperature, with equipment less expensive than many 3D printers, and occurs rapidly enough to achieve full coverage of the film within a few minutes. 3D substrates composed of dense logpile or cubic lattices with part sizes in the mm to cm range, and feature sizes as small as 150 μm were designed and printed using commercially available 3D printers. The deposition procedure was successfully adapted to show full coverage in the lattice substrates. As a result, the ability to design, print, and metallize highly ordered three-dimensional microscale structures could accelerate development of a range of optimized chemical and mechanical engineering systems.
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1411227
- Report Number(s):
- SAND2017-11817J
Journal ID: ISSN 0013-4651; 658300; TRN: US1800201
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 164; Journal Issue: 13; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Jones, Christopher G., Mills, Bernice E., Nishimoto, Ryan K., and Robinson, David B. Electroless Deposition of Palladium on Macroscopic 3D-Printed Polymers with Dense Microlattice Architectures for Development of Multifunctional Composite Materials. United States: N. p., 2017.
Web. doi:10.1149/2.1341713jes.
Jones, Christopher G., Mills, Bernice E., Nishimoto, Ryan K., & Robinson, David B. Electroless Deposition of Palladium on Macroscopic 3D-Printed Polymers with Dense Microlattice Architectures for Development of Multifunctional Composite Materials. United States. https://doi.org/10.1149/2.1341713jes
Jones, Christopher G., Mills, Bernice E., Nishimoto, Ryan K., and Robinson, David B. Wed .
"Electroless Deposition of Palladium on Macroscopic 3D-Printed Polymers with Dense Microlattice Architectures for Development of Multifunctional Composite Materials". United States. https://doi.org/10.1149/2.1341713jes. https://www.osti.gov/servlets/purl/1411227.
@article{osti_1411227,
title = {Electroless Deposition of Palladium on Macroscopic 3D-Printed Polymers with Dense Microlattice Architectures for Development of Multifunctional Composite Materials},
author = {Jones, Christopher G. and Mills, Bernice E. and Nishimoto, Ryan K. and Robinson, David B.},
abstractNote = {A simple procedure has been developed to create palladium (Pd) films on the surface of several common polymers used in commercial fused deposition modeling (FDM) and stereolithography (SLA) based three-dimensional (3D) printing by an electroless deposition process. The procedure can be performed at room temperature, with equipment less expensive than many 3D printers, and occurs rapidly enough to achieve full coverage of the film within a few minutes. 3D substrates composed of dense logpile or cubic lattices with part sizes in the mm to cm range, and feature sizes as small as 150 μm were designed and printed using commercially available 3D printers. The deposition procedure was successfully adapted to show full coverage in the lattice substrates. As a result, the ability to design, print, and metallize highly ordered three-dimensional microscale structures could accelerate development of a range of optimized chemical and mechanical engineering systems.},
doi = {10.1149/2.1341713jes},
journal = {Journal of the Electrochemical Society},
number = 13,
volume = 164,
place = {United States},
year = {Wed Oct 25 00:00:00 EDT 2017},
month = {Wed Oct 25 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 11 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Self-assembled three-dimensional and compressible interdigitated thin-film supercapacitors and batteries
journal, May 2015
- Nyström, Gustav; Marais, Andrew; Karabulut, Erdem
- Nature Communications, Vol. 6, Issue 1
Laser additive manufacturing of stainless steel micro fuel cells
journal, December 2014
- Scotti, Gianmario; Matilainen, Ville; Kanninen, Petri
- Journal of Power Sources, Vol. 272
The upcoming 3D-printing revolution in microfluidics
journal, January 2016
- Bhattacharjee, Nirveek; Urrios, Arturo; Kang, Shawn
- Lab on a Chip, Vol. 16, Issue 10
A review on 3D micro-additive manufacturing technologies
journal, November 2012
- Vaezi, Mohammad; Seitz, Hermann; Yang, Shoufeng
- The International Journal of Advanced Manufacturing Technology, Vol. 67, Issue 5-8
Low-Distortion Surface Functionalization of Polymeric Microstructures
journal, July 2014
- Kuebler, Stephen M.; Narayanan, Ananthakrishnan; Karas, Dale E.
- Macromolecular Chemistry and Physics, Vol. 215, Issue 16
Covalent assembly of metal nanoparticles on cellulose fabric and its antimicrobial activity
journal, September 2012
- Park, Sung Yong; Chung, Jae Woo; Priestley, Rodney D.
- Cellulose, Vol. 19, Issue 6
3D bioprinting of tissues and organs
journal, August 2014
- Murphy, Sean V.; Atala, Anthony
- Nature Biotechnology, Vol. 32, Issue 8
Electroless nickel, alloy, composite and nano coatings – A critical review
journal, September 2013
- Sudagar, Jothi; Lian, Jianshe; Sha, Wei
- Journal of Alloys and Compounds, Vol. 571
Electroless Pd and Ag deposition kinetics of the composite Pd and Pd/Ag membranes synthesized from agitated plating baths
journal, March 2009
- Ayturk, M. Engin; Ma, Yi Hua
- Journal of Membrane Science, Vol. 330, Issue 1-2, p. 233-245
Multiscale metallic metamaterials
journal, July 2016
- Zheng, Xiaoyu; Smith, William; Jackson, Julie
- Nature Materials, Vol. 15, Issue 10
Plating on acrylonitrile–butadiene–styrene (ABS) plastic: a review
journal, January 2016
- Olivera, Sharon; Muralidhara, Handanahally Basavarajaiah; Venkatesh, Krishna
- Journal of Materials Science, Vol. 51, Issue 8
Route to Three-Dimensional Metallized Microstructures Using Cross-Linkable Epoxide SU-8
journal, August 2007
- Chen, Yun-Sheng; Tal, Amir; Kuebler, Stephen M.
- Chemistry of Materials, Vol. 19, Issue 16
Laser powder-bed fusion additive manufacturing: Physics of complex melt flow and formation mechanisms of pores, spatter, and denudation zones
journal, April 2016
- Khairallah, Saad A.; Anderson, Andrew T.; Rubenchik, Alexander
- Acta Materialia, Vol. 108
3D Printing of Interdigitated Li-Ion Microbattery Architectures
journal, June 2013
- Sun, Ke; Wei, Teng-Sing; Ahn, Bok Yeop
- Advanced Materials, Vol. 25, Issue 33, p. 4539-4543
Additive Manufacturing of Metal Cellular Structures: Design and Fabrication
journal, February 2015
- Yang, Li; Harrysson, Ola; Cormier, Denis
- JOM, Vol. 67, Issue 3
An efficient and scalable approach for generating topologically optimized cellular structures for additive manufacturing
journal, October 2016
- Robbins, J.; Owen, S. J.; Clark, B. W.
- Additive Manufacturing, Vol. 12
Selective electroless plating to fabricate complex three-dimensional metallic micro/nanostructures
journal, February 2006
- Formanek, Florian; Takeyasu, Nobuyuki; Tanaka, Takuo
- Applied Physics Letters, Vol. 88, Issue 8
A new palladium-free surface activation process for Ni electroless plating on ABS plastic
journal, April 2009
- Tang, Xuejiao; Bi, Chengliang; Han, Changxiu
- Materials Letters, Vol. 63, Issue 11
Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes
journal, March 2011
- Zhang, Huigang; Yu, Xindi; Braun, Paul V.
- Nature Nanotechnology, Vol. 6, Issue 5, p. 277-281
Fabrication of 3D metal/polymer microstructures by site-selective metal coating
journal, October 2007
- Takeyasu, N.; Tanaka, T.; Kawata, S.
- Applied Physics A, Vol. 90, Issue 2
Ultralight Metallic Microlattices
journal, November 2011
- Schaedler, T. A.; Jacobsen, A. J.; Torrents, A.
- Science, Vol. 334, Issue 6058
Metal-nanoshelled three-dimensional photonic lattices
journal, January 2008
- Kaneko, Koshiro; Yamamoto, Kazuo; Kawata, Satoshi
- Optics Letters, Vol. 33, Issue 17
Metal Deposition Deep into Microstructure by Electroless Plating
journal, August 2005
- Takeyasu, Nobuyuki; Tanaka, Takuo; Kawata, Satoshi
- Japanese Journal of Applied Physics, Vol. 44, Issue No. 35
3D printing of a heterogeneous copper-based catalyst
journal, February 2016
- Tubío, Carmen R.; Azuaje, Jhonny; Escalante, Luz
- Journal of Catalysis, Vol. 334
Latest advances in the manufacturing of 3D rechargeable lithium microbatteries
journal, July 2015
- Ferrari, Stefania; Loveridge, Melanie; Beattie, Shane D.
- Journal of Power Sources, Vol. 286, p. 25-46
Initiator-Integrated 3D Printing Enables the Formation of Complex Metallic Architectures
journal, December 2013
- Wang, Xiaolong; Guo, Qiuquan; Cai, Xiaobing
- ACS Applied Materials & Interfaces, Vol. 6, Issue 4
Selective Functionalization of 3-D Polymer Microstructures
journal, February 2006
- Farrer, Richard A.; LaFratta, Christopher N.; Li, Linjie
- Journal of the American Chemical Society, Vol. 128, Issue 6
Process of direct copper plating on ABS plastics
journal, November 2006
- Gui-xiang, Wang; Ning, Li; Hui-li, Hu
- Applied Surface Science, Vol. 253, Issue 2
A novel surface activation method for Ni/Au electroless plating of acrylonitrile–butadiene–styrene
journal, December 2011
- Tang, Xuejiao; Wang, Jingang; Wang, Chengjun
- Surface and Coatings Technology, Vol. 206, Issue 6
Works referencing / citing this record:
A Numerical model of exchange chromatography through 3-D lattice structures
journal, February 2018
- Salloum, Maher; Robinson, David B.
- AIChE Journal, Vol. 64, Issue 5
Dynamic energy absorption characteristics of additively-manufactured shape-recovering lattice structures
journal, January 2019
- Davami, Keivan; Mohsenizadeh, Mehrdad; Munther, Michael
- Materials Research Express, Vol. 6, Issue 4